Middle Paleozoic mafic magmatism and ocean plate stratigraphy of the South Tianshan,Kyrgyzstan

The tectonic history of the Kyrgyz South Tianshan in the western Central Asian Orogenic Belt (CAOB) remains controversial, first of all, due to the limited amount of geochemical and isotope data. Our paper presents the first results of a detailed geochemical study (major and trace elements, Sr, Nd and Pb isotopes) of Middle Paleozoic mafic volcanic and subvolcanic rocks of the Ferghana and Atbashi–Kokshaal accretionary belts of the South Tianshan orogen in Kyrgyzstan, which formed during the evolution of the Turkestan Ocean. A special focus is given to the relation between magmatic rocks and sedimentary units of marine origin, chert, siliceous shale/mudstone, volcanogenic–carbonate clastics, seamount carbonates, and turbidites, which we consider as elements of Ocean Plate Stratigraphy (OPS). The age range of marine sediments is Late Silurian to Early Carboniferous, but the age of the most volcanic rocks associated with fossil-bearing OPS sediments is Devonian. The magmatic rocks have geochemical affinity to oceanic island basalts (OIB-type) and, to a lesser extent, mid-oceanic ridge (MORB-type) basalts associated with hemipelagic siliceous mudstone and pelagic chert. The rocks with OIB-type affinity are associated with chert, siliceous shale and carbonaceous clastics and carbonates. They are enriched in TiO₂, LREE (La/Sm_n = 1.9), and Nb (Zr/Nb_av. = 10), have differentiated HREE (Gd/Yb_n = 2.0), medium to low εNd (~ 5.7) and are characterized by clear Nb positive anomalies in normalized multi-element plots (Nb/Th_pm = 1.3, Nb/La_pm = 1.1). The OIBs formed by relatively low degrees of melting (< 5%) of mantle sources in the garnet stability field and erupted in an oceanic island setting. The MORB-type samples associated with siliceous mudstone and chert are less enriched in incompatible elements, possess flat REE and multi-element pattern, and show higher εNd values (~ 9.1); they were probably produced by high-degree melting of spinel lherzolite and/or harzburgite and erupted in a mid-oceanic ridge setting. The geological, lithological and geochronological data suggest that the OPS units with dominantly OIB-type basalts formed at one or several seamount chains of the Turkestan Ocean, which were accreted to the Kazakhstan continent, and thus contribute to our understanding of the Paleozoic tectonic evolution of the western CAOB during the Serpukhovian–Bashkirian.     

Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints

Nominally anhydrous phases (clinopyroxene (cpx), orthopyroxene (opx), and olivine (ol)) of peridotite xenoliths hosted by the Cenozoic basalts from Beishan (Hebei province), and Fansi (Shanxi province), Western part of the North China Craton (WNCC) have been investigated by Fourier transform infrared spectrometry (FTIR). The H₂O contents (wt.) of cpx, opx and ol are 30–255 ppm, 14–95 ppm and ~ 0 ppm, respectively. Although potential H-loss during xenolith ascent cannot be excluded for olivine, pyroxenes (cpx and opx) largely preserve the H₂O content of their mantle source inferred from (1) the homogenous H₂O content within single pyroxene grains, and (2) equilibrium H₂O partitioning between cpx and opx. Based on mineral modes and assuming a partition coefficient of 10 for H₂O between cpx and ol, the recalculated whole-rock H₂O contents range from 6 to 42 ppm. In combination with previously reported data for other two localities (Hannuoba and Yangyuan from Hebei province), the H₂O contents of cpx, opx and whole-rock of peridotite xenoliths (43 samples) hosted by the WNCC Cenozoic basalts range from 30 to 654 ppm, 14 to 225 ppm, and 6 to 262 ppm respectively. The H₂O contents of the Cenozoic lithospheric mantle represented by peridotite xenoliths fall in a similar range for both WNCC and the eastern part of the NCC (Xia et al., 2010, Journal of Geophysical Research). Clearly, the Cenozoic lithospheric mantle of the NCC is dominated by much lower water content compared to the MORB source (50–250 ppm). The low H₂O content is not caused by oxidation of the mantle domain, and likely results from mantle reheating, possibly due to an upwelling asthenospheric flow during the late Mesozoic–early Cenozoic lithospheric thinning of the NCC. If so, the present NCC lithospheric mantle mostly represents relict ancient lithospheric mantle. Some newly accreted and cooled asthenospheric mantle may exist in localities close to deep fault.     

