西准噶尔马拉苏早泥盆世火山岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其大地构造意义

马拉苏地区早泥盆世地层为一套滨海—浅海相火山—沉积岩系,对其中的火山岩夹层进行锆石U-Pb同位素定年和岩石地球化学研究,定年结果显示有大量的新太古代和中新元古代锆石,表明该区存在古老的大陆地壳物质。火山岩样品Si O2含量为52.38%~69.6%,Na2O含量为2.80%~4.85%,K2O为0.16%~0.96%,Ti O2为0.5%~1.96%,Al2O3为14.62%~18.18%,Mg O(1.08%~5.75%)变化范围较大,Mg#值在22.92~38之间,具有高钠、低钾的特征,属于钙碱性、低钾拉斑系列。稀土元素总量∑REE=73×10-6~115×10-6,LREE/HREE值为2.66~3.25,具有明显的Eu负异常(0.83~0.92)。玄武安山岩样品相对富集K、Rb、Ba、Sr等大离子亲石元素,亏损Nb、Ta、Zr、Hf等高场强元素,与典型火山弧玄武岩地球化学特征一致。英安斑岩样品也具有富集大离子亲石元素、亏损Nb、Ta、Ti等高场强元素的特征,反映源区可能有较多壳源物质的加入,其稀土元素配分曲线和微量元素蛛网图与玄武安山岩相似,表明其可能为同源岩浆演化的产物。综合研究认为,这套火山岩具有岛弧火山岩特征,形成于板块俯冲拼贴过程中的岛弧环境。     

武夷山新元古代蛇绿混杂岩岩石地球化学特征

岩石地球化学研究表明,华南造山带东段武夷山新元古代蛇绿混杂岩中的玄武岩和安山岩可以分为两种类型:一种为拉斑玄武岩类,TiO2含量为2.26%～2.59%(平均2.43%),轻稀土元素比重稀土元素富集,(La)N/(Yb)N=6.4～9.4(平均7.8),相对富集Nb、Ta和Ti,微量元素特征类似于洋岛玄武岩;另一种岩石属于钙碱系列,TiO2含量为0.69%～0.93%(平均0.83%),表现为轻稀土元素富集,(La)N/(Yb)N=4.2～12.6(平均8.4),略显Eu负异常,并以低Nb、Ta、Ti等元素为特征,富集Ba、Rb、Th、K等大离子亲石元素,具有岛弧玄武岩的特征,属于俯冲作用的产物。蛇绿混杂岩中这两类岩石共生,记录了扬子地块和华夏地块之间古大洋消减闭合和弧-弧碰撞拼贴的历史。     

西秦岭天水地区李子园群变质火山岩的地球化学特征及其地质意义

西秦岭天水地区的早古生代李子园群为一套中浅变质的沉积-火山岩系。沉积岩系主要由变质碎屑岩和碳酸盐岩组成,火山岩系主要由变玄武岩、变玄武安山岩和变安山岩组成,包括岛弧型火山岩和玻安岩。岛弧型火山岩SiO2含量介于48.79%~54.64%之间,TiO2含量较低(0.29%~0.88%);稀土元素分布型式呈LREE略富集型,富集大离子亲石元素(LILE)Cs、Sr、Th、U,相对亏损Rb、K和高场强元素(HFSE)Nb、P、Sm、Ti和Y,具Nb负异常,类似于低钾岛弧拉斑玄武岩和钙碱性玄武岩特征。玻安岩具有中等的SiO2含量(53.59%~59.28%),低的TiO2含量(0.24%~0.48%);相对中等的MgO含量(4.90%~4.96%)、较低的CaO/Al2O3比值(0.39~0.54)和较高的Mg#值(0.54~0.58)、Al2O3/TiO2比值(33.88~64.29);同时具有较低的Ti/Zr比值(15~83)、V/Zr比值(2.18~8.35)和较高的Zr/Y比值(3.82~12.08),相对富集大离子亲石元素(LILE),特别是Rb、Ba、Th,而亏损高场强元素(HFSE),如Nb、Ta、P、Ti、Y、Yb,显示为亏损MREE的U型稀土元素分布型式。岛弧型火山岩和玻安岩的存在表明,李子园群及其中的中基性火山岩系形成于俯冲带之上的岛弧或弧前环境。     

