山东乳山金青顶金矿床金的赋存状态研究

山东乳山金青顶金矿床是一种硫化物石英脉型金矿床,富含黄铁矿,研究黄铁矿中金矿物特征,可以为金矿的勘探、矿石的选冶以及矿床成因提供理论支撑。本文通过电子探针能谱仪和波谱仪对金青顶金矿黄铁矿中金矿物的矿物学特征、化学成分和赋存状态进行了精细研究,探讨了黄铁矿与金矿的成因关系。结果表明金主要以自然金和碲金银矿的形式存在,另含少量的碲金矿,包裹在黄铁矿之中或者充填在黄铁矿的裂隙中。金矿物的形成可能是成矿流体体系达到金的过饱和从而直接沉淀所形成。     

扬子板块西缘攀西地区白草矿区黄铁矿标型元素特征及其指示意义

黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义。以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征。结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为46.030%、52.815%,介于岩浆成因与热液成因之间,根据矿石特征,黄铁矿以岩浆成因为主,并有少量热液作用参与;将白草矿区黄铁矿δFe-δS特征与金川等典型铜镍硫化物矿床黄铁矿对比,表明白草矿区黄铁矿为典型的岩浆熔离型;由于存在钒钛磁铁矿,Co/Ni值多小于5,说明钒钛磁铁矿与硫化物存在共生关系;岩浆内生成因黄铁矿S/Se值小于15000,白草矿区黄铁矿S/Se值为812~10466,显示白草矿区黄铁矿为岩浆内生成因;Se/Te值随温度降低而升高,显示上述4类矿石黄铁矿结晶顺序为浸染状矿石→致密块状矿石→斑杂状矿石→网脉状矿石;原始地幔标准化主量、微量元素蛛网图显示白草矿区黄铁矿兼具岩浆成因与热液成因。综上所述,攀西地区白草矿区黄铁矿成因主要以岩浆熔离作用为主,并含有少量热液作用。     

黄铁矿随时间（t）变化对金吸附的动态实验

在Ａｕ（Ⅲ）－Ｃｌ络合溶液和常温常压条件下，黄铁矿随时间（ｔ）变化对金吸附的动态实验表明：整个吸附过程明显分为两个阶段．前一个阶段是快速达到平衡的吸附过程，随着平衡的建立，金的沉淀速度迅速变小，随后即进入缓慢吸附阶段，溶液中金的浓度按指数函数关系衰减．不同粒度黄铁矿实验结果的横向比较显示，粒度越细，金的沉淀速度越快，沉淀金的总量也越多。     

黄铁矿热电性研究在谢家沟金矿评价中的应用

谢家沟金矿是胶东地区新发现的大型金矿床,矿床类型为“焦家式”与“玲珑式”的过渡类型。对矿床3种主要矿石类型、不同中段的22个矿石样品进行了黄铁矿热电性测试,结果表明黄铁矿以N型导电为主,早期形成的黄铁绢英岩中黄铁矿热电系数最大,主成矿阶段形成的黄铁矿—黄铜矿绢英岩次之,晚期的黄铁矿—黄铜矿石英脉最小;从+130m中段到+242m中段,N型黄铁矿的出现率逐渐变小,热电系数也随之下降,认为矿体的浅部已被剥蚀,N型黄铁矿出现率表现较好的连续性说明深部资源潜力很大。     

二道沟金矿床中黄铁矿晶体形态及热电性与金矿化的关系

已有文献认为:空穴型黄铁矿的存在对金成矿有利。作者对二道沟金矿床的研究表明,金矿化程度不仅与黄铁矿的热电性有关,而且与黄铁矿的晶体形态关系十分密切。富矿体中黄铁矿晶体形态复杂,种类多并以五角十二面体为主,叶夫济科娃晶体形态得分值(XFeS_)高;含矿较贫或不含矿的岩体黄铁矿晶体形态简单,种类少并以立方体为主,叶夫济科娃晶体形态得分值(XFeS_2)低。     

Application of sedimentary pyrite in paleo-environment:a case study of Meihe Formation

The indices related to sedimentary pyrite are widely used in paleo-environmental studies;however its application principles and flaws have not been presented in detail so far , therefore it is necessary to review the controlling factors of them .In this study the authors described the application principles in detail , including py-rite morphology, C/S ratio, DOP, size distribution, sulfur isotope, and further discussed the C-S-Fe system in oil shale in Meihe Formation which indicates oxic or suboxic conditions during oil shale deposition .The concen-tration of TOC and S in the oil shale in Meihe Formation is more than that in background mudstone , and the py-rite formation is limited by sulfate .Therefore studying the indices related to pyrite proves to be of great impor-tance.     

