东太平洋CC区西区表层沉积物黏土矿物和地球化学特征

本文以太平洋CC区西区12个表层沉积物样品作为研究对象,对其粒度、化学组分和矿物成分进行分析,讨论其沉积环境和物质来源。研究区地处深海,主要以深海黏土和硅钙质黏土为主,含有少量的硅质黏土、黏土质硅质软泥和黏土质钙质软泥。黏土矿物成分主要是蒙皂石和伊利石,含有部分的高岭石和绿泥石。黏土矿物组成表明,区内沉积物主要是陆源,由高空气流携带而来,南极底流和热液活动对其物源的来源有一定影响。沉积物地球化学特征也表明,物源以陆源为主,稀土元素分布曲线和北太平洋表层海水稀土曲线类似,且表现出强的Ce亏损,表明生物活动导致的生物沉降对表层沉积物也有一定的影响。     

Distribution,provenance, and dispersal pattern of clay minerals in surface sediments,Bransfield Strait,Antarctica

Clay minerals of the surface sediments of Bransfield Strait, Antarctica, exhibit distinctive geographical distributions: kaolinite has the highest concentration near the shore of the South Shetland Islands in the northern strait (20%); chlorite, near Smith Island in the northwestern strait; illite, on the continental shelf off the Antarctic Peninsula in the southern strait (80%); and smectite, close to the Penguin and Bridgeman islands in the northeastern strait (25%). This distribution pattern, combined with hydrographic and climatic data for the strait, are used to infer clay mineral provenance and dispersal patterns.     

南海南部沉积物中黏土矿物组成变化及其古沉积信息记录初探

通过对南海南部2个代表13万a以来柱状沉积样品高分辨率的黏土矿物组成分析,认为所研究的黏土矿物主要为陆源碎屑成因,埋藏过程中的成岩变化或黏土矿物自生特征不明显,而以采样点南面加里曼丹岛、菲律宾东、西两侧的火山群岛和湄公河流域为主要陆源的地质条件、风化环境及物质迁移途径的差异控制了南海南部沉积物中黏土矿物组成的空间和时间变化.研究发现,沉积物样品中较高的蒙皂石含量对应于地质历史上的暖期,而较低的蒙皂石含量对应于冷期.伊利石的行为及其古海洋指示意义则与蒙皂石相反.将柱状沉积物样品上高分辨率的黏土矿物组成分析作为一种研究方法,有助于研究晚第四纪以来南海陆源碎屑物的源区特征、迁移途径及海区古环境演变.     

Clay-mineral suites,sources, and inferred dispersal routes: Southern California continental shelf

Clay mineralogy is useful in determining the distribution, sources, and dispersal routes of fine-grained sediments. In addition, clay minerals, especially smectite, may control the degree to which contaminants are adsorbed by the sediment. We analyzed 250 shelf sediment samples, 24 river-suspended-sediment samples, and 12 river-bed samples for clay-mineral contents in the Southern California Borderland from Point Conception to the Mexico border. In addition, six samples were analyzed from the Palos Verdes Headland in order to characterize the clay minerals contributed to the offshore from that point source. The <2 microm-size fraction was isolated, Mg-saturated, and glycolated before analysis by X-ray diffraction. Semi-quantitative percentages of smectite, illite, and kaolinite plus chlorite were calculated using peak areas and standard weighting factors. Most fine-grained sediment is supplied to the shelf by rivers during major winter storms, especially during El Ni?o years. The largest sediment fluxes to the region are from the Santa Ynez and Santa Clara Rivers, which drain the Transverse Ranges. The mean clay-mineral suite for the entire shelf sediment data set (26% smectite, 50% illite, 24% kaolinite+chlorite) is closely comparable to that for the mean of all the rivers (31% smectite, 49% illite, 20% kaolinite+chlorite), indicating that the main source of shelf fine-grained sediments is the adjacent rivers. However, regional variations do exist and the shelf is divided into four provinces with characteristic clay-mineral suites. The means of the clay-mineral suites of the two southernmost provinces are within analytical error of the mineral suites of adjacent rivers. The next province to the north includes Santa Monica Bay and has a suite of clay minerals derived from mixing of fine-grained sediments from several sources, both from the north and south. The northernmost province clay-mineral suite matches moderately well that of the adjacent rivers, but does indicate some mixing from sources in adjacent provinces.     

