Shifts in the Processes of Oxygen and Nutrient Balances in the River Elbe since the Transformation of the Economic Structure

The reduction of pollution in the river Elbe since 1990 has resulted in changes in the processes taking place in the river. The heterotrophic degradation which dominated until 1990 was accompanied by a lack of oxygen, floating masses of sewage fungi, and sludge formation in the areas of still water. Since the early 1990s, autotrophic processes have come to dominate, with an increase in pH fluctuations and the oxygen production potential, but evidently not the chlorophyll level during the growing season. The degradable organic pollution of the Elbe is determined by algae production. The high levels of ammonium previously encountered in the Elbe were attributable to not only dischargers but also in particular the lack of oxygen in the water. Via heterotrophic nitrate assimilation, nitrate served as an oxygen reserve, resulting in high levels of nitrite. At present, when the oxygen contents are sufficient, the concentration reductions of nitrate and nitrite along the reach of the Elbe are approximately parallel, which in view of the lack of ammonium indicates the denitrification of microzones low in oxygen. The relative proportion of structurally bound substance turnover will become increasingly important for the Elbeπs material budget.     

Methods to calculate sedimentation rates of floodplain soils in the middle region of the Elbe River

This study presents different methods to quantify the historic and recent sedimentation of floodplain soils along the Elbe River. These methods include the comparison of surface elevations, the quantification of sedimentation with the aid of anthropogenic and geogenic tracers, sediment trap studies, and the calculation of load balances. Selected results from sites at the lower section of the middle Elbe River are presented and verified. The results show that several methods are suitable. In future work it should be possible, depending on the available soil and sediment data, to calculate sedimentation in Elbe River floodplain and the loss of retention volume for larger areas.     

Reaction of fish larvae to the water of the River Elbe at Hamburg harbour

The River Elbe is one of the biggest streams carrying pollutants of all kinds into the North Sea. However, investigations of direct effects of the Elbe water on river life are not numerous. Early life stages of common whitefish and carp were reared under comparable conditions in water of the River Elbe, and in tap water, respectively. No direct effects on the viability of the fry could be found by observing mortality and growth rates in both treatments. Whitefish larvae were severely infested by parasitic ciliates which were able to build up a dense population in the river water. In these experiments life conditions for the protozoa seemed to be much better than in tap water. Mortality rates of early larvae of common whitefish were lower in the Elbe water than in tap water. Mortality, growth rate and starvation resistance of carp fry was equal in river and tap water.     

Heavy metal transport in large river systems: heavy metal emissions and loads in the Rhine and Elbe river basins

Pollutant transport and management in the Rhine and Elbe basins is still of international concern, since certain target levels set by the international committees for protection of both rivers have not been reached. The analysis of the chain of emissions of point and diffuse sources to river loads will provide policy makers with a tool for effective management of river basins. The analysis of large river basins such as the Elbe and Rhine requires information on the spatial and temporal characteristics of both emissions and physical information of the entire river basin. In this paper, an analysis has been made of heavy metal emissions from various point and diffuse sources in the Rhine and Elbe drainage areas. Different point and diffuse pathways are considered in the model, such as inputs from industry, wastewater treatment plants, urban areas, erosion, groundwater, atmospheric deposition, tile drainage, and runoff. In most cases the measured heavy metal loads at monitoring stations are lower than the sum of the heavy metal emissions. This behaviour in large river systems can largely be explained by retention processes (e.g. sedimentation) and is dependent on the specific runoff of a catchment. Independent of the method used to estimate emissions, the source apportionment analysis of observed loads was used to determine the share of point and diffuse sources in the heavy metal load at a monitoring station by establishing a discharge dependency. The results from both the emission analysis and the source apportionment analysis of observed loads were compared and gave similar results. Between 51% (for Hg) and 74% (for Pb) of the total transport in the Elbe basin is supplied by inputs from diffuse sources. In the Rhine basin diffuse source inputs dominate the total transport and deliver more than 70% of the total transport. The diffuse hydrological pathways with the highest share are erosion and urban areas. Copyright © 2002 John Wiley & Sons, Ltd.     

