内蒙古赤峰南窝铺铀矿床英安岩的SHRIMP锆石U-Pb年龄、地球化学特征及地质意义

南窝铺铀矿床位于西拉木伦缝合带以南、康宝—围场—赤峰断裂带(华北北缘断裂带的一部分)以北的白乃庙加里东期岛弧带和华北古板块北缘海西期俯冲—碰撞带,属沽源—红山子铀成矿带北东段红山子—广兴铀成矿亚带的一个铀矿床,铀矿体赋存在额里图组安山岩—英安岩—流纹岩组合中。该组合中的英安岩SHRIMP锆石n(206Pb)/n(238U)加权平均年龄为268.1±2.5 Ma(N=15,MSWD=0.85),结合安山质角砾凝灰岩的锆石U-Pb年龄为277.1±0.9 Ma,指示额里图组安山岩—英安岩—流纹岩的地质时代属早二叠世(乌拉尔世)—中二叠世(瓜德鲁普世)早期;英安岩SiO2=65.49%~68.23%,K2O=1.83%~2.56%,Na2O=4.13%~5.01%,(K2O+Na2O)=5.96%~7.47%,K2O/Na2O=0.43~0.59,(FeO+Fe2O3)=3.13%~4.63%,MgO=1.25%~1.79%,在TAS图解上落入亚碱性系列英安岩区,在FAM图解上落入钙碱性系列范围,在SiO2—K2O图解上落入中钾钙碱性系列范围,在Na2O—K2O图解上落入I型花岗岩区;Al2O3=15.74%~16.77%,CaO=2.87%~3.59%,A/CNK=0.95~1.12(平均为1.04,<1.1),标准矿物刚玉(C)的含量为0~1.74%,平均为0.96%,指示源岩为I型岩浆岩;英安岩稀土元素总量低,富集轻稀土,Eu无明显负异常,ΣREE=76.5×10-6~95.4×10-6,(La/Yb)N=4.97~12.5(平均8.95),δEu=0.80~1.13(平均0.94),稀土配分模式为右倾型,与安第斯型钙碱性系列火山岩基本一致。英安岩明显富集大离子亲石元素Rb、Th、U、K、Sr等和亏损高场强元素Nb、Ta、P、Ti等,微量元素蛛网图与安第斯型钙碱性系列火山岩的形式一致,在Ce—SiO2、Al2O3—Ga图解上均落入I型花岗岩区,在Ta—Yb、Nb—Y构造环境判别图解上落入火山弧花岗岩区域(VAG)及同碰撞花岗岩(syn-COLG)交界处,在Rb—(Y+Nb)、Rb—(Yb+Ta)构造环境判别图解上落入火山弧花岗岩区域(VAG),指示英安岩形成于俯冲作用下的岛弧环境。南窝铺铀矿床英安岩地质时代、岩石系列和形成构造环境的确定,不仅证实了早二叠世—中二叠世早期额里图组是红山子—广兴铀成矿亚带一个新的赋矿层位,而且揭示了岛弧型安山岩—英安岩—流纹岩组合也赋存有与火山岩有关的热液型铀矿,为深入开展热液型铀矿成矿理论的研究和进一步扩大铀矿勘查范围提供了新的基础资料。     

