望天鹅火山岩石地球化学特征及其成因

东北吉林望天鹅新生代火山岩（7．04—1．86Ma）主要由玄武粗安岩和碱性流纹岩组成。玄武粗安岩的SiO2介于49．38％-53．31％之间;K2O＋Na2O为4．27％-7．72％;∑REE为163．69×10^-6-258．55×10^-6,Eu异常不明显,δEu为0．72～1．17;碱性流纹岩具高SiO2（70．39％～71．49％）含量,高碱（K2O＋Na2O为9．28％～9．49％）,高稀土总量（∑REE介于309．30×10^-6～465．03×10^-6之间）,明显的Eu负异常,3Eu为0．52～0．71。碱性流纹岩的微量元素含量较玄武粗安岩高,且具有明显的Sr、P、Ti负异常。望天鹅火山岩的^87Sr／^86Sr比值在0．705156-0．709029之间,而^144Nd／^143Nd比值变化较小,介于0．512295～0．512602之间;放射性成因Pb同位素变化范围也较小,^206Ph／^204Pb为17．254～18．090,^207Ph／^204Pb为15．460～15．507,^208Pb／^204Ph为37．278—38．048。综合分析火山岩的主量元素、微量元素和Sr-Nd—Pb同位素特点,初步认为望天鹅火山的玄武粗安岩和碱性流纹岩具有相同的地幔源区。玄武粗安岩起源于微弱富集上地幔,在上升过程中结晶分异形成了碱性流纹岩。     

Oxygen isotopic study of the Cretaceous granitic rocks in Japan

The ( ¹⁸O values of nine Cretaceous granitic rocks from the low P/T type regional metamorphic zone of Japan are +10.0 to +13.2 relative to SMOW, while ten Cretaceous granitic rocks from the non-metamorphic zone are +7.9 to +9.8. The ¹⁸O-enrichment in the former rocks is mainly attributed to oxygen isotopic exchange between the granitic magma and the surrounding metamorphic rocks during regional metamorphism. The assimilation of ¹⁸O-rich country rocks is also possible in the cases such as gneissose granite and migmatite.The oxygen isotopic ratios of quartz-biotite pairs in the granitic rocks indicate that they are isotopically in near-equilibrium with each other. The quartz-biotite isotopic equilibrium temperatures estimated for these rocks range from 550° to 670° C. Feldspar is occasionally isotopically in disequilibrium with other minerals. This may be caused by exchange of oxygen isotopes between feldspar and hydrothermal or meteoric water after crystallization.     

Carbon isotopic study on coexisting calcite and graphite in the Ryoke metamorphic rocks,northern Kiso district,central Japan

Carbon isotope fractionation between coexisting calcite and grpahite ( ¹³C_cc-gr) has been determined in metamorphosed limestones and calc-silicate rocks from the Ryoke metamorphic belt in the northern Kiso district. In this district, the Ryoke metamorphic rocks, ranging from the lower greenschist facies to the upper amphibolite facies, are widely distributed. The fractionation of ¹³C/¹²C between calcite and graphite decreases regularly with increasing metamorphic grade and is independent of absolute ¹³C values of calcite. This evidence suggests that carbon isotopic exchange equilibrium has been attained during metamorphism even in the greenschist facies and isotopic modification, possibly caused by retrogressive metamorphism, is not distinguished. For T=270–650° C, the fractionation is expressed by the following equation: ¹³C_cc-gr=8.9×10⁶T^–2–7.1 (T in °K).This equation has a slope steeper than the current results on the ¹³C_cc-gr versus 10⁶T^–2 diagram. It can be used as a potential geothermometer for almost the entire temperature range of metamorphism. ¹³C values of carbonaceous matter in unmetamorphosed limestones in this district are approximately –22, due to its biogenic origin. Graphite from metamorphosed limestones is also considered to be of biogenic origin but shows enrichment of ¹³C due to isotopic exchange with calcite. ¹³C values of graphite as well as ¹³C_cc-gr confirm that zone II represents the lowest grade zone of Ryoke metamorphism. The maximum equilibrium fractionation of ¹³C between calcite and graphite is considered to be approximately 23%, which corresponds to 270° C. Below this temperature, it seems that carbon isotopic exchange between the minerals does not occur.Calcite in marble from the higher grade zones has relatively lower ¹³C and ¹⁸O values. The depletion of heavy isotopes is considered to be caused by the loss of ¹³C and ¹⁸O enriched carbon dioxide during decarbonation reactions. For oxygen, it is considered that isotopic exchange with metamorphic fluids plays an important role in lowering the ¹⁸O value of calcite in some higher grade marbles.     

