Hydrodynamics and scale up in Rushton turbine flotation cells: Part 1 — Cell hydrodynamics

The effect of operating parameters on the hydrodynamics of three geometrically similar Rushton turbine flotation cells with volumes of 2.25, 10 and 50 dm³ was determined. The operating parameters investigated were superficial gas velocity (J_g), impeller rotational speed (N), and frother (methyl isobutyl carbinol, MIBC) concentration.     

楚雄盆地油气资源亟待勘查发现

中国南方（四川盆地除外）海相中、古生界油气勘查已有半个世纪的历史,其中的楚雄盆地因具备形成大中型油气区的物质基础和有利的构造环境而成为油气勘探的突破口。楚雄前陆盆地烃源岩主要发育在€₁、O_1-2、D_1-2、T₃y、T₃l、T₃g、T₃s及J_1-2中,盆地内2个重要的储盖组合分别为中上泥盆统-上三叠统下部海相层和三叠统上部陆相层-中下侏罗统。中国南方油气勘探战略思路是绕着地台边缘走,因为地台上生烃条件不好,加之后期改造变形复杂、抬升强烈、演化程度高等,不利于油气藏形成。      

Exploring the influence of loading geometry on the plastic flow properties of geological materials: Results from combined torsion + axial compression tests on calcite rocks

For technical reasons, virtually all plastic deformation experiments on geological materials have been performed in either pure shear or simple shear. These special case loading geometries are rather restrictive for those seeking insight into how microstructure evolves under the more general loading geometries that occur during natural deformation. Moreover, they are insufficient to establish how plastic flow properties might vary with the 3rd invariant of the deviatoric stress tensor (J₃) which describes the stress configuration, and so applications that use those flow properties (e.g. glaciological and geodynamical modelling) may be correspondingly compromised. We describe an inexpensive and relatively straightforward modification to the widely used Paterson rock deformation apparatus that allows torsion experiments to be performed under simultaneously applied axial loads. We illustrate the performance of this modification with the results of combined stress experiments performed on Carrara marble and Solnhofen limestone at 500°–600 °C and confining pressures of 300 MPa. The flow stresses are best described by the Drucker yield function which includes J₃-dependence. However, that J₃-dependence is small. Hence for these initially approximately isotropic calcite rocks, flow stresses are adequately described by the J₃-independent von Mises yield criterion that is widely used in deformation modelling. Loading geometry does, however, have a profound influence on the type and rate of development of crystallographic preferred orientation, and hence of mechanical anisotropy. The apparatus modification extends the range of loading geometries that can be used to investigate microstructural evolution, as well as providing greater scope for determining the shape of the yield surface in plastically anisotropic materials.     

Analytical methods for measuring the parameters of interstellar gas using methanol observations

The excitation of methanol in the absence of external radiation is analyzed, and LTE methods for probing interstellar gas considered. It is shown that rotation diagrams correctly estimate the gas kinetic temperature only if they are constructed using lines whose upper levels are located in the same K-ladders, such as the J₀?J_?1E lines at 157 GHz, the J₁?J₀E lines at 165 GHz, and the J₂?J₁E lines at 25 GHz. The gas density must be no less than 10⁷ cm^?3. Rotation diagrams constructed from lines with different K values for their upper levels (e.g., 2_K?1_K at 96 GHz, 3_K?2_K at 145 GHz, 5_K?4_K at 241 GHz) significantly underestimate the temperature, but enable estimation of the density. In addition, diagrams based on the 2_K?1_K lines can be used to estimate the methanol column density within a factor of about two to five. It is suggested that rotation diagrams should be used in the following manner. First, two rotation diagrams should be constructed, one from the lines at 96, 145, or 241 GHz, and another from the lines at 157, 165, or 25 GHz. The former diagram is used to estimate the gas density. If the density is about 10⁷ cm^?3 or higher, the latter diagram reproduces the temperature fairly well. If the density is around 10⁶ cm^?3, the temperature obtained from the latter diagram should be multiplied by a factor of 1.5–2. If the density is about 10⁵ cm^?3 or lower, then the latter diagram yields a temperature that is lower than the kinetic temperature by a factor of three or more, and should be used only as a lower limit for the kinetic temperature. The errors in the methanol column density determined from the integrated intensity of a single line can be more than an order of magnitude, even when the gas temperature is well known. However, if the J₀?(J ? 1)₀E lines, as well as the J₁?(J ? 1)₁A⁺ or A^? lines are used, the relative error in the column density is no more than a factor of a few.     