Petrogenesis of high-Ti mafic dykes from Southern Qiangtang,Tibet: Implications for a ca. 290 Ma large igneous province related to the early Permian rifting of Gondwana

The presence and/or generation mechanism of a mantle plume associated with early Permian rifting on the northern margin of Gondwana are topics of debate. Here we report LA–ICP–MS U–Pb zircon ages, whole-rock geochemistry, and Sr–Nd isotope data for high-Ti mafic dykes from southern Qiangtang, Tibet, with the aim of assessing if a mantle plume formed in this region during the early Permian. Zircon U–Pb dating of diabase dykes yielded ages of 290.6 ± 3.5 Ma and 290.1 ± 1.5 Ma, indicating they were emplaced during the early Permian. Whole-rock geochemistry shows that these mafic dykes are alkaline (Nb/Y = 0.73–0.99), have high TiO2 (3.6%–4.8%), and have ocean-island basalt (OIB)-like trace element patterns with enrichments in Nb, Ta, and Ti. Whole-rock Sr–Nd isotope data show a relatively narrow range of εNd(t) (+ 2.29 to + 3.53), similar to basalts produced by a mantle plume (e.g., Emeishan continental flood basalts (ECFB)). Elemental and isotope data suggest that the dykes have undergone fractionation crystallization of mafic minerals and have experienced negligible crustal contamination. These mafic rocks show an affinity to OIB and may have been generated by partial melting of an OIB-type, garnet-bearing asthenospheric mantle source. On the basis of a similar emplacement age to the Panjal Traps basalts in the Himalayas, combined with a tectonic reconstruction of Gondwana in the early to middle Permian, our work suggests that the high-Ti mafic dykes in the Southern Qiangtang terrane and the coeval Panjal Traps basalts in the Himalayas together comprise a ca. 290 Ma large igneous province linked to a mantle plume, which probably played an active role in early Permian rifting on the northern margin of Gondwana and was related to circum-Pangea subduction.     

Origin of Late Cenozoic Abaga–Dalinuoer basalts,eastern China: Implications for a mixed pyroxenite–peridotite source related with deep subduction of the Pacific slab

Continental intraplate basalts (15.42–0.16 Ma) from Abaga–Dalinuoer volcanic field (ADVF) in central Inner Mongolia of eastern China, as a part of Cenozoic volcanic province along eastern margin of the Eurasian continent, provide a good opportunity to explore potential links between deep subduction of the Pacific slab and continental intraplate volcanism. In this study, we report an integrated dataset of whole-rock K–Ar ages, major and trace elements and Sr–Nd–Pb isotopes, and olivine major and minor elements for the Abaga–Dalinuoer basalts (ADBs), and propose that mantle source lithology of the ADB magmas may consist of both pyroxenite and peridotite. The ADBs display low SiO₂ (42.3–50.2 wt.%), high MgO (7.3–11.4 wt.%) and moderate K₂O + Na₂O (3.8–6.4 wt.%), and can be subdivided into basanites, alkali basalts and tholeiitic basalts that are all characterized by ocean island basalt (OIB)-like rare earth elements (REE) and enrichment in both large ion lithosphile elements (LILE) and high field strength elements (HFSE). Olivine phenocrysts have higher Ni and Fe/Mn and lower Mn, Ca and Ca/Fe relative to those from peridotite melts, but exhibit clearly lower Ni contents (< 2500 ppm) compared with expected Ni range (> 3000 ppm) for olivines crystallized from olivine-free pyroxenite melts. Estimated compositions of the ADB primary magmas, together with olivine compositions, suggest an iron-rich mantle source related with silica-deficient pyroxenite that is most likely derived from deeply subducted Pacific oceanic crust. Additionally, peridotite and recent subducted sediments are also required to account for high Ni and MgO in primary magmas together with their trace elements and Sr–Nd–Pb isotope systematics. We suggest that a mixed pyroxenite–peridotite source lithology can better match observed whole-rock and olivine signatures in the ADB, compared with either peridotite only or olivine-free pyroxenite only source lithology. In our model, pyroxenite melts would either react with or mechanically mix with peridotite, and the proportion of pyroxenite melts may range from 30% to 45% for mechanical mixing scenario. A continuous spectrum from tholeiitic to alkali melts revealed by melt-peridotite reaction experiment can explain formation of primary magmas of basanites, alkali basalts and tholeiitic basalts by increasing melting degree of a similar mantle source. Relatively higher ²⁰⁶Pb/²⁰⁴Pb of the ADB may suggest more significant role of recent (< 0.5 Ga) subducted Pacific oceanic materials, in contrast to other Cenozoic basalts in eastern China (e.g., Changbai basalts) that exhibit varying contributions from ancient (> 1.5 Ga) subducted continental sediments. We emphasize that coupled geochemical and geodynamic links (i.e., subduction polarity) between deeply subducted Pacific slab and continental intraplate volcanism in eastern China may exist, which directly support the involvement of deeply subducted Pacific materials in petrogenesis of the ADB. From the perspective of plate motion kinetics, decompression partial melting of upwelling fragmented Pacific slab (silica-deficient pyroxenite + recent subducted sediments) may be triggered by rollback of deeply subducted Pacific slab during Late Cenozoic times. Continental intraplate volcanism in the ADVF generally started with termination of opening of the Japan Sea, suggesting that deep subduction of the Pacific slab may have been an important geodynamic mechanism responsible for tectono-magmatic evolution of northeastern Asia. We suggest that the ADBs have the potential to shed light on genetic links between continental intraplate volcanism and deep subduction of the Pacific slab in geochemical and geodynamic processes.     

