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1.
This paper uses the momentum--space optical potential method to calculate the e--H2O scattering elastic cross sections at the energy range from 6 eV to 50 eV, and the differential cross sections in the angle from 0° to 180° at 40 eV and 50 eV. The polarisation is taken into account via an emphab initio equivalent-local potential. The cross sections are compared with experimental measurements and other theoretical calculations.  相似文献   

2.
Geometry and vibrational frequencies of the ground state of Si2O2 molecule are studied using density function theory (DFT) at the level of cc-pvtz and 6-311++G**. It is found that the optimizing value by B3lyp/cc-pvtz is closer to the experimental data. The excited properties under different external electric fields are also investigated by the time-dependent-DFT method. Transitions from the ground state of Si2O2 molecule to the first singlet state under different external electric fields can take place more easily. The corresponding absorption spectral line is about 360 nm in wavelength and the excitation energy is about 3.4 eV.  相似文献   

3.
掺铝氧化锌厚膜制备及其对三甲胺和海产品鲜度的敏感性   总被引:2,自引:0,他引:2  
用烧结法制备掺铝氧化锌厚膜,把氧化锌粉末分别同0%,1%,3%,5%的Al2O3粉末机械研磨混合均匀,在1100℃下烧3h,再同粘合剂,有机溶剂混合制成浆料,用刮刀法在氧化铝基片上浆料制成膜,在100℃下烘干后再经1100℃烧结2h。膜的灵敏度的测量方法是将膜放在玻璃管内加热到测量温度,测量膜暴露在一定浓度TMA气体或由牡蛎放出的气体时电阻值的变化。测量温度为200,250,300℃和400℃,T  相似文献   

4.
Partial pressure of CO2 in surface sea water (pCO2) was measured continuously off Sanriku in May, 1997 by a new pCO2 measurement system. We have examined the relation of pCO2 to physical factors such as temperature, salinity and density, chemical and biological factors such as nutrients and carbonate system and chlorophylla. In the Kuroshio region pCO2 was not correlated to physical, chemical and biological factors in the range of 260 to 290 μatom. In transition water (Tr1) between Kuroshio and the Oyashio second branch, pCO2 was weakly correlated to physical factors and strongly correlated to nutrients. In transition water (Tr2) between the Oyashio first and second branches, pCO2 was highly correlated to temperature (SD: 10.9 μatom) and salinity (SD: 8.6 μatom) and also to nutrients. In transition water (Tr1+Tr2), pCO2 was highly multivariately correlated to temperature (T), salinity (S), chlorophylla (CH) (or nitrate+nitrite (N)) as follows, pCO2(μatom)= 10.8×T(°C)+27.7×S+2.57CH(μg/1) −769, R2= 0.86, SD = 20.9, or pCO2(μatom)= 3.9×T(°C)+25.5×S+16.0NO3(μM) −686, R2= 0.99, SD = 6.4. Moreover, pCO2 was predicted by only two factors, one physical (S) and the other chemical/biological (N) as follows: pCO2 (μatom)=32.8×S+19.4N−908, R2=0.97, SD=8.4. The pH measured at 25°C was well correlated with normalized pCO2 at a fixed temperature. In the Oyashio region pCO2 was decreased to 160 μatom, probably because of spring bloom, but was not correlated linearly to chlorophylla. The results obtained showed the possibility of estimating pCO2 of the Oyashio and transition regions in May by satellite remote sensing of SST, but the problem of estimation of pCO2 in Kuroshio water remains to be solved.  相似文献   

5.
This paper calculates the structural parameters, electronic and optical properties of orthorhombic distorted perovskite-type TbMnO3 by first principles using density functional theory within the generalised gradient approximation. The calculated equilibrium lattice constants are in a reasonable agreement with theoretical and experimental data. The energy band structure, density of states and partial density of states of elements are obtained. Band structures show that TbMnO3 is an indirect band gap between the O 2p states and Mn 3d states, and the band gap is of 0.48 eV agreeing with experimental result. Furthermore, the optical properties, including the dielectric function, absorption coefficient, optical reflectivity, refractive index and energy loss spectrum are calculated and analysed, showing that the TbMnO3 is a promising dielectric material.  相似文献   

