新疆北部二台北花岗岩体的两期同位素交换反应

对阿尔泰二台北花岗岩体的２０个岩石样品的共生长石、石英、黑云母做了氧、氢同位素组成测定．二台北岩体经历了两期同位素交换反应．第２期与大气水的Ｄ／Ｈ,~１８Ｏ／~１６Ｏ交换造成了第２组样品的δ~１８Ｏ_长石和δ_黑云母值显著降低;黑云母的Ｄ／Ｈ组成相对于~１８Ｏ／~１６Ｏ组成对大气水蚀变的反应更加灵敏．第１期与富~１８Ｏ的流体发生~１８Ｏ／~１６Ｏ交换,造成了反转△~Ｏ_石英－长石关系．富~１８Ｏ的流体来源于地壳深部的脱水反应;脱水熔融是花岗岩源区熔融的重要机制．深部流体具有围绕岩体分布的外封皮性质,它对地表流体构成了有效的屏蔽。     

吉林红旗岭地区造山后镁铁-超镁铁岩体的年代测定及其意义

吉林省中部红旗岭地区镁铁-超镁铁杂岩广泛发育,年代学资料表明,红旗岭-漂河川岩体形成于晚三叠纪(距今约216Ma),与该区A型花岗岩的年龄相当,但略微年轻一些。岩石学和地球化学特征表明,镁铁-超镁铁岩普遍可见包橄结构,橄榄石晶体平衡岩浆属于高MgO玄武质岩浆,微量元素和同位素模拟结果均显示岩浆源区主要为亏损地幔或新生岩石圈地幔。根据这些结果,同时结合相关研究,提出这些镁铁-超镁铁杂岩体的形成与该区大量造山后A型花岗岩带的形成相吻合,其形成主要是由于造山后期岩石圈板块的拆沉减薄效应,软流圈地幔上隆及大量幔源岩浆上侵,底垫于地壳底部,并经历了强烈的结晶分异作用     

柴北缘西段花岗岩锆石SHRIMP U-Pb定年及其岩石地球化学特征

柴北缘西段出露的花岗岩主要有赛什腾山、团鱼山、嗷唠河和三岔沟等岩体,这些岩体的走向为北西向,与区域构造线方向基本一致．岩体的锆石SHRIMP U—Pb定年结果表明,它们的时代从早古生代的奥陶纪到晚古生代的泥盆纪和二叠纪．其中,赛什腾山岩体为（465．4±3．5）Ma,团鱼山岩体两期侵入岩的年龄分别为（469．7±4．6）和（443．5±3．6）Ma;它们均属早古生代奥陶纪;而嗷唠河岩体的石英闪长岩为（372．1±2．6）Ma,属晚古生代泥盆纪;三岔沟岩体也由两期侵入岩组成,其年龄分别为（271．2±1．5）和（260．4±2．3）Ma,属二叠纪．花岗岩的岩石地球化学特征表明,柴北缘早古生代花岗岩具有岛弧或活动大陆边缘花岗岩的属性,原岩可能为中元古代（1．03～1．15Ga）形成的、来源于亏损地幔的拉斑玄武质洋壳,它们的形成与板块的俯冲作用有关;晚古生代花岗岩继承了早古生代花岗岩的特点,其原岩可能为中元古代（1．18—1．29Ga）的岛弧根部下地壳,岩浆物质成分以壳幔混合源为主,它们的形成与造山隆起后不同块体之间的均衡调整有关．     

