Relationships between bacterial-algal proliferating and mass extinction in the Late Devonian Frasnian-Famennian transition: Enlightening from carbon isotopes and molecular fossils

The five major mass extinctions which occurred in the transition of the Ordovician-Silurian (440 Ma), Late Devonian Frasnian-Famennian (F-F) (370 Ma), Permian-Triassic (250 Ma), Triassic-Jurassic (205 Ma) and Cretaceous-Paleogene (65 Ma) are significant phenomena in the Phanerozoic global environment and organic evolution. Their corresponding extinction rates of marine invertebrate at the level of genus and family are 60% (genus) and 26% (family), 57% and 22%, 82% and 51%, 53% and 22%, …     

Coherent variations of the obliquity components in global ice volume and ocean carbon reservoir over the past 5 Ma

The Milankovi theory stresses that the summer insolation in the high northern latitudes that is dominated by the precession cycle controls the glacial/interglacial cycles in global climate change.If the climate system responds linearly to the external insolation forcing,the precession cycle of 23 or 19 ka should dominate the variations in the climatic proxy records.I performed spectral and evolutive cross spectral analyses on the high resolution benthic 18O and 13C records from the South China Sea and the North Atlantic,the proxies of global ice volume and ocean carbon reservoir respectively.I found that the obliquity instead of the eccentricity or the precession is the most marked cycle in the global ice volume and ocean carbon reservoir variations over the past 5 Ma.The analysis further reveals that only at the obliquity band instead of the eccentricity or the precession band does the global ice volume and ocean carbon reservoir display consistently high coherency and stable phase relationship over the past 5 Ma.The consistently positive or near-zero phases of the benthic 18O relative to the benthic13C at the obliquity band suggest that the global carbon cycle is involved in the polar ice sheet growth as an important internal feedback,not a determinative driving factor.The obliquity instead of the precession or the eccentricity takes the dominant role of driving the global climate change during the Pliocene and Pleistocene.     

Early onset and origin of 100-kyr cycles in Pleistocene tropical SST records

The large 100-kyr cycles evident in most late-Pleistocene (0–0.6 Ma) paleoclimatic records still lack a satisfactory explanation. Previous studies of the nature of the transition from the early Pleistocene (1.2–1.8 Ma) 41-kyr-dominated climate regime to the 100-kyr world have been based almost exclusively on benthic foraminiferal oxygen isotopic (δ¹⁸O) data. It is generally accepted that the late Pleistocene 100-kyr cycles represent a newly evolved sensitivity to eccentricity/precession, superimposed on an earlier, and largely constant, response to obliquity and precession forcing. However, orbitally-resolved Pleistocene sea surface temperature (SST) records from a variety of oceanic regions paint a rather different picture of the global climate transition across the mid-Pleistocene transition (MPT, 0.6–1.2 Ma). Reanalysis of these SST records shows that: (1) an early onset of strong 100-kyr-like cycles in two low-frequency bands (～ 120–145 kyr and ～ 60–80 kyr), derived from the bundling of two/three obliquity cycles into grand cycles (obliquity subharmonics), occurred in tropical SST records during the early Pleistocene, (2) these two early Pleistocene periods converge into the late-Pleistocene 100-kyr period in tropical SST records, (3) the dominance of 100-kyr SST power in the late Pleistocene coincides with a dramatic decline in the 41-kyr SST power, and (4) the correlation of timing of glacial terminations with eccentricity/precession variation could well extend back into the early Pleistocene. We demonstrate that most of these features also occur in δ¹⁸O records, but in a much more subtle manner. These features could be explained in two plausible ways: a shift in climate sensitivity from obliquity to eccentricity/precession (a modified version of the conventional view) or an increasingly nonlinear response to orbital obliquity across the MPT. However, our examination of the development of ～100-kyr cycles favors an obliquity bundling mechanism to form late Pleistocene 100-kyr cycles. We therefore suggest that the late Pleistocene 100-kyr climatic cycles are likely a nonlinear response to orbital obliquity, although the timing of late Pleistocene 100-kyr climatic cycles and their early forms appears to be paced by eccentricity/precession.     