广东省典型矿区生态复绿遥感调查研究

以多期遥感数据为数据源,采用人机交互解译方法提取了广东省大宝山多金属矿、云浮硫铁矿、石菉铜矿3个典型矿区生态复绿的位置、面积、变化趋势,结合野外实地调查,查明了矿区生态复绿现状,结果表明:大宝山多金属矿共有3个生态复绿区,生态复绿面积总计约10.08万m~2;云浮硫铁矿生态复绿区主要位于东南部采场,面积总计约65.21万m~2;石菉铜矿总计有生态复绿区25.4万m~2,其中已复绿区15.4万m~2,正在复绿区10.0万m~2,还有大片区域急需复绿。最后总结了3个矿区生态复绿措施和效果,并提出值得借鉴的地方和存在的不足。该文采用的技术方法能够为其他矿区特别是大范围矿区生态复绿的快速提取提供有益的参考。     

青海德尔尼铜(钴)矿床矿石矿物特征及其地质意义

青海德尔尼铜(钴)矿床赋存于东昆仑阿尼玛卿蛇绿岩套中部,岩石类型主要有蛇纹石化的方辉橄榄岩、纯橄榄岩和二辉橄榄岩,矿石类型主要为块状、条带状含铜黄铁矿矿石,矿床成因存在多种认识。通过野外详细观察、室内显微镜下矿石矿物特征鉴定以及电子探针分析,确定德尔尼铜(钴)矿床的矿石矿物主要为黄铁矿,其次为磁铁矿、磁黄铁矿、黄铜矿、闪锌矿和方铅矿等,矿石结构以半自形粒状结构为主;钴元素在早期黄铁矿中比较富集,晚期黄铁矿中较贫,w(Co)/w(Ni)值指示黄铁矿与巴西Sossego铁氧化物-铜-金矿一致;早期黄铁矿、黄铜矿、闪锌矿的微量元素质量比值指示矿床成矿温度为200℃~300℃,属于中温环境,进一步证明了该矿床不是岩浆型矿床,属于海底喷流-沉积成因。矿床成矿过程可划分为4个阶段:海底喷流-沉积阶段、构造变形阶段、热液阶段和表生氧化阶段,其中前两个阶段为铜、钴、锌的主要成矿期。     

滩间山黑色岩系金矿床金的赋存状态研究

黑色岩系金矿床具有重要的经济价值，滩间山金矿床为多因复成成因，黄铁矿是其最主要的矿石矿物。穆斯堡尔诺分析和金的浸取实验表明：滩间山金矿的黄铁矿中除存在大量金矿物（自然金或银金矿）外，尚存在１．２７％的晶格金，这部分金是一种潜在的金矿资源。此外，文中还探讨了晶格金的形成机理。     

山东旧店金矿金矿物特征及其意义

以山东平度旧店金矿床中金矿物作为研究对象,通过对金矿物的形态、物性、主成分及微量元素等特征的研究,认为旧店金矿中主要金矿物为银金矿、自然金,主要载金矿物为石英、黄铁矿、黄铜矿、方铅矿、闪锌矿等。金主要以银金矿形式产出,金银矿少量,自然金很少。金矿物赋存状态主要为裂隙金、包体金、晶隙金等,呈粒状、板状、针状产出,银金矿与石英、黄铁矿依存关系最为密切。旧店金矿金的成色集中在600～800之间,平均744.13,说明旧店金矿经历了中温成矿环境,且成矿时间较短,是以金石英多金属硫化物阶段为主成矿期。     