湘北华容地区小墨山花岗岩体SHRIMPU—Pb年龄及地球化学特征

小墨山岩体侵位于中元古代冷家溪群中,由两期侵人体组成,早期为粗中粒-中粒斑状黑云母二长花岗岩;末期为细粒黑（二）云母二长花岗岩。通过锆石SHRIMPU—Pb法测得岩体侵位年龄为122．5±2．1Ma（20）,MSWD=1．9,成岩时代为早白垩世。主元素中,SiO2变化于67．20％～75．16％,K20含量高,且K2O〉Na2O,K2O／Na2O为1．16～1．72;ASI值变化于0．96～1．10之间,平均1．02,属准铝质-微过铝质、高钾钙碱性系列。岩石明显富集大离子亲石元素,亏损高场强元素,Rb／Sr=0．27～15．13;Nb／Ta=15．9～17．1,为锶和铌亏损型。EREE总体较高,重稀土含量相对较高,轻重稀土分馏稍弱,∑Ce／∑Y为0．49～6．18,（La／Yb）。为0．66～15．54。有较高的εNd（t）,为-6．8～-8．7;T2DM相对较小（1．47～1．62Ga）。综合研究表明,小墨山花岗岩石为壳源型富黑云母过铝花岗岩类（CPG）,其成因应为下地壳物质和上地壳物质混合而成,与花岗岩底侵作用或注入地壳中的幔源岩浆有关,形成的构造背景为陆内挤压造山向非造山转换的后造山拉张环境,是在紧随侏罗纪挤压造山运动之后的构造松驰和拉张减薄条件下所形成。     

中国东部碱性花岗岩氢氧同位素特征及其地球动力学意义

对中国东部五个有代表性的碱性花岗岩体氢氧同位素研究表明,δ18O基本正常的苏州和福州碱性花岗岩D亏损分别受单阶段与连续岩浆去气作用的影响,后期大气降水的扰动相对较弱．D-18O同步亏损特征明显的碾子山和山海关碱性花岗岩则主要受岩浆期后大气降水高温亚固态同位素交换机理的制约青岛复式花岗岩基则较为复杂,可能受岩浆去气与晚期大气降水交换的联合作用．未明显受后期地质作用扰动、典型的中国东部碱性花岗岩浆氢氧同位素组成分别为δD＝（50±5）‰和δ18＝（7．5±1．0）‰这表明中国东部碱性花岗岩是由稳定同位素组成基本正常的内地壳或上地幔物质通过低程度部分熔融产生的,而不是由再循环亏损源区物质产生的低δ18O岩浆结晶分异形成的．中国东部碱性花岗岩总体上表现出的D亏损纬度效应,预示自中生代以来其所在板块位置未发生过大规模水平位移同时,碱性花岗岩与拉张环境之间的内在联系表明,至少在中生代中国东部大陆岩石圈地壳处于拉张减薄状态．     

后碰撞幔源岩浆活动、底垫作用及准噶尔盆地基底的性质

准噶尔盆地周边地区广泛发育晚古生代后碰撞花岗岩类、基性_超基性杂岩和火山岩 .它们普遍具有正的εNd(t)值 ,表明岩浆起源于亏损地幔 ,并不同程度地受到地壳物质的混染 .幔源岩浆及其分异产物在上地壳侵位只是深部地质过程的浅部反映 ,大量的幔源岩浆很可能在壳幔界面附近和下地壳中发生底垫作用 ,成为准噶尔盆地基底的组成部分 .如果准噶尔盆地的基底是残留洋壳 ,除非发生高度部分熔融 ,否则不可能产生基性_超基性杂岩 .即使准噶尔盆地具有老陆壳基底 ,也会因为幔源岩浆底垫作用而受到强烈改造 .这种解释可以与地球物理资料相容 .     

新疆二台北花岗岩矿物-水氧同位素交换反应动力学

新疆北部二台北花岗岩共生矿物表现出显著的~(18)O/~(16)O不平衡关系,尤其是石英、长石具有倒转△~(18)O_(石英-长石)关系(△~(18)O_(石英-长石)<0).上述关系表明在花岗岩-水之间发生了~(18)O/~(16)O交换反应.根据质量平衡约束关系对岩石与外来流体的初始δ~(18)O值作了估计.定量模拟表明:二台北岩体流体流动速率约为3×10~(-14)mol/s,水-岩反应时限为0.8～3Ma,水/岩比介于0.79～3.08.以流体δ~(18)O值为变量对流体路径及其不均一性作了估计.     