Last glacial–Holocene sediment sequences in N. Aegean basins: structure,accumulation rates and clay mineral distribution

The vertical distribution patterns of grain-size parameters, carbonate and organic carbon contents, and clay mineral abundances were examined in ten sediment cores from basins of the northern Aegean Sea. Sedimentation rates for Holocene deposition were determined on the basis of 11 ¹⁴C datings and indirectly from the age of the lower sapropel S1; they were estimated at 14.9, 18.9–21.8 and 34.7 cm 10³ year^–1 for the North Skyros, Athos, and North Limnos basins respectively. The sedimentation rates decrease gradually towards the southern basins, as a consequence of the greater distance from sediment supply sources. Also, sedimentation rates appear to decrease from the last glacial to Holocene units. The clay minerals illite, smectite, kaolinite and chlorite were identified in the cores. Generally, illite is the predominant mineral, showing a north–south-decreasing trend, followed by smectite; both minerals have a terrigenous origin, and smectite occurrence is higher in basins located near Limnos Island where volcanic formations prevail. Terrigenous illite is abundant in the sapropel S1, exhibiting the highest content of all sedimentological units. High illite content is unusual in eastern Mediterranean sapropels. This pattern is attributed to the proximity of the N. Aegean Sea basins to Balkan and Turkish land sources. In general, sediment mass gravity flow processes coupled with seasonal deposition from nepheloid layers are the predominant sedimentation mechanisms in the N. Aegean basins. The relative sea-level stand, the proximity to terrigenous sources (rivers), the morphology of the N. Aegean basins (small dimensions, isolated, steep slopes), as well as seismic activity and strong bottom currents are probably the major factors controlling sedimentation in the region.     

东菲律宾海帕里西维拉海盆第四纪黏土矿物组合特征及物源分析

应用X射线衍射(XRD)方法对东菲律宾海帕里西维拉海盆的两个重力柱状样F090815和F100609的第四纪沉积物进行了黏土矿物分析。结果表明,南北两个柱状样黏土矿物呈现不同的组合特征。南部的F090815岩心蒙皂石含量(平均50%)最高,伊利石(平均37%)次之,含少量的绿泥石和高岭石(平均13%);北部的F100609岩心为伊利石含量(平均47%)最高,蒙皂石(平均39%)次之,含少量的绿泥石和高岭石(平均14%)。根据黏土矿物含量及特征变化可将两根柱状样划分为4段,并根据黏土矿物组合特征及化学指数和结晶度,认为蒙皂石主要来源于研究区东部紧邻的马里亚纳海槽基性火山物质的蚀变;伊利石主要来源于物理风化作用强烈的陆地,并很可能与亚洲风尘有关;绿泥石与伊利石有着相同的来源;高岭石在此区含量非常低,也证明了与伊利石和绿泥石来源相同。另外,两柱状样黏土矿物特征变化趋势不同,是由于整个F090815孔所揭示的地层大概只相当于F100609孔的第IV段沉积期,是该沉积期更高分辨率的反映。     

晚上新世以来菲律宾海盆XT4孔黏土矿物特征及其古环境意义

菲律宾海是典型风尘汇聚区,菲律宾海远离吕宋岛的深海沉积物是重建构造尺度亚洲风尘演化历史的良好载体.选取菲律宾海盆XT4孔沉积物开展了黏土矿物研究,并结合前人研究成果,在明确该孔黏土矿物来源的基础上,探讨了晚上新世以来亚洲风尘的演化历史及其可能的影响机制.菲律宾海盆XT4孔黏土矿物以伊利石为主,平均含量为39％,蒙脱石含...     

帕里西维拉海盆西北部表层沉积物中粘土矿物的分布特征及物源分析

提要应用X射线衍射(XRD)方法对菲律宾海帕里西维拉海盆西北部的257个表层沉积物样品<2μm粘土组分进行了分析。结果表明,本研究区粘土矿物的组合特点是伊利石含量最高(平均含量47%),蒙皂石含量次之(平均含量35%),高岭石和绿泥石含量均很低(平均含量小于10%)。根据该区表层粘土矿物中伊利石、蒙皂石相对含量的分布,可以大体上分为两种含量组合类型,据此也可以划分出两个组合分区:Ⅰ.富伊利石分区,主要位于帕劳海脊和帕里西维拉海沟之间的大部分区域的地形平坦处;Ⅱ.富蒙皂石分区,主要位于研究区东部帕里西维拉海沟附近和南部零星区域。根据粘土矿物的平面分布特征,结合个别样品的扫描电子显微镜(SEM)和X射线能谱(EDS)分析,认为伊利石主要来源于研究区以西陆地及周边岛屿。伊利石的化学指数和结晶度指数表明,伊利石形成于物理风化较强的气候环境并可能与中国内陆黄土有关系,区内大部分蒙皂石具有富铁并含少量镁的特征,基性火山物质的蚀变是其主要成因,高岭石和绿泥石以陆源为主;风力的吹扬是研究区伊利石物质来源的主要输送方式,洋流作用对粘土矿物,尤其是蒙皂石矿物的分布具有一定影响。     

