坦桑尼亚伦圭新生代火山岩的地球化学特征及岩石成因

伦圭新生代火山岩位于东非裂谷西支最南端,已有的大量地质与地球化学证据表明伦圭火山岩是典型的碱性双峰式火山岩,其SiO2含量在46％～56％之间出现明显的间断.基性火山岩和酸性火山岩均表现出富集轻稀土元素,轻、重稀土元素强烈分馏,无明显Eu异常的特征.基性岩大离子亲石元素Rb、Ba、Th、U、Sr富集,高场强元素Zr、Hf、Ti亏损,Nb-Ta相对于La弱亏损,具有低Th/Ce(<0.05)和Th/La(0.07～0.09)值.酸性岩不相容元素整体上呈现不同程度的富集,Sr、P、Ti亏损,Nb-Ta相对于La弱富集,显示较强的岩浆分异作用.基性岩和酸性岩均表现出一定的Pb富集,说明有微量的地壳混染.基性岩εNd(t)为+1.50～+3.70,(87 Sr/86 Sr)i为0.7048～0.7057;除T19样品具有负的εNd(t)值外,其他所有酸性岩εNd(t)值介于+0.21～+5.13,(87Sr/86Sr)i为0.7043～0.7061,可见伦圭基性火山岩和酸性火山岩Sr、Nd同位素特征具有一致性.根据同位素地球化学和元素地球化学特征,认为其基性岩来源于一个整体亏损的地幔,并受到了大陆岩石圈地幔的混染,而酸性火山岩则是基性岩浆分离结晶作用的产物.     

闽东南基性岩脉成因及动力学背景研究：Sr-Nd同位素、元素地球化学

闽东南的海边斜闪煌斑岩脉和赤湖辉长岩脉分别形成于晚白垩世和古新世,为高钾钙碱性和钙碱性系列岩石,具有高Al、Na_2O>K_2O的特征;岩浆演化过程中可能经历了以橄榄石、单斜辉石为主的结晶分异作用。海边和赤湖基性岩脉具有相对富集大离子亲石元素和轻稀土元素,亏损高强场元素特征,不相容元素蛛网图显示出大陆边缘弧的地球化学特征,以Nb、Ta、Ti负异常为特征;海边和赤湖明显富集轻稀土元素,(La/Yb)_N分别为5.0～10.9和11.2～12.0。具有高Sr同位素初始值和低ε_(Nd)(t)值,海边的(~(87)Sr/~(86)Sr)_i:0.70577～0.707574,ε_(Nd)(t):-8.1～-1.8,赤湖的(~(87)Sr/~(86)Sr)_i:0.70547～0.70552,ε_(Nd)(t):-0.2～0.6。根据Sr、Nd同位素、微量元素研究及野外地质观察,本区基性岩脉的岩浆在上升侵位过程中未发生地壳物质混染。通过Sr、Nd同位素和微量元素等研究,认为地幔源区的演化与古太平洋板块俯冲密切相关,俯冲流体交代地幔楔、消减洋壳携带的海洋与陆源沉积物参与地幔源区的混合,形成本区基性岩脉的富集地幔源区,大离子亲石元素和轻稀土元素特别富集是俯冲流体与沉积物共同参与源区演化的结果。海边和赤湖基性岩脉形成的构造背景属于活动大陆边缘弧,构造性质应为活动陆缘拉张带(或裂谷带)。晚白垩世和古新世,闽东南发生了地壳拉张事件,与中国东南部晚白垩世以来的地壳拉张期次是一致。     

湖南桃江地区印支期辉绿岩成因——地球化学、年代学和Sr-Nd-Pb同位素约束

对湖南桃江地区江石桥辉绿岩进行了LA-ICP-MS锆石U-Pb定年,获得的岩浆侵位年龄为229±2.3Ma(n=8,MSWD=1.8,2σ)。其低钾(K_2O/Na_2O=0.14~0.16),贫碱(K_2O+Na_2O=2.89%~2.96%),富集大离子亲石元素(Rb、Ba、Th、U),亏损高场强元素(Nb、Ta、Ti),呈轻稀土元素弱富集,无Eu、Ce异常,富集放射性成因Pb,低(~(87)Sr/~(86)Sr)_i(0.706052~0.706437),较低正ε_(Nd)(t)(1.54~1.86)的特征,表明岩石来源于下地壳物质和亏损地幔的混合源区。综合前人的研究结果认为,在印支运动造山后的伸展背景下,软流圈上涌导致区域下地壳及部分地幔物质发生熔融,形成辉绿岩岩浆并向上侵位而成。     

