新疆吐鲁番盆地陆相白垩纪与古近纪界线的环境指标

通过对新疆吐鲁番盆地白垩纪和古近纪陆相地层的氧化物、碳酸钙、有机碳含量分析以及有机碳稳定同位素的测试,并通过w(Fe³⁺)/w(Fe²⁺)比值指示的古温度研究,探讨了该地区白垩系-古近系界线的特征以及古气候特点。研究表明在白垩系/古近系界线附近各项环境指标发生了明显的变化。在白垩纪末期,有机碳同位素δ¹³C_org明显偏正,Al₂O₃、Fe₂O₃含量降低;而进入古新世,δ¹³C_org明显偏负,Al₂O₃、Fe₂O₃含量升高。对w(Fe³⁺)/w(Fe²⁺)比值指示的古温度计算表明,在白垩纪末期大气温度比较低,而进入古新世气温回升,这与进入古新世有机碳稳定同位素明显偏负的特征一致。     

甘-新北山地区二叠纪镁铁-超镁铁质岩体造岩矿物化学特征及其岩石学指示

二叠纪镁铁-超镁铁质岩体在北山造山带广泛分布,其中多发育铜镍硫化物矿化,并集中在新疆北山坡北和甘肃北山柳园地区。本文对柳园地区二叠纪骆驼山(283Ma)和西南山(277Ma)矿化岩体中早期结晶的造岩矿物开展矿物化学分析,并对甘-新北山地区矿化岩体的主要造岩矿物进行系统对比研究。骆驼山和西南山岩体主要由单辉橄榄岩、二辉橄榄岩、橄榄辉石岩、橄榄辉长岩和辉长岩组成,主要造岩矿物为橄榄石、单斜辉石、斜方辉石、斜长石和角闪石,及少量铬尖晶石和金云母。铬尖晶石Cr^#值范围为52.2～70.4,TiO₂含量为1.1%～4.0%,Al₂O₃含量为8.1%～18.9%。橄榄石Fo值范围为78～86,Ni含量为856×10^-6～2121×10^-6,Ca含量为71.3×10^-6～720×10^-6。斜方辉石主要为顽火辉石和少量古铜辉石;单斜辉石为透辉石和普通辉石,Mg^#范围为86～88,Al^Ⅳ...     

基于包络线消除法的岩石光谱对应分析

岩石光谱特征是岩性识别的物理基础。选取常见的10种岩石类型15种岩石样品的光谱数据,对其进行均值、重采样、平滑、水汽吸收波段拟值等预处理,以消除岩石光谱噪声,然后通过包络线消除法,获得了岩石光谱特征参数,发现云母板岩（风化面）吸收特征最为明显;对包络线消除处理后的光谱数据进行对应分析,提取出R型主因子载荷,得到第一主因子轴代表主要的阳离子、阴离子诊断波段和水分子吸收波段,第二主因子轴代表少数阳离子的特征波段,获得与岩石相关的特征波段为385~525 nm、735~1 365 nm、1 435~1 785 nm、1 890~1 952 nm、1 995~2 310 nm,并找出了主要吸收波段的物理含义。通过对应分析二维图像,将岩石光谱分为4类,从第一类到第四类吸收深度逐渐变浅,吸收面积呈递减趋势,吸收宽度逐渐变窄,吸收峰逐渐增多,Fe²⁺和Fe³⁺吸收峰增多,铁化、泥化蚀变现象更明显。用聚类分析法对分类结果进行验证发现,分类结果有较好的对应性。从而为岩石和成像光谱图像数据精细分类提供参考依据,实现了对岩石高光谱海量数据的有效提取,进而为遥感矿产预测和找矿提供依据。     

