Oxygen isotope stratigraphy and events in the northern South China Sea during the last 6 million years

Based on the stable isotopic analysis of more than 1000 samples of planktonic and benthic foraminifers from ODP Site 1148 in the northern South China Sea (SCS), the oxygen isotope stratigraphy has been applied to the last 3 million years for the first time in the SCS. Furthermore, the paleoceanographic changes in the northern SCS during the last 6 million years have been unraveled. The benthic foraminiferal δ¹⁸O record shows that before δ3.1 Ma the SCS was much more influenced by the warm intermediate water of the Pacific. The remarkable decrease in the deepwater temperature of the SCS during the period of 3.1-2.5 Ma demonstrates the formation of the Northern Hemisphere ice-sheet. However, the several sea surface temperature (SST) reductions during the early and middle Pliocene, reflected by the planktonic foraminiferal δ¹⁸O, might be related to the ice-sheet growth in the Antarctic region. Only those stepwise and irreversible SST reductions during the period of δ2.2-0.9 Ma could be related to the formation and growth of the Northern Hemisphere ice-sheet.     

A possible Younger Dryas-type event during Asian monsoonal Termination 3

1 Introduction The Younger Dryas (YD) cold spell is one of the most prominent abrupt climate change events in the past and a key feature of the last glacial termination. A great agreement has been attained in terms of the tim- ing and geographic extent of…     

Climatic variations in the past 140 ka recorded in core RM, east Qinghai-Xizang Plateau

The sequences of climatic evolution are reconstructed by the analyses of δ¹³C and δ¹⁸O of carbonate from core RM in the Zoige Basin since 140 kaB. P. During the Last Glaciation there existed at least seven warm climatic fluctuations and five cold events correlated with the records of ice core and deep sea, and during the preceding last interglacial period there were two cold climatic variations coinciding with the record of ice core GRIP. These results de-pict climatic instability in east Qinghai-Xizang Plateau over the last interglacial period. In addition, the environmental proxies of the carbonate content and pigments indicate the similar results to the stable isotope record from core RM. Project supported by the Chinese Climbing Project (85-029-02-01).     

Molecular biomarker record of paleooceanographic environment in the East China Sea during the last 35000 years

By reference of the δ¹⁸O and δ¹³C isotopic compositions of G.sacculifer and accelerator mass spectrometry (AMS)¹⁴C dates, the U _K ³⁷ , ∑C _– ²¹ /∑C _+- ²² and Pr/Pn in core DGKS9603 have been used to characterize the changes of paleooceanographic environment occurring in the East China Sea (ECS) during the last 35000 years. The stratigraphic records of these proxies have shown that during the last 35 ka the Okinawa Trough has gone through 7 stronger cold-climate events (C₁–C₇) and 9 terrigenous matter-decreasing events (e₂–e₉), of which, the C₁ corresponds to the cold episode occurring in the middle late Holocene, C₂–C₄ and C₇ correspond to the H₁–H₄ events, respectively. e₁ and e₃–e₈ correspond to the decrease of sea surface temperature (SST), respectively. The terrigenous inputs increased when Heinrich events occurred. Climate colding resulted in the decrease of terrigenous matter transported by rivers, and the increase of that transported by winter monsoon. Heinrich events are closely related to East Asia monsoon. During the Last Glacial Maximum (LGM, 15.5–25.8 Cal ka BP), reduction environment fluctuated strongly, bringing forth three stronger reduction events (R₁–R₃) and one weaker reduction event (O), of which, R₁–R₃ correspond to the decrease of SST and increase of terrigenous nutrient and O corresponds to the decrease of terrigenous nutrient. The fluctuation of reduction condition must be related to the change of sea surface productivity.     

A quick cooling event of the East Asian monsoon responding to Heinrich Event 1: Evidence from stalagmite δ<Superscript>18</Superscript>O records

Based on TIMS U-series dating results and annual band counting method, an annual-resolution time scale from 17450 to 14420 aBP has been established for a stalagmite from the Hulu Cave at Tangshan, Nanjing. A high-resolution oxygen isotopic record reveals decadral-centural oscillations in air temperature in the East Asian monsoon climate area during the last glacial maximum. The most conspicuous feature in the oxygen isotopic record in the period is the particular cold event synchronized with the last Heinrich event (H1) in the northern Atlantic deep-sea records. This particular cold event, beginning at 16140 ± 100 aBP, shows a rapid cooling down with a magnitude of 7–8°C in air temperature within 36 years. Furthermore, δ¹⁸O record demonstrates that the event lasted 790 years with gradually warming tendency (10 cycles of air temperature oscillations) after the remarkable cooling down. We believed that this unique pattern of event recorded in the stalagmite δ⁸O might be controlled by various factors including changes of insolation at mid-latitude Northern Hemisphere, the southern extend of the last ice-rafted event in the North Atlantic and changes of the Equatorial Pacific sea surface temperature.     