大兴安岭中南段中生代的构造热演化

通过对大兴安岭中南段中生代火山 深成岩同位素年龄的测定 ,对不同阶段岩浆活动的构造背景进行分析 ,从而确立了该区构造岩浆演化的序列 :晚三叠世以含幔源包体的基性 超基性岩侵位为标志的初始幔隆 ,早 中侏罗世以辉绿岩岩墙群侵入为标志的中、上部地壳伸展 ,晚侏罗世强烈的粗面质火山岩喷发 ,早白垩世板内非造山性质的碱性 亚碱性花岗岩侵位 ,同时还形成了基性岩墙和玄武岩 .据此 ,可以认为中生代大兴安岭的隆升与幔隆背景下深部岩浆上涌密切相关 .这一研究为进一步探讨大兴安岭造山模式奠定了基础 .     

脉状金矿床的时空分布、地质特征和成矿流体来源

脉状金矿床(Lode Gold Deposit)在全球广泛分布,是最具经济价值的金矿床类型之一.成矿时代、成矿流体和金的来源一直都是认识脉状金矿床成因的中心议题.全球脉状金矿床的成矿时代主要集中在三个时期,即:新太古代(2.8～2.5Ga)、古元古代(2.1～1.8Ga)和新元古代至今(700Ma至今).基于对脉状金矿床的成矿过程和成矿流体的认识,目前普遍认为其成矿流体来源主要有4种,包括变质流体、与花岗岩体有关的岩浆-热液流体、俯冲流体和幔源熔/流体.文章重点介绍了幔源熔/流体成矿过程的主要特点以及幔源熔/流体的成分特征和金富集机理,并简要介绍了辽东地区与幔源熔/流体有关的脉状金矿床的一些最新研究进展.这些研究表明,含水的交代大陆岩石圈地幔部分熔融产生的幔源熔/流体,可能是华北克拉通一些中生代脉状金矿床(如五龙金矿)成矿流体的主要来源.     

西昆仑空巴克石英闪长岩类地球化学特征及构造环境分析

西昆仑空巴克石英闪长岩为原特提斯洋基本闭合,康西瓦韧性剪切带活动的产物。岩体属强过铝质、钙碱性系列偏碱性浅成相花岗岩类,大多属I型花岗岩,少数为S型花岗岩,构造环境为晚加里东期活动陆缘碰撞造山带环境。岩浆源为壳幔混源型。     

Two stages of isotopic exchanges experienced by the Ertaibei granite pluton, northern Xinjiang, China

¹⁸O/¹⁶O and D/H of coexisting feldspar, quartz, and biotite separates of twenty samples collected from the Ertaibei granite pluton, northern Xinjiang, China are determined. It is shown that the Ertaibei pluton experienced two stages of isotopic exchanges. The second stage of¹⁸O/¹⁶O and D/H exchanges with meteoric water brought about a marked decrease in the δ¹⁸O values of feldspar and biotite from the second group of samples. The D/H of biotite exhibits a higher sensitivity to the meteoric water alteration than its¹⁸O/¹⁶O. However, the first stage of¹⁸O/¹⁶O exchange with the¹⁸O-rich aqueous fluid derived from the dehydration within the deep crust caused the Δ¹⁸O_{Quartz-Feldspar} reversal. It is inferred that the dehydration-melting may have been an important mechanism for anatexis. It is shown that the deep fluid encircled the Ertaibei pluton like an envelope which serves as an effective screen to the surface waters.     