新疆库鲁克塔格西段早泥盆世橄榄辉长岩年代学、地球化学特征及其地质意义

对新疆库鲁克塔格西段乌斯腾高勒东南橄榄辉长岩进行系统的锆石U-Pb年代学、全岩地球化学及Sr?Nd?Hf同位素研究,确定了岩石成因,并探讨其构造背景及地质意义。LA-ICP-MS锆石U-Pb年代学研究表明,橄榄辉长岩结晶年龄为410.3±5.7 Ma （MSWD = 0.56）,属早泥盆世岩浆活动的产物。全岩地球化学表明,岩石具有高Al₂O₃ 和CaO、贫碱、低P₂O₅和TiO₂的特征,属于低钾拉斑系列;岩石具有较高的Mg^#值（72.27～75.04）、明显的Eu正异常（δEu = 1.12～1.38）,其轻稀土元素轻微富集,重稀土元素相对平缓;微量元素蛛网图上岩石富集大离子亲石元素（如Rb、Ba、K、Sr）和Pb元素,亏损高场强元素（如Nb、Ta、P、Ti）。全岩Sr 同位素初始比值（⁸⁷Sr/⁸⁶Sr）_i值（0.703 663～0.704 013）相对较小,ε_Nd（t）值（-2.32～+4.98）变化范围较大,锆石ε_Hf（t）值为+7.8～+12.5。该岩体为俯冲板片流体改造过的相对较浅、对应于尖晶石二辉橄榄岩稳定区域的亏损地幔楔部分熔融,部分熔融比例在2%～10%之间,其母岩浆形成过程中遭受低程度的地壳物质混染,并经历了斜长石的堆晶作用和较弱的橄榄石和单斜辉石的结晶分异作用。结合区域已有地质资料,本文认为塔里木北缘库鲁克塔格地区在古生代中期经历了南天山洋南向俯冲过程,橄榄辉长岩产于主动大陆边缘环境,该时期大陆地壳生长方式为垂向生长,指示塔里木北缘具有增生造山带的属性。     

柴北缘察汗诺辉长岩成因:岩石地球化学、锆石U-Pb年代学与Lu-Hf同位素制约

柴北缘察汗诺地区广泛发育中生代辉长岩、闪长岩、花岗闪长岩和花岗岩。LA-ICP-MS锆石U-Pb测年结果表明, 辉长岩²⁰⁶ Pb/²³⁸ U加权平均年龄为246±0.7 Ma, 形成于中三叠世早期。辉长岩SiO₂(50.61%~54.41%)和全碱含量(2.36%~3.72%)低, 里特曼指数为0.54~1.12, 属于中钾钙碱性系列岩石; Mg^#(73~79)和Cr(342×10^-6~753×10^-6)、Ni(45.1×10^-6~145×10^-6)含量高, LREE/HREE为4.74~5.67, 富集U、Th等大离子亲石元素, 亏损Nb、Ta、Ti等高场强元素, 呈现出与典型俯冲作用密切相关的弧岩浆岩特征。锆石Lu-Hf同位素分析结果显示, 辉长岩ε_Hf(t)值为-2.24~+1.37, 研究表明察汗诺辉长岩岩浆源区因受俯冲板片流体交代而富集, 岩石主要起源于富集地幔的部分熔融。空间上, 察汗诺辉长岩与东昆仑布尔汗布达、鄂拉山以及西秦岭同仁-泽库等同时代的钙碱性岩浆岩, 共同构成了古特提斯洋向北俯冲的大陆边缘弧。     

青海赛什腾地区遥感影像岩石信息提取研究

赛什腾地区隶属柴北缘构造带,岩性复杂多变,前人对研究区岩性界线的划分较为笼统,笔者等选择Landsat- 8 OLI、ASTER和Sentinel- 2A为数据源,采用最佳波段指数确定各影像的波段组合,凸显不同岩石的边界;将ASTER短波红外波段与Landsat- 8 OLI、Sentinel- 2A可见光—近红外波段协同处理,构成Landsat- 8+ASTER（LA）数据和Sentinel- 2A+ASTER（SA）数据,分析重采样岩石标准光谱信息,拟定不同岩石波段运算公式,基于多重分形理论选定不同岩石类型的阈值范围,获取主要岩性的分布;根据重采样的黑云母标准光谱曲线,选取SA数据2262 nm波段和2336 nm波段进行定向主成分分析,采用Crosta法阈值分割第二主成分,划分黑云母异常等级,将其与岩性分布相关联,识别出研究区主要岩性分布。通过岩石实测光谱分析、薄片镜下鉴定与野外地质调查相结合的方法完善解译结果。岩性提取结果显示,小赛什腾山东侧新发现“U”型条带,为辉长岩—英云闪长岩—二长花岗岩,重新圈定达肯大坂群第三岩组和第四岩组,滩间山群一组,花岗岩,二长花岗岩,黑云母花岗岩,流纹岩,似斑状石英闪长岩,石英闪长岩,英云闪长岩,辉长闪长岩和辉长岩等岩石的边界。此次基于多源遥感数据岩性识别方法研究对青海赛什腾地区野外地质调查工作具有指导意义,可为高山峡谷区地质填图提供技术参考。     