内蒙古赤峰南窝铺铀矿床英安岩的SHRIMP锆石U-Pb年龄、地球化学特征及地质意义

南窝铺铀矿床位于西拉木伦缝合带以南、康宝—围场—赤峰断裂带（华北北缘断裂带的一部分）以北的白乃庙加里东期岛弧带和华北古板块北缘海西期俯冲—碰撞带,属沽源—红山子铀成矿带北东段红山子—广兴铀成矿亚带的一个铀矿床,铀矿体赋存在额里图组安山岩—英安岩—流纹岩组合中。该组合中的英安岩SHRIMP锆石n(206Pb)/n(238U)加权平均年龄为268.1±2.5 Ma（N=15,MSWD=0. 85）,结合安山质角砾凝灰岩的锆石U-Pb年龄为277.1±0.9 Ma,指示额里图组安山岩—英安岩—流纹岩的地质时代属早二叠世（乌拉尔世）—中二叠世（瓜德鲁普世）早期;英安岩SiO2=65. 49%~68.23%,K2O=1.83%~2.56%,Na2O=4.13%~5.01%,(K2O+Na2O)=5.96%~7.47%,K2O/Na2O=0.43~0.59,(FeO+Fe2O3)=3.13%~4.63%,MgO=1.25%~1.79%,在TAS图解上落入亚碱性系列英安岩区,在FAM图解上落入钙碱性系列范围,在SiO2—K2O图解上落入中钾钙碱性系列范围,在Na2O—K2O图解上落入I型花岗岩区;Al2O3=15. 74%~16. 77%,CaO=2. 87%~3. 59%,A/CNK=0. 95~1. 12（平均为1.04,<1.1）,标准矿物刚玉（C）的含量为0~1.74%,平均为0.96%,指示源岩为I型岩浆岩;英安岩稀土元素总量低,富集轻稀土,Eu无明显负异常,ΣREE=76.5×10-6~95.4×10-6,(La/Yb)N=4.97~12.5（平均8.95）,δEu=0.80~1.13（平均0.94）,稀土配分模式为右倾型,与安第斯型钙碱性系列火山岩基本一致。英安岩明显富集大离子亲石元素Rb、Th、U、K、Sr等和亏损高场强元素Nb、Ta、P、Ti等,微量元素蛛网图与安第斯型钙碱性系列火山岩的形式一致,在Ce—SiO2、Al2O3—Ga图解上均落入I型花岗岩区,在Ta—Yb、Nb—Y构造环境判别图解上落入火山弧花岗岩区域（VAG）及同碰撞花岗岩（syn- COLG）交界处,在Rb—(Y+Nb)、Rb—(Yb+Ta)构造环境判别图解上落入火山弧花岗岩区域（VAG）,指示英安岩形成于俯冲作用下的岛弧环境。南窝铺铀矿床英安岩地质时代、岩石系列和形成构造环境的确定,不仅证实了早二叠世—中二叠世早期额里图组是红山子—广兴铀成矿亚带一个新的赋矿层位,而且揭示了岛弧型安山岩—英安岩—流纹岩组合也赋存有与火山岩有关的热液型铀矿,为深入开展热液型铀矿成矿理论的研究和进一步扩大铀矿勘查范围提供了新的基础资料。     

初论西藏过铝花岗岩

西藏主要过铝花岗岩岩体有61个,其岩石类型主要有电气石花岗岩、白云母花岗岩和二云母花岗岩.岩石的SiO2=65.7y.52%,A/CNK=1.05～2.26,C-norm=1.2～3.1,表明西藏过铝花岗岩属白云母强过铝花岗岩类型,为岩浆成因.岩石具较强的负Eu异常,(87Sr/86Sr)i值较高,为0.72199～0.75513;εNd(t)值较低,为-16.0～-9.6;δ18O值较高,为 8.9‰～ 18.79‰;结合La/Sm-La图解,表明其形成过程中没有地幔的卷入,为泥质岩石部分熔融的产物,岩浆来源于上地壳.QAP图解、R1-R2图解、Rb-(Y Nb)图解等均表明其为大陆碰撞构造环境.西藏过铝花岗岩发生在2个大陆地壳板块的碰撞阶段,岩浆来源于上地壳的重熔.喜马拉雅过铝花岗岩是陆内俯冲的岩石学记录,而冈底斯带过铝花岗岩更可能是特提斯洋壳北向俯冲的岩石学响应.     

西藏八宿吉利地区新发现寒武纪变质花岗岩锆石U-Pb年龄、地球化学特征及其地质意义

八宿吉利地区寒武纪变质花岗岩位于曲扎湖-提卡一带,主要由变质二长花岗岩和变质花岗闪长岩组成。这一新发现对于认识和恢复原特提斯构造历史演化具有重要意义。锆石CL图像显示变质花岗岩锆石为岩浆成因。锆石LA-ICP-MS测年得出片理化变质二长花岗岩年龄为503.7±4.7Ma、变质花岗闪长岩年龄为494.7±3.4Ma,表明该岩体形成时代属于寒武纪。通过岩石地球化学分析,变质二长花岗岩SiO2含量介于69.87%~79.89%之间;变质花岗闪长岩SiO2含量介于66.63%~70.15%之间。前者Al2O3含量变化于12.36%~14.82%,Na2O含量为2.54%~7.16%,K2O含量为0.15%~5.95%,K2O/Na2O=0.02~2.34;后者Al2O3含量变化于14.66%~15.41%,Na2O含量为3.60%~5.63%,K2O含量为0.77%~2.78%,K2O/Na2O=0.14~0.77,属于钙碱性-碱性过铝质花岗岩。在侵入岩构造环境Rb-(Y+Nb)判别图解、Rb-(Yb+Ta)判别图解中,样品均落入“火山弧花岗岩”区域中,表明其形成于大陆边缘火山弧环境。结合锆石测年结果及区域地质背景分析,认为吉利地区变质花岗岩形成于冈瓦纳大陆裂离卡穷微陆块阶段,同时表明原特提斯洋形成最早时限可追溯至寒武纪。     