Interaction of tides and storm surges at the Elbe River mouth

The main regularities in the interaction of tides and storm surges at river mouths are discussed. A study of the Elbe River mouth area is used to describe the processes of interaction of the eustatic sea level rise, tides, surges, and river flow and special features of formation of maximum water levels. As shown, the intensification of cyclonic activity over the Northern Atlantic in the second half of the XX century resulted in more frequent extremely high storm surges at the Elbe River mouth. An assessment is given for possible changes in the regime of tides and surges at the Elbe River mouth in the XXI century, which may be caused by the acceleration of the eustatic sea level rise. The impact of local hydraulic engineering works (diking, dredging, and channel straightening) on maximum water levels within the town of Hamburg is analyzed.     

Behaviour of Different Molecular-weight Fractions of DOC of Elbe River Water during River Bank Infiltration

This paper reports changes in dissolved organic carbon concentration β(DOC) and the relation between UV-active and non-UV-active components determined for Elbe river water and river bank infiltrate in the Torgau river basin between 1992 and 1994. Using an ultrafiltration method, the fractionation of the DOC content was obtained for the fractions > 10 000 g/mol, 1 000…10 000 g/mol, and < 1 000 g/mol. The spectral absorption coefficient at 254 nm a₂₅₄ of the molecular-weight fractions was also measured. The mean total DOC concentration of Elbe river water decreased from 6.0 mg/L to below 3.9 mg/L along two investigated flowpaths. Two thirds of the decrease occurred within the first few metres of the river bed and one third along the 350 m length of the groundwater flowpaths. The a₂₅₄ values showed a significant decrease from 14.8 1/m in Elbe river water to 7.8 1/m in the aquifer. Along a flowpath, the proportion of low-molecular weight fraction of DOC increased, the proportion of high-molecular weight fraction decreased, and the proportion of the 1 000…10 000 g/mol molecular-weight fraction remained relatively stable. The Elbe river water contained the main portion of UV-active compounds in the fraction 1 000…10 000 g/mol, and this was also the case for samples of river infiltrate. For the high-molecular weight fraction, mainly non-UV-active compounds were attenuated in the river bed sediment.     

Chlorinated Hydrocarbons in Sediments of the Elbe Catchment Area – Analytical Methods and Status of Pollution

A survey was conducted to determine the status of pollution of surficial sediments in the Elbe catchment area (Germany, Czech Republic) for the period 1992 to 1994. Chlorinated benzenes, PCBs, DDT and its metabolites, and HCH isomers were determined by GC/ECD following a simultaneous steam distillation-extraction procedure. Most of the investigated compounds showed increased concentration levels in sections of the Elbe or its main tributaries exceeding the target value II (quality criteria ARGE Elbe). Patterns of chlorinated hydrocarbons could be traced back from the Elbe into tributaries, and in some cases, links between patterns and inputs or long-term effects of former chemical production sites were supposed.     

Assessment of Water Quality in the Elbe River at Flood Water Conditions Based on Cluster Analysis,Principle Components Analysis,and Source Apportionment

An assessment of water quality measurements during a spring flood in the Elbe River is presented. Daily samples were taken at a site in the middle Elbe, which is part of the network of the International Commission for the Protection of the Elbe River (IKSE/MKOL). Cluster analysis (CA), principal components analysis (PCA), and source apportionment (APCS apportioning) were used to assess the flood‐dependent matter transport. As a result, three main components could be extracted as important to the matter transport in the Elbe River basin during flood events: (i) re‐suspended contaminated sediments, which led to temporarily increased concentrations of suspended matter and of most of the investigated heavy metals; (ii) water discharge related concentrations of pedogenic dissolved organic matter (DOM) as well as preliminary diluted concentrations of uranium and chloride, parameters with stable pollution background in the river basin; and (iii) abandoned mines, i.e., their dewatering systems, with particular influence on nickel, manganese, and zinc concentrations.     

Geochemical characterisation and erosion stability of fine‐grained groyne field sediments of the Middle Elbe River

Because of the significant reduction of flow velocity relative to the main current there is an accumulation of sediment material in the centre of the groyne fields over time (years to decades) up to a maximum of 1.5 m. Based on the element‐ and compound‐specific depth functions of this fine‐grained material with high organic matter content the sedimentation history of the Elbe River sediments concerning the environmentally relevant nutrients and pollutants can be reconstructed. It could be shown that the fresh sediments are less polluted than the deeper older ones. During the extreme flood of the river Elbe in August 2002 the critical erosion shear stress in the groyne fields was high enough to remobilise a considerable portion of the sediment depot. The hazard to the environment is high due to the fact that a significant part of the remobilised polluted sediments was distributed over the recent floodplain which is normally used as pasture. Thus these groyne field sediments represent a temporary danger for the water quality of the river Elbe. But the hazard of the solids sedimented in the recent floodplain of the river can be viewed as long‐lasting.     