青海赛什腾地区遥感影像岩石信息提取研究

赛什腾地区隶属柴北缘构造带,岩性复杂多变,前人对研究区岩性界线的划分较为笼统,笔者等选择Landsat- 8 OLI、ASTER和Sentinel- 2A为数据源,采用最佳波段指数确定各影像的波段组合,凸显不同岩石的边界;将ASTER短波红外波段与Landsat- 8 OLI、Sentinel- 2A可见光—近红外波段协同处理,构成Landsat- 8+ASTER（LA）数据和Sentinel- 2A+ASTER（SA）数据,分析重采样岩石标准光谱信息,拟定不同岩石波段运算公式,基于多重分形理论选定不同岩石类型的阈值范围,获取主要岩性的分布;根据重采样的黑云母标准光谱曲线,选取SA数据2262 nm波段和2336 nm波段进行定向主成分分析,采用Crosta法阈值分割第二主成分,划分黑云母异常等级,将其与岩性分布相关联,识别出研究区主要岩性分布。通过岩石实测光谱分析、薄片镜下鉴定与野外地质调查相结合的方法完善解译结果。岩性提取结果显示,小赛什腾山东侧新发现“U”型条带,为辉长岩—英云闪长岩—二长花岗岩,重新圈定达肯大坂群第三岩组和第四岩组,滩间山群一组,花岗岩,二长花岗岩,黑云母花岗岩,流纹岩,似斑状石英闪长岩,石英闪长岩,英云闪长岩,辉长闪长岩和辉长岩等岩石的边界。此次基于多源遥感数据岩性识别方法研究对青海赛什腾地区野外地质调查工作具有指导意义,可为高山峡谷区地质填图提供技术参考。     

东天山四顶黑山层状岩体地质特征及成矿潜力分析

东天山黄山岩带因发育众多镁铁质-超镁铁质岩体和岩浆铜镍硫化物矿床而备受地质学者关注。四顶黑山岩体位于该岩带最东端,具有层状岩体特征;岩石类型有单辉橄榄岩、橄榄辉石岩、橄榄苏长辉长岩、橄榄辉长岩、辉石角闪岩、辉长岩、角闪辉长岩、闪长岩,主要造岩矿物为贵橄榄石、古铜辉石、透辉石、普通角闪石和斜长石,岩体分异较好,蚀变较发育。通过矿物显微结构特征观察以及计算得出:四顶黑山岩体中橄榄石最先结晶,其开始结晶温度大约在1419℃左右;古铜辉石和透辉石在橄榄石之后开始结晶,结晶温度分别在1100℃左右和900～1100℃之间,两矿物相在岩石中可以共存。岩体中橄榄岩相、苏长岩相发育,以及贵橄榄石+古铜辉石的矿物组合特征,表明岩体具有形成铜镍(铂)矿床的有利条件。     

北太行紫荆关基性岩体的成因: 岩石学和地球化学证据

通过对北太行紫荆关晚中生代基性岩体的岩石学和地球化学特征研究, 讨论其岩浆源区特征及成因.结果表明, 紫荆关岩体主要由橄榄二辉石岩、角闪辉长岩和闪长岩等岩石组成.橄榄二辉石岩具有明显的堆晶结构, 可能是堆晶成因, 而角闪辉长岩和闪长岩可能是堆晶形成之后的残余岩浆的结晶.闪长岩中的斜长石显示复杂的结构和成分环带, 相对富钠的核部见富钙斜长石叠加, 后者又向富钠斜长石演化.闪长岩中的单斜辉石也显示复杂的成分环带, 主要是最边部的MgO含量比紧邻的内侧辉石更高.这表明在闪长岩形成过程中有新的幔源高温富镁的岩浆注入.以上各岩石类型具有类似的地球化学性质, 包括较强的稀土分异((La/Yb)_N比值为5.76~23.13), 高Sr/Y比值(50.95~146.13), 富集K、Sr、Ba等大离子亲石元素和LREE, 亏损Nb、Zr、Ti等高场强元素和HREE, Eu异常不明显.都显示富集的Sr-Nd同位素特征, I_Sr=0.7058~0.7066, ε_Nd(t) =-13.8~-18.2.这些特征表明紫荆关基性岩体的母岩浆来源于EM1型富集地幔的部分熔融.橄榄辉石岩和角闪辉长岩具有类似的Nd同位素成分(主要为ε_Nd(t) =-15.0~-16.6), 但形成较晚的闪长岩的ε_Nd(t) 值却比较高(-13.8~-14.6), 也支持新的幔源岩浆在晚期的注入.      

