An urban geomonumental route focusing on the petrological and decay features of traditional building stones used in Madrid, Spain

The stone traditionally used to build cities contributes to their personality and attests to the geological substrate on which they stand. While stone decay in the built heritage can be attributed to a number of causes, anthropic activity has a particularly significant impact. The geomonumental routes project is one of the initiatives proposed in recent years for urban routes that convey geological fundamentals by observing the rocks present in heritage structures. Its innovative approach addresses traditional stone properties, original quarrying sites and mechanisms of decay. Madrid’s Royal Palace is a fine example of the use of traditional building stone in the centre of the Iberian Peninsula. In the geomonumental route proposed, the building doubles as an in situ laboratory that affords an overview of the main petrological properties of the two traditional stones most commonly used in the city’s built heritage, the forms of decay they are subject and the factors underlying such alterations. This route constitutes a tool for showing the main petrological features and decay forms in traditional building stones found in urban heritage façades, with a special focus on anthropic impact, primarily air pollution and the use of conservation treatments that time has proven to be unsuitable.     

Testing of Sydney dimension sandstone for use in the conservation of heritage buildings

This paper deals with the scientific assessment of the physical properties of sandstone used in the conservation of Sydney's historic heritage sandstone buildings. The local Hawkesbury Sandstone has been widely used for all manner of constructions since the early days of the first settlement. In the nineteenth century, dimension sandstone quarries existed all over the Sydney region, and the demand for the stone was great. During this time, a true ‘freestone’ known as ‘yellow block’ sandstone, in which bedding planes were absent, was quarried extensively. This sandstone is also known as a ‘self-colouring’ sandstone, where the rock, although grey when quarried, turns a yellow–brown after a few months exposure to the atmosphere. It can be easily carved and was eminently suitable for the ornate Victorian architecture of the time. There are very few quarries within the Sydney region today capable of producing ‘yellow block’ sandstone. Whenever possible, sandstone from suitable building excavations, particularly on the Pyrmont Peninsula, is used for this work. Conservation work is extremely expensive and the building elements that most need replacement, the overhanging and decorative elements, are usually those that cost the most. It is essential that the most durable replacement stone be selected. Thus, a strict regime of scientific testing is used for any major conservation project, in order to determine the physical properties of possible replacement stone. This is the province of the geologist and involves visual observation in the quarry or excavation, which is a simple, cost-effective means of weeding out poor quality stones, followed by laboratory engineering tests to establish the physical parameters of a sandstone and finally, petrographic analysis. The results of such tests, combined with careful sampling, ensure the best possible quality of replacement material.     

British decorative stones: finding the UK top ten

British geology reveals many good looking rocks, both ‘soft’ and ‘hard’, some of which were once highly prized for their polished decorative uses. They were quarried, cut, shaped and finished in a locally‐based British decorative stone industry that flourished twice, first in the Middle Ages, based largely on Purbeck marble from Dorset and also alabaster from Derbyshire, and then again in the nineteenth century when diverse sources of coloured and textured stone were pursued to the far corners of the British Isles. Today only the finished products survive; the pillars, panels and pavement adorning some fine but dusty architecture, but the stones commonly languish unrecognized and unappreciated. This anonymity is quite out of line with the heritage status of their settings and it will take a bit more geological awareness to put that right. A recent project aimed at rediscovering just one regional category of British decorative stones, the Devonshire marbles, has revealed how diverse and extensively‐used the fuller range of British decorative stones actually is. Not only do they embellish buildings from the merely modest to some of our finest, they were latterly chosen, specified, designed and coordinated by some of our greatest architects. Much work needs to be done to recognize British decorative stones in architectural settings and to restore them to their proper place in our national heritage. It is hoped that this article will throw light on the task ahead.     

The use of local stone in the buildings of the Isle of Wight

The charm of the Isle of Wight, so much appreciated by visitors and the local population alike, is very much a combination of its delightful scenery and unique assemblage of vernacular buildings. These buildings range from isolated farmhouses to elaborate manor houses, castles and churches all constructed using the indigenous stone resources of the island. Today, these stone buildings, many of which date back to medieval times, are increasingly in need of conservation repair to maintain them for future generations. Essential to such conservation work is the safeguarding of the island's indigenous building stone sources as many of the stones used are unique to the island and no longer quarried. Protecting these stone sources could also provide stone for new building projects which would help to further enhance the character of the island's towns and villages.     