6.
In the east of China's seas, there is a wide range of the continental shelf. The nutrient cycle and the carbon cycle in the east of China's seas exhibit a strong variability on seasonal to decadal time scales. On the basis of a regional ocean modeling system(ROMS), a three dimensional physical-biogeochemical model including the carbon cycle with the resolution(1/12)°×(1/12)° is established to investigate the physical variations, ecosystem responses and carbon cycle consequences in the east of China's seas. The ROMS-Nutrient Phytoplankton Zooplankton Detritus(NPZD) model is driven by daily air-sea fluxes(wind stress, long wave radiation, short wave radiation, sensible heat and latent heat, freshwater fluxes) that derived from the National Centers for Environmental Prediction(NCEP) reanalysis2 from 1982 to 2005. The coupled model is capable of reproducing the observed seasonal variation characteristics over the same period in the East China Sea. The integrated air-sea CO_2 flux over the entire east of China's seas reveals a strong seasonal cycle, functioning as a source of CO_2 to the atmosphere from June to October, while serving as a sink of CO_2 to the atmosphere in the other months. The 24 a mean value of airsea CO_2 flux over the entire east of China's seas is about 1.06 mol/(m~2·a), which is equivalent to a regional total of3.22 Mt/a, indicating that in the east of China's seas there is a sink of CO_2 to the atmosphere. The partial pressure of carbon dioxide in sea water in the east of China's seas has an increasing rate of 1.15 μatm/a(1μtm/a=0.101 325Pa), but p H in sea water has an opposite tendency, which decreases with a rate of 0.001 3 a~(–1) from 1982 to 2005.Biological activity is a dominant factor that controls the pCO_2 air in the east of China's seas, and followed by a temperature. The inverse relationship between the interannual variability of air-sea CO_2 flux averaged from the domain area and Ni?o3 SST Index indicates that the carbon cycle in the east of China's seas has a high correlation with El Ni?o-Southern Oscillation(ENSO).  相似文献   

7.
Stage C5 copepodids and adult females of the herbivorous copepod Calanoides carinatus were sampled in the Angola-Benguela frontal region and northern Benguela upwelling area off Namibia in February–March 2002, using a multiple opening/closing net system. Respiration rates of C5s collected between 400m and 700m were measured onboard at the simulated in situ temperature of 8°C and at sea surface temperature (SST ≥20°C). These data were compared to the oxygen demand of epipelagic individuals of C. carinatus caught in the upper 30m and incubated at ambient SST. Deep-living C5s consumed 0.21 ± 0.08ml O2 h?1 (g dry mass)?1 at 8°C and 0.96ml O2 h?1 (g dry mass)?1 (range 0.84–1.09) at 25.9°C. These results were substantially lower than respiration rates of 5.23 ± 0.55ml O2 h?1 (g dry mass)?1 in epipelagic individuals incubated at SST. The results reveal a reduction by 96% of metabolic rate in deep-living, diapausing C5s relative to surface-dwelling, active individuals. Only 14.4% of this metabolic reduction is explained by the lower ambient temperature at depth and a Q10 value of 2.34. Therefore, the major fraction (81.6%) of the metabolic reduction is attributable to active physiological changes or processes during diapause at depth. The study emphasises the importance for herbivorous copepods, in areas with a highly variable food supply, to adopt a dormant phase in their life cycle in order to survive long periods of starvation.  相似文献   