中天山卡瓦布拉克地区早泥盆世—晚 石炭世中-基性侵入岩的年代学、 岩石成因及构造意义

中天山卡瓦布拉克地区中-基性侵入岩由石英闪长岩、斜长岩和橄榄辉长岩组成。锆石LA-ICP-MS U-Pb同位素分析结果表明,石英闪长岩形成于412.2±3.2 Ma,斜长岩形成于297.1±3.1 Ma,分别代表晚古生代早期和晚期的岩浆活动。石英闪长岩的ε_Hf（t）值介于为+0.3～+15.4,对应的二阶段模式年龄T_DM2 = 1 381～427 Ma。斜长岩的ε_Hf（t）值为+6.4～+11.3,对应的单阶段模式年龄T_DM = 678～498 Ma。地球化学分析结果显示,它们均富集轻稀土和大离子亲石元素、亏损高场强元素。基于野外地质、岩相学和地球化学特征,并结合区域地质资料认为,石英闪长岩形成于早泥盆世南天山洋北向俯冲于中天山地块之下的活动大陆边缘环境,是幔源岩浆和壳源岩浆混合的产物;斜长岩和橄榄辉长岩形成于伸展环境,其母岩浆来自被俯冲带流/熔体交代过的年轻岩石圈地幔。橄榄辉长岩中的多期捕获锆石年龄揭示中天山基底经历了长期多期次构造热事件,其中最老的年龄（2 767～2 663 Ma）能否说明中天山存在太古代基底有待于进一步研究。     

The Asama igneous complex, central Japan: An ultramafic-mafic layered intrusion in the Mikabu greenstone belt, Sambagawa metamorphic terrain

The Asama igneous complex comprises layered mafic and ultramafic plutonic rocks exposed over about 500×6000 m in the Mikabu greenstone belt, Sambagawa metamorphic terrain of Mie Prefecture; its margins terminate by faults, and there is no trace of chilled rocks. The exposed layered sequence is about 460 m thick, and includes dunite, plagioclase wehrlite, olivine gabbro and two-pyroxene gabbro. The crystallization sequence of essential cumulus minerals is olivine, followed by plagioclase and clinopyroxene together, and finally the appearance of orthopyroxene. Olivine systematically varies in composition from Fo₈₉ to Fo₇₈ with stratigraphic height in the lower to middle portion of the layered sequence. The composition of clinopyroxene changes from Ca₄₉Mg₄₆Fe₅ to Ca₄₀Mg₄₇Fe₁₃ upward in the layered sequence; cumulus orthopyroxene, which occurs at the top of the exposed layered sequence, has a composition of Ca₂Mg₇₄Fe₂₄. Cumulus chromite occurs as disseminated grains in peridotitic rocks, and tends to increase its Fe³⁺/(Cr+Al+Fe³⁺) ratio with stratigraphic height. The most aluminous chromite [Cr/(Cr+Al) = 0.48] occurs in dunite that crystallized shortly before plagioclase began to separate as an essential phase. The Cr/(Cr+Al) ratio of the most aluminous chromite, coupled with the crystallization order of essential minerals, suggests that the Asama parental magma was moderately enriched in plagioclase and clinopyroxene components in the normative mineral diagram plagioclase-clinopyroxene-orthopyroxene. It was similar to a Hawaiian tholeiite and different from the Bushveld and Great “Dyke” parental magmas that were more enriched in orthopyroxene component; it also differed from mid-oceanic ridge basalts that are more depleted in the orthopyroxene component. The Asama clinopyroxene and chromite show characteristically high TiO₂ contents and are also similar to those in Hawaiian tholeiites. The Asama igneous complex probably resulted from the crystallization of a magma of a Hawaiian (oceanic-island) tholeiite composition and formed in an oceanic island regime.     

