Detection of interstellar hydrogen sulfide in cold, dark clouds

We have detected interstellar hydrogen sulfide (H2S) toward the cold, dark clouds L134N and TMC 1. We derive total column densities of approximately 2.6 x 10(13) cm-2 and approximately 7.0 x 10(12) cm-2 at the SO peak of L134N and at the NH3 peak of TMC 1, respectively. Since the expected gas phase reactions leading to the formation of H2S are thought to be endothermic, grain surface reactions may play a major role in the synthesis of this species in cold, dark clouds. If the carbon abundance is high and grain surface reactions are the dominant formation route, H2CS would be expected to form instead of H2S, and the abundances of H2CS have been observed to be high where those of H2S are low in L134N and TMC 1.     

The detection of acetaldehyde in cold dust clouds

Observations of the 1(01) --> 0(00) rotational transitions of A and E state acetaldehyde are reported. The transitions were detected, for the first time in interstellar space, in the cold dust clouds TMC-1 and L134N, and in Sgr B2. This is also the first time acetaldehyde has been found in a dust cloud and is the most complex oxygen-bearing molecule yet known in this environment. We find a column density of 6 x 10(12) cm-2 in TMC-1, comparable to many other species detected there, and an approximately equal column density in L134N. In the direction of Sgr B2, the CH3CHO profile appears to consist of broad emission features from the hot molecular cloud core, together with absorption features resulting from intervening colder material. We also report the possible detection of HC9N toward IRC +10 degrees 216 through its J = 33 --> 32 transition. Implications for cold dust cloud chemistry and excitation are discussed.     

Nitrogen sulfide in quiescent dark clouds

We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models.     

Charge transfer reactions at interfaces between neutral gas and plasma: Dynamical effects and X‐ray emission

Charge‐transfer is the main process linking neutrals and charged particles in the interaction regions of neutral (or partly ionized) gas with a plasma. In this paper we illustrate the importance of charge‐transfer with respect to the dynamics and the structure of neutral gas‐plasma interfaces. We consider the following phenomena: (1) the heliospheric interface ‐ region where the solar wind plasma interacts with the partly‐ionized local interstellar medium (LISM) and (2) neutral interstellar clouds embedded in a hot, tenuous plasma such as the million degree gas that fills the so‐called “Local Bubble”. In (1), we discuss several effects in the outer heliosphere caused by charge exchange of interstellar neutral atoms and plasma protons. In (2) we describe the role of charge exchange in the formation of a transition region between the cloud and the surrounding plasma based on a two‐component model of the cloud‐plasma interaction. In the model the cloud consists of relatively cold and dense atomic hydrogen gas, surrounded by hot, low density, fully ionized plasma. We discuss the structure of the cloud‐plasma interface and the effect of charge exchange on the lifetime of interstellar clouds. Charge transfer between neutral atoms and minor ions in the plasma produces X‐ray emission. Assuming standard abundances of minor ions in the hot gas surrounding the cold interstellar cloud, we estimate the X‐ray emissivity consecutive to the charge transfer reactions. Our model shows that the charge‐transfer X‐ray emission from the neutral cloud‐plasma interface may be comparable to the diffuse thermal X‐ray emission from the million degree gas cavity itself (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Upper limits for the ethyl-cyanide abundances in TMC-1 and L134N: Chemical implications

We have sought interstellar ethyl-cyanide via its 2₀₂–1₀₁ transition towards two cold, dark clouds and report upper limits of the total column densities of 3×10¹²cm^–2 and 2×10¹²cm^–2 for TMC-1 and L134N, respectively. We also observed the 2₀₂–1₀₁ transition of vinyl cyanide previously identified in TMC-1 by Matthews and Sears (1983b). The detection of vinyl cyanide and the non-detection of ethyl cyanide in TMC-1 are consistent with gas phase ion-molecule chemical models, and there is thus no necessity of invoking grain surface synthesis for vinyl cyanide in cold clouds.     