Late Changhsingian radiolarian biostratigraphy from Guangxi,South China and its correlation to conodonts

A well-preserved, abundant radiolarian fauna was obtained from three sections: the Dongpan, Liuqiao, and Paibi sections, in southern Guangxi, South China. Sixteen species belonging to Albaillella and Neoalbaillella, including seven undetermined species, are recognized. On the basis of stratigraphic distribution of these species, two radiolarian zones, the Albaillella triangularis Zone and the Albaillella yaoi Zone, are established. The correlation between radiolarian zones and conodont zones is suggested based on the discovery of coexisting conodonts. Albaillella triangularis and Albaillella yaoi zones correspond to Neogondolella postwangi and Neogondolella yini zones respectively.     

柴达木盆地东部三湖地区四系米兰柯维奇旋回分析

自然伽马曲线包含丰富的地质信息，能够很好地反映由气候变化引起的地层旋回.本文采用频谱分析对柴达木盆地三湖地区第四系自然伽马测井曲线进行了系统分析.作为频谱分析方法之一的快速傅里叶变换能够将自然伽马曲线从时间（深度）域转换为频率域，然后分析每一个峰值频率的波长及其相互之间的比率关系，寻找那些波长比率与米兰柯维奇周期比率相同或相似的频率，从而捕获高频旋回信息.研究结果表明第四系地层中很好地保存了高频的米兰柯维奇旋回，这样的沉积旋回主要由地球轨道的周期性变化而导致的古气候变化引起的.偏心率周期引起的地层旋回厚度变化范围在92.00~115.00 m之间，黄赤交角引起的地层旋回厚度变化范围在24.55~63.43 m之间，岁差引起的地层旋回厚度变化范围在16.8~26.35 m之间.黄赤交角和岁差是影响该区米兰柯维奇旋回的主要因素，其中岁差的影响最大，而偏心率的影响最小.     

Frasnian-Famennian boundary events in Tarim Basin,Xinjiang, Northwest China

The Frasnian-Famennian Boundary Event (Kellwasser Event) is one of the seven strongest Phanerozoic faunal turnovers. The importance of this first order of global bio-event was taken into consideration when the International Subcommission on Devonian Strat…     

Phosphatic microspherules and their geobiological implications from the Frasnian-Famennian transition at the Yangdi section,Guilin, South China

Abundant perfectly-preserved phosphatic microspherules have been discovered across the Frasnian-Famennian(F-F)transition from the Yangdi section in Guilin,Guangxi,South China.They are mostly spherical or elliptical in shape and about 150μm in diameter with smooth exterior surfaces.Each microspherule consistently possesses a small dimple on the surface.The internal texture of microspherules consists of concentric light-colored apatite and dark-colored organic matter bands alternating around a central core.Conodonts have also been found preserved together with phosphatic microspherules in the same horizon,and the abundance of the former is obviously higher than that of the latter.Laser Raman spectral studies show close similarities in spectral patterns between the outer shells of phosphatic microspherules and the blade of the conodont genus Palmatolepis sp.,as well as between the microspherule nucleus and the platform of the same conodont genus.Furthermore,the statistical results and geochemical data demonstrate that the elevated abundance of phosphatic microspherules roughly coincides with the blooms of bacteria and algae,but is later than the sharp increase of oceanic nutrients.The phosphatic microspherules are interpreted here to be the‘otoliths’secreted by conodont animals based on the compositional similarities between phosphatic microspherules and conodonts and their interrelated abundances.In addition,an analogous study reveals morphological and textural similarities between fish otoliths and phosphatic microspherules.The formation of phosphatic microspherules is probably related to seawater eutrophication.We speculate that the explosive growth of bacteria and algae is probably caused by the enrichment of nutrients that is most likely associated with the increase of terrestrial inputs,submarine hydrothermal activities or the upwelling anoxic bottom waters in the late Devonian,which would stimulate the conodont animals to secrete phosphatic microspherules—the‘otoliths’of conodont animals.This study reveals the coupling relationship between organisms and environments from the perspective of phosphatic microspherules and provides new evidence for the cause of faunal crisis during the Late Devonian F-F transition.     