Lead and strontium isotopes in rocks of the Absaroka volcanic field,Wyoming

The Absaroka volcanic field is comprised of predominant andesitic volcaniclastic rocks and less abundant potassium-rich mafic lavas (shoshonites and absarokites). Strontium and lead isotopic variations preclude a simple derivation from an isotopically uniform source: Sr⁸⁷/Sr⁸⁶, 0.7042 to 0.7090; Pb²⁰⁶/Pb²⁰⁴, 16.31 to 17.30; Pb²⁰⁸/Pb²⁰⁴, 36.82 to 37.64. We postulate that these rocks were derived from a lower crust or upper mantle which underwent a preferential loss of uranium relative to lead approximately 2800±200 m.y. ago. Variations in lead and strontium isotopic compositions are thought to reflect small inhomogeneities in U/Pb and Rb/Sr ratios in the source.Publication authorized by the Director, U.S. Geological Survey.     

Rubidium,strontium content and strontium isotopic composition of strongly alkalic basaltic rocks from the Cape Verde islands

The Cape Verde islands are characterized by the presence of very strongly alkalic lavas. Cenozoic volcanics—covering the broadest compositional range present in the archipelago—and ranging from alkali-basalts to phonolites, associated with plutonic essexites and nepheline syenites, were analyzed for Sr isotopic compositions and concentrations in K, Rb and Sr. The close values of the Sr⁸⁷/Sr⁸⁶ ratios (ranging from 0.7029 to 0.7033) indicate a comagmatic origin for the different rock types; no correlation appears between the Sr isotopic composition and the K-content of the lavas, thus indicating that the lavas with high K₂O/K₂O + Na₂O ratio are generated from a primary magma by differentiation at shallow depths. The values of the Sr isotopic composition are distinctly lower than most values obtained for lavas of other oceanic islands. The origin of the magma type is discussed on the basis of these isotopic compositions and the K/Rb and Rb/Sr ratios: it is suggested that the primary magma has a nephelinitic composition and was formed by partial melting of a small fraction of undepleted mantle peridotite, containing phlogopite; the deeper part of the mantle where this nephelinitic magma generates would have a strontium isotopic ratio of about 0.703 and a Rb/Sr ratio lower than that of the upper part.     

大陆碰撞过程的火山岩响应：以西藏林周林子宗火山岩为例

印度-亚洲大陆碰撞伴生有大量火山活动,其中,林子宗火山岩发育最广,遍布碰撞带北侧的冈底斯带,形成长逾1200 km的火山岩带。林周地区作为林子宗火山岩的命名地,该套火山岩发育相对齐全,为安山岩、流纹岩及相应的火山碎屑岩夹沉积碎屑岩组合,顶部发育巨厚流纹质凝灰岩,可以划分出三个火山旋回,其生成时代介于63.89~48.73 Ma。岩石学和地球化学资料显示,林子宗火山岩自下而上SiO₂和K₂O含量以及Al₂O₃饱和度增加,其岩浆从早到晚由中性、中钾和准铝质变化到酸性、高钾和过铝质,晚期喷发巨厚的火山灰流,反映区域地壳明显的加厚,由早期的30~40 km变化到晚期的50~60 km。火山岩相对富集Cs、Rb、K、U,亏损Ta、Nb、Ti、Sr、Ba、P,早期与桑日组安山岩地球化学特征相近,而中—晚期与乌郁、扎嘎等地渐新世高钾火山岩相似,表明早期岩浆具有新特提斯洋俯冲板片印迹,而中—晚期具有后碰撞作用特点。林子宗火山岩作为印度-亚洲大陆碰撞过程的响应,记录着古新世至始新世（64~48 Ma）印度-亚洲大陆之间的碰撞向碰撞后演化过程。     

湖南益阳早前寒武纪镁铁质-超镁铁质火山岩的Sm-Nd同位素年龄

益阳地区出露的似层状 -层状镁铁质 -超镁铁质火山岩的时代归属有不同的观点。研究认为其主要岩石类型为玄武质科马提岩和拉斑玄武岩。岩石地球化学和同位素年龄显示 :玄武质科马提岩 Sm-Nd全岩等时线年龄为 ( 3 0 2 8± 47) Ma,属中、新太古代洋中脊 -岛弧火山岩 ;拉斑玄武岩年龄为 ( 2 2 1 6± 3 8) Ma,属古元古代。这一结果揭示了早前寒武纪在古扬子微板块(川中微板块 )东南有多岛弧洋盆 ,湖南深部地壳有绿岩基底。     