The Yanbian Terrane (Southern Sichuan Province,SW China): A Neoproterozoic arc assemblage in the western margin of the Yangtze Block

The magmatic and tectonic history of the Yangtze Block and its possible affinity with other Neoproterozoic arc terranes are important elements in the reconstruction of Neoproterozoic plate tectonics. The Yanbian Terrane in the western margin of the Yangtze Block is a typical arc assemblage composed of a flysch-type sedimentary sequence intruded by gabbroic and granodioritic plutons. The sedimentary sequence consists chiefly of tuffaceous material with interlayered chert, sandstone, and pillow basalts. Laser ablation ICP-MS U–Pb dating of detrital zircons from the sandstones yield ages as young as 840 Ma. The Gaojiacun and Lengshuiqing mafic intrusions are dated at 812 ± 3 Ma and 806 ± 4 Ma, respectively, using the SHRIMP zircon U–Pb technique. Geochemical data show that both the Gaojiacun and Lengshuiqing intrusions have arc signatures, with ɛNd(t) values of +1.5 to +6.0, initial ⁸⁷Sr/⁸⁶Sr ratios of 0.705–0.706 and pronounced negative Nb–Ta and Zr–Hf anomalies. Their geochemical variations are best explained by fractional crystallization without major crustal contamination. The Yanbian Terrane represents a typical arc assemblage formed on the western edge of the Yangtze Block during Neoproterozoic time. The sedimentary sequence was deposited in an oceanic setting, probably in a back arc basin environment. The depleted, subduction-modified lithospheric mantle wedge above the subduction zone was the source of melts from which the mafic plutons were crystallized. This scenario suggests subduction of oceanic lithosphere eastward (present-day orientation) underneath the Yangtze Block.     

Recycling oceanic crust for continental crustal growth: Sr–Nd–Hf isotope evidence from granitoids in the western Junggar region,NW China

The juvenile component of accretionary orogenic belts has been declining since the Archean. As a result, there is often controversy regarding the contribution of oceanic basalts to Phanerozoic crustal growth, as in the case of the Central Asian Orogenic Belt (CAOB). Here we report on three groups of Late Carboniferous (316–305 Ma) granitoids in the western Junggar region of northern Xinjiang, NW China, which is part of the southwestern CAOB. They consist of adakites and I and A-type granites, and as a whole have the most depleted isotopic compositions (ε_Nd(t) = + 6–+9, (⁸⁷Sr/⁸⁶Sr)_i = 0.7030–0.7045, and ε_Hf(t) = + 12–+16) among the granitoids of the CAOB. These features are nearly identical to those of pre-Permian ophiolites in northern Xinjiang, and are clearly different from those of Carboniferous basalts in the western Junggar region. These relationships indicate that the granitoids were mainly derived from recycled oceanic crust by melting of subducted oceanic crust (e.g., adakites), and of the middle–lower crust of intra-oceanic arc that mainly consisted of oceanic crust (e.g., I and A-type granites). Based on evidence from the CAOB, we suggest that recycling of oceanic crust has made a significant contribution to continental crustal growth and evolution during the Phanerozoic.     

The Zhaheba ophiolite complex in Eastern Junggar (NW China): Long lived supra-subduction zone ocean crust formation and its implications for the tectonic evolution in southern Altaids

The composite Zhaheba ophiolite complex, exposed in Eastern Junggar in the Southern Altaids, records an unusually long record of oceanic crust and magmatic arc evolution. The Zhaheba ophiolite complex consists of ultramafic rocks, gabbro, diorite, basalt and chert intruded by diabase dikes and diorite porphyry. These rocks are overlain by a several-km-thick section of tuffaceous rocks, volcaniclastic sedimentary rocks, and intermediate volcanic rocks. The igneous rocks of the ophiolite complex show negative Nb and Ta anomalies and LREE enrichment relative to HREE, suggesting the influence of fluids derived from a subducting oceanic slab. The LA-ICPMS U–Pb age of zircons from gabbro is 495.1 ± 3.5 Ma. Zircon ages from diorite and basalt are 458.3 ± 7.2 Ma and 446.6 ± 6.0 Ma, respectively. The basalt is locally overlain by bedded chert. Diabase dikes and diorite porphyry yield the U–Pb ages of 421.5 ± 4.1 Ma and 423.7 ± 6.5 Ma, respectively. The age of stratigraphically lower part of the overlying volcanic–volcaniclastic section is constrained to be about 410 Ma, the maximum depositional age of the tuffaceous sandstone from U–Pb detrital zircon ages. Late rhyolite at the top of the stratigraphic section yielded a U–Pb zircon age of 280.3 ± 3.7 Ma. The age and stratigraphic relationships for the Zhaheba ophiolite complex and related rocks suggest that the period of ~ 70 Ma of initial supra-subduction magmatism was followed by construction of a mature island arc that spanned an additional 140 Ma. Many other ophiolites in the southern Altaids appear to record similar relationships, and are represented as substrates of oceanic island arcs covered by island arc volcanism in supra-subduction zone. The occurrence of the Zhaheba ophiolite complex with tuffaceous and intermediate to felsic volcanic rocks is different from the rock association of classic Tethyan SSZ ophiolites but similar to some ophiolites in North America. Although the Zhaheba ophiolite belt is flanked by the Dulate arc in the north and Yemaquan arc in the south, it cannot stand a suture between two arcs. It is suggested that Devonian–Carboniferous Dulate arc was built on the late Cambrian–middle Ordovician Zhaheba supra-subduction oceanic crust. The late Carboniferous rocks and early Permian rocks in Dulate arc are interpreted to form in the extensional process within Zhaheba–Dulate arc composite system.     