Comparison of hydrodynamic models of different complexities to model floods with emergency storage areas

A flood emergency storage area (polder) is used to reduce the flood peak in the main river and hence, protect downstream areas from being inundated. In this study, the effectiveness of a proposed flood emergency storage area at the middle Elbe River, Germany in reducing the flood peaks is investigated using hydrodynamic modelling. The flow to the polders is controlled by adjustable gates. The extreme flood event of August 2002 is used for the study. A fully hydrodynamic 1D model and a coupled 1D–2D model are applied to simulate the flooding and emptying processes in the polders and flow in the Elbe River. The results obtained from the 1D and 1D–2D models are compared with respect to the peak water level reductions in the Elbe River and flow processes in the polders during their filling and emptying. The computational time, storage space requirements and modelling effort for the two models are also compared. It is concluded that a 1D model may be used to study the water level and discharge reductions in the main river while a 1D-2D model may be used when the study of flow dynamics in the polder is of particular interest. Further, a detailed sensitivity analysis of the 1D and 1D–2D models is carried out with respect to Manning's n values, DEMs of different resolutions, number of cross-sections used and the gate opening time as well as gate opening/closing duration. Copyright © 2008 John Wiley & Sons, Ltd.     

Identifizierung ausgewählter Pestizide im Wasser mit Hilfe eines screening-Systems auf Grundlage der Dünnschichtchromatographie

After their extraction from water, 16 water pollutants of the families of triazines, urea herbicides, phenoxycarboxylic acids and organochlorine and organophosphorus insecticides are separated and identified by thin-layer chromatography. The method is suitable for routine analyses and was tested on model waters, inclusive of water from the Elbe river. The rate of redetection is up to 80%, the detection limit is at 0.5… 2 μg of the individual pollutants.     

Mitochondrial DNA provides evidence of a double origin for the stone crayfish Austropotamobius torrentium in the Elbe basin

The stone crayfish Austropotamobius torrentium is the smallest native European crayfish, restricted to central and southeast Europe. Northeast boundary of its range is located within the Elbe basin but considerable uncertainties existed regarding its status in this area. Until recently, known stone crayfish populations in the Elbe basin were very scattered and human translocations have been implicated in such distribution pattern. Discoveries of additional populations in the Czech Republic and Saxony (east Germany) nevertheless suggest that the species may have been more widespread there. We provide data on genetic variation (based on 181 sequences of the mitochondrial COI gene) of 20 representative populations from the Elbe basin (both from the Czech Republic and Saxony). We tested whether the haplotype variation is consistent with a scenario of natural dispersal or whether long-range transport has been involved. All analysed individuals from the easternmost, geographically isolated Czech stone crayfish population carried a haplotype previously recorded only in Slovenia and its vicinity; it is therefore likely that such population has been introduced by humans. In contrast, all remaining studied populations were dominated by a haplotype widespread in adjacent regions of species’ distribution in Germany, and additional haplotypes differing by point mutations were occasionally detected. This is consistent with a scenario of a postglacial colonization from Bavaria (southeast Germany). Our study provides evidence for a double origin of stone crayfish populations in the upper Elbe basin, with both natural and anthropogenic factors likely affecting the present diversity and distribution of this species.     

Application of Ultrafiltration for Characterization of the DOC of Elbe River Water

An ultrafiltration methodology and the results of its application on Elbe river water are presented. Compared with other methods, Ultrafiltration allows fractionation of the molecular-weight fractions of DOC for higher volumes of solution in a shorter time. To characterize the molecular-weight fractions, the sum parameter DOC (β(DOC)) and the absorption coefficient at 254 nm a₂₅₄ were measured, together with determination of a₂₅₄/ β(DOC) for further characterization of the DOC fractions and to provide information about changes in parts of the UV-active substances of the total dissolved organic material. In the period May 1992 to November 1994, the DOC molecular-weight composition of 65 samples of Elbe river water were determined. At two sampling locations (Torgau-East and Meissen), the DOC content β(DOC) was approximately 6 mg/L. The high-molecular weight fraction (> 10000 g/mol) gave a mean of 13% of the total DOC content β₀(DOC). The measurements showed that the molecular composition of DOC in the Elbe does not greatly differ. There was also no clear seasonal influence on the molecular-weight composition of the DOC content. During the period of investigation, the percentage part of β(DOC) and a₂₅₄/β(DOC) of the high-molecular weight fraction of the total dissolved organic material increased, while the a₂₅₄/β(DOC) values of the middle molecular-weight fraction remained fairly constant. The dependence of β(DOC) on discharge of the Elbe river is low. Changes in molecularweight composition of DOC were only observed during the steepest increase in river discharge during a flood event, with another spectrum of substances responsible for the increase in β(DOC) when compared with the β(DOC) for low or middle water level.     