8.
Concentration and stable isotopic compositions (δ 18O) of dissolved O2 were measured in seawater samples collected from the Philippine Sea in June 2006. The in-situ O2 consumption rate and the isotopic fractionation factor (α r ) during dissolved O2 consumption were obtained from field observations by applying a vertical one-dimensional advection diffusion model to the deep water mass of about 1000–4000 m. The average O2 consumption rate and α r were, respectively, 0.11 ± 0.07 μmol kg−1yr−1 and 0.990 ± 0.001. These estimated values agree well with values from earlier estimations of Pacific deep water. The in-situ O2 consumption rates are two or more times higher north of 20°N, although the value of α r was not significantly different between the north and south. Its levels varied rapidly in the water mass of less about 2000 m depth. These results suggest that organic matter from the continent imparts a meaningful contribution to the upper water in the northern part of the area; it might produce the strong O2 minimum that is evident in the water mass from about 1000–2000 m in the northern part of the Philippine Sea.  相似文献   

9.
The generalised gradient approximation based on density functional theory is used to study the structural and electronic properties of the endohedral fullerene dimer (N2@C60)2. Four N atoms sit at the cage centres in the form of two N_2 molecules. The density of states and Mulliken charge analysis explore that the energy levels from -6 to -10 eV are mainly influenced by the N2 molecules.  相似文献   

10.
Rates of respiration and ammonia excretion of Euphausia hanseni and Nematoscelis megalops were determined experimentally at four temperatures representative of conditions encountered by these euphausiid species in the northern Benguela upwelling environment. The respiration rate increased from 7.7 µmol O2 h?1 gww ?1 at 5 °C to 18.1 µmol O2 h?1 gww ?1 at 20 °C in E. hanseni and from 7.0 µmol O2 h?1 gww ?1 (5 °C) to 23.4 µmol O2 h?1 gww ?1 (20 °C) in N. megalops. The impact of temperature on oxygen uptake of the two species differed significantly. Nematoscelis megalops showed thermal adaptations to temperatures between 5 °C and 10 °C (Q10 = 1.9) and metabolic constraint was evident at higher temperatures (Q10 = 2.6). In contrast, E. hanseni showed adaptations to temperatures of 10–20 °C (Q10 = 1.5) and experienced metabolic depression below 10 °C (Q10 = 2.6). Proteins were predominantly metabolised by E. hanseni in contrast to lipids by N. megalops. Carbon demand of N. megalops between 5 and 15 °C was lower than in E. hanseni versus equal food requirements at 20 °C. It is concluded that the two species display different physiological adaptations, based on their respective temperature adaptations, which are mirrored in their differential vertical positioning in the water column.  相似文献   

11.
A vertically integrated dynamic ice sheet model is coupled to the atmosphere-ocean-sea ice-land surface climate model recently developed by Wang and Mysak (2000). The background lateral (east-west) ice sheet discharge rate used by Gallee et al. (1992) is reduced and the planetary emissivity is increased (to parameterize the cooling effect of a decrease of the atmospheric CO2 concentration), in order to build up substantial ice sheets during a glacial period and hence set the stage for ice sheet-thermohaline circulation (THC) interactions. The following iceberg calving scheme is then introduced: when the maximum model height of the North American ice sheet reaches a critical value (2400 m), a prescribed lateral discharged rate is imposed on top of the background discharge rate for a finite time. Per a small prescribed discharge rate, repeated small iceberg calving events occur, which lead to millennial-scale climate cycles with small amplitudes. These are a crude representation of Dansgaard-Oeschger oscillations. Over one such cycle, the zonally averaged January surface air temperature (SAT) drops about 1.5°C at 72.5°N. However, a large prescribed lateral discharge rate leads to the shut down of the THC. In this case, the January SAT drops about 5°C at 72.5°N, the sea ice extent advances equatorward from 57.5° to 47.5°N and the net ice accumulation rate at the grid of maximum ice sheet height is reduced from 0.24 to 0.15 m/y. Since data strongly suggest that a collapsed THC was not a steady state during the last glacial, we restore the THC by increasing the vertical diffusivity in the North Atlantic Ocean for a finite time. The resulting climate cycles associated with conveyor-on and conveyor-off phases have much larger amplitudes; furthermore, the strong iceberg calving events lead to a larger loss of ice sheet mass and hence the period of the oscillations is longer (several thousand years). This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

