Evaluation of gas production rates in some comets

Emission fluxes of CN, C₂ and C₃ carbon-bearing molecular species observed in the coma of comets Bennett (1969i 1970II), West (1975n 1976VI), P Halley (1982i), Hartley-Good (19851) and Bradfield (1987s) are analysed in the framework of Haser model. CN, C₂ and C₃ production rates are determined using recently derived fluorescence efficiencies. The dependence of CN, C₂ and C₃ production rates on the heliocentric distance and the possible correlations among these radicals is studied and briefly discussed.     

The origin of the CN radical in comets: A review from observations and models

The origin of CN radicals in comets is not completely understood so far. We present a study of CN and HCN production rates and CN Haser scale lengths showing that: (1) at heliocentric distances larger than 3 AU, CN radicals could be entirely produced by HCN photolysis; (2) closer to the Sun, for a fraction of comets CN production rates are higher than HCN ones whereas (3) in the others, CN distribution cannot be explained by the HCN photolysis although CN and HCN production rates seem to be similar. Thus, when the comets are closer than 3 AU to the Sun, an additional process to the HCN photolysis seems to be required to explain the CN density in some comets.The photolysis of HC₃N or C₂N₂ could explain the CN origin. But the HC₃N production rate is probably too low to reproduce CN density profile, even if uncertainties on its photolysis leave the place for all possible conclusions. The presence of C₂N₂ in comets is a reliable hypothesis to explain the CN origin; thus, its detection is a challenging issue. Since C₂N₂ is very difficult to detect from ground-based observations, only in situ measurements or space observations could determine the contribution of this compound in the CN origin.Another hypothesis is a direct production of CN radicals by the photo- or thermal degradation of complex refractory organic compounds present on cometary grains. This process could explain the spatial profile of CN inside jets and the discrepancy noted in the isotopic ratio ¹⁴N/¹⁵N between CN and HCN. Laboratory studies of the thermal and UV-induced degradation of solid nitrogenated compounds are required to model and validate this hypothesis.     

Haser model CN,C2 and C3 production rates in some comets

Emission fluxes of CN, C₂ and C₃ species observed in the coma of some comets are analysed in the framework of Haser model. CN, C₂ and C₃ production rates are determined using recently derived fluorescence efficiencies and dependence of CN, C₂ and C₃ production rates on the heliocentric distance is studied. Evidence for a burst type activity around January 15, 1974 in the post-perihelion period of comet Kohoutek (1973f) is observed.     

An analysis of spectrophotometric observations of comets Austin (1982g) and Bradfield (1980t)

Post-perihelion observed emission fluxes at 388 nm (CN) and 516 nm (C₂) of the coma of comets Austin (1982g) and Bradfield (1980t) are analysed in the framework of the Haser model. Ratios of Haser model CN and C₂ parent production rates with expansion velocity show that each comet behaves normally. For comet Austin (1982g), the Q _CN/v and Q _c2/v values decrease with increase of heliocentric distance of comet. For an assumed %; activity of the total spherical surface area of the nucleus, the water vaporization theory coupled with derived water production rates from the International Ultraviolet Explorer H and OH flux data yields a nuclear diameter of about 6 km for comet Austin (1982g). For comet Bradfield (1980t), the derived nuclear diameter is expected to be of about 1 km. In each comet, the dust mass production rates as well as ratio of dust-to-gas mass production rates decrease with increase of heliocentric distance of comet.     

A taxonomic survey of comet composition 1985-2004 using CCD spectroscopy

A summary is presented of our spectroscopic survey of comets extending for roughly 19 years from 1985 to 2004 comprising data for 92 comets of which 50 showed good emissions. All data were re-analyzed using consistent reduction techniques. Our observations of comets over several apparitions and comets observed over an extended period indicate no major changes in compositional classification. To our regret, no major unidentified cometary features were found in our surveyed spectral region of 5200-10400 Å. Absolute production rates for the dominant parent molecule H₂O and the daughter species C₂, NH₂ and CN are determined within the limits of the Haser model as are values for the dust continuum, Afρ. From these data, production rate ratios are calculated for C₂/H₂O, NH₂/H₂O, CN/H₂O and Afρ/H₂O. Excluding the odd Comets Yanaka (1988r), 43P/Wolf-Harrington and 19P/Borrelly, with unusual spectra, our set of comets exhibited relatively uniform composition. Detailed analyses of our data resulted in four taxonomic classes:

-

Comets of typical composition (∼70%); exhibiting typical ratios with respect to water of C₂, NH₂, and CN.

