Formation of gold–silver sulfides and native gold in Fe–Ag–Au–S system

We carried out experiments on crystallization of Fe-containing melts FeS₂Ag_0.1–0.1xAu_0.1x (x = 0.05, 0.2, 0.4, and 0.8) with Ag/Au weight ratios from 10 to 0.1. Mixtures prepared from elements in corresponding proportions were heated in evacuated quartz ampoules to 1050 ºC and kept at this temperature for 12 h; then they were cooled to 150 ºC, annealed for 30 days, and cooled to room temperature. The solid-phase products were studied by optical and electron microscopy and X-ray spectroscopy. The crystallization products were mainly from iron sulfides: monoclinic pyrrhotite (Fe_0.47S_0.53 or Fe₇S₈) and pyrite (Fe_0.99S_2.01). Gold–silver sulfides (low-temperature modifications) are present in all synthesized samples. Depending on Ag/Au, the following sulfides are produced: acanthite (Ag/Au = 10), solid solutions Ag_2–xAu_xS (Ag/Au = 10, 2), uytenbogaardtite (Ag/Au = 2, 0.75), and petrovskaite (Ag/Au = 0.75, 0.12). They contain iron impurities (up to 3.3 wt.%). Xenomorphic micro- (<1–5 μm) and macrograins (5–50 μm) of Au–Ag sulfides are localized in pyrite or between the grains of pyrite and pyrrhotite. High-fineness gold was detected in the samples with initial ratio Ag/Au ≤ 2. It is present as fine and large rounded microinclusions or as intergrowths with Au–Ag sulfides in pyrite or, more seldom, at the boundary of pyrite and pyrrhotite grains. This gold contains up to 5.7 wt.% Fe. Based on the sample textures and phase relations, a sequence of their crystallization was determined. At ~1050 ºC, there are probably iron sulfide melt L₁ (Fe,S ? Ag,Au), gold–silver sulfide melt L₂ (Au,Ag,S ? Fe), and liquid sulfur L_S. On cooling, melt L₁ produces pyrrhotite; further cooling leads to the crystallization of high-fineness gold (macrograins from L₁ and micrograins from L₂) and Au–Ag sulfides (micrograins from L₁ and macrograins from L₂). Pyrite crystallizes after gold–silver sulfides by the peritectic reaction FeS + L_S = FeS₂ at ~743 ºC. Elemental sulfur is the last to crystallize. Gold–silver sulfides are stable and dominate over native gold and silver, especially in pyrite-containing ores with high Ag/Au ratios.     

Assessment of gold mineralisation in Osu–Amuta–Itagunmodi areas,Southwestern Nigeria

Tight conglomerate reservoirs have complex pore structure and strong heterogeneity which could bring great difficulties in the identification of oil and wa     

Platiniferous gold–tourmaline aggregates in the gold–palladium belt of Minas Gerais,Brazil: implications for regional boron metasomatism

Mineralogy and Petrology - The platiniferous gold–palladium belt of Minas Gerais, Brazil, forms an approximately 240-km-long, roughly north–south-trending domain that includes numerous...     

Kysylga gold–silver deposit in the terrigenous sequences of the Verkhoyansk–Kolyma mesozoides

The paper reports the mineralogical and geochemical features of the Kysylga gold deposit located in the hornfelsed Norian sedimentary rocks and classified with low-sulfide gold–quartz type of deposits typical of the Verkhoyansk–Kolyma metallogenic province. Detailed typomorphic study of the major minerals (quartz, arsenopyrite, and gold) of the ore veins shows that the deposit is assigned to the gold–silver type. Mineralogical and geochemical data substantiate this conclusion.     