Thermal emission of methanol and other molecules at millimeter wavelengths

The paper reports the results of a survey of Galactic star-forming regions in the methanol lines 8_?1–7₀ E at 229.8 GHz, 3_?2–4_?1 E at 230.0 GHz, 0₀–1_?1 E at 108.9 GHz, and a series of J ₁–J ₀ E lines near 165 GHz. In addition to the methanol lines, lines of methyl cyanide (CH₃CN), cyanoacetylene (HC₃N), methyl formate (HCOOCH₃), and sulphur dioxide (SO₂) were detected. Analysis of the data indicates that the methanol emission arises in warm (30–50 K) gas.     

The Fragmentation in a Protoplanetary Disk and the Properties of the Resultant Self-Gravitating Clumps

We study the fragmentation properties in the protoplanetary disk and properties of the resultant self-gravitating clumps using our newly constructed disk model. Our disk model includes the mass inflall term from a molecular cloud core and the photoevaporation winds effect. We adopt the conventional fragmentation criterion to judge whether a protoplanetary disk can fragment. In this work, we follow our previous work to investigate the properties of the resultant self-gravitating clumps. In our calculation, the initial masses of the resultant self-gravitating clumps lie in the range of tens of M_J to more than one hundred of M_J, where M_J is the Jupiter mass. These initial masses can seemingly account for the masses of extrasolar planets in magnitude. We also calculate the subsequent gas accretion of clumps in 1.27 × 10⁴ yr after the formation of self-gravitating clumps. We find that the subsequent gas accretion of self-gravitating clumps is very efficient, and the clump masses grow to hundreds of M_J and the physical radii R_c of clumps increase to about 10 AU. Additionally, we also calculate the orbital migration of clumps. We find that most clumps have short migration timescale to be accreted onto the protostar, and only a small fraction of clumps have long migration timescale (>10⁶ yr) to successfully become gas giant planets. These results are consistent with previous studies.     

Oil potential of the Lower Mesozoic deposits of the Khapchagai megaswell of the Vilyui syneclise

Analysis of all available geological, geophysical, and field data on some gas condensate fields discovered within the Khapchagai megaswell (Vilyui syneclise of the Siberian Platform) as early as the 1960s shows the presence of oil rims in Lower Triassic (horizon T₁-III in the Srednevilyuiskoe and Tolonskoe gas condensate fields and horizon T₁-Kh in the Mastakhskoe gas condensate field) and Lower Jurassic (horizons J₁-I and J₁-II in the Mastakhskoe gas condensate field) deposits. The C₃ oil reserves in these rims are estimated at several tens of millions of tons of oil. The results are indicative of the oil potential of the Lower Mesozoic deposits not only of the Vilyui syneclise but also _{of the Lena–Vilyui petroliferous province as a whole, which was always characterized as a gas-bearing province in summary reports.}     

Ferromagnetic or antiferromagnetic Fe III spin configurations in sheet silicates

Mössbauer spectra of glauconite and nontronite recorded at temperatures down to 1.3K and in applied fields up to 4.5 T show that Fe III spin configurations are respectively ferromagnetic and antiferromagnetic. It is shown that in a particular material depending on the distribution and concentration of Fe III in the silicate sheet either mode might occur. A new model of competing nearest-neighbour (J ₁) and next-nearest-neighbour (J ₂) magnetic exchange interactions in the triangular lattice is introduced to account for the results. From available magnetic susceptibilities we estimate ∣J ₁∣～6∣J ₂∣. The results lead to the conclusion that the Fe III cations are highly ordered in glauconite and occupy cis sites so as to maximize their mutual separations.     