Origin of melt pockets in mantle xenoliths from southern Patagonia,Argentina

Peridotite mantle xenoliths collected north of Gobernador Gregores, Patagonia, affected by cryptic and modal metasomatism bear melt pockets of unusually large size. Melt pockets consist of second generation olivine (ol2), clinopyroxene (cpx2) and spinel (sp2) ± relict amphibole (amph) immersed in a yellowish vesicular glass matrix. Amphibole breakdown was responsible for melt pocket generation as suggested by textural evidence and proved by consistent mass-balance calculations: amph → cpx2 + ol2 + sp2 + melt. Composition of calculated amphibole in amphibole-free melt pockets is very similar to that measured in amphibole-bearing melt pockets from the same xenolith, i.e. amphibole was consumed in the melt pocket generation process. In melt pockets devoid of relict amphibole, mass-balance calculations show remarkable differences between the calculated amphibole and the measured amphibole compositions in melt pockets from the same xenolith. The participation of minor proportions of a consumed reactant phase could be a reasonable explanation. In some samples the calculated phase proportion of glass is in excess compared to modal estimations based on backscattered electron images, probably because a portion of the generated melt was able to migrate out of the melt pockets. Compositional inhomogeneity of cpx2 and variable Ti Kd in cpx2 vs. glass in the same melt pocket reflect fast nucleation and growth and disequilibrium crystallisation, respectively. This and the difference between forsterite content in calculated equilibrium olivine and second generation olivine, suggest that mineral equilibrium was inhibited by rapid quenching of melt pockets.     

A LREE-depleted component in the Afar plume: Further evidence from Quaternary Djibouti basalts

Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K–Ar ages are presented for Quaternary (0.90–0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (La_n/Sm_n = 0.76–0.83), with ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous ¹⁴³Nd/¹⁴⁴Nd (ε_Nd = + 5.9–+ 7.3) and Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.47–18.55, ²⁰⁷Pb/²⁰⁴Pb = 15.52–15.57, ²⁰⁸Pb/²⁰⁴Pb = 38.62–38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.     

Revisiting Early–Middle Jurassic igneous activity in the Nanling Mountains,South China: Geochemistry and implications for regional geodynamics

Early–Middle Jurassic igneous rocks (190–170 Ma) are distributed in an E–W-trending band within the Nanling Tectonic Belt, and have a wide range of compositions but are only present in limited volumes. This scenario contrasts with the uniform but voluminous Middle–Late Jurassic igneous rocks (165–150 Ma) in this area. The Early–Middle Jurassic rocks include oceanic-island basalt (OIB)-type alkali basalts, tholeiitic basalts and gabbros, bimodal volcanic rocks, syenites, A-type granites, and high-K calc–alkaline granodiorites. Geochemical and isotopic data indicate that alkaline and tholeiitic basalts and syenites were derived from melting of the asthenospheric mantle, with asthenosphere-derived magmas mixing with variable amounts of magmas derived from melting of metasomatized lithospheric mantle. In comparison, A-type granites in the study area were probably generated by shallow dehydration-related melting of hornblende-bearing continental crustal rocks that were heated by contemporaneous intrusion of mantle-derived basaltic magmas, and high-K calc-alkaline granodiorites resulted from the interaction between melts from upwelling asthenospheric mantle and the lower crust. The Early–Middle Jurassic magmatic event is spatially variable in terms of lithology, geochemistry, and isotopic systematics. This indicates that the deep mantle sources of the magmas that formed these igneous rocks were significantly heterogeneous, and magmatism had a gradual decrease in the involvement of the asthenospheric mantle from west to east. These variations in composition and sourcing of magmas, in addition to the spatial distribution and the thermal structure of the crust–mantle boundary during this magmatic event, indicates that these igneous rocks formed during a period of rifting after the Indosinian Orogeny rather than during subduction of the paleo-Pacific oceanic crust.     

Tectonic evolution of the North Qinling Orogen from subduction to collision and exhumation: Evidence from zircons in metamorphic rocks of the Qinling Group