-

Tempel 1 type (∼22%); having a deficiency in C₂ but normal NH₂ abundance.

-

G-Z type (∼6%); having both low C₂ and NH₂ ratios.

-

The unusual object Yanaka (1988r) (∼2%?); no detectable C₂ or CN emission but normal NH₂.

It is uncertain whether there is a clear separation between the comets of typical composition and those with C₂ depletion, or whether the latter consists of a group showing a continuum of decreasing C₂/CN ratios. Our spectroscopic investigations result in a visual record of the various compositional classes, which are illustrated in a number of figures. Production rate comparisons with the comet photometry program of Schleicher and A'Hearn [A'Hearn, M.F., and 4 colleagues, 1995. Icarus 118, 223-270] for 13 comets in common yielded good agreement once the different scale lengths are taken into account. An investigation into the possible origin of our compositional groups with respect to dynamical families of comets shows that the Halley family exhibits essentially no C₂ depletion. These objects were presumably formed in the region of Saturn and Uranus and scattered into the Oort cloud. Comets formed in the space near Neptune, responsible for the scattered Kuiper Belt show a mixture of “typical” and C₂ depleted objects, while we associate comets formed in-situ in the classical Kuiper belt with our C₂ depleted group.     

A Multi-Wavelength Simultaneous Study of the Composition of the Halley Family Comet 8P/Tuttle

We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH₂ (0,9,0) 610 nm bands using UVES at UT2 we determined ¹²C/¹³C = 90 ± 10 and ¹⁴N/¹⁵N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH₃ of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C₃ and C₂ production rates and the parent and daughter scale lengths up to 5.2 10⁵ km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H₂O, HCN, C₂H₂, CH₄, C₂H₆, and CH₃OH.     

Comet classification with new methods for gas and dust spectroscopy

We present the results of a program of comet long-slit spectroscopy with the Kast Dual Spectrograph on the 3-m Shane Telescope at Lick Observatory. A total of 26 comets, from a variety of dynamical families, were observed on 39 different nights from 1996 to 2007. A new statistical method extracted the twilight sky from comet frames, because traditional sky subtraction techniques were inadequate. Because previously published Haser model parent and daughter scale lengths did not fit the data well, unbiased ranges of scale lengths were searched for the best-fitting pairs. Coma gas production rates for OH, CN, C₂, C₃, NH, NH₂, and OH confirmed the widely reported carbon-chain depletion for a sub-class of comets, most notably high-perihelion Jupiter-family comets observed at r_h > 1.5 AU, with different behaviors for C₂ and C₃. Our long-slit spectroscopy data was also adapted for the A(θ)fρ dust production parameter. The assumption that A(θ)fρ is constant throughout the nucleus was not upheld. High dust-to-gas ratios for comets with large perihelia were not a selection effect, and suggest that the dust was released earlier in the formation of the coma than the gas. The dust-to-gas ratio did not exhibit any evolutionary traces between different comet dynamical families. The comet survey illuminates the diversity among comets, including the unusually carbon poor Comet 96P/Machholz.     