Groundwater depth affects the daily course of gas exchange parameters of Populus euphratica in arid areas

In this case study, the diurnal courses of gas exchange in Populus euphratica at different groundwater depths in the lower reaches of Tarim River were investigated to understand the effects of soil hydrology on photosynthesis and water use efficiency (WUE) of vegetation in arid desert area. It was found that the photosynthetic rate (P _N) was not sensitive to the change of groundwater depth (GD) within the range of 4.2?C6.8?m. Compared to stomatal conductance (g _s) and transpiration rate (E) of P. euphratica grown at GD 4.2, 5.6 and 5.8?m, g _s and E at GD 6.8?m both markedly declined in June, suggesting that P. euphratica at deeper GD can avoid overall water loss by stomatal adjustment. The intrinsic water use efficiency of P. euphratica first decreases with the increasing GD, but when GD increased to 6.8?m, intrinsic WUE increased by 1.2?C2.2 fold, compared with the WUE of P. euphratica at GD 4.2?C5.8?m, indicating that intrinsic WUE of P. euphratica will increase when the plant suffers from moderate drought stress.     

Possible errors in helium analyses of soil gases by mass spectrometers having constant-pressure inlet systems

Published data suggest that soil gas helium concentrations of 5.28–5.34 ppm v/v over uranium and hydrocarbon deposits are significantly anomalous compared to the ambient atmospheric background of 5.24 ppm. However, analyses for helium by mass spectrometers having constant-pressure inlet systems, from which most of these data are derived, are subject to errors of equivalent magnitude. These errors arise when the major component composition of unknown and standard gases differ, for the different gases have different flow rates through the inlet system — relative rates being O₂ < dry air < water-saturated air < N₂ < CO₂ CH₄. Soil gas compositions can vary greatly and, compared to a dry air standard, the flow-rate of a water-saturated gas containing 10% biogenic CO₂ will increase, enhancing the apparent He content to 5.33 ppm. Accurate helium analyses can be achieved by using a constant-volume inlet and integrating the detector response over the period of the samples' passage through the detector.     

Assessment of the mutual impact between climate and vegetation cover using NOAA-AVHRR and Landsat data in Egypt

The objective of the current study is to use satellite data to assess the mutual influence between vegetation and climate. The Ismailia Governorate was selected as a case study to investigate the impact of vegetation cover expansion on both land surface and air temperature from 1983 to 2010 and vice versa. This observation site was carefully selected as a clear example of the high rate of the reclamation and vegetation expansion process in Egypt. Land surface temperature (LST) was estimated through the Advanced Very High Resolution Radiometer (a space-borne sensor embarked on the National Oceanic and Atmospheric Administration) data while air temperature (T _air) was collected from ground meteorological stations in the study area. Irrigated agriculture is the largest consumer of freshwater resources. However, consistent information on irrigation water use is still lacking. Relative humidity, wind speed, solar radiation, and T _air data were inserted in the Penman–Monteith equation to calculate potential evapotranspiration (ET_o), while both LST and T _air were used to observe the relative water status of the study area as a result of the water deficit index (WDI). Then, both WDI and ET_o were used to calculate actual evepotranspiration (ET_C.). The results showed that LST decreased by about 2.3 °C while T _air decreased by about 1.6 °C during the study period. The results showed also that the vegetation cover expanded from 25,529.85 ha in 1985 to 63,140.49 ha in 2009 with about 147 % increase. This decrease in LST and air temperature was according to the expansion of the cultivated land that was proved through the processing of three Landsat TM and Landsat ETM+ imageries acquired in June 19, 1985, June 7, 1998, and June 29, 2009. The vegetation water consumption was affected by the decreasing surface and air temperature. The results showed that the water deficit index decreased by about 0.35, and actual evapotranspiration increased by about 2.5 mm during the study period.     