The North Qinling Block (NQB) is an important segment of the Qinling Orogen in Central China. Here we report the results from SIMS geochronology and oxygen isotopes, as well as LA-MC-ICPMS Hf isotopic analyses on zircon grains from a suite of metamorphic rocks (felsic gneisses, garnet plagioclase amphibolites, and retrograde eclogite dikes) in the Qinling Group of the NQB. The age data show that these rocks underwent at least two episodes of metamorphism with the peak at 483–501 Ma, followed by 454–470 Ma retrograde metamorphism. These results are generally coeval with the periods of 500–480 Ma for peak metamorphism and 460–420 Ma for retrograde metamorphism previously obtained from the HP/UHP metamorphic rocks of the NQB. During the prograde and retrograde metamorphism, widespread fluid and melt circulation within the block has been identified from the geochemical features of the metamorphic zircons. The fluids that circulated in the felsic gneisses and retrograde eclogite dikes originated from the dehydration of altered oceanic basalts as inferred from the exceedingly low Th/U ratios, positive ε_Hf(t) (> 5) and extremely δ¹⁸O (10.01–13.91‰) values in metamorphic zircons. In contrast, the melt involved in the formation of garnet plagioclase amphibolites appears to have been derived from continental sediments interlayered with the oceanic basalts since zircons crystallized during the peak and retrograde metamorphism show typical magmatic features with high U and Th contents and Th/U ratios and enriched Hf (ε_Hf(t) = − 5.42 to − 0.18) and oxygen isotope composition (δ¹⁸O around 8‰). Geochronological and geochemical features of the magmatic cores of the clear core-rim textured zircons demonstrate that the protoliths of the gneisses were intermediate-acid volcanic rocks erupted before Neoproterozoic (800 Ma), which is further supported by the intrusion of basaltic magma of asthenospheric origin as represented by protoliths of retrograde eclogite dikes, with the oldest magmatic zircon formed at 789 Ma. The protoliths of garnet plagioclase amphibolites appear to be altered oceanic basalts but had been significantly affected by the melt during the metamorphism. Combined with the previous studies, the Qinling Group experienced overall subduction in the Early Paleozoic. The NQB as represented by the Qinling Group was most likely a discrete micro-block in the Neoproterozoic, and underwent deep subduction in the Cambrian (483–501 Ma) and exhumation in Ordovician (454–470 Ma). We propose that the NQB preserves a complete cycle of tectonic evolution of an orogen from an oceanic basin spreading, and micro-continent formation to deep subduction and exhumation.     

Remnants of late Permian–Middle Triassic ocean islands in northern Tibet: Implications for the late-stage evolution of the Paleo-Tethys Ocean

In this paper we present new data for the Tianquan (TQ) and Dabure (DB) ocean islands in the western segment of the Longmuco–Shuanghu–Lancangjiang suture zone, northern Tibet, including the results of major and trace element analyses, zircon U–Pb dating, and Hf isotope analyses. Our aim was to assess the genesis of these ocean islands and to consider the implications for the tectonic evolution of the region as a whole. Both TQ and DB retain an ocean-island-type double-layered structure comprising a volcanic basement (basalt and andesite) and an oceanic sedimentary cover sequence (conglomerate, limestone, and chert). The basalts and andesites in the TQ and DB are enriched in light rare earth elements and high field strength elements (Nb, Ta, Zr, Hf, and Ti), yielding chondrite-normalized REE patterns and primitive-mantle-normalized trace element patterns that are similar to those of ocean island basalts. Given the small and generally positive ε_Hf(t) values of the TQ andesites (+ 4.25 to + 6.22) and DB andesites (− 0.59 to + 1.97, mostly > 0), we conclude that the basalts were derived from the partial melting of garnet peridotite in the mantle and that the andesites were formed by fractional crystallization of the mafic parent magma derived from the garnet peridotite mantle. The ascending magmas underwent varying degrees of fractional crystallization but were not contaminated by crustal material. These features indicate that both TQ and DB are typical ocean islands that formed in an ocean basin. Geochemical analyses of cherts from TQ and DB show that they contain terrigenous material, indicating the proximity of a continental margin. The andesites of TQ contain zircons that yield two U–Pb ages of 251 Ma. Given that ages of 246, 247, and 254 Ma had been reported previously, we conclude that TQ formed during the late Permian–Early Triassic. The andesites of DB contain zircons that yield U–Pb ages of 242 and 246 Ma. Taking into account the youngest age of 244 Ma from the DB basalt, we conclude that DB formed during the Middle Triassic. These data, combined with the geological history of the region, indicate that the development of the Longmuco–Shuanghu–Lancangjiang Paleo-Tethys Ocean continued after the early Permian and that the closure of this ocean was diachronous from east to west. The eastern segment of the ocean closed during the Early Triassic; however, the western segment remained at least partially open until the Middle Triassic, although the ocean was relatively small at this time. The ocean finally closed in the Late Triassic.     

Isotope geochemistry of Jeongok basalts,northernmost South Korea: Implications for the enriched mantle end-member component

