同位素水化学指示的新疆孔雀河流域地下水与地表水关系

地下水是孔雀河流域农业灌溉的主要水源之一,其对本地区经济发展的支撑作用日益增强。为实现孔雀河流域水资源合理开发和生态保护,采用环境同位素和水化学方法,研究了孔雀河流域地下水与地表水关系。结果表明:地下水的主要补给来源为河水。含水层成因类型和现代河道分布共同控制着孔雀河流域地下咸淡水的空间分布格局;氢氧稳定同位素对不同水体的相互转化指示作用较强,但难以区别更新世与全新世的地下水;3 H和14 C放射性同位素组分对地下水循环演化及更新能力的指示作用较好,14 C年龄变化特征可以很好指示承压水的运移方向和速率;13 C可作为初步判断地下水类型或年龄的参考指示剂;大量渠系引水灌溉使得潜水接受地表水入渗补给能力增强,更新能力显著提高,但承压水目前的开采利用仍以消耗更新能力差的老水为主。当地应优化调整地下水开发格局,减少流域中游河套内农灌区承压水开采量,加大流域下游微咸水分布区潜水开采利用,降低潜水位,减轻土壤盐渍化,促进水土资源开发的良性循环。     

金华地区地下水同位素特征及更新能力研究

金华地区位于金衢盆地东段,对其地下水同位素特征及更新能力研究对于整个盆地地下水资源研究具有重要意义,通过分析研究区内稳定同位素氘(D)和氧(~(18)O)以及放射性同位素氚(~3H)和碳(~(14)C)的空间分布特征,建立了金华地区降水线方程为:δD=8.29δ~(18)O+15.9,讨论了地表水、潜水、红层地下水的环境同位素的组成特征,对潜水及红层地下水的更新能力进行了评价。结果表明,金华地区降水线方程斜率及截距均大于全球大气降水;潜水、红层地下水及地表水三者联系密切;潜水、红层地下水在接受降水的补给后经历了不同程度的蒸发作用;红层地下水D和~(18)O同位素明显向下游富集;潜水~3H值介于6.6～19.0TU,~(14)C年龄显示为现代水,因此其可更新能力较强,红层地下水放射性~(14)C年龄为3020～5360BP,可更新能力较弱,红层地下水3H值介于4.4～12.3TU,表明红层地下水中有现代水的混入,δ~(18)O随着地下水的年龄的增加而偏负。     

银川平原深层地下水14C年龄校正

地下水¹⁴C年龄的校正精度取决于对地下水溶解无机碳演化过程中影响地下水¹⁴C活度主要因素的准确识别及其影响程度的定量评价。以银川平原为例,在进行银川平原承压水反向地球化学反应路径模拟的基础上,识别出影响区内深层地下水碳酸演化的主要作用并进行深层地下水¹⁴C年龄的校正。研究认为,控制银川平原深层地下水化学演化的主要反应路径为碳酸盐矿物的沉淀和长石、角闪石、石膏等矿物的溶解以及Ca-Na离子交换。地下水流路径上所发生的水文地球化学反应对路径上¹⁴C的浓度变化影响较小。地下水¹⁴C年龄校正结果表明,除补给区和承压水水位漏斗区外,银川平原承压水年龄均在2 000 a以上,属“古水”,天然条件下径流缓慢、地下水更新速度小。在承压水水位漏斗区外,沿地下水流方向,地下水年龄逐渐增大;而在承压水集中开采区,承压水的年龄明显小于路径上游地下水,潜水与承压水之间的垂向水力联系比较密切。     

基于同位素与水化学分析法的地下水补径排研究——以苏锡常地区浅层地下水为例

在分析研究区浅层地下水空间分布特征的基础上,采用同位素与化学分析相结合的方法研究苏锡常浅层地下水的补径排条件。利用氢氧同位素的分析结果,建立潜水与微承压水的δD-δ18O关系曲线,分析潜水含水层与河流、湖泊等地表水体关系以及微承水的蒸发程度;利用放射性同位素氚与14C研究微承水与现代水的补给关系;利用常规的水化学分析方法研究浅层地下水补给源的变化问题。结合研究区地下水水位、地层岩性、地形、地貌等多方面因素综合分析了浅层地下水的补径排条件,从而指导苏锡常地区浅层地下水合理开发利用。     