Polarimetry and Photometry of Comet C/2004 Q2 (Machholz)

We present results of polarimetry and photometry of comet C/2004 Q2 (Machholz) obtained with the 0.7-m telescope of Institute of Astronomy at the Karazin Kharkiv National University on February 3 and 4, and March 4 and 14, 2005. The observations were carried out with a one-channel photoelectric photometer-polarimeter. The IHW continuum UC (λ3650/80 Å), BC (λ4845/65 Å), RC (λ6840/90 Å) and emission filters CN (λ3871/50 Å), C₃ (λ4060/70 Å), and C2 (λ5140/90 Å) were used. Degree of the comet polarization at phase angles ≈ 52° and ≈44° in the red continuum was close to that for so called dusty comets. The comet had a typical spectral gradient of polarization ΔP/Δλ=0.86% per 1000 Å. In the framework of the Haser model we have found the gas production rates Q of the CN, C₃ and C₂ species and the dust production rates Afρ on February 4 and March 14, 2005. The ratio log[Afρ (BC)/Q(CN)] was compared with data for other comets. The normalized spectral gradient of cometary dust S’(BC,RC) was 8.7%/1000 Å for February 4 and 17.0%/1000 Å for March 14. We conclude that comet C/2004 Q2 (Machholz) in many respects is a typical dusty comet.     

Vaporization in comets: The icy grain halo of comet west

The variation with heliocentric distance of the production rates of various species in Comet West (1975n=1976 VI) is explained with a cometary model consisting of a CO₂-dominated nucleus plus a halo of icy grains of H₂O or clathrate hydrate. We conclude that the parents of CN and C₃ are released primarily from the nucleus but that the parent of C₂ is released primarily from the halo of icy grains.     

CN, C2 radicals and dust in Comets Shoemaker-Levy 1991 T2 and P/deVico 1995 S1

The results of the multiaperture photometry of Comet Shoemaker-Levy 1991 T2 in the pre-perihelion and P/deVico in the post-perihelion period with the narrowband CN, C₂ and Blue Continuum (BC) IHW filters are presented. A Haser model of the molecular coma was used for the determination of the parent and daughter scale-lengths and production rates of the radicals. The comets showed some substantial differences between their parent scale-lengths. The CN parent scale-length (at 1.0 AU) was 16×¹⁰³ km for Comet Shoemaker-Levy and 39×¹⁰³ for P/deVico, the C₂ parent scale-lengths were respectively 29×¹⁰³ and 54×¹⁰³ km. Such divergences could be interpreted in the frame of different scenarios of emission of cometary parents, either from a nucleus or from a volume source. The daughter scale-lengths for these comets were quite similar, namely: 306×¹⁰³ and 318×¹⁰³ km for CN and 69×¹⁰³ and 66×¹⁰³ km for C₂. We determined the Afρ parameter for apertures of different radii. A Monte Carlo model of the dust coma was used to obtain the dust ejection velocity. It was of the order of 0.1 km s⁻¹ for both comets. The power index of the distribution of the β-parameter of dust particles (ratio of light pressure to the solar gravitation) was of the order of 3 for C/Shoemaker-Levy and close to 2 for P/deVico. The dependence on heliocentric distance (rh) of the radical and dust production rates for P/deVico in the range of 0.7-1.0 AU was described by the power law function with a power index equal to: 5.55±0.14 for CN, 5.70±0.24 for C₂ and 5.22±0.19 for dust. Relative abundances of the dynamically new Comet Shoemaker-Levy and short-period P/deVico were quite similar with an enhancement of C₂ comparing with standard values taken from A'Hearn et al. (1995).     

Charge coupled device (CCD) spectroscopy of comets: Tuttle,Stephan-Oterma,Brooks 2, and Bowell