晚古生代古亚洲洋俯冲作用:来自珲春前山镁铁质侵入岩的年代学和地球化学记录

珲春地区前山镁铁质侵入岩主要由橄榄辉长岩、苏长岩和辉长闪长岩组成,形成年龄273±2Ma,为早二叠世侵入岩。该岩体显示出岛弧拉斑玄武岩的元素地球化学特征,弱富集LREE且正Eu(Eu/Eu*=1.05～1.44)异常的REE配分模式,在不相容元素中富集大离子亲石元素(LILE)如Ba和Sr,亏损高场强元素(HFSE)(La/Nb=2.8～4.8;Zr/Sm=8.0～22.5),与起源于流体交代地幔楔部分熔融的岛弧低钾拉斑玄武岩类似。在同位素特征上低放射成因Sr,高放射成因Nd和Hf(87Sr/86Sr(i)=0.70295～0.70375;εNd(t)=+4.5～+6.4;εHf(t)=+9.6～+14.6),反映其来源于同位素组成亏损的交代地幔。结合区域地质背景,我们认为前山镁铁质岩形成于晚古生代期间古亚洲洋向华北板块的俯冲作用背景,其亏损Nb-Ta、Zr-Hf及Hf-Nd同位素解耦特点说明该岩体最有可能来源于俯冲流体交代的地幔楔。     

新疆中天山巴仑台地区晚石炭世＋εNd辉长岩体的岩石学和同位素地球化学研究

新疆巴仑台附近出露的辉长岩(骆驼沟岩体)是中天山地区出露最大的晚石炭世基性侵入体,该岩体分带明显,由边部的细粒辉长玢岩(冷凝边)逐渐过渡到内部的中粗粒辉长玢岩.中粗粒辉长玢岩的εNd值(+5.10～+5.74)和初始87Sr/86Sr比值(0.7055～0.7058)变化很局限,但边缘相细粒辉长玢岩的εNd值(+4.25～+7.28)变化较大而初始87 Sr/86 Sr值(0.7058～0.7059)变化较小.三个细粒辉长玢岩全岩样品构成一条Rb-Sr等时线,等时线年龄321±10Ma(MSWD=1.5,初始87 Sr/86 Sr值0.705725±0.000084),这与位于该地区以西大面积出露的粗面安山岩的锆石SHRIMP年龄(313Ma)接近.与晚石炭世粗面安山岩类似,骆驼沟辉长岩富集La、Sr和Ba.高的+εNd值表明形成骆驼沟辉长岩的岩浆具有亏损地幔的性质,但明显偏高的初始87Sr/86Sr比值说明骆驼沟辉长岩不是亏损地幔直接部分熔融的产物,而可能是亏损地幔来源的岩浆与富La、Ba、Sr的长英质岩浆混合(或者与相应火山岩同化混染)的结果.     

江西广丰、玉山盆地橄榄玄粗岩的SHRIMP锆石U-Pb定年和Sr-Nd-Pb-O元素同位素特征

华夏古板块与扬子古板块结合带内的广丰、玉山红色碎屑沉积盆地均有橄榄玄粗岩产出,SHRIMP锆石UPb年代学研究表明,橄榄玄粗岩锆石U-Pb年龄为93±1 Ma,属晚白垩世早期的产物。广丰盆地橄榄玄粗岩(~(87)Sr/~(86)Sr)_i值为0.706 191~0.706 352,εNd(t)值为0.27~0.55,(~(206)Pb/~(204)Pb)_i值为18.045~18.080,(~(207)Pb/~(204)Pb)_i值为15.503~15.543,(~(208)Pb/~(204)Pb)_i值为38.240~38.256;玉山盆地橄榄玄粗岩(~(87)Sr/~(86)Sr)_i值为0.705 856~0.706 024,εNd(t)值为1.74~1.93,(~(206)Pb/~(204)Pb)_i值为17.956~18.063,(~(207)Pb/~(204)Pb)_i值为15.456~15.498,(~(208)Pb/~(204)Pb)_i值为38.195~38.232。在(~(87)Sr/~(86)Sr)_i-(~(206)Pb/~(204)Pb)_i、(~(143)Nd/~(144)Nd)_i-(~(206)Pb/~(204)Pb)_i和(~(143)Nd/~(144)Nd)_i-(~(87)Sr/~(86)Sr)i图解中,广丰、玉山盆地橄榄玄粗岩均位于亏损地幔(DMM)和EMⅡ型富集地幔之间,而且(~(87)Sr/~(86)Sr)_i和(~(206)Pb/~(204)Pb)_i呈正相关,(~(143)Nd/~(144)Nd)_i和(~(206)Pb/~(204)Pb)_i呈负相关,指示其源区中可能均有DMM和EMⅡ型地幔的贡献;玉山盆地橄榄玄粗岩更偏向DMM端员,指示其DMM端员所占的比例更高。广丰、玉山盆地橄榄玄粗岩具有EMⅡ型地幔的贡献,说明华夏古板块与扬子古板块结合带的岩石圈地幔与华夏古板块的岩石圈地幔属相同类型,为华夏古板块俯冲于扬子古板块之下提供了新的证据。     