12.
基于海洋环流模式POP和生物地球化学模型OCMIP-2,建立了全球海洋碳循环模式,并用于对全球海洋碳循环的模拟研究。该模式在大气CO2为283×10-6条件下,积分3 100 a,达到工业革命前的平衡态。在此基础上,用历史时期观测的大气CO2浓度进行强迫,模拟了历史时期的海洋碳循环。模拟的无机碳浓度、总碱度与基于观测得到的结果基本一致,模式能够较好地模拟全球碳循环过程。模拟结果表明,在北半球中高纬度和南半球的中纬度,海洋是大气CO2的主要汇区;在赤道南北纬20°之间和南大洋50°S以南,海洋表现为大气CO2的源区。在1980s海洋吸收CO2速率(以C计)为1.38 Pg/a,1990s为1.55 Pg/a。海洋中人为碳在北大西洋含量最大,向下到达海底并向南输运到30°N附近;在南极附近,浓度较小,深度达到3 000 m;在中纬度,人为碳被限制在温跃层以上。  相似文献   

13.
Shells of the rocky shore intertidal gastropod Osilinus turbinatus (von Born), often abundant in archaeological deposits in the Mediterranean region, are a potential source of data on palaeotemperature, palaeoseasonality and archaeological seasonality. To evaluate this species as a climate archive, investigations of annual patterns of shell growth and of monthly variations in oxygen isotopes in shell carbonates were made on different populations in NW Sicily. Mark-recapture experiments at San Vito lo Capo and Mazzaforno show that O. turbinatus grows almost continuously throughout the year but at different rates in different seasons. Around 75% of the yearly shell growth occurs in the autumn and winter. On average, larger/older shells produce narrower annual growth increments than smaller/younger ones. Conspicuous growth lines in larger/older shells show that growth stops during the hottest part of the summer. Oxygen isotope analyses on monthly collected shells of O. turbinatus from three shores (Cala Grande, Monte Cofano and Mazzaforno) show that the isotope values record temperature variations through the year. In all the datasets, surface seawater temperatures (SSTs) calculated from δ18OSHELL mostly underestimate measured SSTs, offsets being generally greater in summer. Minimum annual offsets range from 0.0°C to 0.7°C and maximum annual offsets from 3.1°C to 8.7°C. δ18OSHELL values fail to record temperatures higher than 25°C. Careful selection of shells to be analysed can reduce offsets between δ18OSHELL temperature estimates and measured SSTs for many parts of the year, except the hottest. Allowing for this, shells of O. turbinatus offer good potential as climate archives and for archaeological studies of seasonal patterns of human foraging for shellfish.  相似文献   

14.
The natural gas generation process is simulated by heating source rocks of the Yacheng Formation, including the onshore-offshore mudstone and coal with kerogens of Type II_2-III in the Qiongdongnan Basin. The aim is to quantify the natural gas generation from the Yacheng Formation and to evaluate the geological prediction and kinetic parameters using an optimization procedure based on the basin modeling of the shallow-water area. For this, the hydrocarbons produced have been grouped into four classes(C_1, C_2, C_3 and C_(4-6)). The results show that the onset temperature of methane generation is predicted to occur at 110℃ during the thermal history of sediments since 5.3 Ma by using data extrapolation. The hydrocarbon potential for ethane, propane and heavy gaseous hydrocarbons(C_(4-6)) is found to be almost exhausted at geological temperature of 200℃ when the transformation ratio(TR) is over 0.8, but for which methane is determined to be about 0.5 in the shallow-water area. In contrast, the end temperature of the methane generation in the deep-water area was over 300℃ with a TR over 0.8. It plays an important role in the natural gas exploration of the deep-water basin and other basins in the broad ocean areas of China. Therefore, the natural gas exploration for the deep-water area in the Qiongdongnan Basin shall first aim at the structural traps in the Ledong, Lingshui and Beijiao sags, and in the forward direction of the structure around the sags, and then gradually develop toward the non-structural trap in the deep-water area basin of the broad ocean areas of China.  相似文献   