Nonlinear coupling between 100 ka periodicity of the paleoclimate records in loess and periodicities of precession and semiprecession

It is apparent that there are three periods in various Quaternary paleoclimate records, the pe-riod of the Earth抯 orbital eccentricity cycles, ~100 ka, the period of the Earth抯 obliquity cycles, 41 ka, and the periods of the precession cycles, 23 ka and…     

Forcing mechanism of the Pleistocene east Asian monsoon variations in a phase perspective

The variations of the Earth’s geometry (ETP) pre-dominate climate changes such as monsoon on the Earth[1], serving as its external forcing. The loess/ paleosol sequence in Central China provides a good record of terrestrial deposition to study the evolution of the east Asian monsoon[2―4]. However, the deep sea deposition, due to its high resolution dating and abun-dant climate proxies, should be able to provide more climatic information in the geological time, such as the forcing mechanis…     

Cyclostratigraphy of the Induan (Early Triassic) in West Pingdingshan Section, Chaohu, Anhui Province

The Induan sequence in the West Pingdingshan Section, Chaohu, Anhui Province, displays a series of superimposed mudstone/limestone cycles. The lithological character of the cycles, combined with power spectral and wavelet analysis of magnetic susceptibility readings, reveals 12 short eccentricity and 56 precession Milankovitch cycles - obliquity cycles are not apparent. The uniformity of cycle thicknesses indicates a stable depositional setting making this section ideal to perform various geo-logical studies. Accordingly, the Induan Stage is estimated to have lasted 1.1 Ma, and the depositional rate for this part of the section is about 3.7 cm/ka. This places the Induan-Olenekian boundary in the West Pingdingshan Section at about 251.5 Ma based on an age of 252.6 Ma for the Permian-Triassic boundary.     

过去2．5百万年间黄土与深海古气候变化周期的对比分析

过去２．５Ｍａ间宝鸡黄土粒度记录和深海氧同位素曲线的Ｆｏｕｒｉｅｒ功率谱分析结果表明：在１．６Ｍａ以上部分，两者的周期性相当一致；但在２．５-１．６Ｍａ时段，两者的周期记录差异很大．深海氧同位素曲线记录的全球大陆冰量变化周期以与地轴倾斜度有关的０．０４１Ｍａ为主，而黄土粒度曲线记录的内陆风力强度变化周期则以与偏心率有关的０．４Ｍａ和０．１Ｍａ为主．造成这种异同的原因是：在２．５-１．６Ｍａ时段，内陆风力强度变化主要受地球轨道变化驱动，而从１．６Ｍａ前开始，转而主要受全球大陆冰量变化驱动．     

Responses of foraminiferal isotopic variations at ODP Site 1143 in the southern South China Sea to orbital forcing

The foraminiferal δ ¹⁸O and δ ¹³C records for the past 5 Ma at ODP Site 1143 reveal the linear responses of the Plio-Pleistocene climatic changes in the southern South China Sea to orbital forcing at the obliquity and precession bands. The phase of the δ ¹⁸O variations with the orbital forcing is opposite to that of the δ ¹³C, which may be caused by the frequent El Niño events from the equatorial Pacific. The amplification of the Northern Hemisphere Ice Sheet at ñ3.3 Ma probably affected the development of the 100-ka climatic cycles. Its further spreading may spur the 100-ka climatic cycle to become the dominant cycle in the late Pleistocene. The “Mid- Pleistocene Transition” event has localized influence on the isotopic variations in the southern South China Sea. The foraminiferal δ ¹³C records for the past 5 Ma at Site 1143 are highly coherent with the orbital forcing at the long eccentricity band, and lead the δ ¹⁸O records at the shorter eccentricity band, highlighting the importance of the carbon cycle in the global climate change.     