The dynamics of phytoplankton, bacteria and heterotrophic flagellates at two Banks near Magdeburg in the River Elbe (Germany)

The main objectives of this study were to describe the seasonal standing stock dynamics of phytoplankton, bacterioplankton and heterotrophic flagellates in the highly eutrophic River Elbe (Germany), and to compare the seasonal patterns observed with other streams. Emphasis was placed on examining and assessing abiotic and biotic controlling factors influencing the structure and dynamics of the riverine plankton. All the physico-chemical and biological parameters determined were within the range or somewhat higher (in the case of phytoplankton abundance and biomass) than reported for other large streams. The underwater light conditions resulting from atypically short phytoplankton growth periods of about 6 months per year and the low phytoplankton carbon to chl a ratio of 23 were identified as a major limiting factor for phytoplankton development in the River Elbe. The seasonal distribution pattern of bacterioplankton indicated probable tight trophodynamical coupling both with phytoplankton and with heterotrophic flagellates, whereas heterotrophic flagellates showed a more trophic link with bacterial densities. Although approximately constant DOC and DON levels throughout the year sustained bacterial growth rates, during the phytoplankton growing season an increase of bacterial standing stocks was observed. Although the left-bank sampling site of the Elbe is strongly influenced by the tributaries Mulde and Saale containing higher concentrations of chloride, nitrogen nutrients, heavy metals and organic pollutants, no clear differences were observed between the two sides of the river concerning the biological parameters measured. Possible reasons and the slightly higher phytoplankton abundance and diversity at the right bank are discussed.     

Scenarios of global municipal water-use demand projections over the 21st century

Abstract

A comparison study is presented of three methods for evaluating trends in drought frequency: the standardized precipitation index (SPI), the Palmer drought severity index (PDSI), and a new method for estimation of dry spells (DS), which is based on average daily temperature and precipitation, and takes into account the length of a spell. The methods were applied to climate data from 450 stations in the Elbe River basin for the period 1951–2003, as well as data from several stations with longer observed time series. Statistical methods were used to calculate trend lines and evaluate the significance of detected trends. The dry spells estimated with the new method show significant trends in the whole lowland part of the Elbe basin during the last 53 years, and at the 10% level almost everywhere in the German part of the basin excluding mountains and the area around the river mouth. The SPI and PDSI methods also revealed significant trends, but for smaller areas in the lowland. The new DS method provides a useful supplement to other drought indices for the detection of trends in drought frequency. Furthermore, the DS method was able to detect statistically significant trends in areas where the other two methods failed to find significant trends, e.g. in the loess region in the southwest of the German part of the basin, where small insignificant changes in climate can lead to significant changes in water fluxes. This is important, because the loess region is the area within the basin having the highest crop yields. Therefore, additional research has to be done to investigate possible impacts of detected trends on water resources availability, and possible future trends in drought frequency under climate change.     

Modelling and inversion of electromagnetic data using an approximate plate model

This paper presents a computational method for the interpretation of electromagnetic (EM) profile data in the frequency domain using a thin plate model within a two-layer earth. The modelling method is based on an integral equation formulation, where the conductor is represented by a lattice structure composed of two-dimensional surface elements. Several approximations are used to simplify the theoretical basis and to decrease the computation time. The simple parametric model allows efficient use of optimization methods. We employ a linearized inversion scheme based on singular value decomposition and adaptive damping. The new forward computation method and the parameter optimization are combined in the computer program, emplates . The modelling examples demonstrate that the approximate method is capable of describing the characteristic behaviour of the EM response of a thin plate-like conductor in conductive surroundings. The efficacy of the inversion is demonstrated using both synthetic and field data. An optional depth compensation method is used to improve the interpreted values of the depth of burial. The results show that the method is cost effective and suitable for interactive interpretation of EM data.     