喀什平原区地下水同位素年龄特征及更新速率分析

为分析喀什平原区300 m以浅地下水年龄和更新速率,准确划分地下水流系统,采用了3H和14C放射性同位素测试方法,对采集的120组地下水样品中3H和14C同位素组成进行了分析,研究了喀什平原区不同区域地下水的年龄特征。结果表明,研究区大部分潜水氚值为12.2~39.6 TU,地下水年龄从山前冲洪积砾质平原至细土平原区逐渐增大,为10~50年;在中部库木塔格背斜隆起一带,潜水氚值小于10 TU,地下水年龄大于500年,形成地下水年龄分水岭;区内地下水14C年龄约为2 000~13 000年,反映了地下水补给时段差异较大。从山前冲洪积砾质平原上游至冲积细土平原中部地区,地下水更新速率约为2%~7%,属积极交替带;冲积细土平原中下游地区,地下水更新速率约为1%~2%,属较积极交替带;在冲积细土平原下游地区,地下水更新速率均小于1%,属弱交替带。     

新疆喀什三角洲地下水流系统的水化学和同位素标记

新疆喀什三角洲地下水“水质型”缺水问题较为突出，开展地下水流系统研究具有实际意义.采用水化学和环境同位素年龄测试法，在对喀什三角洲地下水含水系统划分基础上，对地下水化学和循环更新特征进行了分析研究.结果表明:三角洲含水系统由山前倾斜冲洪积平原潜水、河流冲积平原潜水和河流冲积平原承压水构成.沿地下水流向，水化学类型演化为HCO₃·SO₄-Ca→SO₄-Ca→SO₄·Cl-Mg·Na→SO₄·Cl-Na，TDS增高，水质趋向盐化.山前倾斜冲洪积平原为溶滤-径流区，河流冲积平原为径流-累盐区.研究区地下水更新速率为0.03%~16.35%·a-1，具有山前倾斜冲洪积平原潜水>河流冲积平原潜水>河流冲积平原承压水的特征.利用3H估算得出，山前倾斜冲洪积平原潜水年龄为8~49 a，平均值为29 a；河流冲积平原潜水年龄为14~>50 a，其中上部潜水平均年龄为24 a，下部潜水平均年龄大于50 a.利用14C估算得出，河流冲积平原潜水为476~33 623 a，平均值为8 106 a；河流冲积平原承压水为5 186~34 578 a，平均值为30 043 a，与潜水比为“更古老”的水.综合以上特征得出，喀什三角洲地下水含水系统可以划分为2个更新速率较快的局部水流系统（Ⅰ₁和Ⅰ₂）和一个循环滞缓的区域水流系统（Ⅱ）.      

包头平原地下水水循环模式及其可更新能力的同位素研究

同位素研究表明,包头平原中山前倾斜平原和黄河冲积平原区地下水具有不同的水循环模式。山前倾斜平原中,潜水的补给来源为当地雨水的补给,具有大型冲洪积扇典型的水文地球化学分带特点;承压水来源于补给高程较大的基岩裂隙水,主要通过山前断裂侧向补给。在地下水位漏斗区中,承压水δ^18和^3H浓度较高的现象反映有潜水向承压水的越流补给。黄河冲积平原中,黄河灌溉水入渗补给是该地区潜水的重要来源。相比于承压水,山前平原潜水的更新时间较短,循环速度较快,潜水的更新能力明显大于深层承压水。     

基于氚同位素的安阳河中下游流域地下水更新能力研究

利用水中氚值与地下水年龄分布特征和多年平均更新速率,分析安阳河中下游流域地下水更新能力。应用MGMTP重建研究区1953—2016年大气降水氚值,应用集中参数模型(LPMs)计算地下水年龄,采用Le Gal La Shalle等提出的方法估算潜水与泉水多年平均更新速率。研究结果表明:(1)潜水与泉水由近20多年来大气降水补给。潜水样点受局部水文地质条件控制,补给径流条件差异明显。(2)小南海泉平均滞留时间23 a,多年平均更新速率3.6%,水量呈不断衰减趋势。(3)安阳河冲洪积扇扇后缘为补给区,受地表水渗漏与大气降水入渗补给,更新能力较强。扇中部至京港澳高速路地带为现代地下水,年龄40~60 a。扇前缘为现代与次现代地下水的混合水,年龄大于60 a,更新能力较弱。(4)剥蚀岗丘与冲洪积平原深层承压水为较老地下水,更新能力极弱。因此,对小南海泉域的保护需要加强,并在短时期内能取得明显成效。受南水北调中线水源补给及限量地下水开采影响,安阳市区地下水降落漏斗大幅度缩减。     