南海粘土矿物组合特征及其环境意义

利用X射线衍射法(XRD)对南海12个海底表层沉积物和20个悬浮物样品中粘土矿物组成和分布特征进行了综合分析。结果表明:(1)研究区的表层沉积物粘土矿物以伊利石为主,其次为绿泥石、高岭石、伊/蒙间层矿物以及蒙皂石;悬浮物粘土矿物是以绿泥石为主,其次为高岭石、蒙皂石、伊利石以及伊/蒙间层矿物。(2)粘土矿物的组成和分布特征主要受气候条件、物质来源、水动力条件及相互间稀释作用的制约。伊利石的含量随离岸距离和水深的增加呈增大趋势;高岭石则在近岸区特别是河口区富集;绿泥石在西部沿岸海区的含量较低,在东部岛弧和北部台湾岛附近海区的含量较高;蒙皂石与火山作用密切相关,在东部火山岛弧附近海区含量较高。(3)粘土沉积物的来源以河流输入为主,海洋自生和风尘搬运对该区的沉积影响不大。(4)深海悬浮物粘土矿物的组成变化能够很好地指示短尺度气候环境的变迁,伊利石的结晶程度对气候和环境变化反映灵敏,其随所处环境的压力增大而变差。     

西北冰洋表层沉积物黏土矿物分布特征及物质来源

西北冰洋表层沉积物黏土矿物分析结果显示其黏土矿物组成的区域分布和变化具有明显的规律性:从楚科奇海到北冰洋深水区,随着水深的增加,蒙皂石和高岭石含量增高,绿泥石和伊利石含量降低。自西往东,伊利石结晶度值降低,化学指数升高。根据Q型聚类分析获得的黏土矿物组合特征,结合周缘陆地的地质背景、河流及洋流情况,对研究区进行了黏土矿物组合分区,讨论了其黏土矿物来源。楚科奇海表层沉积物黏土矿物组合在靠近阿拉斯加一侧海域以Ⅰ类为主,靠东西伯利亚海一侧主要有Ⅱ类、Ⅲ类和Ⅳ类,中部主要为Ⅵ类,主要是西伯利亚和阿拉斯加的火山岩、变质岩以及一些含高岭石的沉积物以及古土壤等,经风化、河流搬运入海,在北太平洋的3股洋流及西伯利亚沿岸流的作用下沉积形成的。西北冰洋深水区表层沉积物的黏土矿物组合以Ⅰ类和Ⅴ类为主,表明其沉积物来源为欧亚陆架和加拿大北极群岛周缘海域的海冰沉积和大西洋水体的搬运以及加拿大马更些河的河流物质输入。     

大凌河与辽河入海口沉积物黏土矿物组成研究

采用X射线物相分析,对大凌河和辽河13个表层沉积物样品和4个柱状样中168个现代沉积物样品的主要黏土矿物含量组成进行分析。研究结果表明:大凌河沉积物黏土矿物组合为蒙脱石-伊利石-高岭石-绿泥石,辽河沉积物黏土矿物组合为伊利石-蒙脱石-绿泥石-高岭石。大凌河沉积物中蒙脱石与伊利石百分含量比值多大于1,而辽河沉积物该比值都小于1,且通过ISKc端元图能较清晰地区分两类沉积物,黏土矿物可以作为两条河流沉积物的判别标志。大凌河流域和辽河流域均以物理风化为主,辽河流域物理风化略强。流域内地质背景和气候条件等因素的差异造成了两条河流沉积物黏土矿物组成的不同。     