South Korea separates two mantle source domains for Late Cenozoic intraplate volcanism in East Asia: depleted mid-ocean-ridge basalt (MORB) mantle-enriched mantle type 1 (DMM-EM1) in the north and DMM-EM2 in the south. We determined geochemical compositions, including Sr, Nd, Pb, and Hf isotopes for the Jeongok trachybasalts (∼0.51 to 0.15 Ma K–Ar ages) from northernmost South Korea, to better constrain the origin and distribution of the enriched mantle components. The Jeongok basalts exhibit light rare earth element (LREE)-enriched patterns ([La/Yb]_N = 9.2–11.6). The (La/Yb)_N ratios are lower than that of typical oceanic island basalt (OIB). On a primitive mantle-normalized incompatible element plot, the Jeongok samples show OIB-like enrichment in highly incompatible elements. However, they are depleted in moderately incompatible elements (e.g., La, Nd, Zr, Hf, etc.) compared with the OIB and exhibit positive anomalies in K and Pb. These anomalies are also prime characteristics of the Wudalianchi basalts, extreme EM1 end-member volcanics in northeast China. We have compared the geochemistry of the Jeongok basalts with those of available Late Cenozoic intraplate volcanic rocks from East Asia (from north to south, Wudalianchi, Mt. Baekdu and Baengnyeong for DMM-EM1, and Jeju for DMM-EM2). The mantle source for the Jeongok volcanics contains an EM1 component. The contribution of the EM1 component to East Asian volcanism increases toward the north, from Baengnyeong through Jeongok to Mt. Baekdu and finally to Wudalianchi. Modeling of trace element data suggests that the Jeongok basalts may have been generated by mixing of a Wudalianchi-like melt (EM1 end-member) and a melt that originated from a depleted mantle source, with some addition of the lithospheric mantle beneath the Jeongok area. In Nd–Hf isotope space, the most enriched EM1-component-bearing Jeongok sample shows elevation of ¹⁷⁶Hf/¹⁷⁷Hf at a given ¹⁴³Nd/¹⁴⁴Nd compared with OIB. Recycled pelagic sediments may explain the EM1-end-member component of northeastern Asian volcanism, possibly from the mantle transition zone.     

Geophysical,magmatic, and metallogenic manifestations of a mantle plume in the upper reaches of the Aldan and Amur Rivers

Gravity models of the crust and upper mantle to a depth of 100 km are analyzed to study structural relationships of tectonic and tectonophysical media of different rigidities with the distribution of shallow ore deposits above the Aldan-Zeya plume. The spatial correlation of ore clusters and districts with high crustal viscosity inhomoheneities at depths of 10, 20, and 35 km shows distinct stepwise behavior. On the other hand, media of decreased viscosity are observed in the lower crust (at depths of 25–30 km), subcrustal (40–50 km) layers, and asthenosphere (at a depth below 70 km). They are related to chambers of the complete or partial melting (heat sources) of magmatic and ore occurrences near the Earth’s surface. Lateral metallogenic zoning in the spatial distribution of the ore deposits is due to the spread and redistribution of magmas and ore-forming fluids, shielded by rigid plates in the lower crust. A naturally determined series of ore parageneses is observed from center to flanks of the plume: Au, Mo → Au, Ag, Pb, Zn → Au, Pb, Zn → Au, W → Au, Sb → W, Sn → Sn. The mutual position of the tectonomagmatic structures of different ranks within the plume head obeys hierarchical and fractal laws.     

Late Devonian OIB alkaline gabbro in the Yarlung Zangbo Suture Zone: Remnants of the Paleo-Tethys?

The Yarlung Zangbo Suture Zone (YZSZ) is believed to be composed of material largely derived from the destruction of the Neo-Tethys that occurred from early Mesozoic to early Cenozoic. We report here geochronological and petrological data obtained for newly discovered alkaline gabbro blocks embedded in a mélange zone of the western YZSZ. Single zircon U–Pb analyses from one representative gabbro sample by SIMS (Secondary Ion Mass Spectrometry) yielded a combined crystallization age of about 363.7 ± 1.7 Ma (1σ). In situ Hf isotopic analyses yielded ε_Hf(t) values of + 2.6 to + 5.5, suggesting an enriched mantle source. All of the gabbro samples show typical Ocean Island Basalt (OIB) affinity with little or no continental crust contamination. They also display strong geochemical similarities with the Hawaii basalts and the Xigaze seamount basalts suggestive of their intra-oceanic setting. These observations, in combination with the Early Carboniferous layered gabbros reported at Luobusa, indicate that these rocks could represent remnants of the Paleo-Tethys. We propose that a branch ocean separating the Western Qiangtang terrane and the Lhasa terrane from the Gondwana continent might have been present during the Late Devonian and the Early Carboniferous, providing new constrains on the configuration of Paleo-Tethys in Tibetan Plateau during early Late Paleozoic.     

The Algodões amphibolite–tonalite gneiss sequence,Borborema Province,NE Brazil: Geochemical and geochronological evidence for Palaeoproterozoic accretion of oceanic plateau/back-arc basalts and adakitic plutons

Field relationships, geochemistry and U–Pb zircon and Sm–Nd whole-rock geochronology are used to constrain the genesis of Palaeoproterozoic massive amphibolites and orthogneisses of the Algodões Sequence, Central Ceará Domain, Northeastern Brazil. The 2236 ± 55 Ma-old Algodões amphibolites show trace element geochemical signature and positive εNd(t) values similar to Phanaerozoic oceanic plateau basalts and less often to back-arc basalts. The amphibolites are intruded by tonalitic to quartz-dioritic gneisses of the Cipó unit which were dated at 2160–2170 Ma and 2130 Ma. Neodimium isotope data and whole-rock geochemistry for these gneisses show they are akin to juvenile arc plutonics of the adakitic suite. The likely occurrence of Palaeoproterozoic plateau basalts and arc plutonics in this part of northeastearn Brazil render comparisons with similar terranes elsewhere in South America and Africa, which in turn indicate a significant contribution of accretionary orogens in the early assembly of the Columbia Supercontinent.     