辽吉地区古元古代造山作用的大陆动力学过程及其壳内响应

古元古代是地质演化历史中一个重要转折时期,探讨其大陆动力学特征、机制、过程及其壳内响应具有重要的科学意义．本文以辽吉地区古元古代造山带为例,结合同位素年代学资料,综合分析了该区大陆动力学过程的构造、变质、岩浆、沉积等方面壳内响应特征最后,将该区深部大陆动力学过程划分为三大历史阶段：1)造山期前伸展阶段,包括建造伸展期和改造伸展期,深部底侵发生,壳内响应出现基底裂解、盖层顺层滑脱、拉张型垂向递增变质、岩浆呈席状侵位等;2)造山期挤压收缩阶段,俯冲碰撞,岩石田地幢可能出现拆沉,壳内响应出现招皱逆冲、双侧造山、侧向递增变质、碰撞型岩浆作用发生、早期岩浆底辟再就位等;3)造山期后伸展塌陷阶段,大陆岩石田在重力均衡作用下发生微弱伸展塌陷,出现环斑花岗岩侵位,等压冷却为特征的退变质表明没有明显的伸展剥蚀,没有出现明显的山根．     

Internal circulation in a buoyant two-fluid Newtonian sphere: implications for composed magmatic diapirs

Igneous plutons frequently show chemical zoning. The most commonly documented zoning is with the lighter, more silicic, rocks in the centre of the body and the denser, more basic, rocks in the external zone (normal zoning). Less commonly, some plutons show reverse zoning so that the more basic rocks occupy the centre. Widespread evidence shows that zoning in many plutons is the result of interaction between basic and silicic melts.

This work studies, by means of finite difference numerical models, pluton zoning which is due to internal circulation in diapirs comprising two magmas of different composition. Diapirs are modelled here as buoyant isothermal spheres composed of two Newtonian fluids rising through a Newtonian ambient fluid. Ratios of viscosities and densities of the two fluids were varied and the results demonstrated two different styles of internal circulation in rising spheres. The first style, termed “coupled circulation”, is characterised by continuous overturning of both the fluids in a single cell, evolving through both normal and reverse compositional zoning. The overturns stir the fluids and enhance both magma mingling and mixing. Coupled circulation develops in spheres comprising fluids of similar densities and viscosities. As these properties become increasingly different the internal circulation tends to decouple. “Decoupled circulation”, is characterised by circulation of the fluids in two separate cells. Decoupling stops the overturns between the two magmas so that the diapir preserves a reverse zoning throughout its rise, with the denser fluid occupying the central zone. There is less possibility of magma mingling in diapirs undergoing decoupled circulation. Thus, pairs of magmas of similar properties, such as andesite and rhyolite, are most likely to develop coupled circulation leading to both normal and reverse zoning in diapirs; whereas magmas of very different properties, such as basalt and rhyolite, are most likely to decouple resulting in reverse zonation.

The models indicate that reverse zoning would be the most common internal pluton geometry if zoning were controlled by internal circulation alone. Model diapirs which rise along channels of warm, low viscosity wall-rock (hot Stokes' models) or low viscosity shear zones show an increased tendency towards coupled circulation and more intense mechanical stirring of the magmas.     

Metasomatic hydrous fluids in amphibole peridotites from Zabargad Island (Red Sea)

Combining textural, petrological, chemical and isotopic (Sr, H and O) data for amphiboles and whole rocks from the Zabargad peridotite diapir allows three different events to be distinguished. During each event, which can be related to a specific tectonic process of the rifting of the Red Sea, hydrous fluids produced amphiboles.

The first and the second generations of amphiboles have characteristics consistent with the involvement of mantle-derived hydrous fluids. The first generation consists of scarce Ti-pargasites which crystallized from small amounts of fluid at temperatures of around 900–1000°C. Their growth was linked to magma percolation in the peridotites before their deformation during diapiric uplift. The second generation consists of Cr-pargasites which crystallized locally (and abundantly) during reaction between the peridotites and a sodium/potassium-bearing hydrous fluid at temperatures of around 700–800°C. These amphiboles grew synchronously with the diapiric uplift. The hydrous fluids probably originated in the sub-continental mantle and were released during the diapiric uplift of the peridotites.