Comprehensive chemical analyses of natural cordierites: implications for exchange mechanisms

Cordierite samples from pegmatites and metamorphic rocks have been analysed for major [electron microprobe analysis (EMPA)] and trace elements [inductively coupled plasma mass spectrometry (ICP-MS), secondary ion mass spectrometry analyses (SIMS)] as well as for H₂O and CO₂ (coulometric titration), and the results evaluated in conjunction with published data in order to determine which exchange mechanisms are significant. Apart from the homovalent substitutions FeMg₋₁ and MnMg₋₁ on the octahedral site, some minor KNa₋₁ on the Ch0 channel site, and Fe³⁺Al₋₁ on the T₁1 tetrahedral site, the three most important substitution mechanisms are those for the incorporation of Li on the octahedral sites (NaLi□₋₁Mg₋₁), and of Be and other divalent cations on the tetrahedral T₁1 site (NaBe□₋₁Al₋₁ and Na(Mg,Fe²⁺)□₋₁Al₋₁). The dominant role of the last vector is clearly demonstrated. We propose a new generalized formula for cordierite: ^Ch(Na,K)_0–1 ^VI(Mg,Fe²⁺,Mn,Li)₂ ^IVSi₅ ^IVAl₃ ^IV(Al, Be, Mg, Fe²⁺, Fe³⁺)O₁₈ *x^Ch(H₂O, CO₂…). Our results show that the population of (Mg, Fe²⁺) on the T₁1-site is limited to about 0.08 a.p.f.u. Other exchange mechanisms that were encountered in experiments operate only under P–T conditions or in bulk compositions that are rarely realized in nature. Routine analyses by electron microprobe in which Li and Be are not determined can be plotted as (Mg+Fe+Mn) versus (Si+Al) to assess whether significant amounts of Li and Be could be present. These amounts can be calculated as Li (a.p.f.u.)=Al+Na–4 and Be (a.p.f.u.)=10–2Al–M²⁺–Na.     

重金属污染土壤修复的Pb2+钝化产物稳定性

自然状态下土壤中重金属元素是否稳定存在是重金属污染固化修复技术中的核心问题。本文以常见重金属离子Pb²⁺为例,分析土壤中重金属离子与常见离子基团结合的稳定性。将第一性原理应用于Pb的存在形态和稳定性的分析,计算了PbCO₃、PbSO₄、PbCl₂、Pb₃（PO₄）₂、PbAl₂O₄和Pb₃Fe₂（PO₄）₄的自由能、能带和态密度。首先推断Pb²⁺和CO₃^2-、SO₄^2-、Cl^-、PO₄^3-等土壤中常见阴离子的结合稳定性,再判断加入金属阳离子Al³⁺和Fe³⁺对体系稳定性的影响。结果表明：铅化合物自由能从高到低趋势为PbCl₂、PbAl₂O₄、PbCO₃、PbSO₄、Pb₃（PO₄）₂、Pb₃Fe₂（PO₄）₄,其相应的结构稳定性顺序从大到小为Pb₃Fe₂（PO₄）₄、Pb₃（PO₄）₂、PbSO₄、PbCO₃、PbAl₂O₄、PbCl₂。通过对能带和态密度的分析,首先确定了SO₄^2-和PO₄^3-的引入能够增强含Pb体系的稳定性,进一步加入金属阳离子Fe³⁺会使体系更稳定。推测SO₄^2-、PO₄^3-为治理Pb²⁺污染合适的官能团,应选择容易释放SO₄^2-、PO₄^3-的物质作为合适的钝化剂。在实际应用中可选择磷酸二氢钠、无水硫酸钠、脱硫石膏等作为钝化剂。     

Petrology and geochemistry of shoshonitic plutons from the western Kunlun orogenic belt, Xinjiang, northwestern China: implications for granitoid geneses