Engineering properties of Hınıs ignimbrites and their usability as a building stone (Erzurum, Turkey)

The survival of several ancient monuments made of ignimbrites in Hınıs town (Erzurum-Anatolia), which has suffered from intense annual temperature fluctuations and strong seismic activity, can mainly be attributed to use of suitable building stones. This paper examines the usability as building stones of Middle Miocene Hınıs ignimbrites that widely outcrop in and around Hınıs town. The petrographical, geochemical, mechanical, and physical properties determined lead to categorization of the ignimbrites as four different types. The Hınıs ignimbrites contain dasite–trachy–andesite and rhyolite. Rhyolite is the strongest material whereas the other types, being more porous, are weaker, lighter, and have good heat-insulation properties. Being light (easily transportable, machinable, and workable), good heat insulators, environmentally friendly (because of natural ventilation), sufficiently elastic to sustain seismic loading in the area under study, and more cost-effective than artificial stones, Hınıs ignimbrites are certainly a preferable option for use as light building stone. These ignimbrites are not suitable for use as floor covering, however, (because of rapid abrasion) or for building structural columns (because of low strength).     

福建寿山石分布及其特点

寿山石因产自福州寿山而得名,开采历史悠久。寿山石一般分田坑石、水坑石、山坑石,因品种与产出地域不同,矿物成分也存在差异,保养方法也有区别。     

观赏石及其分类

本文首先介绍了观赏石的概念,然后提出了观赏石的命名原则,进而按矿物的化学成分和晶形、岩石的成因、化石种类、陨石的化学和矿物成分、天然造型、用途等方面对观赏石进行了分类。最后阐明了观赏石是重要的自然资源。     

Patterns of halite (NaCl) crystallisation in building stone conditioned by laboratory heating regimes

The crystallisation of soluble salts within the pores of the stone is widely recognised as a major mechanism causing the deterioration of the stone-built architectural heritage. Temperature, in turn, is one of the main controls on this process, including salt precipitation, the pressure of crystallisation and the thermal expansion of salts. Most laboratory experiments on decay generated by salts are just carried out with convective heating regimes, while in natural environments building stones can undergo radiative and convective heating regimes. The thermal response of stone to these different heating regimes is noticeably different and might influence the crystallisation patterns of a salt within a stone. The aim of this work is to raise awareness on the different patterns of crystallisation of NaCl within a porous stone tested with different heating regimes (convection and radiation) and the implications that this could have on the design of experimental modelling of natural weathering conditions in laboratory simulations. Results show that heating regime affects the sodium chloride distribution within a stone with high percentage of microporosity. In this case, radiation heating facilitates the generation of subefflorescences, while convection heating promotes efflorescences. This has a clear implication both on the stone decay in natural environments and on the methodologies for testing salt decay, as subefflorescences are more destructive than efflorescences. In this sense, the use of convective heating in laboratory experimentation might underestimate the potential damage that sodium chloride may generate. This counsels the use of radiation heating test methods in addition to convection for the laboratory study of salt crystallisation.     

北京房山大理岩的岩石学微观特征及风化机理讨论

北京地区许多石质古建筑都使用了房山大石窝的大理岩来建造的。本文以汉白玉(白色大理岩)和青白石(青色大理岩)为例,通过薄片镜下观察、X射线衍射(XRD)、X射线荧光(XRF)、扫描电镜(SEM)和电子探针等测试手段,对房山大理岩的岩石学微观特征进行了研究。研究对象为取自房山大石窝的新鲜岩样和取自北京古代石质建筑的风化剥落物。结果证实北京大理岩主要矿物成分是白云石,部分大理岩还含有一定量的石英。基于图像处理软件,对汉白玉和青白石矿物晶体的粒径进行了统计分析。在此基础上,从温度变化、酸雨的溶解、水的溶蚀、微裂隙的盐类充填的角度分析了大理岩的风化机理。相关研究可为北京大理岩石质文物的修复保护提供科学参考。     

Determination of deterioration of the main facade of the Ferit Paşa Cistern by non-destructive techniques (Konya,Turkey)

Building stones have long been one of the most widely used construction materials in the world. Building stones used in historical monuments are deteriorated partly or completely depending on the environmental and atmospheric effects. In recent years, non-destructive test methods have been used to assess deterioration of building stones used in historical monuments. Gödene stone is one of the building stones being widely used in the historical buildings in the Konya region, Central Anatolia. The most deterioration effects are observed in the Ferit Pa?a Cistern among the historical structures built with Gödene stone in the region. The aim of this study is to assess the deteriorating effects in the street façade of the Ferit Pa?a Cistern via non-destructive testing methods (Schmidt hardness rebound value, P-wave velocity, humidity measurement and thermal imaging) and create maps of deteriorated features. Turkey’s historic places are integrated to Turkish culture, efforts are made to conserve heritage through rehabilitation. Therefore, this study will help developers and federal managers during the project planning stage by providing technical data.     