Carbon-14 study of groundwater in the sedimentary rocks at the Tono study site,central Japan

Isotopic investigations using ¹⁴C of groundwater were carried out to understand the hydraulic conditions in the sedimentary rocks at the Tono study site, central Japan. ¹⁴C activities of groundwater observed range from 2 to 32 % Modern Carbon (pMC). Measured ¹⁴C activities of groundwater are corrected by the isotopic mass balance model based on ¹⁴C activities, δ¹³C values, concentrations of the dissolved inorganic carbon (DIC) and δ¹³C values of non-active carbon dissolved into the groundwater from carbonate minerals and organics. Assuming that the groundwater reservoir is comparable to the piston flow situation, the relative ¹⁴C ages of groundwaters were calculated from the corrected ¹⁴C activity. The relative ¹⁴C age suggests that the groundwater infiltration from the upper part of the sedimentary rocks to the lower part takes several thousands of years, or that the groundwater in the lower part of sedimentary rocks is derived from long distance flow from the surface through the unconformity between the sedimentary rocks and basement granite. The flow rate calculated by relative ¹⁴C ages shows similar values to those estimated by computer simulation using hydraulic pressure and conductivity data. Hydraulic conditions at the Tono study site inferred from ¹⁴C activity agree with those suggested from hydrogeological analyses. Isotopic approaches using ¹⁴C activity can be applied as geochemical evaluation for interpretations from the hydraulic study.     

Rare-earth and trace elements in the Quaternary volcanic rocks of Hokkaido,Japan

Seven rare-earth elements (La, Ce, Sm, Eu, Tb, Yb, Lu) and Co, Cr, Sc, Ba, Hf and Th have been determined by non-destructive neutron activation analysis on the Quaternary volcanic rocks in Hokkaido, Japan. The trace-element abundances are discussed in terms of the petrological problems, particularly the origin of calc-alkali magma. On the basis of the La/Sm ratio and the contents of K, Ba, Th and La, lateral variations in the contents of trace elements exist across the Kurile and the northern Honshū arcs. The calc-alkali rocks can be classified into three types which correspond to Kuno's three basalt-magma types. There is no essential difference in the rare-earth patterns between the basaltic rocks and the associated calc-alkali rocks in each petrographic province. This suggests that the calcalkali rocks may be derived from the basaltic magmas by fractional crystallization under certain conditions.     

A strontium isotopic study of Smackover brines and associated solids,southern Arkansas

The isotopic composition of Sr has been measured in brine samples from the Upper Jurassic Smackover Formation in southern Arkansas; ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios range from 0.7071 to 0.7101. With one exception, the 32 Smackover brines contain Sr which is significantly more radiogenic than the Sr in Late Jurassic sea water, indicating sizable Sr contributions from detrital sources. Isotopic analyses of core samples from rock units associated with the brines and regional stratigraphic relationships suggest that the radiogenic Sr was released from detrital minerals in Bossier shale to interstitial fluids expelled from the underlying Louann Salt in the North Louisiana salt basin. These fluids migrated through the Bossier Formation updip to the South Arkansas shelf, where they entered the upper Smackover carbonate grainstone. The radiogenic fluids mixed with Sr-rich interstitial marine waters that had the isotopic composition of Late Jurassic sea water; mixing in variable proportions resulted in the random distribution pattern of variable ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios that is observed in Smackover brines within the 5000 km² study area. Isotopic analyses of nonskeletal carbonate grains and coexisting coarse calcspar cement from the upper Smackover grainstone imply that the grains were diagenetically stabilized in the presence of interstitial marine waters, whereas the calcspar cement is a relatively late diagenetic phase precipitated after the arrival of radiogenic fluids.     

准噶尔盆地腹部早二叠纪-晚石炭纪火山岩的构造背景分析

从中生代到新生代,准噶尔盆地腹部地区连续沉积,缺少腹部地区的样品,因此准噶尔地区晚古生代构造演化的研究常集中于盆地周围的褶皱造山带。本文通过对早二叠纪-晚石炭纪钻井岩心样品的地球化学、岩石学特征进行研究。结果表明: 1)许多钻井的不同层位中,都发育着表明水上喷发环境的褐色凝灰岩; 2)准噶尔盆地腹部早二叠纪-晚石炭纪火山岩主要是碱性玄武岩、安山岩及少量的流纹岩,样品的大部分以高碱为特征,反映了喷发于陆上增厚地壳的构造背景; 3)岩心观察、薄片鉴定及主量和微量元素的分析结果表明,晚古生代准噶尔盆地腹部属于大陆构造背景。石炭系火山岩的底部也许存在许多的古老陆块基底。     