渭河平原地下水分布特征与环境同位素研究——以白杨水源地为例

白杨水源地座落在渭河下游重镇——渭南市西北约5km处，为渭河冲积平原的一部分。区内第四纪松散堆积物巨厚，地形平坦，降水充沛，地表水丰富，为地下水储存提供了良好的空间。按含水介质的埋藏条件可划分为潜水、浅层承压水、中层承压水和深层承压水4个含水岩组。为了进一步研究地下水的补给形成机制、储存运移过程、排泄开采条件，本文结合环境同位素（包括14C、13C、3H、D和18O）对水源地地下水年龄、地下水运动速率以及一些水文地质参数进行研究和探讨。而同位素测定表明：水源地潜水为现代水，3H含量较高，河水补给量占1/2     

利用稳定同位素方法识别内蒙古佘太盆地地下水补给来源

为研究近几十年来佘太盆地地下水补给变化情况,通过现场调查分析,对佘太盆地浅层地下水开展同位素样品采集工作,并测定了其氢、氧稳定同位素的值。在分析同位素分布特征及变化规律的基础上,结合当地地质及水文地质条件识别了地下水补给来源和补给区并构建了浅层地下水的补给模式图,探讨了区域上浅层地下水的补给流动状况。通过分析研究区大气降水和地下水中的氢氧稳定同位素的变化特征发现:当地大气降水并不是地下水的主要补给来源,其补给源区为周边山区,补给来源主要是周边山区的大气降水,且地下水所经历的蒸发作用较明显;盆地的东、西部地下水的补给源区不尽相同,西部的补给区高程要高于东部的补给区高程,但两部分地下水所经历的蒸发强度基本相同。     

Isotopic characteristics of precipitation, surface and ground waters in the Yinchuan plain, Northwest China

The isotopic characteristics of hydrogen and oxygen of various water bodies in the Yinchuan plain were investigated. A total of 131 water samples were collected and another 99 water samples collected by other scholars and the International Atomic Energy Agency were referred to in the study. The stable isotopic compositions of precipitation and lake waters are influenced by dry climate and strong evaporation of the area, and the slope of local meteoric water line and lake water line are smaller than that of global meteoric water line. The isotopic compositions of the Yellow River water are significantly lower than the weighted averages of local atmospheric precipitation and are controlled by the runoff of upstream areas. The isotopes of phreatic water suggest that the single phreatic water is predominantly recharged by the bedrock fissure water of Helan Mountain, while the phreatic water in multilayer structure area is recharged by multiple sources. The confined waters in the area may be recharged under cooler climate conditions than the present, which makes the heavy isotopes depleted. The ³H contents of various water bodies are in the following order: the Yellow River water > multilayer phreatic water > single phreatic water > lake water > drainage ditch water > upper confined water > lower confined water. This is in accordance with the recharge, discharge and circulation conditions of the specific water bodies. The isotope compositions of waters in the Yinchuan plain are mainly affected by external water recharge rather than local precipitation. This study is meaningful and helpful in understanding the groundwater flow systems and water cycle in the area.     

松嫩平原地下水流动模式的环境同位素标记

采用同位素水文学方法并结合传统水文地质方法,识别松嫩平原地下水流动模式。氢氧稳定同位素和地下水年龄分布表明该区地下水流动系统流动模式呈现出局部流、中间流和区域流系统。地下水中氚分布深度指示局部水流系统为现代水循环系统,以垂向运动为主要特征,循环深度一般小于50 m,山前区可达100m以下;区域流系统存在于深部承压含水层,以侧向水平径流为主要运动特征。松辽边界附近的环境同位素特征存在明显的差别,指示天然状态下可视为零通量边界。同位素示踪剂也反映出嫩江和地下水的相互作用关系,在齐齐哈尔以北,江水补给地下水;在齐齐哈尔以南,地下水向嫩江排泄。     