Chlorine-bearing molecules in cold and warm interstellar clouds

A new time-dependent model of chlorine chemistry in cold and warm TMC-1 and Orion clouds was constructed using results of recent laboratory and theoretical studies on the reaction of chlorine molecules. The chemistry of chlorine was found to be fairly simple in dense interstellar clouds. Only the species Cl and HCl have a significant fractional abundance. Our results for the HCl molecule are in agreement with those obtained from the observation and from theoretical values of Orion cloud.     

Shock chemistry in the molecular clouds associated with SNR IC 443

Several interstellar molecules have been detected toward the highly perturbed B and G clouds associated with the supernova remnant IC 443 via their 3 mm transitions, including N2H+, SiO, SO, CN, HNC, and H13CO+. The (J, K) = (1, 1) and (2, 2) inversion lines of metastable ammonia have also been observed, as well as the J = 3-2 transition of HCO+ at 1.2 mm. Analysis of the (1, 1) and (2, 2) inversion lines of NH3 indicates minimum gas kinetic temperatures of TK = 70 K toward cloud B, and TK = 33 K in cloud G. Modeling of the J = 1-0 and J = 3-2 transitions of HCO+ implies densities greater than 10(5) cm-3 toward both positions. These data clearly show that hot and dense material is present in IC 443, and they suggest the presence of shocks in both regions. A careful analysis of the HCO+ lines indicates that the HCO+ abundance is at most enhanced by factors of a few over that found in cold, quiescent gas. This conclusion contradicts past claims of HCO+ abundance enhancements of several orders of magnitude in the perturbed regions. The N2H+ abundance was also found to be similar to that in cold gas, suggesting that there is no increase in ionization in the clouds. The abundances of SO and CS, as well as CN and NH3, do not appear to differ significantly from those found in cold dark clouds, although chemistry models predict sulfur-containing species to undergo high-temperature enhancements. SiO, however, is found to have an abundance in the perturbed gas 100 times larger than the upper limits observed in the dark cloud TMC 1, a result in agreement with high temperature chemistry models. In addition, the HNC/HCN ratio in both IC 443 B and G was found to be approximately 0.1--far from the ratio of 1 predicted by low-temperature ion-molecule chemistry, but similar to the values observed in clouds where elevated temperatures are present.     

On the angular momentum in star formation

We discuss the rotation of interstellar clouds which are in a stage immediately before star formation. Cloud collisions seem to be the principal cause of the observed rotation of interstellar clouds. The rotational motion of the clouds is strongly influenced by turbulence.Theories dealing with the resolution of the angular momentum problem in star formation are classified into five major groups. We develop the old idea that the angular momentum of an interstellar cloud passes during star formation into the angular momentum of double star systems and/or circumstellar clouds.It is suggested that a rotating gas cloud contracts into a ring-like structure which fragments into self-gravitating subcondensations. By collisions and gas accretion these subcondensations accrete into binary systems surrounded by circumstellar clouds. Using some rough approximations we find analytical expressions for the semi-major axis of the binary system and for the density of the circumstellar clouds as a function of the initial density and of the initial angular velocity of an interstellar cloud. The obtained values are well within the observational limits.     

Turbulent molecular clouds

Stars form within molecular clouds but our understanding of this fundamental process remains hampered by the complexity of the physics that drives their evolution. We review our observational and theoretical knowledge of molecular clouds trying to confront the two approaches wherever possible. After a broad presentation of the cold interstellar medium and molecular clouds, we emphasize the dynamical processes with special focus to turbulence and its impact on cloud evolution. We then review our knowledge of the velocity, density and magnetic fields. We end by openings towards new chemistry models and the links between molecular cloud structure and star-formation rates.     

Variations in the HCN/HNC abundance ratio in the Orion molecular cloud

We have used observations of the rare isotopes of HCN and HNC to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio [HCN]/[HNC] decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. We determine the kinetic temperature in the regions we have studied from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways than those in the general interstellar cloud material.     