Variations of stable isotopic compositions in precipitation on the Tibetan Plateau and its adjacent regions

There is no temperature effect in the southern Tibetan Plateau and South Asia to the south of the Tanggula Mountains. Amount effect has been observed at a few sampling stations accounting for about a half of the statistical stations. There is notable temperature effect in the middle and northern Tibetan Plateau and its adjacent Central Asia to the north of the Tanggula Mountains. Because vapor directly originates from low-latitude oceans, the relative heavy δ¹⁸O with small variation characterizes the rainfall in South Asia. A sharp depletion of the stable isotopic compositions in precipitation takes place from Kyangjin on the southern slope of the Himalayas to the Tanggula Mountains in the middle plateau. From the Tanggula Mountains to the northern Tibetan Plateau, the δ¹⁸O in precipitation increases with increasing latitude.     

Temporal and spatial variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>15</Superscript>N and <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O for atmospheric N<Subscript>2</Subscript>O above the oceanic surface from Shanghai to Antarctica

During the 22nd Chinese Antarctic Research Expedition (CHINARE-22), the atmospheric gas samples above the oceanic surface and near the surface were collected on the track for the scientific ship “Xuelong” and on Millor Peninsula of eastern Antarctica, respectively, using the Tedlar gas bags. Every day the sampling times were 10:00 and 22:00 (local time), respectively. In the laboratory, high-precision measurement of the isotopic compositions for N₂O in these gas samples was conducted using Thermo Finnigan MAT-253 Isotopic Mass Spectrometer with a fully automated interface for the pre-GC concentration (PreCon) of trace gases. The temporal and spatial variations of δ ¹⁵N and δ ¹⁸O in atmospheric N₂O were analyzed. The mean δ ¹⁵N and δ ¹⁸O-N₂O values above the oceanic surface were (7.21±0.50)‰ and (44.52±0.52)‰, respectively. From 30°N to Antarctica, the δ ¹⁵N (6.05‰–7.88‰) linearly increased with the rate of about 0.01‰ with the latitude while the δ ¹⁸O (43.05‰–48.78‰) showed a large fluctuation. The δ ¹⁵N negatively correlated with air temperature and N₂O concentration, and slightly positively correlated with δ ¹⁸O. The summertime variations of δ ¹⁵N and δ ¹⁸O-N₂O appeared the same trend on Millor Peninsula of eastern Antarctica. They significantly positively correlated with each other and negatively with N₂O concentration. The δ ¹⁵N and δ ¹⁸O-N₂O at different sites averaged (7.42±0.35)‰ and (44.69±0.49)‰, respectively, slightly higher than those above the oceanic surface, significantly higher than those of atmospheric N₂O in the low-latitude regions of Northern Hemisphere. The predominant factors affecting the spatial variations of δ ¹⁵N and δ ¹⁸O values were also discussed. The isotopic data given in this study can help to investigate the global and regional N₂O budgets. Supported by the National Natural Science Foundation of China (Grant Nos. 40676005 and 40406001)     

Deglacial sea surface temperature and salinity increase in the western tropical Atlantic in synchrony with high latitude climate instabilities

A sediment core from the western tropical Atlantic covering the last 21,000 yr has been analysed for centennial scale reconstruction of sea surface temperature (SST) and ice volume-corrected oxygen isotopic composition of sea water (δ¹⁸O_ivc-sw) using Mg / Ca and δ¹⁸O of the shallow dwelling planktonic foraminifer Globigerinoides ruber (white). At a period between 15.5 and 17.5 kyr BP, the Mg / Ca SST and δ¹⁸O_ivc-sw, a proxy for sea surface salinity (SSS), reveals a warming of around 2.5 °C along with an increase in salinity. A second period of pronounced warming and SSS increase occurred between 11.6 and 13.5 kyr BP. Within age model uncertainties, both warming intervals were synchronous with air temperature increase over Antarctica and ice retreat in the southern South Atlantic and terminated with abrupt centennial scale SSS decrease and slight SST cooling in conjunction with interglacial reactivation of the meridional overturning circulation (MOC). We suggest that during these warm intervals, production of saline and warm water of the North Brazil Current resulted in pronounced heat and salt accumulation, and was associated with warming in the southern Atlantic, southward displacement of the intertropical convergence zone and weakened MOC. At the termination of the Younger Dryas and Heinrich event 1, intensification of cross-equatorial heat and salt transport caused centennial scale cooling and freshening of the western tropical Atlantic surface water. This study shows that the western tropical Atlantic served as a heat and salt reservoir during deglaciation. The sudden release of accumulated heat and salt at the end of Younger Drays and Heinrich event 1 may have contributed to the rapid reinvigoration of the Atlantic MOC.     