Building stone employed in the historical monuments of Eastern Sicily (Italy). An example: the ancient city centre of Catania

An archaeometric study of the stone materials employed in the Late Baroque historical monuments of the ancient city centre of Catania was carried out. Lithological maps of a selection of monuments, transferred to a digital format, revealed that the stone materials are both magmatic and sedimentary rocks, the colours of which are matched in a peculiar type of bichromy. Particular attention focused on sedimentary rocks, which consist of various types of limestone quarried near the city of Syracuse (Hyblean Plateau, south-eastern Sicily). Carbonate rocks were characterised in terms of mineralogy, petrography and geochemistry, by studying rock samples from both monuments and historical extraction sites. Results showed that, although only one name was historically attributed to the above lithotypes (i.e. “Pietra di Siracusa‘’), they were quarried from many locations and, as they belong to various geological formations, they therefore exhibit great variety. In order to examine the durability of Hyblean limestones employed in works of cultural heritage interest, salt crystallisation tests were carried out according to standard procedure norms (UNI EN 12370 (1999) Determination of resistance to crystallisation of salts, 6p). Results are consistent with the forms of deterioration observed in the monuments, and highlight the close relationship between textural characteristics and damage. Our purpose is to provide a basic tool, which may be useful both for conserving monuments of cultural heritage and for their restoration.     

South Australian geology and the State Heritage Register: an example of geoconservation of the Naracoorte Caves complex and karst environment

South Australia’s State Heritage Register contains 2294 listed places, the majority of which are from the ‘Built’ environment, ranging from settlers’ huts, community buildings, historical industrial sites to magnificent stone mansions. Only 96 places are linked to the ‘Natural’ environment. The Register listings protect heritage places from alteration, damage or removal without formal prior consultation, compulsory under the South Australian Development Act. ‘Natural’ environments are landscape-based and oriented towards Geological, Archaeological, Palaeontological and Speleological heritage (‘GAPS heritage’). A process to provide a greater balance between ‘Natural’ and ‘Built’ listings has initiated a series of State Heritage ‘Natural’ environment assessments, mostly of single sites. Two individual caves in the Naracoorte Caves National Park are already entered in the State Heritage Register as single sites. However, an innovative broader multiple-site nomination has focused on the many different but significant GAPS features contained within the 25 caves of the Naracoorte Caves National Park, providing a further level of protection for the land and the caves’ exteriors and interiors. The example of the Naracoorte Caves draws attention to the number of important land and coastal karst (limestone) features across South Australia that were generated by steady geological uplift of three large sections of Oligocene–Miocene limestone—the Nullarbor Plain, the Murray Basin and the Gambier Karstfield (which includes Naracoorte and Mount Gambier), resulting in specific karst forms worthy of a broader coordinating management approach across South Australian karst parks.     

石材与人类

随着人类文明的进步与发展,石材的应用在不同的国家和民族形成了各自的地域文化和民族文化,中国是世界上应用石材最早的国家之一,有着悠久的历史,是中国民族文化不可分割的一部分,近年来,随着对石材深加工的深入研究,使天然石材越来越显露出它的艺术魅力。     

浙江多色青田石岩石地球化学特征及成因

多色青田石是浙江青田石中的一个重要品种,具颜色丰富、纹理多变的特点。通过岩相学观察、X射线粉晶衍射物相分析、全岩主量及微量元素和同位素地球化学分析,对多色青田石的岩石学特征、矿物成分、类型划分进行详细研究,并论证了多色青田石的成矿物质、成矿流体来源及成因。研究表明:多色青田石按主要组成矿物划分属于叶蜡石型青田石和绢云母型青田石;其颜色主要与组成矿物中Fe、Ti、Cr、Mn致色元素的类型和含量有关,其次与赤铁矿(褐铁矿)浸染组成矿物的微晶间隙和充填微裂隙有关。多色青田石的成矿母岩为中酸性火山岩,成矿流体来源与大气降水有关。多色青田石主要由早期充填成因的叶蜡石矿物和晚期由中低温热液蚀变改造早期叶蜡石形成的绢云母矿物构成,是多期多阶段热液蚀变交代成矿作用的产物,多色青田石中常保留高温矿物红柱石。     