The third generation consists of amphiboles (pargasitic hornblende, hornblende sensu lato and tremolite) which are localized in shear zones and veins. They crystallized at temperatures estimated between 700°C and 450°C, again from a sodium/potassium-bearing hydrous fluid. However, this fluid is extraneous to the peridotites, as shown by the Sr, H and O isotope compositions which suggest seawater penetration either during or after the final emplacement of the peridotite diapir.

Although the peridotite diapir was emplaced in granulitic gneisses of the pan-African deep continental crust, no evidence was found for a contribution of hydrous continental fluids in the production of the amphiboles present in the peridotite bodies of Zabargad Island.     

Granitic plutonism as an indicator of microplates in the Palaeozoic of central and eastern Maine

Oxygen and strontium isotope ratios have been used to characterize source regions for granitic magmas for a transect across the northern Appalachian orogen in central and eastern Maine. The northwestern plutons (Katahdin and Seboeis) have δ¹⁸O values of 10.3–13.3 and initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7083 and 0.7066, respectively. The central plutons (Bottle Lake and Center Pond) have lower δ¹⁸O values (8.2–9.9) and initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7055). The southeastern plutons (Lucerne and Deblois) have δ¹⁸O values (9.0–11.0) but initial ⁸⁷Sr/⁸⁶Sr ratios (0.7077 and 0.7041, respectively) which are intermediate between the northwestern and central plutons.Source models derived from these results and other petrological and geochemical data reflect the juxtaposition of discrete source regions by transcurrent faulting, which may be related to oblique plate motions. This model illustrates the importance of microplate accretion in the Palaeozoic history of the northern Appalachian orogen.     

Gold solubility in silicate melts and fluids: Advances from high-pressure and high-temperature experiments

The solubility of Au in silicate melts and fluids governs the enrichment and migration of Au during the formation of magmatic-hydrothermal Au deposits. Large Au deposits require vast amounts of Au to migrate from the upper mantle-lower crust to the shallow crust, and high Au solubility in magma and hydrothermal fluid facilitates the formation of Au-rich magma and fluid in the crust and mantle source and efficient transport. This paper reviews recent high-pressure and high-temperature experimental studies on Au species in magmas and hydrothermal fluids, the partitioning behavior of Au between silicate melts and fluids, and the effects of temperature, pressure, oxygen fugacity, sulfur fugacity, silicate melt composition, and volatiles(H_2O, CO_2, chlorine, and sulfur) on the solubility of Au in magma. We show that the solubility of Au in magma is largely controlled by the volatiles in the magma: the higher the content of reduced sulfur(S~(2-) and HS~-) in the magma, the higher the solubility of Au. Under high-temperature, high-pressure, H_2O-rich, and intermediate oxygen fugacity conditions, magma can dissolve more reduced sulfur species, thus enhancing the ability of the magma to transport Au. If the ore-forming elements of the Au deposits in the North China Craton originate from mantle-derived magmas and fluids, we can conclude, in terms of massive Au migration, that these deep Au-rich magmas might have been generated under H2 O-rich and moderately oxidized conditions(S~(2-) coexists with S~(6+)). The big mantle wedge beneath East Asia was metasomatized by melts and fluids from the dehydration of the Early Cretaceous paleo-Pacific stagnant slab, which not only caused thinning of the North China Craton, but also created physicochemical conditions favorable for massive Au migration.     

Trace element characteristics of the fluid liberated from amphibolite-facies slab: Inference from the metamorphic sole beneath the Oman ophiolite and implication for boninite genesis