西准噶尔马拉苏早泥盆世火山岩LA-ICP-MS 锆石U-Pb 年龄、地球化学特征及其大地构造意义

马拉苏地区早泥盆世地层为一套滨海—浅海相火山—沉积岩系,对其中的火山岩夹层进行锆石U-Pb同位素定年和岩石地球化学研究,定年结果显示有大量的新太古代和中新元古代锆石,表明该区存在古老的大陆地壳物质。火山岩样品SiO2含量为52.38%~69.6%,Na2O含量为2.80%~4.85%,K2O为0.16%~0.96%,TiO2为0.5%~1.96%,Al2O3为14.62%~18.18%,MgO（1.08%~5.75%）变化范围较大,Mg#值在22.92~38之间,具有高钠、低钾的特征,属于钙碱性、低钾拉斑系列。稀土元素总量∑REE=73×10-6~115×10-6,LREE/HREE值为2.66~3.25,具有明显的Eu负异常（0.83~0.92）。玄武安山岩样品相对富集K、Rb、Ba、Sr等大离子亲石元素,亏损Nb、Ta、Zr、Hf等高场强元素,与典型火山弧玄武岩地球化学特征一致。英安斑岩样品也具有富集大离子亲石元素、亏损Nb、Ta、Ti等高场强元素的特征,反映源区可能有较多壳源物质的加入,其稀土元素配分曲线和微量元素蛛网图与玄武安山岩相似,表明其可能为同源岩浆演化的产物。综合研究认为,这套火山岩具有岛弧火山岩特征,形成于板块俯冲拼贴过程中的岛弧环境。     

新疆阿尔泰东南缘哈拉乔拉镁铁质岩体地球化学特征与地质意义

哈拉乔拉镁铁质岩体位于新疆阿尔泰造山带东南缘, 主要岩石类型有辉长岩、辉长苏长岩、含长辉石岩、橄榄辉长岩和橄长岩.哈拉乔拉岩体具有低TiO₂(0.09%~1.28%)、低碱(Na₂O+K₂O=0.37%~0.78%)的特点, 属于拉斑玄武岩系列; 富集大离子亲石元素和轻稀土元素, 亏损高场强元素(Nb、Ta等), ε_Nd(t)为-2.62~-0.78, ε_Sr(t)为37.49~45.28.元素地球化学和Nd-Sr同位素组成表明, 岩浆源区为被消减板片交代改造过的富集型岩石圈地幔.原生岩浆为高镁拉斑玄武岩浆, 岩浆演化过程中主要发生了橄榄石、单斜辉石以及斜长石的分离结晶/堆晶, 后期有钛铁矿的析出.      

松树南沟金矿区玄武安山岩锆石U-Pb年代学地球化学及其动力学意义

对松树南沟金矿区大面积出露的玄武安山岩进行了年代学和地球化学研究,厘定了成岩时代探讨了岩石形成的构造环境。研究表明,玄武安山岩中岩浆锆石LA-MC-ICP-MS U-Pb加权平均年龄为450±2 Ma,MSWD=1.8,属晚奥陶世。主量元素显示玄武安山岩样品Si O2含量介于51.1%~55.4%,平均52.8%,属中-基性的钙碱性火山岩。岩石稀土总量较低,ΣREE为29.6×10-6~163.8×10-6,平均114.2×10-6。岩石的(La/Yb)N为3.70~12.17,平均7.73,显示出轻稀土元素相对富集、重稀土元素相对亏损的特征。样品δEu为0.61~0.89,平均0.78,具有弱的负铕异常。微量元素显示出富集大离子亲石元素(Rb、Th、U),相对亏损Nb、Ta、Ti,无明显的Zr和Hf异常,具有岛弧玄武岩的地球化学特征。该文认为松树南沟金矿区玄武安山岩形成于北祁连洋向南侧中祁连陆块俯冲的构造环境,其成因可能与洋壳俯冲环境下流体交代的岩石圈地幔部分熔融有关。     