Determining proper strategies for Iran’s dimensional stone mines: a SWOT–AHP analysis

Iran has very high potential for production and export of dimension stone (rock quarried to size and shape specifications); nevertheless, in spite of growing mine production during the past decade, in many instances this potential has been overlooked. Construction, decorative, and facing stones of Iran are among the highest-quality products in the world. In this paper, Iran’s dimensional stone mines are analyzed using strengths, weaknesses, opportunities and threats (SWOT) analysis in combination with analytic hierarchy process (AHP). SWOT analysis is a tool commonly used for analyzing both the internal and external environments in order to attain a systematic approach and support for a decision situation. Conventionally, SWOT analysis is qualitative and does not quantify the effect of the factors. Consequently, it is not effective in priority setting. To overcome this limitation, SWOT analysis has been used in combination with other quantitative multi-criteria decision making methods especially the AHP. In this study, first an environment analysis was performed by an expert team familiar with these mines. In this way, the SWOT factors were identified and the subfactors which had very significant effects on the success of these mines were determined. Using the SWOT subfactors, the SWOT matrix and alternative strategies based on these subfactors were developed. Subsequently, the strategies were prioritized and the best strategies for Iran’s dimensional stone mines were determined.     

The use of X-ray tomography in the study of water repellents and consolidants

To reduce the weathering rate of natural building stones, a wide variety of water repellents and consolidants are commercially available. Although a lot of research is performed on these products, it remains difficult to determine which product is appropriate to use for a certain type of building stone. Each type of building stone has its own petrographic characteristics (mineralogy, texture, …), leading to typical physical and technical properties which influence its rate of decay. The localisation of the products inside a stone type is not only depending on the properties of the products themselves, but also linked to the texture and structure of the stone. The impregnation depth of the products strongly influences their efficiency and is therefore a key issue in the determination if a product is functional for a certain type of stone. X-ray micro-CT has recently been introduced as a non-destructive material evaluation technique for engineering and geology purposes. The fact that micro-CT can provide information about the internal structure and properties of natural building stones, is a major advantage in the study of their conservation. Firmly linked with more classical research techniques, this non-destructive technique offers an extra dimension to the cultural heritage research.In this paper, non-destructive X-ray computed micro-tomography (micro-CT) turns out to be a powerful tool as it can visualise the presence of water repellents and consolidants inside the stone and can help to detect the influence that these treatments exert on porosity and pore-size distribution. For the visualization of the product its atomic number and density and the amount of product inside the natural building stone is crucial. Besides the contrast in attenuation, the resolution of the micro-CT also needs to be taken into account to obtain a good contrast between stone and product. By doping with 3-bromopropyltrimethoxysilane, more contrast occurs between the stone material and the conservation product. When the amount of product inside the samples is very low and the product is homogeneously spread inside the sample, the doped product is difficult to distinguish from the stone material due to the resolution of the micro-CT. When the amount of doped product inside the stone material reaches a certain threshold value, the dope will appear in the 2D cross-sections derived from micro-CT, creating a good visualization of the products inside the stone samples.     

X射线粉晶衍射仪鉴别鸡血石

鸡血石品种按产地可划分为昌化鸡血石和巴林鸡血石两种,根据鸡血石的血色、血量、浓度、血型和地子的颜色、透明度、光泽、硬度、杂质及裂绺等综合特征,可区分昌化鸡血石和巴林鸡血石。通过X射线粉晶衍射仪测试,能快速准确地区分昌化鸡血石和巴林鸡血石,并鉴定鸡血石中血的真假。     

麦饭石的净化机理

作者通过对麦饭石理化性质的研究,认为麦饭石具有吸附和溶出两大特性。它对水质的净化作用,是通过表面吸附、胶体吸附和生成沉淀而实现的。净化作用的强度受粒度、蚀变程度和溶液的PH等因素的影响。麦饭石对金属离子有选择性吸附。它能改变溶液的PH。     

Non-periglacial stone stripes? An example from North Wales

A set of active stone stripes below a small debris cone in North Wales is described. In form they do not appear to resemble stone stripes described elsewhere. They are of particular note because their form is not controlled by conventional periglacial processes, but by stones moving downslope when sheep disturb the debris cone above. This downslope movement of stones has resulted in a complex pattern of stripes and horizontal terraces, the exact form of which appears to be controlled by probability. These observations add to the debate over the mode of formation of active stone stripes in Britain and the role of non-periglacial processes.