15.
A time-series sediment trap was deployed from December 1994 to February 2002 at the mouth of Tokyo Bay (35°03′ N, 139°40′ E; water depth, 850 m). Sinking particles were obtained with a time interval of one week at a depth of approximately 100 m above the sea floor. Observed total mass fluxes varied from 3.3 to 226.7 g/m2/day with an average of 28.0 g/m2/day. Concentrations of rare earth elements, Al, Ca and Si in particulate materials were measured. The combustible fraction at 450°C is assumed to be equivalent to the organic matter content. Contents of biogenic materials, namely organic matter, opal and calcium carbonate, were about 30% and the content of lithogenic material was about 70%. Using La/Yb ratios of particles from the sediment trap and Tama-gawa River and surface sediment of Tokyo Bay, it was estimated that about 50% of the lithogenic particles collected in the sediment trap at the mouth of Tokyo Bay originated from resuspended surface sediment in Tokyo Bay. An increasing trend of Opal/CaCO3 ratio in the sinking particles was found in the spring season. It is suggested that the relative increase of diatoms is due to the decreasing dissolved inorganic nitrogen input into Tokyo Bay.  相似文献   

16.
汪金涛  陈新军  高峰  雷林 《海洋与湖沼》2014,45(6):1185-1191
东南太平洋茎柔鱼(Dosidicus gigas)是短生命周期种类,其资源量极易受到海洋环境变化的影响。根据2003—2012年我国鱿钓船在东南太平洋的生产统计数据,以及茎柔鱼栖息地的海表温度(SST)、海面高度(SSH)、叶绿素a浓度(chl a)数据,利用相关性分析法分析茎柔鱼资源丰度和补充量(以单位捕捞努力量渔获量为指标,t/d)与栖息海域20°S—20°N、110°W—70°W的SST、SSH、chl a浓度的相关性,获取相关系数大的关键海区位置,同时加入茎柔鱼产卵场、索饵场最适表层水温范围占总面积的比例(分别用PS、PF表示)两个参数,建立三种基于主要环境因子的误差反向传播(EBP)神经网络资源补充量预报模型,进行了比较。结果表明:茎柔鱼资源丰度与SST、SSH、chl a浓度的相关系数最大值海域为7月份的Point1(13°N,102°W)海区、9月份的Point3(11°N,102°W)海区和3月份的Point5(8°S,107°W)海区;资源补充量与SST、SSH、chl a浓度的相关系数最大值海域为6月份的Point2(8°N,103.5°W)海区、2月份的Point4(12°N,97.5°W)海区和10月份的Point6(10°S,93.5°W)海区。EBP神经网络预报模型结果认为:基于产卵环境关键影响因子的方案2(以Point2的SST、Point4的SSH、Point6的chl a浓度、PS作为模型输入因子)和基于全部环境关键影响因子的方案3(以Point1与Point2的SST、Point3与Point4的SSH、Point5与Point6的chl a浓度、PS、PF作为模型输入因子)的两种神经网络预报模型均方误差较小,其准确率可达90%左右。  相似文献   

17.
We investigated marine and terrestrial environmental changes at the northern Japan margin in the northwestern Pacific during the last 23,000 years by analyzing biomarkers (alkenones, long-chain n-alkanes, long-chain n-fatty acids, and lignin-derived materials) in Core GH02-1030. The U 37K′-derived temperature in the last glacial maximum (LGM) centered at 21 ka was ∼10°C, which was 2°C lower than the core-top temperature (∼12°C). This small temperature drop does not agree with pollen evidence of a large air temperature drop (more than 4°C) in the Tokachi area. This disagreement might be attributed to a bias of U 37K′-derived temperature within 2.5°C by a seasonal shift in alkenone production. The U 37K′-derived temperature was significantly low during the last deglaciation. Because this cooling was significant in the Kuroshio-Oyashio transition zone, the temperature drops are attributable to the southward displacement of the Kuroshio-Oyashio boundary. Abundant lignin-derived materials, long-chain n-alkanes and long-chain n-fatty acids indicate a higher contribution of terrigenous organic matter from 17 to 12 ka. This phenomenon might have resulted from an enhanced coastal erosion of terrestrial soils due to marine transgression and/or an efficient inflow of higher plant debris to river waters from 17 to 12 ka.  相似文献   