The Kellwasser events in the Upper Devonian Frasnian to Famennian transition in the Toc Tat Formation,northern Vietnam

Upper Devonian carbonates of the Toc Tat Formation in the Si Phai Pass area of Dong Van District, northern Vietnam were deposited in carbonate platform, slope, and basin environments. These carbonates yield abundant conodonts indicative of the Palmatolepis nasuta, Pa. linguiformis and Pa. triangularis zones, the Frasnian–Famennian stage boundary being identified by the first occurrence of Pa. triangularis. Two positive carbon isotope excursions are recognized, the lower excursion peaking in the interval of the lower to middle Pa. nasuta Zone, whilst the upper excursion peaks just above the local Frasnian–Famennian boundary. Based on the biostratigraphy, these excursions equate to the Lower and Upper Kellwasser events. Locally, tentaculitoid taxa (Nowakia, Styliolina, Homoctenus, and Metastyliolina?) are abundant in the interval of the Pa. nasuta Zone, but show a drastic decline in abundance before the Lower Kellwasser Event, and only two taxa survived into the Famennian.     

Biotic recovery from the Late Devonian F-F mass extinction event in China

The Frasnian-Famennian (F-F) mass extinction is one of the five great extinctions of marine life during the Phanerozoic. The F-F event killed most of the Devonian reefs, the characteristic Devonian corals, stromatoporoids, bryozoans, nearly all tentaculites, a few superfamilies of brachiopods, such as Atrypacea and Pentameracea and some important elements of goniatites, such as Manticoceras. The end-Frasnian was a phase of mass extinction. A large number of shelly benthos were killed by the F-F event. Early and middle Famennian was the survival interval. The marine faunas were very rare at that time. The late Famennian was the recovery interval. There appeared to have many new taxa in the Strunian stage. It lacked a radiation interval in Late Devonian Famennian because another event (the D-C mass extinction) happened at the Devonian-Carboniferous boundary. Several causes for the F-F mass extinction have been proposed by some geologists, which have been grouped into two broad types, terrestrial and extraterrestrial. The former is related to sea level changes, climate changes and anoxic water event. The latter is linked with some forms of meteorite impact. A large-scale eustatic change of sea level and black shales representing an anoxic environment has been invoked to explain one of the causes for the F-F mass extinction.     

Magnetic mineralogy and paleomagnetism of serpentinized ultramafic rocks from the Braszowice-Brzeźnica fragment of sudetic paleozoic ophiolite

Complex paleomagnetic, rock-magnetic and mineralogical studies were performed on serpentinized utramafic rocks from Braszowice-Brze?nica massif (BB) situated at the southern extremity of the Niemcza Shear Zone, close to the Sudetic Marginal Fault. Studies of magnetic minerals revealed presence of several varieties of magnetite grains, and partly altered Cr-spinels. Paleomagnetic studies revealed stable component HS of natural remanence carried by magnetite formed probably during the initial serpentinization. The directions of HS have good grouping within each locality, but differ between localities. Studies of anisotropy of magnetic susceptibility (AMS) have shown that directions of anisotropy axes are steep instead of horizontal as is common within the Niemcza Shear Zone. Taking advantage of the directions of AMS we rotated the directions of HS and brought them to the reference direction for the Sudetes for 372 Ma. We suggest that after acquiring AMS and HS during the Upper Devonian, the BB became divided into multiple units due to tectonic activity in the region.     