南海西北部表层沉积物黏土矿物分布特征及其来源

黏土矿物研究在示踪物源、源区风化历史乃至洋流变迁能力等方面具有重要的作用,尽管目前对南海表层沉积物黏土矿物宏观分布特征已获得了较系统的认识,但在受珠江和海南岛物源共同影响的南海西北部其高分辨率的黏土矿物学工作还未开展。本文对南海西北部表层沉积物中的黏土矿物组成、结晶学特征进行了分析,讨论了研究区黏土矿物的物质来源。结果表明,南海西北部表层沉积物的黏土矿物组成以伊利石为主（平均45%）,蒙脱石（平均27%）与高岭石（平均21%）次之,绿泥石含量最少（平均6%）。在区域空间分布上,蒙脱石含量呈现西南高东北低的特征,伊利石含量则与之相反;高岭石含量表现为近岸高离岸低,而绿泥石含量呈现离岸高近岸低的特征。总体上,研究区表层沉积物黏土矿物组成与现代珠江沉积物组成差异较大,而与珠江口2.5 ka前的沉积物黏土矿物组成比较接近,并且结合研究区岩心揭露的全新世以来极低的沉积速率（4 cm/ka）以及上部很薄（小于0.6 m）的泥质沉积,推测该区表层沉积物可能并非是现代沉积的结果,更可能主要来自全新世末期古珠江输送的沉积物。除古珠江作为研究区表层沉积物中蒙脱石的一个主要来源外,海南岛北部河流也贡献了少量蒙脱石到其邻近的东南海域。运用高岭石/伊利石比值和伊利石化学指数等进一步对比分析表明,珠江是研究区沉积物中伊利石、高岭石和绿泥石的主要物源,其次台湾和海南岛也可能分别提供了少量富含伊利石/绿泥石和高岭石的沉积物。本工作对于南海西北部沉积物源-汇过程和相应的古环境研究有重要的参考意义。     

Clay mineral assemblages,siliciclastic input and paleoproductivity at ODP Site 1085 off Southwest Africa: A late Miocene–early Pliocene history of Orange river discharges and Benguela current activity,and their relation to global sea level change

A late Miocene to early Pliocene sequence drilled on the continental slope of southwest Africa off the Orange river mouth (ODP Site 1085) has been investigated. Clay mineral assemblages, coarse siliciclastics and benthic foraminifer accumulation rates (BFAR) unravel a step by step evolution of marine and continental environments closely related to sea level variations, ocean circulation and global climate: (1) smectite is a typical tracer of the Orange river load, whereas illite is mostly transported by the Benguela current (like chlorite) and winds, and kaolinite is derived from low latitudes by the poleward undercurrent and the North Atlantic Deep Water (NADW); (2) increased erosion and influence of the Orange river after 9.6 Ma is linked to a sea level drop at a time of Antarctic ice-growth. This has been followed by an increased seasonality of precipitation and high productivity, but low oxygen content and associated dissolution of carbonates; (3) increased productivity and dissolution of carbonates, and coeval increase of continental aridity after 8.9 Ma express a further development of the Benguela current and upwelling; (4) better preservation of carbonates and increased contribution of terrigenous material from northern sources at 6.9 Ma are related to increased circulation of NADW after an early stage of northern hemisphere glaciation; (5) increased erosion and contribution from the Orange river and westward shift of the area of higher productivity from 5.9–5.8 Ma to 5.3–5.2 Ma are related to a significant fall of sea level, and encompass the time of the entire Mediterranean salinity crisis; (6) short-term variations of the smectite/illite ratio (S/I) and BFAR suggest a major control of productivity by wind and current activities (and related upwelling), but may express brief variations of sea level in specific intervals before 8.9 Ma and during the late Messinian especially.     

北极圈海域表层沉积物的黏土矿物特征及其环境意义

应用X射线衍射(XRD)分析技术对北极圈海域15个表层沉积物的黏土矿物进行了研究。结合伊利石的结晶度指数综合分析了研究区黏土矿物的组成和分布特征及其物质来源、沉积环境和水动力条件。结果表明,北极圈海域研究区的黏土矿物以伊利石为主(33%),其次为伊/蒙间层矿物(25%)、绿泥石(23%)、高岭石(15%)以及蒙皂石(4%)。伊利石的开形指数(Ns)都比较小,大多在1~2之间,Ns的分布对物源有一定的指示意义。楚科奇海区具较弱的水动力条件,沉积环境较稳定;白令海具强烈的水动力条件,属于冲刷环境。认为北极圈海域研究区的黏土沉积物均有三方面来源,即河流输入、海洋自生和冰筏搬运物。     

Clay mineralogy of bottom sediment in the Jinhae Bay,Korea

The bottom sediments of Jinhae Bay area contain, on average, 45 % illite, 23 % kaolinite, 17 % intergrade clay, 10 % chlorite, and 5 % smectite. The geographical distribution of the clay minerals shows, in general, an it crease in illite, a decrease in kaolinite, and a slight decrease in chlorite seawards. The distributional trends of smectite and intergrade clay are irregular. The clay fractions of the sediments of Jinhae Bay are supplied from stream-borne sediments and are mixed with sediments transported landwards from the East China Sea. Local erosion and redeposition of the clay fractions of the bottom sediments is caused by rapid tidal currents.     