Broad-band non-thermal emission from molecular clouds illuminated by cosmic rays from nearby supernova remnants

Molecular clouds are expected to emit non-thermal radiation due to cosmic ray interactions in the dense magnetized gas. Such emission is amplified if a cloud is located close to an accelerator of cosmic rays and if energetic particles can leave the accelerator site and diffusively reach the cloud. We consider here a situation in which a molecular cloud is located in the proximity of a supernova remnant which is efficiently accelerating cosmic rays and gradually releasing them in the interstellar medium. We calculate the multiwavelength spectrum from radio to gamma rays which is emerging from the cloud as the result of cosmic ray interactions. The total energy output is dominated by the gamma-ray emission, which can exceed the emission in other bands by an order of magnitude or more. This suggests that some of the unidentified TeV sources detected so far, with no obvious or very weak counterparts in other wavelengths, might be in fact associated with clouds illuminated by cosmic rays coming from a nearby source. Moreover, under certain conditions, the gamma-ray spectrum exhibits a concave shape, being steep at low energies and hard at high energies. This fact might have important implications for the studies of the spectral compatibility of GeV and TeV gamma-ray sources.     

Measurements of the H2(13)CO ortho/para ratio in cold dark molecular clouds.

H2(13)CO has been detected for the first time toward cold dark molecular clouds using the NRAO 12 m telescope. The H2(13)CO ortho/para abundance ratio R for B335, which we report as R approximately 1.7, suggests equilibrium at the local kinetic temperature and appears to be distinctly different from that for both TMC-1 and L134N, where R is close to or higher than the statistical value 3. Since only B335 among the observed positions includes an imbedded IR source, this difference may result from heating of the grain surfaces, providing the energy necessary for desorption of formaldehyde formed on the grains.     

Masses of interstellar clouds

Equilibrium masses of slowly rotating interstellar gas clouds have been calculated using an equation of state for the interstellar gas developed by Penston and Brown. The rotation is found to increase the equilibrium masses, but still the cloud masses are not as large as indicated by other considerations.     

A reanalysis of the HCO+/HOC+ abundance ratio in dense interstellar clouds

New theoretical and experimental results have prompted a reinvestigation of the HCO+/HOC+ abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC+ and H2, which was previously calculated by DeFrees, McLean, and Herbst to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC+ does indeed react efficiently with H2 in interstellar clouds, the calculated HCO+/HOC+ abundance ratio rises to substantially greater value under standard dense cloud conditions than in deduced via the tentative observation of HOC+ in Sgr B2.     

Magnetic confinement of cosmic clouds

The role of the magnetic field in the confinenment or compression of interstellar gas clouds is reconsidered. The virial theorem for an isolated magnetized cloud in the presence of distant magnetic sources is reformulated in terms of moments of the internal and external currents, and an equilibrium condition is derived. This condition is applied to the interaction between isolated clouds for the simple- and artificial-case in which the field of each cloud is a dipole. With the simplest of statistical assumptions, the probability of any given cloud being compressed is calculated as 10%, the magnetic field acting as a medium which transmits the kinetic pressure between clouds. Even when compression occurs the magnetic pressure 1/2B ² may decrease on leaving the cloud surface.Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988.     

Experiments to Study Radiation Transport in Clumpy Media

Clumpiness of the interstellar medium may play an important role in the transfer of infrared continuum radiation in star forming regions (Boisse, 1990). For example, in homogeneous models, C II emission should be confined to the cloud edge (Viala, 1986). However, in star formation regions (such as M17SW, M17 and W51), it is observed to extend deep into the molecular cloud (Stutzki et al., 1988; Keene et al., 1985). One plausible interpretation of these observations is that, due to their clumpiness, the clouds are penetrated by UV radiation far deeper than expected from simple homogeneous models. The interaction of H II regions around young massive stars with a clumpy medium is another area of interest. Molecular clouds are well established to be clumpy on length scales down to the limits of observational resolution. Clumps can act as localized reservoirs of gas which can be injected into the surroundings by photoionization and/or hydrodynamic ablation (Dyson et al., 1995; Mathis et al., 1998). The calculation of radiation transport in hot, clumpy materials is a challenging problem. Approximate, statistical treatments of this problem have been developed by several workers, but their application has not been tested in detail. We describe laboratory experiments, using the Omega laser to test modelling of radiation transport through clumpy media in the form of inhomogeneous plasmas.     