Joint development normal to regional compression during flexural-flow folding: the Lilstock buttress anticline,Somerset, England

Alpine inversion in the Bristol Channel Basin includes reverse-reactivated normal faults with hanging wall buttress anticlines. At Lilstock Beach, joint sets in Lower Jurassic limestone beds cluster about the trend of the hinge of the Lilstock buttress anticline. In horizontal and gently north-dipping beds, J₃ joints ( 295–285° strike) are rare, while other joint sets indicate an anticlockwise sequence of development. In the steeper south-dipping beds, J₃ joints are the most frequent in the vicinity of the reverse-reactivated normal fault responsible for the anticline. The J₃ joints strike parallel to the fold hinge, and their poles tilt to the south when bedding is restored to horizontal. This southward tilt aims at the direction of σ₁ for Alpine inversion.Finite-element analysis is used to explain the southward tilt of J₃ joints that propagate under a local σ₃ in the direction of σ₁ for Alpine inversion. Tilted principal stresses are characteristic of limestone–shale sequences that are sheared during parallel (flexural-flow) folding. Shear tractions on the dipping beds generate a tensile stress in the stiffer limestone beds even when remote principal stresses are compressive. This situation favors the paradoxical opening of joints in the direction of the regional maximum horizontal stress. We conclude that J₃ joints propagated during the Alpine compression caused the growth of the Lilstock buttress anticline.     

Absorption spectra of Cr3+ in Al2O3 under shock compression

Unpolarized absorption spectra of single crystals of Cr³⁺ doped Al₂O₃ (synthetic ruby) have measured using a new, time-resolving, dispersive, streak photographic system over the range ～350 to ～700 nm during a series of shock loading experiments. The crystal field absorptions assigned to the transition ⁴ A _2g→⁴ T _2g were observed to shift in a series of experiments from 555±1 nm at atmospheric pressure to 503±5 nm at 46 GPa. In a single experiment at 32 GPa the ⁴ A _2g→⁴ T _1g transition was observed to shift from 405±1 to 386±5 nm. The present data extrapolate downwards in compression toward the 10 GPa data of Stephens and Drickamer (1961) although both crystal field absorption energies increase considerably less with compression than predicted by the simple ionic point charge model. The single datum observed for the Racah parameter B, 588±38 cm^?1 at 32 GPa, is consistant with previous results to 10 GPa and the trend of decreasing B, with compression expected from the divergence of the data from the point charge model due to increasing covalancy.     

Improving energy efficiency and fouling mitigation for membrane bioreactor in Al-Rustamiyah sewage treatment plant based on hydrodynamics

In Al-Rustamiyah sewage treatment plant in the east of Baghdad city, capital of Iraq, the membrane bioreactor suffering from a severe biofouling problem. The main reason for this problem is inefficient and inadequate aeration process. The objective of this work is to control fouling and to improve the energy efficiency of the submerged membrane bioreactor. Fouling control is achieved by optimizing the two-phase hydrodynamic parameters (air bubble diameter and shear stress), while energy efficiency improved through analysis of flow field. An experimental rig similar to real plant was built, and several operating and design parameters were experimentally tested. The parameters were air flow rate (1–9 L/min), membrane sheets spacing (3, 5, and 7 mm), and air diffuser design (pipe diffuser and disk diffuser). The bubble sizes were measured experimentally using high-speed camera. It was found that larger bubbles were produced at narrow channels between the membrane sheets. Optimization using computational fluid dynamic with ANSYS FLUENT was employed; the results showed that a bubble diameter of 2.5 mm had a slug flow pattern, resulting in better energy saving for a 3 mm space between membrane sheets with a 5 L/min air flow, while maximum shear stress obtained was (4 Pa). Nutrients removal results from synthetic sewage were 97.32, 79.68, and 13% for COD, NH₃–N, and PO ₄ ^?3 , respectively, at 6 days retention time. The results obtained are quite significant in practice because it contributes to improve the efficiency of membrane bioreactor in Al-Rustamiyah sewage treatment plant.     