A series of granitoids from Proterozoic to Cenozoic age occurred in the western Kunlun orogenic belt, Xinjiang, northwestern China. Several intrusions such as the West Datong (Middle Caledonian age), North Kuda (Late Caledonian age) and Kuzigan, Karibasheng, Zankan (Himalayan age) plutons have shoshonitic affinity. Their rock assemblages include (quartz) monzodiorite–(quartz) monzonite–quartz syenite (Middle Caledonian) or monzonitic granite–granite (Late Caledonian) or biotite (monzonitic) granite–diopside granite–diopside syenite (Himalayan). Generally, biotite is iron–phlogopite, with some eastonite and high Mg/(Mg+Fe_T) and Fe³⁺/Fe²⁺ ratio. Amphibole is mainly edenitic hornblende and magnesian hastingsitic hornblende, with some edenite and higher Mg/(Mg+Fe_T) and Fe³⁺/Fe²⁺ ratio. The rocks show SiO₂ contents of 52.77–71.85% and high K₂O+Na₂O (mostly >8%, average 9.14%), K₂O/Na₂O (mostly >1, average 1.50) and Fe₂O₃/FeO (0.85–1.51, average 1.01) and low TiO₂ contents (0.15–1.12%, average 0.57%). Al₂O₃ contents (13.01–19.20%) are high but variable. The granitoids are prominently enriched in LILE, LREE and volatiles such as F. However, the studied shoshonitic granitoids among the three intrusive periods also show differences in isotopic compositions and trace element concentrations, suggesting their different geneses: the origin of the West Datong pluton is probably related to the involvement of subducted oceanic crust sediments into the mantle source; the North Kuda and Himalayan plutons could have been generated by partial melting of subducted oceanic crust sediments or metasediments of thickened continental lower crust in the process of late-orogenic slab break-off or lithospheric thinning.     

A proton- and electron-microprobe study of gallium, nickel and zinc distribution in chromian spinel

Chromian spinels from a number of localities were analyzed by proton and electron microprobes to examine the variation of trace elements in different geological environments. Chromian spinels studied include those representing ophiolitic complexes, layered intrusions in continental areas, Alaskan-type complexes, komatiitic subvolcanic sills, Ni sulfide ores and metamorphosed mafic and ultramafic rocks.

Nickel concentrations range from 30 to 4690 ppm (proton microprobe), with a mean value of 943 ppm. Nickel, favouring the octahedral sites in the spinel structure, displays an overall increase with a decrease in the Cr/(Cr + Al + Fe³⁺) ratio. Nickel partitioning between chromian spinel and mantle silicates appears to be primarily dependent upon the major element composition of the chromian spinel.

Zinc concentrations range from 230 to 9810 ppm (proton microprobe), with a cluster around 500 ppm. Ophiolitic chromian spinels display the lowest overall Zn values. Zinc levels appear to discriminate between chromian spinels in chromitite samples from those occurring as accessory chromian spinel in dunites or other rock types. Chromian spinels that are enclosed in or adjacent to sulfide grains display higher concentrations of Zn. Zinc, strongly favouring the tetrahedral sites, displays a crude negative correlation with the Mg/(Mg + Fe²⁺) ratio and appears to vary as a function of temperature.

All the chromian spinel grains analyzed contain measurable quantities of Ga by proton microprobe, ranging from 10 to 208 ppm. There is a reciprocal relationship between the Ga concentration and the Cr/(Cr +Al + Fe³⁺) ratio and a crude positive correlation between the Ni and Ga concentrations. Measured Ga concentrations in chromian spinel and whole rock samples are supportive of the experimental mineral-melt partition coefficient of Malvin and Drake (1987). Similar to the peridotite xenoliths, mid-ocean ridge basalts and oceanic-island basalts, Ga correlates well with Al₂O₃ in the case of the ophiolitic chromian spinels and most of those representing layered complexes. The ophiolitic chromian spinels seem to have crystallized from melts whose compositions are similar to those of partial melts of the upper mantle.     

利用碳酸盐岩的Fe/Mn比值恢复海洋的氧化还原状态

碳酸盐岩的Fe/Mn元素比值,作为一项新的地球化学指标,可以用于恢复海洋的氧化还原状态.在氧化条件下,Fe³⁺和Mn⁴⁺均不可溶,因此氧化海水中的溶解Fe和Mn的含量均很低.Fe³⁺和Mn⁴⁺在还原条件下可以被细菌还原为可溶的Fe²⁺和Mn²⁺,而氧化还原电位的计算表明,Mn⁴⁺的还原要早于Fe³⁺的还原,因此细菌的Mn还原过程发生在沉积物的更浅层.可溶的Fe²⁺和Mn²⁺向上扩散到海水中,替代碳酸盐岩晶格里的Ca²⁺,因此碳酸盐岩晶格中的Fe²⁺和Mn²⁺的含量受控于来自沉积物孔隙水的扩散,而后者又与水岩界面的氧化还原状态相关.因此可以预测,随着海水变得逐渐缺氧,碳酸盐岩中的Fe/Mn比值会逐渐增高.为了验证这一假说,我们分析了中元古代高于庄组白云岩的Fe/Mn比值.研究发现,几乎所有的样品的Fe/Mn比值介于20～30之间,显著高于泥盆纪末期深水碳酸盐岩和浅水台地碳酸盐岩的Fe/Mn比值.高于庄组碳酸盐岩高的Fe/Mn比值一方面可能指示了中元古代低的大气氧气浓度和海洋的广泛缺氧,也可能反映了白云岩形成于缺氧的沉积物空隙水里.     