Formation conditions of high-grade gold–silver ore of epithermal Tikhoe deposit,Russian Northeast

The Tikhoe epithermal deposit is located in the Okhotsk–Chukotka volcanic belt (OChVB) 250 km northeast of Magadan. Like other deposits belonging to the Ivan’insky volcanic–plutonic depression (VTD), the Tikhoe deposit is characterized by high-grade Au–Ag ore with an average Au grade of 23.13 gpt Au and Au/Ag ratio varying from 1: 1 to 1: 10. The detailed explored Tikhoe-1 orebody is accompanied by a thick (20 m) aureole of argillic alteration. Pyrite is predominant among ore minerals; galena, arsenopyrite, sphalerite, Ag sulfosalts, fahlore, electrum, and küstelite are less abundant. The ore is characterized by abundant Sebearing minerals. Cu–As geochemical specialization is noted for silver minerals. Elevated Se and Fe molar fractions of the main ore minerals are caused by their formation in the near-surface argillic alteration zone. The veins and veinlets of the Tikhoe-1 ore zone formed stepwise at a temperature of 230 to 105°C from Nachloride solution enriched in Mg and Ca cations with increasing salinity. The parameters of the ore-forming fluid correspond to those of epithermal low-sulfidation deposits and assume the formation of high-grade ore under a screening unit of volcanic rocks. In general, the composition of the ore-forming fluid fits the mineralogy and geochemistry of ore at this deposit. The similarity of the ore composition and parameters of the ore-forming fluid between the Tikhoe and Julietta deposits is noteworthy. Meanwhile, differences are mainly related to the lower temperature and fluid salinity at the Julietta deposit with respect to the Tikhoe deposit. The fluid at the Julietta deposit is depleted in most components compared with that at the Tikhoe deposit except for Sb, Cd, and Ag. The results testify to a different erosion level at the deposits as derivatives of the same ore-forming system. The large scale of the latter allows us to predict the discovery of new high-grade objects, including hidden mineralization, which is not exposed at the ore field flanks and beyond them.     

Preliminary analysis on roles of metal–organic compounds in the formation of invisible gold

The paper comprises new analytical data on the nature and occurrence of gold in solid pyrobitumen, closely associated with the main gold-bearing sulfide arsenic ores of the Bakyrchik gold deposit (Kazakhstan), related to post-collisional magmatic-hydrothermal origin. Gold mineralization of the deposit occurs mainly in the form of an “invisible” type of gold in the structures of arsenian pyrite and arsenopyrite, and the form of gold-organic compounds of pyrobitumen in carbonaceous-terrigenous sequences of Carboniferous formation. Microscopic and electron microscopic analysis, Raman and FT-Infrared analysis, mineralogical and three-step sequential extraction analysis (NH₂OH·HCl, H₂O_2, HNO₃ + HCl) has been carried out using 9 ore samples (from 3 different types of ores) for a comprehensive study of pyrobitumen and sulfide arsenic ores focusing mainly on organic matter. The sequentially extracted precious metal content of pyrobitumen reaches up to 7 ppm gold and other metals like Ag 4 ppm, Pt 31 ppb, and Pd 26 ppb, forming metal–organic compounds, while arsenic sulfide minerals incorporate 11 ppm gold, 39 ppm Ag, 0.49 ppm Pt. The enrichment of gold associating with organic matter and sulfide ore minerals was confirmed in this study. Organic matter was active in the migration of gold and the capture of gold by pyrobitumen. Moreover, the reductive organic matter agent released gold, most likely for the sulfide arsenic ore minerals. Pyrobitumen was a decisive factor in the concentration, transportation, and preservation of gold in the deposit.

     

Processes of high-T fluid–rock interaction during gold mineralization in carbonate-bearing metasediments: the Navachab gold deposit,Namibia