Active strike–slip faulting and macroscopically nonrigid deformation of volcanic rocks in central Japan inferred from a paleomagnetic study

Detailed paleomagnetic investigation of a pyroclastic flow deposit has clarified the deformation mode around an active fault. In central Japan, the early Quaternary Nyukawa Pyroclastic Flow Deposit is cut by the active dextral Enako fault. Activity level of the fault is evaluated on the basis of geological and geomorphological surveys. Then, paleomagnetic samples are collected from 22 sites at exposures located on a lineament that is adjoining and parallel to the Enako fault. Stable thermoremanent magnetization (TRM) of the pyroclastic deposit is isolated through progressive thermal and/or alternating field demagnetization tests. Untilted site-mean directions of the TRMs simultaneously acquired during initial cooling indicate significant clockwise vertical-axis rotation. The lineament was then activated with right-lateral motions through the early Quaternary. Together with the late Quaternary activities along the adjoining Enako fault evaluated by our study, the present result exemplifies a migration of active segments within a fault system during the Quaternary. Paleomagnetic directions on the strike–slip fault are not concordant with uniform deformation predicted by the model of rotation of rigid blocks aligned on a master fault, but suggestive of a periodic deformation as a result of intense fracturing and differential rotation of blocks bounded by nested parallel faults.     

Neodymium and strontium isotopic characteristics of New Zealand granitoids and related rocks

Initial ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of Phanerozoic granitoids and related intrusions of the New Zealand block display a mixing-type array indicative of the involvement in their sources of old continental crustal material, most likely of Proterozoic age. _Sr(T) values range from –4 to +273 (⁸⁷Sr/⁸⁶Sr=0.7041–0.7233), while _Nd(T) ranges from +2.7 to –11.0. Preexisting metasedimentary rocks have generally higher _Sr and lower _Nd (ranging to present-day values of +646 and –15.0, respectively), and, particularly for the Mesozoic intrusives, are isotopically appropriate mixing end-members. The widespread, early Paleozoic Greenland Group graywackes, which are derived from Proterozoic sources, are modeled as the source of the crustal end-member mixing with mantle-derived mafic magmas to produce the intrusive rocks. Four different types of models are applied to the isotopic and trace-element (Rb, Sr, Ba, REE) data: simple mixing; mixing with a partial melt of the metasedimentary rock, with or without isotopic equilibrium; and assimilation-fractional crystallization. Based on these models, some constraints may be applied on petrogenesis (e.g., the lack of high Rb concentrations points to the presence of biotite, and HREE depletion points to the presence of garnet); however, the models fail to adequately explain all the data. The New Zealand granitoids show similarities in isotopic character not only to rocks from offshore islands on the New Zealand block, but also to similar-aged granitoids in adjacent regions of Antarctica and Australia. This points to similarities in crustal character between continental blocks formerly proximal in Gondwanaland. We note an overall increase in _Nd and decrease in _Sr in felsic magmas from the Paleozoic to the Mesozoic to the Cenozoic in New Zealand, indicative of a decrease over time in the level of influence of recycled continental crust in subduction-related magmatism.Division Contribution No. 4538 (582)     

Strontium isotopic studies of the volcanic rocks of the Saunda arc,Indonesia, and their petrogenetic implications

Pleistocene and Recent lavas from the Sunda arc range from those showing affinities with the island arc tholeiitic series, through a spectrum of calc-alkaline to high-K alkaline rocks. The tholeiitic rocks have relatively low ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios averaging 0–7043; the calc-alkaline rocks show a wide range (from 0.7038 to 0.7059, averaging 0.7048); the high-K alkaline rocks average 0.7045. A rhyolitic ignimbrite from Sumatra has an ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio of 0.7139.The relationship between ${}^{87}\text{Sr}{}^{86}\text{Sr}$ and major and trace element geochemistry is variable and complex. Lavas from the same volcano sometimes show significant differences in ${}^{87}\text{Sr}{}^{86}\text{Sr}$ despite close geochemical relationships. Rocks of the calc-alkaline suite show a regular decrease in ${}^{87}\text{Sr}{}^{86}\text{Sr}$ from West Java to Bali and there is some evidence for increasing ${}^{87}\text{Sr}{}^{86}\text{Sr}$ with increasing depth to the Benioff zone. Calc-alkaline and tholeiitic rocks from the Sunda arc have significantly higher ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios than those from other island arcs, except from those arcs where continental crustal involvement has been inferred (e.g. New Zealand).A model of ⁸⁷Sr enrichment due to isotopic equilibration of oceanic crust with sea water and disequilibrium melting in the slab and/or mantle is favoured to explain the Sr isotopic composition of the tholeiitic and normal calc-alkaline lavas. Calc-alkaline lavas with high ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios are best explained by either sialic contamination, or the presence of alkali basalt as a component of the downgoing slab. The Sr isotopic data for the high-K alkaline lavas suggest a mantle origin. The high ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio in the Lake Toba rhyolite implies a crustal origin.     