18.
The third Chinese National Arctic Research Expedition(CHINARE) was conducted in the summer of 2008.During the survey,the surface seawater partial pressure of CO_2(pCO_2) was measured,and sea water samples were collected for CO_2 measurement in the Canada Basin.The distribution of pCO_2 in the Canada Basin was determined,the influencing factors were addressed,and the air-sea CO_2 flux in the Canada Basin was evaluated.The Canada Basin was divided into three regions:the ice-free zone(south of 77°N),the partially ice-covered zone(77°–80°N),and the heavily ice-covered zone(north of 80°N).In the ice-free zone,pCO_2 was high(320 to 368μatm,1 μatm=0.101 325 Pa),primarily due to rapid equilibration with atmospheric CO_2 over a short time.In the partially ice-covered zone,the surface pCO_2 was relatively low(250 to 270 μatm) due to ice-edge blooms and icemelt water dilution.In the heavily ice-covered zone,the seawater pCO_2 varied between 270 and 300 μatm due to biological CO_2 removal,the transportation of low pCO_2 water northward,and heavy ice cover.The surface seawater pCO_2 during the survey was undersaturated with respect to the atmosphere in the Canada Basin,and it was a net sink for atmospheric CO_2.The summertime net CO_2 uptake of the ice-free zone,the partially ice-covered zone and the heavily ice-covered zone was(4.14±1.08),(1.79±0.19),and(0.57±0.03) Tg/a(calculated by carbon,1Tg=10~(12) g),respectively.Overall,the net CO_2 sink of the Canada Basin in the summer of 2008 was(6.5±1.3) Tg/a,which accounted for 4%–10% of the Arctic Ocean CO_2 sink.  相似文献   

19.
This paper evaluates whether a thermodynamic ocean-carbon model can be used to predict the monthly mean global fields of the surface-water partial pressure of CO2 (pCO2SEA) from sea surface salinity (SSS), temperature (SST), and/or nitrate (NO3) concentration using previously published regional total inorganic carbon (CT) and total alkalinity (AT) algorithms. The obtained pCO2SEA values and their amplitudes of seasonal variability are in good agreement with multi-year observations undertaken at the sites of the Bermuda Atlantic Timeseries Study (BATS) (31°50’N, 60°10’W) and the Hawaiian Ocean Time-series (HOT) (22°45’N, 158°00’W). By contrast, the empirical models predicted CT less accurately at the Kyodo western North Pacific Ocean Time-series (KNOT) site (44°N, 155°E) than at the BATS and HOT sites, resulting in greater uncertainties in pCO2SEA predictions. Our analysis indicates that the previously published empirical CT and AT models provide reasonable predictions of seasonal variations in surface-water pCO2SEA within the (sub) tropical oceans based on changes in SSS and SST; however, in high-latitude oceans where ocean biology affects CT to a significant degree, improved CT algorithms are required to capture the full biological effect on CT with greater accuracy and in turn improve the accuracy of predictions of pCO2SEA.  相似文献   

20.
为了解自末次间冰期以来这一地区的古海水表层温度变化,应用气相色谱技术对取自冲绳海槽东侧的Z14?6孔的长链(C37)不饱和烯酮进行了分析。结果发现,该孔Uk37在0.83—0.95之间,其变化趋势与两种浮游有孔虫N.dutertrei和G.sacculifer的氧同位素组成一致。根据Uk37重建的SST在24.0—27.5℃之间变化,最高值27.5℃出现在MIS-5,最低值24℃出现在MIS-2(LGM)。从LGM到全新世SST增加约2℃。这与早期在附近地区根据Uk37重建的SST变化趋势一致。根据重建的SST自LGM以来的变化,作者认为现代黑潮洋流系统最晚在约10kaB.P.后已在冲绳海槽重新建立。许多早期研究揭示的黑潮在7.5—7kaB.P.的加强可能与全新世大暖期有关。  相似文献   

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