The Navachab gold deposit in the Damara belt of central Namibia is hosted by a near-vertical sequence of amphibolite facies shelf-type metasediments, including marble, calc-silicate rock, and biotite schist. Petrologic and geochemical data were collected in the ore, alteration halos, and the wall rock to evaluate transport of elements and interaction between the wall rock and the mineralizing fluid. The semi-massive sulfide lenses and quartz–sulfide veins are characterized by a complex polymetallic ore assemblage, comprising pyrrhotite, chalcopyrite, sphalerite, and arsenopyrite, native bismuth, gold, bismuthinite, and bismuth tellurides. Mass balance calculations indicate the addition of up to several orders of magnitude of Au, Bi, As, Ag, and Cu. The mineralized zones also record up to eightfold higher Mn and Fe concentrations. The semi-massive sulfide lenses are situated in the banded calc-silicate rock. Petrologic and textural data indicate that they represent hydraulic breccias that contain up to 50 vol.% ore minerals, and that are dominated by a high-temperature (T) alteration assemblage of garnet–clinopyroxene–K-feldspar–quartz. The quartz–sulfide veins crosscut all lithological units. Their thickness and mineralogy is strongly controlled by the composition and rheological behavior of the wall rocks. In the biotite schist and calc-silicate rock, they are up to several decimeters thick and quartz-rich, whereas in the marble, the same veins are only a few millimeters thick and dominated by sulfides. The associated alteration halos comprise (1) an actinolite–quartz alteration in the biotite schist, (2) a garnet–clinopyroxene–K-feldspar–quartz alteration in the marble and calc-silicate rock, and (3) a garnet–biotite alteration that is recorded in all rock types except the marble. The hydrothermal overprint was associated with large-scale carbonate dissolution and a dramatic increase in CO₂ in the ore fluid. Decarbonation of wall rocks, as well as a low REE content of the ore fluid resulted in the mobilization of the REE, and the decoupling of the LREE from the HREE. The alteration halos not only parallel the mineralized zones, but may also follow up single layers away from the mineralization. Alteration is far more pronounced facing upward, indicating that the rocks were steep when veining occurred. The petrologic and geochemical data indicate that the actinolite–quartz– and garnet–clinopyroxene–K-feldspar–quartz alterations formed in equilibrium with a fluid (super-) saturated in Si, and were mainly controlled by the composition of the wall rocks. In contrast, the garnet–biotite alteration formed by interaction with a fluid undersaturated in Si, and was mainly controlled by the fluid composition. This points to major differences in fluid–rock ratios and changes in fluid composition during alteration. The alteration systematics and geometry of the hydrothermal vein system are consistent with cyclic fluctuations in fluid pressure during fault valve action. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Geochronology and isotopic–geochemical characteristics of magmatic complexes of gold–silver ore–magmatic structures in the Chukotka sector of the Russian Arctic coast

The first results of SHRIMP dating of magmatic complexes and associated gold–silver deposits and ore occurrences (Kupol, Dvoinoe, Moroshka, and others) in the Chukotka sector of the Russian Arctic coast are discussed. The petrological and isotopic–geochronological data are used for reconstructing their formation conditions.     

Utilization of SPOT 5 data for mapping gold mineralized diorite–tonalite intrusion,Bulghah gold mine area,Saudi Arabia

The present study utilizes the processed SPOT 5 data to discriminate and to generate 1:10,000 geologic image map to delineate the mineralized diorite–tonalite intrusion around Bulghah gold mine area, Saudi Arabia. The rock units exposed in the area include gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite. Gold mineralization at Bulghah mine is hosted mainly by Syn- to Late-tectonic diorite–tonalite intrusion aligned along N–S direction and is associated mainly with cataclastic zones and quartz veins. Gossans and jasparoidal gossans (Hulayfah group), recorded at the western side of Bulghah mine area as discontinuous small lenses, can be easily discriminated on 4/2 and 4/3 band ratio SPOT images by their white and black image signatures, respectively. Granitoids (gneissose granite and alkali granite) are easily discriminated in 3/2 ratio image, in which gneissose granite has gray image signature, whereas alkali granite has dark gray image signature. On the SPOT false color composite band ratios image (3/2 R, 4/2 G, and 4/3 B), gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite have sky blue, blood red, bluish light brown, orange, brick red, and deep blue colors, respectively. Fusion of the false color composite SPOT ratios image (3/2 R, 4/2 G, and 4/3 B) with the high spatial resolution SPOT pan image is performed using IHS transformation method. The fused image is used to delineate the mineralized diorite–tonalite intrusion and to produce 1:10,000 geologic image map for Bulghah gold mine area. The present study reveals the usefulness of the processed SPOT 5 data for adding new extensions at the southern and northern boundaries of diorite–tonalite intrusion.     