西菲律宾海盆I8孔黏土矿物的物源分析

应用X-射线衍射(XRD)方法分析了菲律宾海盆西部I8柱状样35个沉积物样品中的黏土矿物组分,结果表明:I8孔中黏土矿物以伊利石(40%)为主,蒙皂石(28%)和绿泥石(20%)次之,高岭石(12%)相对较低,且伊利石结晶度较好。黏土矿物来源分析表明,伊利石主要来源于亚洲大陆的风尘输入;蒙皂石主要源于研究样品周围火山物质的蚀变;而绿泥石和高岭石可能主要源自吕宋岛风化产物。     

700年以来冲绳海槽南部黏土矿物来源及其对沉积环境的响应

本文对冲绳海槽南部HOBAB4-S2站700年以来的黏土矿物组成及结晶学特征进行了研究和分析,并对该区的物质来源以及黏土矿物所记录的东亚季风的演化历史进行了探讨。研究发现冲绳海槽南部HOBAB4-S2站黏土矿物组合总体是以伊利石（59%~77%,平均含量69%）和绿泥石（11%~17%,平均含量14%）为主,蒙脱石（5%~23%,平均含量12%）和高岭石含量（2%~6%,平均含量4%）则相对较低。通过黏土矿物研究对物源进行分析,发现冲绳海槽南部研究站位的黏土矿物中,伊利石、绿泥石以及高岭石主要来自于台湾岛上的河流,尤其是兰阳溪,蒙脱石则主要是来自于长江和东海大陆架的悬浮再沉积。蒙脱石/（伊利石+绿泥石）比值可以用来大致反映长江和东海大陆架与台湾岛对研究区物质输入的相对贡献。其相对贡献量的变化很好地记录了小冰期（1405 A.D.—1850 A.D.）东亚夏季风的减弱和台湾岛东北部-冲绳海槽南部地区相对湿润的气候特征。而该比值所指示的现代暖期（1960 A.D.）夏季风强度的减弱则可能主要是受到人类活动的影响。     

The distribution characteristics of clay minerals in the northern South China Sea

The clay minearals are composed of illite, chlorite, kaolinite, montmorillonite and mixed-layer minerals in the submarine sediments of the northern South China Sea. Three types of clay mineral zone can be recognized on the basis of the distributive regularity of clay minerals, submarine relief, hydrodynamic conditions and depositional characteristics in this region. Apart from the northern mainland source, kaolinites carried from the Philippines volcanic arc in the east and Malaysia in the south are also assumed to be one of the sources of the clay minerals in the deep sea. The increase of chlorites to the abyssal direction in the west of 116° E might be associated with the residual chlorites carried from the ancient Zhujiang River during the glacial period and the conversion of kaolinite into chlorite submarine volcanoes appear to be one of the sources of the increment of montmorillonite and chlorite around the Huangyan Island. From the distribution pattern of clay minerals in the whole area, it is kn     

长江水下三角洲表层沉积物粘土矿物分布及其影响因素

采用X射线衍射(XRD)分析技术分析了长江水下三角洲地区65个表层沉积物样品的粘土矿物。结果表明,长江水下三角洲粘土矿物主要由伊利石、绿泥石、高岭石和蒙皂石构成;长江水下三角洲亚环境粘土矿物组成则不同,三角洲前缘亚环境中高岭石和绿泥石的平均含量高于前三角洲的含量,而前三角洲亚环境中伊利石和蒙皂石的平均含量高于三角洲前缘的含量。研究区粘土矿物主要来自长江流域,属于长江源,其分布主要受沉积动力环境和粘土本身性质的制约。     

镇江下蜀土中的黏土矿物及其古环境意义

镇江大港砖瓦厂下蜀黄土剖面30个样品的X衍射分析和半定量结果表明,该剖面黏土矿物组合为伊利石-蛭石-高岭石型,其中以伊利石（52.8%～70%）和蛭石（20.6%～38.5%）为主;古土壤层的伊利石相对含量高于黄土层,蛭石的变化与之相反,二者互为消长.高岭石含量为6.0%～11.1%,在古土壤中的含量略高于黄土层.从剖面底部（S4）至顶部（S1）, 伊利石相对含量略呈增加趋势,蛭石和高岭石则略呈减少趋势.镇江下蜀黄土中的黏土矿物组合类型与北方黄土明显不同,伊利石的结晶度总体上也较北方黄土差,反映下蜀黄土堆积区相对温暖、湿润,风化淋滤作用相对较强.从黏土矿物组合和含量来看,下蜀黄土经历了中等强度的风化作用.