Coupled lithium- and iron isotope fractionation during magmatic differentiation

In this study, we investigated Fe and Li isotope fractionation between mineral separates of olivine pheno- and xenocrysts (including one clinopyroxyene phenocryst) and their basaltic hosts. Samples were collected from the Canary Islands (Teneriffa, La Palma) and some German volcanic regions (Vogelsberg, Westerwald and Hegau). All investigated bulk samples fall in a tight range of Li and Fe isotope compositions (δ⁵⁶Fe_wr = 0.06–0.17‰ and δ⁷Li_ma = 2.5–5.2‰, assuming δ⁷Li of the olivine-free matrix is virtually identical to that of the bulk sample for mass balance reasons). In contrast, olivine phenocrysts display highly variable, but generally light Fe and mostly light Li isotope compositions compared to their respective olivine-free basaltic matrix, which was considered to represent the melt (with δ⁵⁶Fe_ol = ? 0.24 to 0.14‰ and δ⁷Li_ol = ? 10.5 to + 6.5‰, respectively). Single olivine crystals from one sample display even a larger range of δ⁵⁶Fe_ol between ? 0.7 and + 0.1‰. One single clinopyroxene phenocryst displays the lightest Li isotope composition (δ⁷Li_cpx = ? 17.7‰), but no Fe isotope fractionation relative to melt. The olivine phenocrysts show variable Mg# and Ni (correlated in most cases) that range between 0.89 and 0.74 and between 300 and 3000 μg/g, respectively. These olivines likely grew by fractional crystallization in an evolving magma. One sample from the Vogelsberg volcano contained olivine xenocrysts (Mg# > 0.89 and Ni > 3000 μg/g), in addition to olivine phenocrysts. This sample displays the highest Li- and the second highest Fe-isotope fractionation between olivine and melt (Δ⁷Li_ol-melt = ? 13; Δ⁵⁶Fe_ol-melt = ? 0.29).Our data, i.e. the variable olivine- at constant whole rock and matrix isotope compositions, strongly indicate disequilibrium, i.e. kinetic Fe and Li isotope fractionation between olivine and melt (for Li also between cpx and melt) during fractional crystallization. Δ⁷Li_ol-melt is correlated with the Li partitioning between olivine and melt (i.e. with Li_ol/Li_melt), indicating Li isotope fractionation due to preferential (faster) diffusion of ⁶Li into olivine during fractional crystallization. Olivine with low Δ⁷Li_ol-melt, also have low Δ⁵⁶Fe_ol-melt, indicating that Fe isotope fractionation is also driven by diffusion of isotopically light Fe into olivine, potentially, as Fe–Mg inter-diffusion. The lowest Δ⁵⁶Fe_ol-melt (? 0.40) was observed in a sample from Westerwald (Germany) with abundant magnetite, indicating relatively oxidizing conditions during magma differentiation. This may have enhanced equilibrium Fe isotope fractionation between olivine and melt or fine dispersed magnetite in the basalt matrix may have shifted its Fe isotope composition towards higher δ⁵⁶Fe. The decoupling of Li- and Fe isotope fractionation in cpx is likely due to faster diffusion of Li relative to Fe in cpx, implying that the large investigated cpx phenocryst resided in the magma for only a short period of time which was sufficient for Li- but not for Fe diffusion. The absence of any equilibrium Fe isotope fractionation between the investigated cpx phenocryst and its basaltic host may be related to the similar Fe^3 +/Fe^2 + of cpx and melt. In contrast to cpx, the generally light Fe isotope composition of all investigated olivine separates implies the existence of equilibrium- (in addition to diffusion-driven) isotope fractionation between olivine and melt, on the order of 0.1‰.     

Evidence for the Jurassic arc volcanism of the Lolotoi complex,Timor: Tectonic implications

We report the first sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon ages with geochemical data from metavolcanic rocks in the Lolotoi complex, Timor. The zircon U–Pb ages of two andesitic metavolcanic rocks yield a permissible range of the Middle Jurassic extrusion from 177 Ma to 174 Ma. The geochemical data indicate that the origins of the basaltic and andesitic metavolcanic rocks are products of prolonged oceanic crust and arc magmatism, respectively. They are originated from partial melting of lherzolites, providing an insight into the tectonic evolution of the forearc basements of the Banda volcanic arc. Thus, parts of the Banda forearc basement are pieces of allochthonous oceanic basalts and Jurassic arc-related andesites accreted to the Sundaland during the closure of Mesotethys, and are incorporated later into the Great Indonesian Volcanic Arc system along the southeastern margin of the Sundaland.     