Spectra of the four comets, Tuttle, Stephan-Oterma, Brooks 2, and Bowell, were taken with a prototype space telescope charge coupled device (CCD) camera using a 500 × 500 Texas Instruments chip. The spectra extended from 5600 to 10,400 Å at a resolution of $\text{～25}\text{A}\text{?}$. The spatial coverage along the slit was 180^?; its resolution was defined by the seeing ($\text{2–3}{}^{\mathrm{?}}$). Both absolute flux scales and spectral albedos were determined with the data reduction procedure which included flat fielding and sky subtraction. Comet Tuttle displayed extensive emissions by NH₂, the red system of CN, and the C₂ Swan bands as well as emissions by the forbidden oxygen lines [OI] ¹D at 6300 and 6364 Å, and the ionic species H₂O⁺. A feature at 6851 Å has been tentatively identified as the 3-0 band of CS⁺. Notable is the absence of the C₂ Phillips bands whose transitions are optimally placed in our spectrum. The much dustier comet, Stephan-Oterma showed emissions by CN, NH₂, and [OI] while only [OI] could be discerned in the noisier Brooks 2 spectrum. The fresh comet Bowell exhibited an unusually extended coma with an albedo times cross section two orders of magnitude larger than the other comets, a very flat albedo spectrum, and no emission features. For Tuttle and Stephan-Oterma, CN and NH₂ column densities using a number of bands were calculated. The CN band intensity ratios show good agreement with theoretical fluorescence models. The spatial profiles for CN and NH₂ were compared to two step Haser model decay calculations. The scale lengths most consistent with the data were compared with values previously reported and with values expected for various photodissociation reactions. Production rates were calculated for CN and NH₂. These should be less model dependent because of the simultaneous collection of spectral and spatial information. The production rate ratios of the parents of CN and NH₂ to the parent of OH are several orders of magnitude smaller than the solar abundance ratios of C/O and N/O.     

Spectroscopy of comet P/Schaumasse

Column density profiles for CN, C₃, C₂ and NH have been determined from a long-slit CCD spectrum of periodic comet P/Schaumasse (1992x). Comparisons of these profiles with Haser models indicate that the ratios of the CN, C₃ and C₂ production rates are typical for a short-period comet. Although the scale lengths for NH and its parent species are uncertain, the results indicate that the production rate for NH is much greater than for either C₂ or CN.     

Photometric studies of comet C/2009 P1 (Garradd) before the perihelion

The results of the photometric observations of comet C/2009 P1 (Garradd) performed at the 60-cm Zeiss-600 telescope of the Terskol observatory have been analyzed. During the observations, the comet was at the heliocentric and geocentric distances of 1.7 and 2.0 AU, respectively. The CCD images of the comet were obtained in the standard narrowband interference filters suggested by the International research program for comet Hale-Bopp and correspondingly designated the “Hale-Bopp (HB) set.” These filters were designed to isolate the BC (λ4450/67 Å), GC (λ5260/56 Å) and RC (λ7128/58 Å) continua and the emission bands of C₂ (λ5141/118 Å), CN (λ3870/62 Å), and C₃ (λ4062/62 Å). From the photometric data, the dust production rate of the comet and its color index and color excess were determined. The concentration of C₂, CN, and C₃ molecules and their production rates along the line of sight were estimated. The obtained results show that the physical parameters of the comet are close to the mean characteristics typical of the dynamically new comets.     

Comet C/2010X1 (Elenin). Unrealized expectations

We present the analysis of the photometric and spectroscopic data obtained for comet C/2010 X1 (Elenin) when it was at a distance of 2.92 AU from the Sun. The observations were made at the prime focus of the 6-m BTA telescope with the SCORPIO focal reducer. The magnitude of the comet, measured in the R _c -band with an 9?? aperture radius amounted to 16?8 ± 0?1. The computed dust production rate was estimated to be about 6 kg/s. The cometary coma manifested the emissions in the (0?C0) band of the CN molecule violet system, and a number of emission band heads of the C₃ molecule. The gas production rate of the molecules is determined using the Haser model and amounts to 1.41 × 10²⁴ and 4.20 × 10²³ molecules per second for CN and C₃, respectively. The ratio of gas production rates log[Q(C₃)/Q(CN)] is equal to ?0.85, which is close to the mean value, determined for a significant number of comets. A normalized gradient of the cometary dust reflectivity, calculated for the 4430?C6840 ? spectral range amounts to 14.3 ± 1.2%.     