Quaternary biogenic opal records in the South China Sea: Linkages to East Asian monsoon, global ice volume and orbital forcing

Particulate fluxes investigated in the central South China Sea (SCS) during 1993―1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary relationship between the surface productivity and East Asian monsoon in the SCS during the late Quaternary glacial and interglacial periods. Based on the studies of opal % and their mass accumulation rates (MAR) at the six sites recovered from the SCS during the “Resolution” ODP Leg 184 and “Sonne” 95 cruise of the Sino-Germany cooperation, opal % and their MARs increased evidently in the northern sites since 470―900 ka, and they enhanced and reduced, respectively, during the glacial and interglacial periods. Whereas they increased obviously in the southern sites since 420―450 ka, and they augmented and declined, respectively, during the interglacial and glacial periods. The vari- ability in opal % and their MARs in the late Quaternary glacial cyclicity indicate the “seesaw” pattern of surface productivity in the SCS. The winter monsoon intensified during the glacial periods, surface productivity increased and decreased, respectively, in the northern and southern SCS. The summer monsoon strengthened during the interglacial periods, surface productivity increased and decreased, respectively, in the southern and northern SCS. The cross spectral analyses between the opal % in the northern and southern SCS during the Quaternary and global ice volume (δ 18O) and orbital forcing (ETP) indicate that the East Asian winter and summer monsoons could be ascribed to the different drive mechanisms. On the orbital time scale, the global ice volume change could be a dominant factor for the winter monsoon intension and temporal variations. As compared with the winter monsoon, the correlative summer solar radiation with the obliquity and precession in the Northern Hemisphere could be a mostly controlling factor for the summer monsoon intension and temporal variations.     

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS ²³⁰Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ ¹⁸O and δ ¹³C, mostly in the 2.3–26 cm part. The δ ¹⁸O and δ ¹³C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ ¹⁸O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ ¹⁸O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ ¹⁸O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ ¹⁸O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ ¹⁸O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)     

Climatic and environmental changes over the last millennium recorded in the Malan ice core from the northern Tibetan Plateau

In this paper, climatic and environmental changes were reconstructed since 1129A.D. based on the Malan ice core from Hol Xil, the northern Tibetan Plateau. The record of δ 18O in the Malan ice core indicated that the warm-season air temperature variations displayed a general increase trend, the 20th-century warming was within the range of natural climate variability, and the warmest century was the 17th century while the warmest decade was the 1610s, over the entire study period. The “Medieval Warm Epoch” and “Little Ice Age” were also reflected by the ice core record. The dust ratio in the Malan ice core is a good proxy for dust event frequency. The 870-year record of the dust ratio showed that dust events occurred much frequently in the 19th century. Comparing the variations of δ 18O and the dust ratio, it is found that there was a strong negative correlation between them on the time scales of 101―102 years. By analyses of all the climatic records of ice cores and tree rings from the northern Tibetan Plateau, it was revealed that dust events were more frequent in the cold and dry periods than in the warm and wet periods.     

Relations between oxygen stable isotopic ratios in precipitation and relevant meteorological factors in southwest China