黑河流域民乐山前隐伏构造带地下水补给与更新

第四系地下水是民乐山前地区居民清洁饮水的重要水源,而复杂的隐伏构造对区内地下水的运移和更新具有重要的控制作用。本文应用环境同位素技术,深入讨论了该区地下水的补给、更新能力以及隐伏构造对地下水更新的影响。结果表明:(1)民乐山前第四系地下水的补给来源包括出山河水渗漏和当地降水入渗,二者对地下水补给的贡献分别为89%和11%;(2)地下水更新能力由山前向下游变差,山前一带地下水更新周期在20～30年之间,下游的六坝北部一带地下水更新周期大于50年;(3)隐伏构造具有明显的阻水作用,导致地下水径流速度减缓。     

Geochemical and isotopic characterization of groundwater from shallow and deep limestone aquifers system of Aleppo basin (north Syria)

Stable isotopes (δ¹⁸O, δ²H and ¹³C) and radioactivity (³H, ¹⁴C) have been used in conjunction with chemical data to evaluate the processes generating the chemical composition, reconstruct the origin of the water and groundwater residence time. The Aleppo basin is comprised of two main limestone aquifers: the first one is unconfined of Paleogene age and the second is confined of Upper Cretaceous age. The chemical data indicate that the dissolution of minerals and evaporation are the main processes controlling groundwater mineralization. The groundwater from the two aquifers is characterized by distinctive stable isotope signatures. This difference in water isotopes is interpreted in terms of difference origin and recharge period. Fresh and brackish shallow groundwater were mostly recharged during the Holocene period. The presence of ³H in several groundwater samples of this aquifer gives evidence that groundwater recharge is going on. Brackish water of the deep confined aquifer has depleted stable isotope composition and very low ¹⁴C activity that indicates recharge during the late Pleistocene cold period.     

Groundwater circulation and hydrogeochemical evolution in Nomhon of Qaidam Basin,northwest China

In this study, analysis of hydrogeological conditions, as well as hydrochemistry and isotopic tools were used to get an insight into the processes controlling mineralization, recharge conditions, and flow pattern of groundwater in a typical arid alluvial-lacustrine plain in Qaidam Basin, northwest China. Analysis of the dissolved constituents reveals that groundwater evolves from fresh water (TDS =300–1000 mg/l) to saline water (TDS ≥5000 mg/l) along the flow paths, with the water type transiting from HCO ₃?Cl–Na ?Mg to HCO ₃?Cl–Na, and eventually to Cl–Na. Groundwater chemical evolution is mainly controlled by water–rock interaction and the evaporation–crystallization process. Deuterium and oxygen-18 isotopes in groundwater samples indicate that the recharge of groundwater is happened by meteoric water and glacier melt-water in the Kunlun Mountains, and in three different recharge conditions. Groundwater ages, estimated by the radiogenic (³H and ¹⁴C) isotope data, range from present to Holocene (～28 ka). Based on groundwater residence time, hydrogeochemical characteristics, field investigation, and geological structure distribution, a conceptual groundwater flow pattern affected by uplift structure is proposed, indicating that shallow phreatic water is blocked by the uplift structure and the flow direction is turned to the northwest, while high pressure artesian water is formed in the confined aquifers at the axis of the uplift structure.     

银川平原主要水环境问题及其对策

基于野外调查、取样分析以及遥感影像等,介绍了银川平原水文地质条件及水资源利用概况,探讨了土壤盐渍化、湖泊湿地萎缩、地下水盐化、地下水超采以及土地荒漠化等水环境问题及其演化成因。结果表明：银川平原地下水主要接受渠系渗漏及灌溉入渗、大气降水入渗、平原周边地下侧向径流、洪水散失、黄河水等补给,地下水排泄方式主要是排水沟排泄、蒸发和人工开采等,大部分地区潜水埋深在3 m以内;地表水主要来源于黄河引水,水资源利用效率不高;土壤盐渍化总面积8.17×104hm2,呈逐年缩减的趋势,主要分布于银川平原北部,平原南部仅分布在邵岗东部、灵武东部秦渠和东干渠等;湖泊湿地总体呈逐渐减少趋势,主要分布在银川平原北部,永宁以北、平罗以南区域比较集中,滩涂沿黄河两岸分布;潜水总含盐量自西向东、自南向北不断增大;银川和石嘴山深层地下水超采严重,地下水降落漏斗面积已超过500 km2;沙漠化土地分布在银川平原的东西两侧;土壤盐渍化及地下水盐化主要由潜水位埋深过浅,蒸发强烈造成的。最后,提出了防治上述水环境问题的对策：进一步加强水资源管理以及地表水与地下水联合调配;提高农业水资源利用效率;完善田间工程配套,实现渠道防渗管道化;改进田间灌溉技术;严格污水排放,积极开展污水净化处理,实行污水资源化;加强对水土环境质量的系统监测。     