Native gold in complex Ti–Zr placers of the southern West Siberian Plain

Typomorphic features of native gold and its contents in complex Ti–Zr placers in the southern West Siberian Plain are reported. Three of the placers are of littoral-marine genesis, and two formed under conditions of an alluvial piedmont plain. Native gold from the studied Ti–Zr placers occurs mainly as flattened thin (?0.1 mm) particles which underwent mechanical action. It is marked by wide fineness variation and the abundance of a very fine (990–1000‰) variety. Most likely, this is chemically transformed clastogenic metal. The gold content of the productive bed (5–30 mg/m³ native gold and 8–140 ppb bulk gold) is consistent with the dispersion of heavy ore and accessory minerals during mechanical migration in water flows simultaneously with their concentration on geochemical barriers. The native-gold content of complex Ti–Zr placers shows a higher negative correlation with the primary source–placer distance than those of Ti and Zr minerals and a positive correlation with the degree of hydrodynamic reworking (gravity concentration) of transit terrigenous material. On the southern framing of the West Siberian Plain, some regions of northern Kazakhstan are promising for gold of complex Ti–Zr placers as well as fine- and thin-gold placers, gold-bearing weathering crusts, and primary gold deposits.     

Environmental assessment of copper–gold–mercury mining in the Andacollo and Punitaqui districts,northern Chile

The Coquimbo region has been one of the richest producers of Cu, Au and Hg in Chile, and some of the deposits have been mined almost continuously since the 16th century. To assess the potential environmental contamination in this region, the authors measured the concentration of Cu, As, Cd, Zn and Hg in samples of stream and mine waters, stream sediments, soils, flotation tailings, and mine wastes in the Andacollo (Cu, Au, Hg) and Punitaqui (Cu–Au, Hg) districts. The concentration of Hg in the atmosphere in these districts were also measured. Although contamination is strongly controlled by the ore in each district, metal dispersion is modified by the degree of metallurgical processing efficiency as shown by the outdated Cu flotation system at Andacollo (stream sediments Cu 75–2200 μg/g). Conversely, more efficient procedures at Punitaqui resulted in less stream contamination, where stream sediments contained Cu ranging from 110–260 μg/g. However, efficient concentration by flotation of a given metal (e.g. Cu) may lead to the loss of another (e.g. Hg up to 190 μg/g in the tailings at Punitaqui), and therefore, to contamination via erosion of the tailings (downstream sediments Hg concentrations up to 5.3 μg/g). Continued use of Hg for Au amalgamation at Andacollo has led to significant contamination in stream sediments (0.2–3.8 μg/g Hg) and soils (2.4–47 μg/g Hg). Communities in this region are underdeveloped, and decades of inefficient treatment of flotation tailings and waste-rock stock piles has resulted in significant contamination of the surrounding landscape.     

Geochemical features of gold–quartz veins in granitoid intrusives and terrigenous masses of the Yana–Kolyma folded belt in the northeast of Russia

The main task of this study was to reveal geochemical and distinctive features of gold–quartz vein ores of deposits in granitoid intrusive bodies and in terrigenous black-schist masses of the Yana-Kolyma folded belt. The results obtained point to the significant role of metamorphism of the enclosing terrigenous carbonaceous masses in ore formation of both types of deposits. The established facts are not contradictory to the metamorphic–magmagene model of the formation of gold deposits in the Yana–Kolyma belt. The geochemical similarity of both types of deposits shows that these are products of the same orogenic system, which confirms the validity of combining these deposits to form a unified gold–quartz formation.     

Tokur gold ore–placer cluster in Amur Province: Geological–structural features and perspective of its development

The geological–structural features and gold-potential perspective of the Tokur ore–placer cluster in the Amur Province have been studied. This ore–placer cluster is a syncline composed of Paleozoic blackshale sequence, which is cut through by Late Paleozoic and Late Mesozoic intrusions. A granitoid massif is suggested at the depth on the basis of geophysical data. The cluster is distinguished by high productivity. Approximately 37 t gold from ore deposits, primarily from the Tokur deposit, and 60 t from placers have been mined out. The Tokur deposit is compared with the Natalka and Degdekan deposits from the Yana–Kolyma Province. Perspectives of the cluster area for large gold–quartz deposits and technogenic gold placers have been estimated.     