天文气候学10万年问题的研究

为了研究第四纪晚更新世(约100万年前到2万年前)古气候的周期变化以及在轨道尺度上气候系统对太阳辐射的响应,本文发展了适合于非线性非平稳数据的分析方法即经验模态分解(EMD),对太阳辐射古气候记录进行了分析,进而重新认识了地球轨道周期变化影响下的太阳辐射的气候意义.研究结果表明,太阳辐射中偏心率的影响是相当大的,而不是以前认为的不到1%的影响,至少它是和太阳辐射的黄赤交角,岁差波段的信号是可以相比拟的.     

Astrochronology of the late Jurassic Kimmeridge Clay (Dorset,England) and implications for Earth system processes

The Late Jurassic Kimmeridge Clay Formation (KCF) is an economically important, organic-rich source rock of Kimmeridgian–Early Tithonian age. The main rock types of the KCF in Dorset, UK, include grey to black laminated shale, marl, coccolithic limestone, and dolostone, which occur with an obvious cyclicity at astronomical timescales. In this study, we examine two high-resolution borehole records (Swanworth Quarry 1 and Metherhills 1) obtained as part of a Rapid Global Geological Events (RGGE) sediment drilling project. Datasets examined were total organic carbon (TOC), and borehole wall microconductivity by Formation Microscanner (FMS). Our intent is to assess the rhythmicity of the KCF with respect to the astronomical timescale, and to discuss the results with respect to other key Late Jurassic geological processes. Power spectra of the untuned data reveal a hierarchy of cycles throughout the KCF with ～ 167 m, ～ 40 m, 9.1 m, 3.8 m and 1.6 m wavelengths. Tuning the ～ 40 m cycles to the 405-kyr eccentricity cycle shows the presence of all the astronomical parameters: eccentricity, obliquity, and precession index. In particular, ～ 100-kyr and 405-kyr eccentricity cycles are strongly expressed in both records. The 405-kyr eccentricity cycle corresponds to relative sea-level changes inferred from sequence stratigraphy. Intervals with elevated TOC are associated with strong obliquity forcing. The 405-kyr-tuned duration of the lower KCF (Kimmeridgian Stage) is 3.47 Myr, and the upper KCF (early part of the Tithonian Stage, elegans to fittoni ammonite zones) is 3.32 Myr. Two other chronologies test the consistency of this age model by tuning ～ 8–10 m cycles to 100-kyr (short eccentricity), and ～ 3–5 m cycles to 36-kyr (Jurassic obliquity). The ‘obliquity-tuned’ chronology resolves an accumulation history for the KCF with a variation that strongly resembles that of Earth's orbital eccentricity predicted for 147.2 Ma to 153.8 Ma. There is evidence for significant non-deposition (up to 1 million years) in the lowermost KCF (baylei–mutabilis zones), which would indicate a Kimmeridgian/Oxfordian boundary age of 154.8 Ma. This absolute calibration allows assignment of precise numerical ages to zonal boundaries, sequence surfaces, and polarity chrons of the lower M-sequence.     