Gas and dust release from comet West (1976VI) nuclear fragments

Emission fluxes of CN, G₂ and C₃ carbon-bearing molecular species observed in the spectra of the nuclear fragment A and D of comet West (1976VI) are analysed in the framework of Haser's two-component model with radial outflow symmetry. Gas production rates have been derived and their ratios obtained. We find these vary as Q r ⁿ (where 1.0r2.6 is the heliocentric distance in AU) with photometric parametern = -4.11 (CN), -2.68 (C₂), -1.89 (C₃) andQ _x /Q _y r ⁿ withn = 2.22 (C₃/CN), 1.42 (C₂/CN), -0.79 (C₂/C₃). The gas-to-dust ratio, dust production rates in arbitrary units, total number of dust particles in the field of view and an effective radius R_eff 2.0 km for the principal nuclear fragmentA is also estimated.     

Spectrophotometric scan of comet 1973 XII Kohoutek

Photoelectric spectrophotometric scans of Comet 1973 XII Kohoutek were made on November 25.85 and 28.85 UT, 1973. The vibrational temperature of C₂, the total numbers of CN and of C₂, and the production rates for CN and C₂ are derived from the observed fluxes. The temperature of C₂ was 4900 K on 25.85 November and 4300 K on 28.85 November. Mean abundance ratio of C₂ to CN was about 2.7. From the variation of production rates with heliocentric distance, it is shown that there was an outburst on 25.85 November in both CN and C₂ productions. For C₂, the production rates are derived by using two coma models, i.e. the Haser's parent-daughter model and the model relevant to a proposition of Yamamoto (1981b) that C₂ is formed via two-step photodissociation of its parent molecules. By comparing the production rate derived from the two models, it can be supported that C₂ is formed via two-step photodissociation rather than one-step photodissociation. In consequence, it is shown that the variation of the production rate with heliocentric distance is largely modified compared with that derived from the Haser's model.     

Chemical Composition Diversity Among 24 Comets Observed At Radio Wavelengths

We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH₃CN,CH₃OH, H₂CO, CO, CS, H₂S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets. From the sub-sample of comets for which contemporary H₂O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH₃OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H₂CO/HCN varies between 1.6 and 10; and H₂S/HCN varies between 1.5 and 7.6. This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.     

Scanner observations of comet Bradfield (1987 s)

Spectrophotometric observations of the head of comet Bradfield (1987 s) during three nights in 1987 are presented. An estimate of the CN, C₂ and C₃ column densities and production rates have been made.     

Absolute spectrophotometry of Comet kohoutek 1973f during post-perihelion passage

Absolute spectrophotometry of the coma of Comet Kohoutek 1973f during post-perihelion period has been presented for seven nights in January 1984. Moderately wide range of heliocentric distance (0.436–0.799 AU) covered during observations allowed us to study the flux variation of emission bands with heliocentric distance. The emission features of CN, CH, C₂, C₃, and NaI have been identified in this comet. The abundances of CN and C₂ have been estimated and the production rates of CN, C₂ and C₃ have been derived. Production rates of CN and C₂ seem to vary as r ^–0.33 and r ^–3.50 respectively. The continuum of the comet became more and more redder as the heliocentric distance of the comet increased and phase angle decreased.     

Observations of C2 Molecules in the Coma of Comets at Mitaka

In order to monitor the various phenomena of comets, we continuously made the near-nucleus imaging observations of comets at National Astronomical Observatory, Mitaka. Here we report on the results of the observations of two spectacular comets. One is the analysis of photometry of C₂ emission images in the coma of comet Hyakutake (C/1996 B2). By comparing the production rates of C₂ radicals with C₂H₂ molecules, we conclude that the most C₂ radicals were originated from C₂H₂, while some of them might be produced from other parents. The second item is the analysis of the morphology of C₂ emission images in the coma of comet Hale-Bopp(C/1995 O1). By applying a ring masking technique, we detected asymmetrical distribution of the C₂ molecules. The results of these two comets might suggest that a portion of C₂ radicals were formed by the disintegration of the small organic dust grains, like the so-called CHON particles. This revised version was published online in July 2006 with corrections to the Cover Date.