新疆三塘湖盆地古生代晚期火山岩地球化学特征及其构造-岩浆演化意义

三塘湖盆地早石炭世安山岩（ECA）、早二叠世粗面岩类（EPT）以及中二叠世玄武岩（MPB）样品都具有大离子亲石元素（LILE）相对于高场强元素（HFSE）富集，Nb和Ta强烈亏损，轻稀土元素（LREE）相对于重稀土元素（HREE）富集，类似于和俯冲带相关的岩浆特征。ECA具有高的Zr／Nb（4．67～12．39），低的Nb／La（0．27～0．30），Ce／Ce＊=0．63～0．89，Sr／Sr＊=1．32．2．49，并具有Ti的负异常，另外（^87Sr／^86Sr）i=0．70408～0．70451，εNd（t）=＋7．42-＋7．88。与ECA相比，EPT大离子亲石元素更为富集，Ti和P的负异常明显，特别是Ce／Ce＊=0．72—1．64，Sr／Sr＊=0．38～1．87，相对较低的Al2O3和CaO含量以及（^87Sr／^86Sr）；=0．70414～0.70481和εNd（t）=＋4．93～＋6．13而区别于ECA。MPB与ECA相比具有较低的大离子亲石元素含量和较高的Nb、Ta含量，Ce／Ce＊=0．69～0．84，Sr／Sr＊=1、44～2．13，未有明显的Ti负异常，（^87St／^86Sr）i=0．70388～0．70396，εNd（t）=＋7．10-＋7．99。所有的地球化学特征表明：早石炭世或更早，三塘湖盆地为与俯冲带相关的构造背景，ECA是典型的弧火山岩，其岩浆主要源于被流体或沉积物交待改造的亏损地幔楔。早石炭世以后，三塘湖地区逐渐进入碰撞后伸展拉张阶段，EPT和MPB都为后造山火山岩。EPT岩浆主要源于亏损软流圈底侵前二叠纪形成的造山组分的部分熔融；MPB的岩浆主要源于亏损地幔的部分熔融，并被前二叠纪形成的造山组分或是年轻地壳混染。三塘湖地区二叠纪伸展拉张的动力学机制主要是由于造山带增厚的岩石圈大范围拆沉而导致的大范围亏损地幔部分熔融岩浆和上部造山组分或是年轻地壳的相互作用，这种造山组分或是年轻地壳具有低的（^87Sr／^86Sr），比值和正的εNd（t）值。火山岩地球化学特征指示没有明显地幔柱的作用特征。     

甘肃白银厂矿田早-中寒武世火山岩形成的构造环境

白银厂矿田早 -中寒武世火山岩主要由钙碱性玄武岩和流纹岩及少量的安山岩组成 ,被认为是大陆裂谷环境下的产物。本文的地球化学分析结果显示 :玄武岩具有低Ti,Nb和Ta负异常、富集LREE ,相对亏损HFSE ,Th/Ta比值高 (介于 9～ 15 ) ,La/Nb >1.4 ,低Ni,Th/La为0 .32～ 0 .5 6;低Zr/Nb(<16) ,(87Sr/ 86 Sr) i 为 0 .70 4～ 0 .70 7,εNd(t) =- 6.4 6,δEu≈ 1的地球化学特点 ;流纹岩同样具有低Ti,Nb和Ta负异常 ,Th/Ta为 6～ 12 ,低Ti/Zr比值 (介于 6.1～ 5 3)之间 ;稀土元素配分为MREE负异常 ,δEu为 0 .5～ 1.1,(87Sr/ 86 Sr) i 为 0 .70 2 6～ 0 .70 4 8,εNd(t)为+ 5 .60～ + 6.14。综合两类岩石的地球化学特征 ,可以推测它们是陆缘弧岩浆作用的产物 ,但并非同源岩浆演化的结果。玄武岩源于富集的岩石圈地幔 ,在岩浆上升过程中发生明显的陆壳混染作用 ,而流纹岩应为镁铁质下地壳部分熔融与地幔物质混合作用的产物     