Molar gas ratios of air entrapped in ice: A new tool to determine the origin of relict massive ground ice bodies in permafrost

The molar ratios of atmospheric gases change during dissolution in water due to differences in their relative solubilities. We exploited this characteristic to develop a tool to clarify the origin of ice formations in permafrost regions. Extracted from ice, molar gas ratios can distinguish buried glacier ice from intrasedimental ground ice formed by freezing groundwaters. An extraction line was built to isolate gases from ice by melting and trapping with liquid He, followed by analysis of N₂, O_2,, Ar, ¹⁸O_O2 and ¹⁵N_N2, by continuous flow mass spectrometry. The method was tested using glacier ice, aufeis ice (river icing) and intrasedimental ground ice from sites in the Canadian Arctic. O₂/Ar and N₂/Ar ratios clearly distinguish between atmospheric gas in glacial ice and gases from intrasedimental ground ice, which are exsolved from freezing water. δ¹⁵N_N2 and δ¹⁸O_O2 in glacier ice, aufeis ice and intrasedimental ground ice do not show clear distinguishing trends as they are affected by various physical processes during formation such as gravitational settling, excess air addition, mixing with snow pack, and respiration.     

A silicon-29 nuclear magnetic resonance study of silicon-aluminum ordering in leucite and analcite

Silicon-29 magic-angle-spinning NMR spectroscopy has been used to investigate the silicon-aluminum distribution in natural samples of analcite and leucite (before and after heat treatment) as well as a leucite synthesized from a gel. Three different simulation programs have been developed to fit the experimental spectra. For two we assume a different aluminum occupancy fraction g _i for each of the three crystallographically distinct tetrahedral sites T _i in leucite and some degree of aluminum avoidance, but an otherwise random arrangement of tetrahedral cations. A third program interchanges Al and Si cations on a lattice of 3×3×3 unit cells to generate an optimized fit. All models predict that the T ₂ sites in natural leucite are deficient in aluminum: g ₁≈0.39, g ₂≈0.16, and g ₃≈0.42 for the fractional Al occupancy at each site, with apparently strict aluminum avoidance. Heat treatment of the sample at 1673 K for a week has little effect on the g _i values but may create some Al-O-Al linkages. In the gel-synthesized leucite, Al occupancies are slightly more uniform than in natural leucite: g ₁≈0.36, g ₂≈0.20, and g ₃≈0.42. For analcite, two distinctly different Si, Al distributions are obtained: (A) g ₁=g ₃≈0.09, g ₂≈0.78 and (B) g ₁=g ₃≈0.46, g ₂≈0.04. Additional NMR measurements on an ion-exchanged sample or an accurate determination of unit-cell dimensions could resolve this ambiguity.     

The generation of ductile and brittle shear bands in a low-angle mylonite zone

In the Saint-Barthélemy Massif, French Pyrenees, a ductile thrust zone developed in gneisses during retrogression from lower amphibolite facies conditions to the upper greenschist facies. The last major structures formed in the zone are isolated shear bands, divided into three types.Anastomosing, inhomogenous ultramylonitic shear bands (Type I) are subparallel to the mylonitic foliation in the gneiss (S_g). Most of these bands developed by ductile deformation processes only.Planar, homogeneous ultramylonite bands (Type II) are usually oblique to S_g. They generated as pseudotachylyte bands by brittle fracturing and underwent strong subsequent ductile deformation.Type III shear bands are planar and oblique to S_g. They consist of pseudotachylyte, weakly affected by ductile deformation.Type I, II and III bands seem to represent progressively younger structures on a local scale, linked to falling P-T conditions. The systematic variation in orientation of the different shear bands with respect to S_g is interpreted as being due to a different response of brittle and ductile structures to the orientation of the kinematic frame and the rock anisotropy.     