First discovery of high-mercury silver in ores of the Rogovik gold–silver deposit (Northeastern Russia)

New data on mercurial mineralization are presented, and a detailed characteristic is given for the first discovery of mercurous silver in ores of the Rogovik gold–silver deposit (the Omsukchan trough, Northeastern Russia). It was found that native silver in the examined ores occurs as finely-dispersed inclusions in quartz filling microcracks and interstitions. It also occurs in associations with kustelite, Ag sulfosalts and selenides, selenitic acanthite, and argyrodite. The mercury admixture varies from “not detected” in the central parts of grains to 0.22–1.70 wt % along the edges, or, in independent grains, to the appearance of Ag amalgams containing 10.20–24.61 wt % of Hg. The xenomorph form of grains of 50 μm or less in size prevails. It is assumed that the appearance of mercurial mineralization is caused by the superposition of products of the young Hg-bearing Dogda–Erikit belt upon the more ancient Ag-bearing Omsukchan trough.

     

Texture and chemistry of pyrite at Chah Zard epithermal gold–silver deposit,Iran

Gold mineralization at Chah Zard, Iran, is mostly concentrated in breccia and veins, and is closely associated with pyrite. Optical and scanning electron microscopy-backscattered electron observations indicate four different pyrite types, each characterized by different textures: porous and fractured py1, simple-zoned, oscillatory-rimmed, framboidal and fibrous py2, colloform py3, and inclusion-rich py4. Laser ablation ICP–MS analysis and elemental mapping reveal the presence of invisible gold in all pyrite types. The highest concentrations (161–166 ppm Au) are found in py2 and py4, which correlate with the highest As concentrations (73,000–76,000 ppm). In As-poor grains, Au concentrations decrease by about two orders of magnitude. Copper, Pb, Zn, Te, Sb, and Ag occur with invisible gold, suggesting that at least part of the gold occurs in nanoparticles of sulfosalts of these metals and metalloids. Gold distribution patterns suggest that only negligible Au was originally trapped in py1 from the initial ore fluids. However, most, if not all, Au was transported and deposited during subsequent overprinting hydrothermal fluid flow in overgrowth rims around the margins of the py2 and within microfractures of py4 grains. Oscillatory zonation patterns for Co, Ni, Sb, Cu, Pb, and Ag in pyrite reflect fluctuations in the hydrothermal fluid chemistry. The LA-ICP–MS data reveal that Cu, Pb and Ag show systematic variations between different pyrite types. Thus, Cu/Pb and Pb/Ag ratios in pyrite may provide a potentially powerful exploration vector to epithermal gold mineralization at Chah Zard district and elsewhere.     

New data on ore geochemistry of the Rodionovskoe gold–quartz deposit,Northeast Russia

The enrichment of gold–quartz ores from the Rodionovskoe deposit in chalcophile elements (Au, Ag, As, Sb) is established. The ores are characterized by small negative Eu anomalies and low REE contents, which are typical of magmatic fluids. Slight enrichment of ores in Bi is evidence of the possible involvement of magmatic fluid in ore formation, which may have been superimposed on early metamorphic quartz veins and veinlets. The variously oriented REE patterns also indicate the presence of another magmatic fluid source, which could be related to the post-ore granitic intrusion. These results generally confirm the metamorphic–magmatic model of the formation of the gold–quartz deposits of the Yana–Kolyma belt. Our data are of practical interest for regional metallogenic forecasts, search, and evaluation of gold deposits.     