新疆西准噶尔庙尔沟岩体的地球化学及年代学研究

新疆西准噶尔庙尔沟岩体侵入于早中石炭世海相火山-沉积建造中,主体由碱长花岗岩组成,局部分布有紫苏花岗岩和碱长花岗岩脉。碱长花岗岩及岩脉高硅、富碱、贫钙,里特曼指数(δ)=2.17~2.98,A/CNK=0.96~1.03,A/NK=1.08~1.13,为准铝质-弱过铝质高钾钙碱性花岗岩,其富集LILEs(Rb、U、K、Th),相对亏损HFSEs(Nb、Ta、P、Ti)和Ba、Sr等,以及强烈Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70370~0.70541,εNd(t)=+4.10~+6.79,tDM=0.57~0.99Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为309±1.4Ma,表明岩体碱长花岗岩的形成时代为晚石炭世。紫苏花岗岩的SiO 2含量为60.88%~62.06%,Al2O3含量为15.50%~15.72%,里特曼指数(δ)=2.59~2.77,A/CNK=0.86~0.88,A/NK=1.50~1.53,为准铝质钙碱性-高钾钙碱性过渡的花岗岩,相对富集LREE(Rb、U、K、Th),而亏损HREE(Nb、Ta、P、Ti)和Sr,以及较显著的Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70382~0.70388,εNd(t)=+6.67~+6.98,tDM=0.59~0.62Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为302.1±2.1Ma,表明岩体紫苏花岗岩的形成时代为晚石炭世。综合庙尔沟岩体的地质特征、地球化学特征、年代学和区域地质背景,认为庙尔沟岩体碱长花岗岩及岩脉为A2型花岗岩,紫苏花岗岩具有A型花岗岩的地球化学性质,且它们是可能来自同一个岩浆源区,属于西准噶尔后碰撞阶段的岩浆活动产物。     

江绍断裂带晚中生代镁铁质火山岩成因及其深部过程意义

本文对沿江绍断裂带的江山和浦江两地区中生代镁铁质火山岩进行了Ar-Ar年代学、岩石学和元素-同位素地球化学研究。Ar-Ar年代学结果显示,江山玄武岩的形成年龄约为99Ma,为晚白垩世喷发产物;浦江玄武岩和玄武质安山岩的喷发时间为111～112Ma,属于早白垩世。两区中生代镁铁质火山岩都为中钾钙碱性系列,根据其地球化学指标可划分为三组:第1组为江山OIB型玄武岩,在微量元素组成上无Nb-Ta亏损和Pb负异常,高ε_(Nd)(t)和低(~(87)Sr/~(86)Sr)_i比值,总体上显示出类似洋岛玄武岩的元素-同位素组成特征;第2组为高钛磷玄武岩,Nb-Ta弱负异常和明显Pb正异常,中等ε_(Nd)(t)和(~(87)Sr/~(86)Sr)_i比值;第3组为低钛磷玄武岩,强烈Nb-Ta负异常和中等Pb正异常,低ε_(Nd)(t)(-6.0～-3.7)和高(~(87)Sr/~(86)Sr)_i为特征。三组镁铁质火山岩相互之间缺乏分异演化关系,也不是同一母岩浆经历地壳混染作用的结果。对比三组镁铁质火山岩的La/Nb、Ba/Nb、Zr/Ba比值和Sr-Nd同位素模拟结果,我们认为江绍断裂带晚中生代玄武岩为软流圈-岩石圈相互作用的产物,从早期(111～112Ma)到晚期(99Ma)镁铁质岩浆地幔源区软流圈组分的比例越来越多而岩石圈成份逐渐减少的趋势。考虑到该区晚中生代的盆岭构造格局与邻区郴州-临武断裂带同时期镁铁质岩浆的产出特点,华南地区在早白垩世晚期到晚白垩世期间发生了强烈的岩石圈伸展-减薄作用。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.