新疆额尔宾山花岗岩侵位年龄和成因及其对南天山洋闭合时代的限定

额尔宾山花岗岩岩体位于南天山晚古生代侵入岩带,对该花岗岩进行锆石U-Pb定年获得296.1±1.8Ma的年龄,为早二叠世。岩石主量元素分析结果表明,该花岗岩的Si O2含量为66.96%~67.3%,富碱(Na2O+K2O=7.53%~7.97%),K2O/Na2O1(1.15~1.27),属高钾钙碱性系列岩石;Al2O3为15.56%~15.62%,Al2O3K2O+Na2O+Ca O,属于过铝型。岩石稀土元素配分模式呈现轻稀土元素(LREE)富集((La/Yb)N=27.03~30.62)、重稀土元素(HREE)亏损((LREE/HREE)=18.2~20.1)、具有中等程度的负Eu异常(δEu=0.64~0.68)。微量元素判别结果显示,其具有I-A型花岗岩过渡的特征。结合区域地质背景综合分析,初步认定该岩体可能形成于南天山同碰撞向后碰撞构造体制转换时期,据此可以推测南天山洋盆闭合时限至少应该在早二叠世以前。     

滇西来利山花岗岩年代学、地球化学特征及其壳源部分熔融成因

与锡矿有关的花岗岩成因一直是地学界关注的焦点。来利山花岗岩位于云南省腾冲—梁河地区(花岗岩带上),构造上属于腾梁花岗岩带。该花岗岩带总体呈北北东向带状展布,构成冈底斯的南延部分。来利山岩体主要由似斑状黑云母二长花岗岩和中粗粒黑云母正长花岗岩组成。本次工作在前人研究的基础上对来利山花岗岩进行了岩石学、地球化学和年代学研究,获得二长花岗岩(14L-4)锆石LA-ICP-MS U-Pb年龄为(52.34±0.68)Ma(MSWD=1.4,n=26)。地球化学数据显示二长花岗岩相对富铝(Al2O3=14.70%~15.27%)、碱(K2O+Na2O=8.07%~8.50%)、钙(Ca O=1.64%~2.56%)、REE、Ba。铝饱和度(A/CNK)为0.97~1.12,平均为1.04,属偏铝质到弱过铝质岩石。正长花岗岩相对富硅(Si O2=74.57%~76.69%)、Rb,强烈亏损Ba、Sr、P、Ti、Eu,铝饱和度(A/CNK)为1.05~1.18,平均为1.09,属弱过铝质岩石。两类花岗岩系同源岩浆于不同阶段侵位形成,二者在矿物学、地球化学、年代学等方面表现出良好的演化关系,均显示S型花岗岩的特征。其形成与印度大陆和亚洲大陆碰撞过程中地壳物质部分熔融有关。     

黑龙江张广才岭一面坡晚三叠世花岗岩地球化学特征和LA-ICP-MS锆石U-Pb年龄

对张广才岭南部一面坡花岗岩的地质学、岩石学、地球化学及锆石U-Pb年龄研究表明,岩石富硅富铝,属于过铝质岩石(A/CNK=1.04~1.07),全碱(K2O+Na2O)含量为8.24%~8.85%,K2O/Na2O值为1.58~1.68,属于高钾钙碱性系列I型花岗岩。岩石富集LREE、Rb、Th、U、K,相对亏损Nb、Ta、P、Ti,具有明显的Eu负异常,LA-ICP-MS锆石206Pb/238U年龄加权平均值为211Ma±4Ma(MSWD=1.4,2σ),代表了花岗岩的结晶年龄。岩石具有相对亏损的锆石Hf同位素组成(εHf(t)=+1.75~+13.81),TDM2为367~1136Ma。结合区域构造环境分析,认为一面坡晚三叠世花岗岩属于I型花岗岩,可能形成于后碰撞伸展构造环境,是岩石圈伸展阶段新增生下地壳物质发生部分熔融的产物。     