Completing the Neogene geological time scale between 8.5 and 12.5 Ma

A much improved high-resolution magnetostratigraphy is presented for the interval between 8.5 and 12.5 Ma in the deep marine astronomically tuned Monte dei Corvi Beach section in northern Italy. This section contains the formally designated boundary between the Middle and Upper Miocene defined by the Tortonian GSSP. The natural remanent magnetization is carried by an unusual low-temperature component of primary origin. According to interpretations of isothermal remanent magnetization (IRM) acquisition curves, the palaeomagnetic signal is most probably carried by iron sulphides, such as greigite or pyrrhotite. The resultant magnetostratigraphy is reliable and can be straightforwardly calibrated to the Astronomically Tuned Neogene Time Scale (ATNTS2004) showing that the section ranges from Chron C5An.2n up to C4.2r-1. The inferred correlation of the Tortonian GSSP to the older part of Chron C5r.2n is confirmed, thereby guaranteeing global correlation potential. In addition, the Monte dei Corvi Beach section has been re-tuned to the new numerical solution La2004 for the interval between 8.5 and 12.9 Ma. This exercise shows that the characteristic cycle patterns are not consistent with a single solution with fixed values for dynamical ellipticity and tidal dissipation. For the younger part of the section, sedimentary cycles show an excellent fit with intricate details of precession/obliquity interference in the nominal La2004_(1,1) solution. However, this solution produces serious mismatches between the sedimentary cycles and the precession/obliquity interference in the interval older than ∼ 10.2 Ma. For this interval changes in tidal dissipation value (while keeping dynamical ellipticity constant at its present-day value) are necessary to maintain a perfect fit. A detailed visual comparison reveals a very good to excellent fit with La2004_(1,1.2) and, to lesser extent, with La2004_(1,0.5). However, La2004_(1,1.2) is the preferred tuning target for the moment in the interval older than 10.2 Ma. The astronomical (re)tuning on precessional scale to La2004_(1,1) yielded slightly different astronomical ages for each basic cycle and, hence, also for the calcareous plankton events and magnetic reversal boundaries with uncertainties ranging within a few thousand years. The age of the Tortonian GSSP turns into 11.625 Ma instead of the previously published 11.608 Ma. Our ages should replace existing ages in the Astronomically Tuned Neogene Time Scale (ATNTS2004).     

Seasonality intensification and long-term winter cooling as a part of the Late Pliocene climate development

A mutual climatic range method is applied to the Mediterranean marine pollen record of Semaforo (Vrica section, Calabria, Italy) covering the period from ∼2.46 Ma to ∼2.11 Ma. The method yields detailed information on summer, annual and winter temperatures and on precipitation during the nine obliquity and precession-controlled ‘glacial’ periods (marine isotope stages 96 to 80) and eight ‘interglacial’ periods (marine isotope stages 95 to 81) characterising this time interval. The reconstruction reveals higher temperatures of at least 2.8 °C in mean annual and 2.2 °C in winter temperatures, and 500 mm in precipitation during the ‘interglacials’ as compared to the present-day climate in the study area. During the ‘glacials’, temperatures are generally lower as compared to the present-day climate in the region, but precipitation is equivalent. Along the consecutive ‘interglacials’, a trend toward a reduction in annual and winter temperatures by more than 2.3 °C, and toward a higher seasonality is observed. Along the consecutive ‘glacials’, a trend toward a strong reduction in all temperature parameters of at least 1.6 °C is reconstructed. Climatic amplitudes of ‘interglacial–glacial’ transitions increase from the older to the younger cycles for summer and annual temperatures. The cross-spectral analyses suggest obliquity related warm/humid–cold/dry ‘interglacial–glacial’ cycles which are superimposed by precession related warm/dry– cold/humid cycles. A time displacement in the development of temperatures and precipitation is indicated for the obliquity band by temperatures generally leading precipitation change at ∼4 kyr, and on the precession band of ∼9.6 kyr in maximum.     

Integrated Upper Carnian to Lower Norian biochronology and implications for the Upper Triassic magnetic polarity time scale

We summarize the ammonoid, conodont and halobiid biochronology of the Upper Carnian to Lower Norian, based on a discussion of data in the Alps, Sicily, Balkans, Turkey, Himalayas and Timor. With this integrated biostratigraphic scale, the Pizzo Mondello section (Sicily) can be recalibrated and the Carnian-Norian boundary more precisely located there. As a result, the magnetostratigraphy of this section is now in good agreement with previous results from Turkey, although the latter series are more condensed. Cross-correlation of available magnetostratigraphic data from marine Tethyan sections allow us to construct a composite Upper Carnian to Upper Norian geomagnetic polarity time scale (GPTS). This GPTS leads us to question previously proposed magnetobiostratigraphic and chronostratigraphic correlations within the Upper Triassic Newark non-marine sedimentary sequence.