烟台金斗山金矿方铅矿的成因矿物学研究

金斗山金矿位于山东省烟台市,是一个新近发现的金矿,该金矿以矿石矿物中大量出现方铅矿而区别于胶东地区其他金矿床。对方铅矿的化学成分、热电性和微量元素组成的研究表明,方铅矿是除黄铁矿外的另一种重要的富金、银矿物。方铅矿的热电导型单一,均为N(电子)型,并且具有较大的热电系数绝对值。形成方铅矿的成矿物质主要来源于围岩,即荆山群黑云母片岩和石榴石黑云母片岩等。     

Gold Deposition by Boiling or Cooling Without Boiling: Genesis of the Sangchon Gold Deposits, Hadong Area, South Korea

In order to understand the mechanism(s) of gold precipitation in the anorthosite- hosted Sangchon gold deposits in the Hadong area, Korea, chemical speciation and reaction path calculations were accomplished by geochemical modeling.The modeling consisted of three- step procedures: reaction with anorthosite, then the simple cooling of the reacted fluid,and finally the boiling of metalliferous fluid. The principal vein minerals of the Sangchon deposits consist of quartz, sericite,kaolinite, pyrite, galena, chalcopyrite, sphalerite and acanthite. The sulfide mineralization is typically zoned from pyrite (preferentially at vein margins) to galena and sphalerite (toward vein center). Electrum is intimately associated with pyrite + chalcopyrite and sphalerite. By comparing the results of modeling with the observed mineral assemblages and paragenesis,the most appropriate evolution path of ore fluids was suggested as follow: reaction of a single fluid with anorthosite at 300℃,then the isobaric cooling of the fluid at temperatures from 2500° to 100℃3 , and then the boiling and cooling of the fluid due to the decrease of pressure and temperature. Calculations also show that all of the observed alteration minerals formed due to fluid - anorthosite interaction at early period, whereas most of sulfides and electrum were precipitated mainly due to cooling.The abundance of gold in veins depends critically on the ratio of total base metals plus iron to sulfide in the aqueous phase,because gold is transported as Au(HS)2- whose solubility is very sensitive to the sulfide activity. Our results of geochemical modeling generally fit to the observed mineral assemblages and mineral composition, indicating the usefulness of numerical simulation for elucidating the genesis of gold deposits.     

青海大场金矿田北缘灭格滩矿区土壤地球化学异常信息提取及找矿预测

灭格滩矿区位于青海北巴颜喀拉造山带大场金矿田北缘。三叠系巴颜喀拉山群昌马河组砂板岩是矿区主要赋矿地层。矿区内构造发育,矿(化)体主要沿NW向构造破碎带分布,产状受破碎带控制。围岩蚀变主要有硅化、黄铁矿化、毒砂化、绢云母化等。1∶10 000土壤地球化学测量Au、As、Sb、Hg元素丰度明显偏高,异常明显,浓集中心突出,各元素异常套合较好,呈NW向带状分布。剖面上元素含量峰值与矿体位置对应良好,据此构建了地质-地球化学找矿模型,能有效指导隐伏矿体的找矿勘查工作。在综合分析矿区地质及土壤地球化学异常特征的基础上,圈定了找矿靶区和成矿远景区,可以为灭格滩金矿区乃至矿田核心区外围找矿勘查工作提供重要参考。      

平度市陶家寨矿区金矿地质特征及成因分析

平度市陶家寨矿区金矿床位于平度市旧店镇西南,属于中温热液裂隙充填石英脉型金矿床,控矿构造以NE向、NNE向断裂为主,具有膨大缩小、分支复合、尖灭再现的特征。区内共圈定金矿体5个,矿体呈脉状、透镜状,严格受断裂带控制。矿石矿物主要为黄铁矿、黄铜矿、方铅矿、闪锌矿等,矿石结构主要为半自形粒状结构、不等粒结构等,矿石构造主要为致密块状构造、团块状构造、网脉状构造、细脉浸染状构造等。矿体围岩为云山单元弱片麻状含石榴石细粒黑云二长花岗岩、北黄单元细粒含黑云二长花岗岩等。     

Mineral occurrence for Dachang gold deposit and its impact on gold recovery rate in Qumarleb County,Qinghai