松树南沟金矿区玄武安山岩锆石U-Pb年代学地球化学及其动力学意义

对松树南沟金矿区大面积出露的玄武安山岩进行了年代学和地球化学研究,厘定了成岩时代探讨了岩石形成的构造环境。研究表明,玄武安山岩中岩浆锆石LA-MC-ICP-MS U-Pb加权平均年龄为450±2 Ma,MSWD=1.8,属晚奥陶世。主量元素显示玄武安山岩样品Si O2含量介于51.1%~55.4%,平均52.8%,属中-基性的钙碱性火山岩。岩石稀土总量较低,ΣREE为29.6×10-6~163.8×10-6,平均114.2×10-6。岩石的(La/Yb)N为3.70~12.17,平均7.73,显示出轻稀土元素相对富集、重稀土元素相对亏损的特征。样品δEu为0.61~0.89,平均0.78,具有弱的负铕异常。微量元素显示出富集大离子亲石元素(Rb、Th、U),相对亏损Nb、Ta、Ti,无明显的Zr和Hf异常,具有岛弧玄武岩的地球化学特征。该文认为松树南沟金矿区玄武安山岩形成于北祁连洋向南侧中祁连陆块俯冲的构造环境,其成因可能与洋壳俯冲环境下流体交代的岩石圈地幔部分熔融有关。     

新疆塔吾尔别克金矿区赋矿火山岩地球化学特征与构造意义

针对塔吾尔别克金矿区赋矿火山岩展开的岩相学和主量、微量及稀土元素地球化学研究,结果显示:该区火山岩w(SiO_2)为48.93%~62.24%,w(K_2O)在1.05%~4.03%,w(TiO_2)为0.55%~0.86%,w(MgO)为2.28%~7.98%,w(Al_2O_3)介于12.04%~17.52%,w(Na_2O+K_2O)值为3.39%~5.59%,里特曼指数σ变化于1.49~2.45,显示钙碱系列火山岩;在TAS图解中该区火山岩样品分布在玄武安山岩—安山岩—英安岩区域;微量元素分析表明,岩石轻稀土相对富集、重稀土元素相对亏损的特点(LREE/HREE=4.72~6.55),且具有明显的的Eu负异常(δEu=0.35~0.67);火山岩整体富集LREE,U,Th,大离子亲石元素Rb,K;亏损高场强元素Nb,Ta,P,Ti;是岛弧岩浆作用的典型地球化学标志。在火山岩La/Yb-Sc/Ti判别图解上,表明火山岩的构造环境与大陆边缘弧密切相关。结合区域构造背景和岩石地球化学特征,推测构造背景可能为俯冲带大陆边缘弧环境。     

大别山北缘凤凰台组砾石地球化学特征及源区构造环境

根据大别山北缘合肥盆地凤凰台组暨毛坦厂组中的榴辉岩、角闪岩、斜长片麻岩等砾石地球化学研究,SiO2含量为43.31%～57.35%,原岩主要为古橄玄武岩-玄武岩-玄武安山岩-玄武粗安岩组成的火山岩,其次为斜长岩和辉绿玢岩等侵入岩.与原始地幔相比,岩石具有LILE富集、Nb-Ta负异常槽明显、Ti强烈亏损等特征.它们可能属于一个由苦橄玄武岩、拉斑玄武岩、英安岩和流纹岩等组成的火山弧,是一个SSZ型岛弧.砾石原岩与北大别杂岩("古岛弧根带")中的镁铁-超镁铁岩带、片麻岩等有成因上的联系.砾石主要不是直接来源于现在遭受剥露的"古岛弧根带",而可能是来自上部的火山弧.     

新疆西准噶尔哈拉阿拉特山火山岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及意义

西准噶尔哈拉阿拉特山一带阿腊德依克赛组火山岩主要由玄武岩、玄武安山岩和安山岩组成。玄武岩LA ICP-MS锆石U-Pb年龄为303.8±2.4 Ma,MSWD=0.82(95%置信度),时代为晚石炭世。火山岩地球化学研究表明,SiO2含量为51.05%~59.31%,TiO2为0.90%~1.33%、全碱K2O+Na2O为3.97%~8.07%,富钠贫钾(Na2O/K2O2)。A12O3为16.58%~19.84%、MgO为2.50%~5.01%,Mg#为35.04~47.62,主体属于亚碱性系列。稀土元素总量高(∑REE=41.12×10-6~73.93×10-6),轻、重稀土分馏较强((La/Yb)N=2.01~5.33),具轻微负Eu异常(Eu/Eu*=0.72~0.88)。相对富集LILE(Ba、Th、K和Sr),轻微亏损HFSE(Zr、Hf),Nb和Ta强烈亏损,Ti轻微亏损。地球化学特征表明岩浆由亏损地幔部分熔融形成,受俯冲带流体的影响,属于博什库尔-成吉斯岩浆弧南部活动大陆边缘火山作用的产物。西准噶尔东部增生造山作用滞后于西部,这为进一步认识西准噶尔地区晚古生代构造演化提供了依据。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an