Trends in intrinsic water-use efficiency of natural trees for the past 100–200 years: a response to atmospheric CO2 concentration

To evaluate how the land carbon reservoir has been acting as a sink to the anthropogenic CO₂ input to the atmosphere, it is important to study how plants in natural forests physiologically adjust to the changing atmospheric conditions. This has been studied intensively using controlled experiments, but it has been difficult to scale short-term observations to long-term ecosystem-level response. This paper derives variations of plant intrinsic water-use efficiency from natural trees for the past 100–200 years using carbon isotope chronologies. This parameter may potentially cause an increase in plant growth rate by improving the efficiency of plant water use, especially in arid environments. Attempts were made to isolate the variations of intrinsic water-use efficiency as a function of only the CO₂ concentration of the atmosphere. The intrinsic water-use efficiency of almost all trees increased with increasing atmospheric CO₂ concentration. This is caused by an increase in the carbon assimilation rate (A) and/or a decrease in the stomatal conductance (g). The increase in plant intrinsic water-use efficiency may imply an increase in plant transpiration efficiency which may have a direct connection with changes in plant biomass.     

Geothermal regime and Jurassic source rock maturity of the Junggar basin, northwest China

We analyze the thermal gradient distribution of the Junggar basin based on oil-test and well-logging temperature data. The basin-wide average thermal gradient in the depth interval of 0–4000 m is 22.6 °C/km, which is lower than other sedimentary basins in China. We report 21 measured terrestrial heat flow values based on detailed thermal conductivity data and systematical steady-state temperature data. These values vary from 27.0 to 54.1 mW/m² with a mean of 41.8 ± 7.8 mW/m². The Junggar basin appears to be a cool basin in terms of its thermal regime. The heat flow distribution within the basin shows the following characteristics. (1) The heat flow decreases from the Luliang Uplift to the Southern Depression; (2) relatively high heat flow values over 50 mW/m² are confined to the northern part of the Eastern Uplift and the adjacent parts of the Eastern Luliang Uplift and Central Depression; (3) The lowest heat flow of smaller than 35 mW/m² occurs in the southern parts of the basin. This low thermal regime of the Junggar basin is consistent with the geodynamic setting, the extrusion of plates around the basin, the considerably thick crust, the dense lithospheric mantle, the relatively stable continental basement of the basin, low heat generation and underground water flow of the basin. The heat flow of this basin is of great significance to oil exploration and hydrocarbon resource assessment, because it bears directly on issues of petroleum source-rock maturation. Almost all oil fields are limited to the areas of higher heat flows. The relatively low heat flow values in the Junggar basin will deepen the maturity threshold, making the deep-seated widespread Permian and Jurassic source rocks in the Junggar basin favorable for oil and gas generation. In addition, the maturity evolution of the Lower Jurassic Badaowan Group (J_1b) and Middle Jurassic Xishanyao Group (J_2x) were calculated based on the thermal data and burial depth. The maturity of the Jurassic source rocks of the Central Depression and Southern Depression increases with depth. The source rocks only reached an early maturity with a R₀ of 0.5–0.7% in the Wulungu Depression, the Luliang Uplift and the Western Uplift, whereas they did not enter the maturity window (R₀ < 0.5%) in the Eastern Uplift of the basin. This maturity evolution will provide information of source kitchen for the Jurassic exploration.     

Methanol radio emission at millimeter wavelengths: New masers at 1.3 and 2.8 millimeters

The results of a search for maser emission in the methanol lines 8_?1-7₀ E at 229.8 GHz, 3_?2-4_?1 E at 230.0 GHz, 0₀-1_?1 E at 108.9 GHz, and in the J ₁-J ₀ E series near 165 GHz in star-forming regions are reported. At least two masers and two candidates have been detected at 229.8 GHz. Thus, methanol masers have been detected in the 1-mm band for the first time. At 108.9 GHz, masers have been detected toward G345.01+1.79 and possibly toward M8E as well. Thermal emission was found toward 28 objects. The 229.8-GHz sources are class I masers, whereas the 108.9-GHz sources are class II masers. An analysis using a large velocity-gradient method shows that the 229.8-GHz masers can appear at densities of about 3×10⁴ cm^?3. The ratios of the flux densities in different class I lines toward DR 21(OH) and DR 21 West can be approximated in models with gas kinetic temperatures of about 50 K. Detection of the 108.9 GHz masers toward G345.01+1.79 and M8E may provide information about the geometry of these objects.