Interstellar SiO as a tracer of high-temperature chemistry

The J = 2-1 transition of SiO has been searched for toward both hot and cold molecular gas. SiO was not detected toward the dark clouds TMC-1, L134 N, and B335, down to column density upper limits of N < 2-4 x 10(10) cm-2. The species, however, has been observed toward all sources with a kinetic temperature greater than or equal to 30 K, with the largest column densities (N approximately 10(13)-10(17) cm-2) measured in the warmest (TK > or = 100 K) material. The abundance of SiO, relative to HCN, is found to be approximately 0.1-1 in the massive star-forming regions toward Orion and NGC 7538; toward the dark clouds, the upper limits to this ratio is less than 0.0002-0.004. A similar enhancement in the warmer regions is reflected in the SiO/H2 ratio as well. A linear relation was found between the natural log of the SiO concentration and 1/TK, suggesting that the species' formation involves a chemically specific process that contains an activation barrier of approximately 90 K. SiO was also found to be underabundant with respect to SO in cold clouds, with SiO/SO < 1/1000, versus SiO/SO > or =, measured in Orion-KL. The formation of SiO is therefore linked closely to the local gas kinetic temperature, rather than the oxygen abundance, and its synthesis is likely to involve high-temperature gas-phase reactions. The species thus may serve as an unambiguous indicator of high-temperature or "shock" chemistry.     

Mass-Stripping Analysis of an Interstellar Cloud by a Supernova Shock

The interaction of supernova shocks and interstellar clouds is an important astrophysical phenomenon since it can result in stellar and planetary formation. Our experiments attempt to simulate this mass-loading as it occurs when a shock passes through interstellar clouds. We drive a strong shock using the Omega laser (∼5kJ)into a foam-filled cylinder with an embedded Al sphere(diameterD=120 μm) simulating an interstellar cloud. The density ratio between Al and foamis∼9. We have previously reported on the interaction between shock and cloud, the ensuing Kelvin-Helmholtz and Widnall instabilities, and the rapid stripping of all mass from the cloud. We now present a theory that explains the rapid mass-stripping. The theory combines (1) the integral momentum equations for a viscous boundary layer, (2) the equations for a potential flow past a sphere, (3) Spalding's law of the wall for turbulent boundary layers, and (4) the skin friction coefficient for a turbulent boundary layer on a flat plate. The theory gives as its final result the mass stripped from a sphere in a turbulent high Reynolds number flow, and it agrees very well with our experimental observations.     

On the detection of interstellar homonuclear diatomic molecules

The pure rotational spectrum of homonuclear diatomic molecules in the interstellar medium is strongly forbidden, and no such spectrum has been detected. In regions of high excitation, vibrational emission may occur, as is widely detected in the case of H₂ in interstellar shocks and photon-dominated regions. However, it is of considerable interest to know the abundance of homonuclear diatomics in quiescent regions. We propose that vibrational emission from homonuclear diatomic molecules in cold clouds may be detectable, where the excitation is mainly through collisions with non-thermal electrons arising from the cosmic-ray ionization of H₂. As an example, we estimate the intensity of emission from N₂ in cold, dark interstellar clouds. We show that such emission is at the limit of detectability with current technology. Other excitation mechanisms may also contribute and enhance this emission.     

Diffuse interstellar band formation in dense clouds

Measurements of the strengths of the diffuse interstellar bands at 4430, 5780 and 5797 Å show that the bands tend to be week with respect to extinction in dense interstellar clouds. Data on 10 stars in the ? Ophiuchi cloud complex show further that the diffuse band-producing efficiency of the grains decreases systematically with increasing grain size. It is concluded that the diffuse bands are not formed in the mantles which accrete on the grains in interstellar clouds, but that they could be produced in the cores of grains or in some molecular species.