内蒙古中部四子王旗地区北极各岩体锆石定年及其岩石化学特征

内蒙古中部四子王旗北极各花岗岩基位于兴蒙造山带的二道井—查干乌拉—红格尔缝合带南缘,主要由正长花岗岩组成。为精确厘定该岩体的形成时代,对其进行了锆石LA-ICP-MS U-Pb定年,获得了(264.0±3.4)M a(MSWD=1.5)的206Pb/238U加权平均年龄,应代表其侵位年龄。岩石地球化学数据显示该岩体具相对富碱、富钾的特征,w(K2O+Na2O)变化于8.0%~9.29%之间,w(K2O)/w(Na2O)比值为1.20~2.59,属于高钾钙碱性岩石系列;w(Rb)/w(Sr)值较低(2.4~4.2),富集大离子亲石元素(LILE),(La/Yb)N介于3.1~13.6之间,亏损高场强元素(HFSE)等特点显示其应为Ⅰ型花岗岩。岩石暗色矿物为黑云母,副矿物出现榍石而未见富铝矿物,富含暗色包体,与过铝质花岗岩相伴生,为较典型的KCG岩石组合,属于由俯冲作用向大陆碰撞演化过程中构造体制转换阶段的产物,而在构造环境判别图解中均落入同碰撞花岗岩区域。同位素定年和岩石地球化学特征表明北极各岩体形成于同碰撞环境,可能是大规模岩浆底侵作用导致地壳熔融的结果。     

青海祁漫塔格虎头崖矿区花岗岩地球化学特征及构造意义

位于青海东昆仑祁漫塔格构造带内的虎头崖矿区花岗岩形成于中—晚三叠世,岩性主要由黑云母二长花岗岩、正长花岗岩组成,局部含闪长质暗色包体。岩石高硅、高钾、富碱,SiO2含量为70.71%~77.67%;K2O含量平均为4.7%;Na2O+K2O为7.86%~9.1%;K2O/Na2O平均为1.36。A/CNK比为1.01,KN/A比为0.86,属于高钾钙碱性系列的微过铝质I型花岗岩类。∑REE含量中等,平均为120.10×10-6;δEu值0.04~0.47;(La/Yb)N值为1.52~8.06。稀土元素球粒陨石标准化曲线显示Eu负异常、HREE较平坦的右倾"V"型特征。岩体富集LIL和HFS元素,而Ba、Sr、Nb、Ti、P元素明显的负异常。微量元素蛛网图和稀土元素球粒陨石标准化图解显示各花岗岩体具有相同的岩浆源区。结合区域地层岩性特征、A/MF-C/MF图解和岩体微量元素蛛网图,认为虎头崖矿区花岗岩是基性源区部分熔融和地壳物质混合的产物。结合地质特征、构造演化背景、元素判别图解等,认为该地区花岗岩类形成的构造环境为碰撞造山期后阶段。     

滇西芒市江东花岗岩体的锆石U-Pb年龄、地球化学特征及构造意义

腾冲地块江东花岗岩体分布于芒市江东镇—项丘一带,主要由黑云母二长花岗岩组成。该花岗岩锆石LA-ICP-MS U-Pb定年结果表明,锆石U-Pb年龄加权平均值为58.29±0.44 Ma,表明该花岗岩体的形成时代属于古新世。岩石地球化学研究表明,该花岗岩具有中等SiO2(68.66%~73.50%),高碱(K2O+Na2O=6.87%~9.04%),高钾(K2O/Na2O=1.87~2.20),铝饱和指数(A/CNK)为0.97~1.36的特征。岩石属钾玄岩—高钾钙碱性系列,为过铝质S型花岗岩。稀土元素总量(ΣREE)为158.85×10-6~304.26×10-6,稀土元素配分曲线呈右倾型,具有弱到中等程度的负铕异常。根据岩石地球化学特征判别,该花岗岩的源岩可能是富含粘土的变质杂砂岩,在构造体制由挤压向拉张转变的后碰撞环境下部分熔融形成的。江东古新世后碰撞环境黑云母二长花岗岩的形成,预示着印度板块与冈底斯-波密-腾冲板块的主体碰撞在60Ma之前(即古新世初期之前)已经发生。冈底斯-滕冲构造带古新世构造岩浆造山事件与新特提斯洋的闭合及印度板块与冈底斯-滕冲板块间的俯冲、碰撞造山作用密切相关。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of