Present-day seismicity of the south-eastern Elbe Fault System (NE Bohemian Massif)

The Variscan Bohemian Massif is disrupted by the NW-SE striking Elbe Fault System in its northern part. The increased tectonic activity associated with this structure is manifested by increased seismicity in the eastern part of the Sudetes. With the use of a temporary local seismic network, the total number of micro-earthquakes located in this region increased to 153 for the period 1996–2003. The local magnitudes vary between −0.6 and 1.8 and the seismic energy was often released in swarm-like sequences. Five seismic events with well-defined P-onset polarities at five or six stations enabled the estimation of focal mechanisms. The present-day activity of the WNW-ESE to NNW-SSE fault systems is discussed on the basis of source mechanisms, the alignment of the epicentres, as well as morphological and geological evidence. The majority of the recent seismic activity is concentrated in a 40–60 km wide zone of a generally NW-SE trend. This structure represents a regional zone of weakness within the SE termination of the Elbe Fault System, defined by a mesh of interconnected faults, of which many are deep-seated and highly permeable and some are associated with light to moderate historical earthquakes. Both in the areas due south and due north of this zone the present-day seismic activity is very low. The increased tectonic activity can be interpreted as a result of the abundance of suitably oriented faults and their interconnection into major fault systems, the proximity of the Outer Carpathian indentor and the Cainozoic volcanic and associated recent post-volcanic activity. The similar character of swarms and their coincidence with the post-volcanic activity in the southeastern part of the Elbe Fault System and in some focal zones of the western Bohemian seismically active area suggests that overpressurized fluids may represent a potential swarm-triggering mechanism.     

计算水平层状介质电阻率权系数的一种方法

本文提出了计算水平层状介质电阻率权系数的一种新方法,阐述了这种计算方法的原理,说明了这种方法的计算速度和精度。文中还给出了三层、四层介质权系数的一些计算结果,并简要分析了权系数的变化特征,特别是负效应和峰值增强效应。     

INTERPRETATION OF THE GRAVITY ANOMALY OVER A CAUSATIVE BODY WITH CIRCULAR SYMMETRY*

The interpretation of the gravity anomaly on a horizontal plane over a causative body having circular symmetry about a vertical axis is considered from a rather unconventional approach. As the analytical expression for the gravity effect of a circular body assumes a closed form only on the axis of symmetry, the interpretation in this approach is carried out with the anomaly profile along the axis—which leads to simpler and faster computation. A numerical method is developed for computation of the anomaly profile along the vertical axis from the horizontal radial profile of the symmetric anomaly by upward continuation. Provision is also made for an end correction when the radial profile has only a limited extension. Some simple geometrical shapes are assumed for the causative body. Its parameters are then determined from least squares fitting of its gravity effects to the observed (upward continued) vertical profile (i) by the steepest descent method and (ii) by the Newton-Raphson method. Some applications of these methods are demonstrated.     

Determination of Chloroethers in Aqueous Samples Using Solid-phase Microextraction

A method for the determination of di- and tetrachlorinated ethers (haloethers) in aqueous samples using solid-phase microextraction (SPME) combined with capillary GC has been developed. Using 100-μm polydimethylsiloxane fibers, the influence of several parameters on the SPME procedure like the exposure time of the fiber in the aqueous sample, the desorption temperature, and the salt content of the sample have been studied. Salt addition has a strong effect on the extraction efficiency of the haloethers investigated. Working with saturated salt solutions, the factor increase of the peak areas was in the range from 5 to 12. These improvements are accompanied by decreased precision and increased equilibration times. The SPME method combined with several detectors (FID, ECD, MS in SIM mode) was evaluated with respect to detection limits, linearities, and precisions. Working with salt addition and FID, detection limits of all compounds investigated were in the range of 0.3 to 1.2 μg/L. Using ECD, the LOD values (limits of detection) were only improved for the tetrachlorinated bis(propyl) ethers (<10 ng/L). Employing mass-spectrometric detection in SIM mode for all chlorinated ethers, detection limits lower than 100 ng/L could be reached. Working with saturated salt solutions, the coefficients of variation were <9% RSD. However, without salt addition, the precision is better than 2.5% RSD for all analytes. Investigations showed that the analysis of the haloethers with SPME is not influenced significantly by the matrix Elbe water. The results of two series of samples demonstrate that SPME-GC-MS allows the sensitive determination of the di- and tetrahalogenated ethers in Elbe river water.