The stages and duration of formation of gold mineralization at copper-skarn deposits (Altai–Sayan folded area)

Gold mineralization at copper-skarn deposits (Tardanskoe, Murzinskoe, Sinyukhinskoe, Choiskoe) in the Altai–Sayan folded area is related to different hydrothermal-metasomatic formations. It was produced at 400–150 ºC in several stages spanning 5–6 Myr, which determined the diversity of its mineral assemblages. Gold mineralization associated with magnetite bodies is spatially correlated with magnesian and calcareous skarns, whereas gold mineralization in crushing zones and along fault sutures in moderate- and low-temperature hydrothermal-metasomatic rocks (propylites, beresites, serpentinites, and argillizites) is of postskarn formation. Different stages were manifested with different intensities at gold deposits. For example, the Sinyukhinskoe deposit abounds in early high-temperature mineral assemblages; the Choiskoe deposit, in low-temperature ones; and the Tardanskoe and Murzinskoe deposits are rich in both early and late gold minerals. Formation of commercial gold mineralization at different copper-skarn deposits is due to the combination of gold mineralization produced at different stages as a result of formation of intricate igneous complexes (Tannu-Ola, Ust’-Belaya, and Yugala) composed of differentiated rocks from gabbros to granites.     

Origins of Nd–Sr–Pb isotopic variations in single scheelite grains from Archaean gold deposits,Western Australia

Accessory gangue scheelite (CaWO₄) from the Archaean Mt. Charlotte lode Au deposit can be divided into two types with different rare earth element (REE) signatures. In some scheelite grains, specific REE signatures are reflected by different cathodoluminescence colours, which can be used to map their often complex oscillatory intergrowths. Domains with specific REE contents from two grains were sampled for Sm/Nd, Rb/Sr and Pb isotopic analyses using a micro-drilling technique.Type I scheelite is strongly enriched in middle REE (MREE) and Eu anomalies are either absent or slightly positive. Four fragments collected from Type I regions of two crystals have initial ⁸⁷Sr/⁸⁶Sr and ε_Nd values ranging from 0.70141 to 0.70163 and +2.5 to +3.5, respectively, and Pb isotope ratios reflecting the composition of greenstone sequence. This may indicate that Nd and Pb have their source, either locally or regionally, in the greenstones. Basic greenstone lithologies have ⁸⁷Sr/⁸⁶Sr<0.7015, and the radiogenic Sr signatures indicate that part of the Sr originated from felsic lithologies located either within or beneath the host greenstone pile. Alternatively, the Sr signature may have evolved from preferential leaching of a Rb-rich mineral during hydrothermal alteration of the greenstone.The REE patterns of Type II scheelite are either flat or MREE-depleted and have strong positive Eu anomalies. Three fragments collected from Type II regions of the same two crystals have initial ⁸⁷Sr/⁸⁶Sr ratios and ε_Nd values between 0.70130 and 0.70146, and +1.1 to +2.6, respectively, and Pb isotope signatures that are once again similar to that of the greenstone. This implies that ⁸⁷Sr/⁸⁶Sr ratios in Type II fluids were closer to those of the host dolerite (0.7008–0.7013), due to more extensive fluid interaction with the dolerite.A positive correlation between Na and REE suggests that REE³⁺ are accommodated by the coupled substitution REE³⁺+Na⁺=2 Ca²⁺ into both Type I and Type II scheelite. This is consistent with a fractional crystallisation model to explain the change in REE patterns from Type I to Type II, but not with a model involving different coupled substitutions and fluids from different origins. We propose that the complex REE and isotopic signatures of scheelite at Mt. Charlotte are related to small (<m) to medium (<km) scale processes involving mixing between “fresh” batches of hydrothermal fluid with fluids that had already been involved in extensive wall-rock alteration.The very high-ε_Nd values measured in some scheelites have been previously used to link gold mineralisation with komatiites containing unusually high Sm/Nd ratios. However, tiny (<20 μm) grains of secondary hydroxyl-bastnäsite were found within micro-fractures of one scheelite grain containing an extremely high-ε_Nd signature. The hydroxyl-bastnäsite probably formed during recent REE redistribution within the scheelite as a result of meteoric fluid circulation. The scale of this cryptic low-temperature alteration is sufficient to explain the anomalously high-ε_Ndi values observed in scheelite from Western Australia.