Destruction of the North China Craton: Delamination or thermal/chemical erosion? Mineral chemistry and oxygen isotope insights from websterite xenoliths

The destruction (or reactivation) of the North China Craton (NCC) is one of the important issues related to the Phanerozoic evolution of eastern China, although the processes of destruction remain debated. Two main mechanisms – delamination and thermal/chemical erosion – have been proposed based on the geochemistry of Mesozoic–Cenozoic basalts and entrained deep–seated xenoliths. A key criterion in distinguishing between these mechanisms is the nature of the melt, derived from delaminated crust or the asthenosphere, that modified the lithospheric mantle. Here we investigate the mechanism of destruction of the NCC based on mineral compositions and oxygen isotopic data from olivines, and strontium isotopic data for clinopyroxenes within websterite xenoliths from the Early Cretaceous Feixian basalts in the eastern NCC. Olivines in websterite xenoliths have higher Mg# (86–86.4), Ni content (2187–2468 ppm), and lower Ca (983–1134 ppm), Ti (58.1–76.1 ppm), and Mn (1478–1639 ppm) contents than olivine phenocrysts (Mg# = 71.0–77.3, Ni = 233–1038 ppm, Ca = 1286–2857 ppm, Ti = 120–300 ppm, and Mn = 2092–4106 ppm) from Late Cretaceous basalts. Additionally, olivines in websterite xenolith have δ¹⁸O values of 7.10 ± 0.21‰ to 8.40 ± 0.21‰, evidently higher than those of typical mantle-derived olivines. Similarly, orthopyroxenes (Opx) and clinopyroxenes (Cpx) in the websterite xenoliths have much higher Mg# (86.3–89.2 and 87.5–90.3, respectively), and Ni contents (1097–1491 ppm and 581–809 ppm, respectively) than orthopyroxene- and clinopyroxene-phenocrysts (Opx: Mg# = 82.2–83.9, Ni = 730–798 ppm; Cpx: Mg# = 74.2–84.6, Ni = 117–277 ppm) from Late Cretaceous basalts. The ⁸⁷Sr/⁸⁶Sr ratios of clinopyroxenes in the websterite xenoliths range from 0.70862 to 0.70979, and are much higher than those of clinopyroxene grains from peridotite xenoliths and basalts. These data indicate that olivines are the residue of ancient lithospheric mantle that was modified intensively by a melt derived from recycled continental crust, and that the silicic and calcic metasomatic melt might have been derived from the partial melting of the subducted Yangtze slab and delaminated lower crust of the NCC. The existence of recycled continental crust in the Mesozoic lithospheric mantle implies that delamination was an important mechanism of destruction of the NCC.     

Carboniferous magmatism and mineralization in the area of the Fuxing Cu deposit,Eastern Tianshan,China: Evidence from zircon U–Pb ages,petrogeochemistry, and Sr–Nd–Hf–O isotopic compositions

The newly discovered Fuxing porphyry Cu deposit is located in the Dananhu–Tousuquan arc, adjacent to the Tuwu–Yandong Cu deposits of Eastern Tianshan, in the southern Central Asian Orogenic Belt. The Fuxing deposit is hosted by volcanic rocks (basalt and dacite) in the Early Carboniferous Qi'eshan Group and Carboniferous felsic intrusions (plagiogranite porphyry, monzogranite, and quartz diorite). New SIMS zircon U–Pb dating indicates that the plagiogranite porphyry and monzogranite emplaced at 332.1 ± 2.2 Ma and 328.4 ± 3.4 Ma, respectively. The basalts are characterized by low SiO₂ contents (47.47–54.90 wt.%), a lack of Eu anomalies, strong depletion of Na, Ta, and Ti elements but positive Sr, U, and Pb anomalies, high Y (20.8–28.2 ppm) and HREE concentrations (Yb = 2.23–3.06 ppm), and relatively low (La/Yb)_N (2.20–3.92) values; the dacite samples have high SiO₂ contents (66.13–76.93 wt.%), clearly negative Eu anomalies, high Mg^# values (36–51), and high Y (41.8–54.9 ppm) and Yb (5.76–8.98 ppm) concentrations. The basalts and dacites exhibit similar signatures as normal arc rocks, and were considered to be derived from partial melting of mantle-wedge peridotite that was previously metasomatized by slab melts. In contrast, the plagiogranite porphyry, monzogranite, and quartz diorite show the same geochemical affinity with modern adakites, which are characterized by high SiO₂ contents (67.55–79.00 wt.%), minor negative to positive Eu anomalies, strong depletion of heavy rare earth elements (Yb = 0.17–1.19 ppm) and Y (1.86–10.1 ppm), positive K, Rb, Sr, and Ba but negative Nb, Ta, Th, and Ti anomalies, and high (La/Yb)_N ratios and Mg^# values. Moreover, these adakitic felsic intrusions display relatively high positive zircon ε_Hf(t) values (+ 11.4 to + 18.3), low ⁸⁷Sr/⁸⁶Sr (0.706080–0.711239), high ¹⁴³Nd/¹⁴⁴Nd (0.512692–0.512922) ratios, and consistent zircon δ¹⁸O values (4.41‰–5.48‰), suggesting that their parental magma were most likely derived from partial melting of the subducted oceanic crust followed by mantle peridotite interaction. Based on the whole-rock geochemical and Sr–Nd–Hf–O isotopic data, as well as detailed petrographic analyses, we further suggest that the Fuxing igneous rocks and associated porphyry Cu mineralization were generated by the northward subduction of the paleo-Tianshan oceanic plate beneath the Dananhu–Tousuquan island arc during the Early Carboniferous.