Major and trace element compositions of amphibolites and quartzose rocks in the 230-m-thick metamorphic sole underlying the mantle section of the Oman ophiolite in Wadi Tayin area were determined to investigate the chemical characteristics of the hydrous fluid released from subducted amphiboltie-facies slab. The fluid-immobile element compositions indicate that protoliths of these rocks are mid-ocean ridge basalt-like tholeiite and deep-sea chert, which is consistent with the idea that these rocks represent Tethyan oceanic crust overridden during the early, intraoceanic thrusting stage of the Oman ophiolite emplacement. The rare-earth element (REE) and high field-strength element concentrations of the amphibolites show limited variations, within a factor of two except for a few evolved samples, throughout transect of the sole. On the other hand, concentrations of fluid-mobile elements, especially B, Rb, K and Ba, in amphibolites are highly elevated in upper 30 m of the sole (> 600 °C in peak metamorphic temperature), suggesting the equilibration with evolved, B-Rb-K-Ba-rich fluids during prograde metamorphism. The comparison with amphibolites in the lower 150 m (500 to 550 °C) demonstrates that the trace element spectra of the fluids equilibrated with the high-level amphibolites may vary as a function of metamorphic temperature. The fluids are characterized by striking enrichments of B, Rb, K and Ba and moderate to minor enrichments of Sr, Li, Be and Pb. At higher temperature (up to 700 °C), the fluids become considerably enriched in light REE and Nb in addition to the above elements. The estimated trace element spectra of the fluids do not coincide with the compositions of basalts from matured intra-oceanic arcs, but satisfactorily explain the characteristics of the low-Pb andesites and boninites found in the Oman ophiolite. Compositional similarity between the boninites of Oman and other localities suggests that the fluids estimated here well represent the amphibolite-derived fluids involved in the magmatism of immatured, hot, shallow subduction zones.     

Dehydration of clastic sediments in subduction zones: Theoretical study using thermodynamic data of minerals

Pseudosections for two sediments and one basalt calculated in the system K₂O–Na₂O–CaO–MgO–FeO–Fe₂O₃–Al₂O₃–TiO₂–SiO₂–H₂O for the P–T range 10 to 35 kbar, 300 to 900°C give useful insights into the amount of H₂O released from oceanic crust in subduction zones. In cold subduction zones (20 kbar–300°C to 35 kbar–500°C) hydrous minerals storing 3 to 4 wt% H₂O are still present in metasediments at depths of 120 km. In the same environment, metabasite releases 1 wt% H₂O in the depth range 100 to 120 km, but 4.5 wt% H₂O is transported to greater depths. In hot subduction zones (300°C hotter than the cold subduction zone at 100 km depth), dehydration events of metasediments in the depth range 50 to 80 km correspond to the breakdown of chlorite and paragonite. In the calculations no further water is released at greater depths because the modal content of phengite, the only hydrous mineral phase at these depths, remains almost constant. For the same P–T path, metabasite shows continuous dehydration between 40 and 80 km releasing almost 3 wt% H₂O. At 120 km depth less than 0.4 wt% of H₂O remains. In an average modern subduction zone (～6°C/km) most dehydration of sediments occurs at depths of 70 to 100 km and that of basalts at depths of 80 to 120 km. Only 1.3 wt% H₂O in metasediments and 1.6 wt% H₂O in metabasalt has the potential to be subducted to depths greater than 120 km. The dehydration behavior of sediments concurs with the generally held idea that subduction zone fluids are most effectively transported to great depths by cold subduction. In hot subduction zones, such as those characteristic of early Earth, most H₂O carried by oceanic crust is liberated at depths less than 120 km and, thus, would not contribute to island‐arc magmatism.     

Role of mantle-derived magma in genesis of early Yanshanian granites in the Nanling Range,South China: <Emphasis Type="Italic">in situ</Emphasis> zircon Hf-O isotopic constraints

Although a number of petrographic observations and isotopic data suggest that magma mixing is common in genesis of many granite plutons, it is still controversial whether the mantle-derived magmas were involved in granites. We carried out in this study a systematic analysis of in situ zircon Hf-O isotopes for three early Yanshanian intrusions dated at ca. 160 Ma from the Nanling Range of Southeast China. The Qinghu monzonite has very homogeneous zircon Hf-O isotopic compositions, εHf(t) =11.6±0.3 and δ18O=5...