湘南道县辉长岩包体的锆石LA-ICP-MS定年、Hf同位组成及其地质意义

道县虎子岩碱性玄武岩筒产出较多的辉长岩包体。用于锆石定年的辉长岩样品的岩石化学特征显示：其K₂O、Fe₂O₃、TiO₂高于其他同类样品,稀土元素、微量元素总量也相对较高,样品的K^*值（2K_N/（Ta_N+La_N））为7.60>1,显示岩浆具有亲岛弧性质,反映源区地幔受到较强的交代作用;Nb^*值（2 Nb_N/（K_N+La_N））为0.11<1,反映基性岩浆侵入时受到了地壳混染;辉长岩中的锆石具有清晰的韵律环带,Th/U值=0.91~4.35,具有岩浆锆石的特征;锆石²⁰⁶Pb/²³⁸U加权平均年龄为（201.50±0.53）Ma,代表了辉长岩的结晶年龄;ε_Hf （t）值为-0.88~4.45,投点落入球粒陨石附近,暗示强烈的壳幔交换作用;Hf模式年龄平均为751 Ma,反映早期地壳对岩石源区的贡献。Hf同位素组成特征反映辉长质岩浆是在印支晚期局部拉张背景下,岩石圈上地幔上隆减压熔融的产物。     

Micro-XANES determination of ferric iron and its application in thermobarometry

Micro-X-ray absorption near-edge structure (XANES) analysis was employed to determine the content of ferric iron in minerals formed in ultrahigh-pressure (UHP) eclogites. It is observed that omphacite and phengite contain significant amounts of Fe³⁺/Fe_tot (0.2–0.6), whereas only very low contents are present in garnet (Fe³⁺/Fe_tot=0.0–0.03), the latter being consistent with results from stoichiometric charge-balance calculations. Furthermore, considerable variations in the Fe³⁺/Fe_tot ratios of omphacite and phengite are observed depending on the textural sites and local bulk chemistry (eclogite and calc-silicate matrix) within one thin section. The oxidation state of isofacial minerals is thus likely to depend on the local fluid composition, which, in the studied case, is controlled by calcareous and meta-basic mineral compositions. These first in-situ measurements of ferric iron in an eclogite sample from the Dabie Shan, E China, are used to recalculate geothermobarometric data. Calculations demonstrate that the temperature during UHP metamorphism was as high as 780 °C, about 80–100 °C higher than previously estimated. Temperatures based on charge balance calculations often give erroneous results. Pressure estimates are in good agreement with former results and confirm metamorphism in the stability field of diamond (43.7 kbar at 750 °C). These P–T data result in a geothermal gradient of ca. 6 °C/km during UHP metamorphism in the Dabie Shan. However, accounting for ferric iron contents in geothermobarometry creates new difficulties inasmuch as calibrations of geothermometers may not be correctable for Fe³⁺ and the actual effect on Mg–Fe²⁺ partitioning is unknown. The present study further shows that micro-XANES is a promising technique for the in situ determination of ferric iron contents without destroying the textural context of the sample: a clear advantage compared to bulk methods.     

The Gaojiacun Mafic-Ultramafic Complex （Sichuan, SW China）：Neoproterozoic Magmatic Activity at the Western Margin of the Yangtze Craton

1 Introduction The Gaojiacun intrusive complex is one of the numerous ultramafic-mafic intrusions in Sichuan Province of China. It was mapped during the 1970s and studied mainly by Chinese scientists (e.g. Geological Team 106, 1975; Shen et al., 1986, 1989; CGGJC, 1986; Yang et al., 1993; Li et al., 1995; Shen et al., 2003; Zhu et al., 2004a). Since the year 2000, China has become one of the largest PGE consumers. While the country can produce only less than 1 ton PGE/year, the Chin…