Based on X-ray diffraction,optical microscopy and scanning electron microscopy analysis of the Dachang gold ore,it is showed that the sulfide of ore is the main carrier minerals of gold. A majority of gold is embedded in pyrite and tetrahedrite as the form of inclusion and a small amount intergrowth with pyrite and gangue mineral,occasionally the presence is in form of monomer natural gold. The main factors which influence the recovery rate are sulfide mineral particle size,and the fine grained sulfide is beneficial for the dissociation and flotation of gold bearing minerals. The monomer dissociation degree of gold bearing minerals can reach91. 3%,when the grinding fineness is less than 0. 074 mm and grain level accounts as 80%. It is not conducive to the flotation of sulfide if the grinding fineness is low or high. It is difficult to completely dissociate the monomer if there is a small amount of pyrite and arsenopyrite in the ore. Therefore,before leaching the gold,it must conduct pretreatment to reach the ideal recovery rate of the gold,like roasting oxidation,pressure oxidation and biological oxidation. The fine microscopic gold has little influence on the gold recovery rate.     

Mineral occurrence for Dachang gold deposit and its impact on gold recovery rate in Qumarleb County,Qinghai

Based on X-ray diffraction, optical microscopy and scanning electron microscopy analysis of the Dachang gold ore, it is showed that the sulfide of ore is the main carrier minerals of gold. A majority of gold is embedded in pyrite and tetrahedrite as the form of inclusion and a small amount intergrowth with pyrite and gangue mineral, occasionally the presence is in form of monomer natural gold. The main factors which influence the recovery rate are sulfide mineral particle size, and the fine grained sulfide is beneficial for the dissociation and flotation of gold bearing minerals. The monomer dissociation degree of gold bearing minerals can reach 91.3% , when the grinding fineness is less than 0. 074 mm and grain level accounts as 80%. It is not conducive to the flotation of sulfide if the grinding fineness is low or high. It is difficult to completely dissociate the monomer if there is a small amount of pyrite and arsenopyrite in the ore. Therefore, before leaching the gold, it must conduct pretreatment to reach the ideal recovery rate of the gold, like roasting oxidation, pressure oxidation and biological oxidation. The fine microscopic gold has little influence on the gold recovery rate.     

卢氏西虎岭黄铁矿床围岩蚀变特征及其找矿意义

文章通过对西虎岭黄铁矿床围岩蚀变的研究认为，围岩蚀变大致可分为６种基本蚀变类型，５个蚀变阶段，３个蚀变带。各蚀变带以矿体为中心对称分布，各带之间呈渐变过渡关系。同时认为矿床成因类型属中低温热液充填型，并指出围岩蚀变的找矿意义。     

硫铁矿山火灾事故预防探讨

本文围绕着减少或杜绝硫铁矿山火灾事故的发生,认真分析了硫铁矿山火灾事故发生的外因、内因,并针对各类原因提出了不同的预防措施。确认抓好火灾预防工作的重点是监测和发现内因火灾的苗头,重点介绍了内因火灾的识别方法、预防措施。     

矿物热电系数及其在地质找矿中的应用

作者的研究表明,在非本征激发区,矿物热电系数随着活化温度的增高而增大;在本征激发区,随活化温度的增高而减小。矿物晶体中所含杂质的种类和含量多少决定矿物的导电类型。矿物热电系数可广泛应用于地质找矿和矿床评价中,以黄铁矿为例,在同一水平面上的含金矿脉,矿脉中黄铁矿热电系数正值高时,其矿石含金量也高。应用黄铁矿热电系数的正高值、混合型和负值可确定矿体和矿体的剥蚀深度。     

八家子铅锌矿区吴家屯矿床矿物特征及银赋存状态

八家子铅锌矿区吴家屯矿床是燕山期形成的热液充填交代脉状铅锌矿床。矿床中除铅锌矿外还伴生有银、硫、铜、锰等多种有益元素。银主要呈微粒自然银、辉银矿、金银矿、银黝铜矿、黝锑银矿、硫砷铜银矿、含碲银矿物等产出,并呈包裹体产于方铅矿、闪锌矿、黄铁矿、黄铜矿、石英等矿物中,或充填于这些矿物的裂隙及晶隙中。少部分银则以类质同象形式存在于方铅矿、黄铁矿矿物中。