辽西白塔地区侏罗纪火山岩岩石学、同位素年代学与地球化学特征

出露于辽西白塔地区的侏罗纪中酸性火山岩及火山碎屑岩组合,主要是由粗安岩、流纹质岩屑晶屑熔结凝灰岩、粗面英安岩和流纹岩组成。通过系统的LA-ICPMS锆石的U-Pb同位素年代学研究,研究区火山岩形成年代为165~149 Ma。岩石地球化学特征显示,酸性火山岩属于钙碱性火山岩系,中性火山岩分别属于碱性火山岩系和中-高钾钙碱性火山岩系,中性岩具有埃达克质岩的地球化学特征,SiO_2≥56.20%、Al_2O_3≥15.09%、MgO≤2.89%、Sr≥561×10~(-6)、Y≤13.15×10~(-6)、Yb≤1.47×10~(-6)和无明显Eu异常。研究区火山岩普遍具有富集大离子亲石元素(Rb、K、Ba、Sr、Pb)和轻稀土元素,亏损高场强元素(Ti、Nb、Ta、P)的特征。其原始岩浆来源于基性下地壳物质的部分熔融,形成于古太平洋板块俯冲影响下板内挤压造山的构造环境。     

东天山觉罗塔格构造带火山岩的铅同位素组成及意义

笔者报道了东天山觉罗塔格构造带中企鹅山群、雅满苏组火山岩和土屋铜矿的斜长花岗斑岩及铜矿石的铅同位素组成,进一步讨论了该成矿带的构造演化。企鹅山群火山岩的铅同位素位于地球演化线的右侧,与北半球铅同位素演化线相比,具有弱富集的特征。斜长花岗斑岩及铜矿石的铅同位素分布在企鹅山群范围之内,与之相似。雅满苏组比企鹅山群富放射成因铅,也具有弱富集的特征。在铅构造模式图解中,企鹅山群位于地幔演化线上,雅满苏组位于造山带演化线附近。雅满苏组的铅同位素具有线性排列特征,位于企鹅山群和中天山花岗岩之间,指示两端员混合的趋势。企鹅山群和雅满苏组火山岩都随着流体交代作用的加强,越来越贫放射成因铅,指示交代地幔楔的流体应主要来自蚀变洋壳,而没有泥质沉积物的参与。雅满苏组比企鹅山群富放射成因铅主要是由于其陆壳基底厚度较大,较强的陆壳混染造成的。     

Strontium isotopic and chemical variations of the granitic rocks in the Tsukuba district,Japan

Initial ⁸⁷Sr/⁸⁶Sr ratios, major and trace element compositions have been determined for the Paleogene granitic rocks in the Tsukuba district, Japan. Isotopic ages strongly suggest that the granitic rocks (seven units) were continuously emplaced and solidified during a short time interval. Initial ⁸⁷Sr/⁸⁶Sr ratios for seven granitic units vary from 0.7082 to 0.7132, while sedimentary and metasedimentary country rocks have ratios at the time of granitic magma emplacement ranging from 0.7149 to 0.7298. Continuous linear arrays for the granitic rocks in the diagrams of initial ⁸⁷Sr/⁸⁶Sr ratios versus some chemical parameters can be explained by either of following two processes. One is the assimilation — fractional crystallization (AFC) process between the parental magma (SiO₂ of 68% and initial ratio of 0.7078) and sedimentary country rocks, and the other is magma mixing process between above parental magma and sediment derived acidic magma (melt) (SiO₂ of 75%). The high initial ratios (0.7078–0.7098) for basic rocks such as gabbro or diorite in the Tsukuba district and the similar characteristics observed in the rocks of Ryoke belt (SW Japan) suggest that the parental magma had the same source region as the basic rocks, probably the lower crustal source.