Identifying the recharge sources and age of groundwater in the Songnen Plain (Northeast China) using environmental isotopes

The recharge sources and groundwater age in the Songnen Plain, Northeast China, were confirmed using environmental isotopes. The isotopic signatures of the unconfined aquifers in the southeast elevated plain and the north and west piedmont, cluster along local meteoric water lines (LMWLs) with a slope of about 5. The signature of source water was obtained by the intersection of these LMWLs with the regional meteoric water line (RMWL). This finding provides evidence that the recharge water for these areas originate from the Changbai Mountains and the Low and High Hingan Mountains, respectively. Groundwater in the unconfined aquifer in the low plain yields a LMWL with a slope of 4.4; its nitrate concentration indicates the admixture of irrigation return flow. The δ-values of the unconfined aquifer in the east elevated plain plot along the RMWL, reflecting recharge by local precipitation. The mean residence time of groundwater in these aquifers is less than 50?years. However, the ¹⁴C age of the groundwater in the confined Quaternary aquifer ranges from modern to 19,500?years, and in the Tertiary confined aquifer from 3,100 to 24,900?years. Modern groundwater is mainly recharged to the Quaternary confined aquifer on the piedmont by local precipitation and lateral subsurface flow.     

A study on groundwater recharge in the Anyanghe River alluvial fan,North China Plain,based on hydrochemistry,stable isotopes and tritium

Studies on groundwater recharge are essential for sustainable exploitation of groundwater resources, especially in areas of extensive groundwater exploitation such as the Anyanghe River alluvial fan (ARAF) in the North China Plain (NCP). However, the recharge sources and processes and the contribution of each recharge flow component remain unclear. This study used hydrochemistry, stable isotopes, and tritium to investigate sources and underlying processes of groundwater recharge, along with the steady flow Mixing Cell Model (MCMsf) to quantify the proportion of each source flow for the shallow confined groundwater system in the medial fan. The results showed that groundwater mainly originates from precipitation occurring on the eastern Taihang Mountain area with average elevation estimated at 700–1,000 m above sea level during the East Asia summer monsoon period since 1952. Recharge mechanisms are: (1) river water seepage for the unconfined aquifers of the proximal and medial fan; (2) lateral flow for the confined aquifers of the medial and distal fan; and (3) precipitation infiltration for the phreatic water system. The MCMsf simulation showed that the shallow confined groundwater system in the central zone of the medial fan mainly recharged by the lateral flow from the proximal fan, a constant and considerable recharge flow from the southwestern and southern hills, and river water seepage in the medial fan; the lateral recharge flow from the Zhanghe alluvial aquifer was insignificant by comparison. The results of this study can act as a valuable reference for sustainable groundwater management in the ARAF.

     

Using geochemical indicators to investigate groundwater mixing and residence time in the aquifer system of Djeffara of Medenine (southeastern Tunisia)

Stable isotopes (??²H, ??¹⁸O and ??¹³C) and radiocarbon (¹⁴C) have been used in conjunction with chemical data to evaluate recharge mechanisms and groundwater residence time, and to identify inter-aquifer mixing in the Djeffara multi-aquifer in semi-arid southeastern Tunisia. The southern part of this basin, the Djeffara of Medenine aquifer system, is comprised of two main aquifers of Triassic and Miocene sandstone. The Triassic aquifer presents two compartments; the first one (west of the Medenine fault system) is unconfined with a well-defined isotope fingerprint; the second compartment is deeper and confined. Multi-tracer results show groundwater of different origins, ages and salinities, and that tectonic features control groundwater flows. Fresh and brackish groundwater from the unconfined part of the Triassic aquifer was mostly recharged during the Holocene. The recharge rates of this aquifer, inferred by ¹⁴C ages, are variable and could reach 3.5?mm/year. Brackish water of the deep confined part of the Triassic aquifer has stable isotope composition and ¹⁴C content that indicates earlier recharge during late Pleistocene cold periods. Brackish to saline water of the Miocene aquifer presents variable isotope composition. Groundwater flowing through the Medenine fault system is mainly feeding the Miocene aquifer rather than the deep confined part of the Triassic aquifer.