The correlations of isotopic ratios in precipitation with temperature, air pressure and humidity at dif- ferent altitudes, in southwest China, are analyzed. There appear marked negative correlations for the δ 18O in precipitation with precipitation amount, vapor pressure and atmospheric precipitable water (PW) at Mengzi, Simao and Tengchong stations on synoptic timescale; the marked negative correlations between the δ 18O in precipitation and the diurnal mean temperature at 400 hPa, 500 hPa, 700 hPa and 850 hPa are different from the temperature effect in middle-high-latitude inland. Moreover, the notable positive correlation between the δ 18O in precipitation and the dew-point deficit △Td at different altitudes is found at the three stations. On annual timescale, the annual precipitation amount weighted mean δ 18O display the negative correlations not only with annual precipitation but also with annual mean temperature at 500 hPa. It can be deduced that, in the years with abnormally strong summer monsoon, more warm and wet air from low-latitude oceans is transported northward along the vapor channel located in southwest China and generates abnormally strong rainfall on the way. Meanwhile, the ab- normally strong condensation process will release more condensed latent heat into atmosphere, and lead to the rise of atmospheric temperature during rainfall, but decline of the δ 18O in precipitation. On the contrary, in the years with abnormally weak summer monsoon, the abnormally weak condensation process will release less condensed latent heat into atmosphere, and lead to the decline of atmos- pheric temperature during rainfall, but increase of the δ 18O in precipitation.     

Temporal variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O of atmospheric water vapor at Delingha

Oxygen stable isotope of atmospheric water vapor is widely used to study the modern process of climate. Atmospheric water vapor samples were collected at Dlingha, northeast of Tibetan Plateau during the period from July 2005 to February 2006. The variation of δ ¹⁸O and the relationships between δ ¹⁸O and both the temperature and specific humidity are analyzed in this paper. Results show that the seasonal variation of δ ¹⁸O of atmospheric water vapor at Delingha is remarkable with higher δ ¹⁸O in summer and lower δ ¹⁸O in winter. The temporal variation of vapor δ ¹⁸O shows obvious fluctuations, with magnitude of over 37‰ The daily variation of the δ ¹⁸O is highly correlated with air temperature. The relationship between δ ¹⁸O and atmospheric water vapor content is complex. Study shows that δ ¹⁸O of atmospheric water vapor is positively correlated with specific humidity in winter in seasonal scale and inversely correlated with specific humidity in summer rainy period. The δ ¹⁸O values of atmospheric water vapor are lower than those of precipitation at Delingha, and the average difference is 10.7‰ Variations of δ ¹⁸O of atmospheric water vapor is also found to be affected by precipitation events, The model results show that the precipitation effect could have caused the vapor δ ¹⁸O in the raining season to lower by 7% in average in July and August. Supported by the National Natural Science Foundation of China (Grant Nos. 40671043, 40571039 and 40771048) and National Basic Research Program of China (Grant No. 2005CB422002)     

Temperature and methane records over the last 2 ka in Dasuopu ice core

High resolution δ¹⁸O and methane records over the last 2ka have been reconstructed from Dasuopu ice core recovered from the Himalayas. Analysis shows that the δ¹⁸O record correlates well with the Northern Hemispheric temperature, Dunde ice core record, and with temperature record in eastern China. The warming trend detected in δ¹⁸O record from the last century is similar to that during the Medieval warm period. There is a dramatic increasing in methane concentration in the Dasuopu ice core, which reached 1031 nmol ⋅ mol^-1 in 1997. Moreover, methane concentration in the Dasuopu ice core is about 15%-20% higher than that in Antarctica and Greenland. There is a positive correlation between methane concentration and δ¹⁸O in Dasuopu ice core.     

The nutrient forms,cycling and exchange flux in the sediment and overlying water system in lakes from the middle and lower reaches of Yangtze River

The 213 m ice core from the Puruogangri Ice Field on the Tibetan Plateau facilitates the study of the regional temperature changes with its δ ¹⁸O record of the past 100 years. Here we combine information from this core with that from the Dasuopu ice core (from the southern Tibetan Plateau), the Guliya ice core (from the northwestern Plateau) and the Dunde ice core (from the north-eastern Plateau) to learn about the regional differences in temperature change across the Tibetan Plateau. The δ ¹⁸O changes vary with region on the Plateau, the variations being especially large between South and North and between East and West. Moreover, these four ice cores present increasing δ ¹⁸O trends, indicating warming on the Tibetan Plateau over the past 100 years. A comparative study of Northern Hemisphere (NH) temperature changes, the δ ¹⁸O-reflected temperature changes on the Plateau, and available meteorological records show consistent trends in overall warming during the past 100 years.     

Water temperature records from corals near the nuclear power plant in southern Taiwan

Coral samples collected at the outlet and the inlet of the Third Nuclear Power Plant were measured for the δ¹⁸O and δ¹³C, indicating the surrounding seawater temperature and physiological/biochemical reactions during coral skeletal growth. The results show that with higher seawater temperature in summer, the values of δ¹⁸O are lower but those for δ¹³C are higher; however, the δ¹⁸O extremes lag six weeks behind the δ¹³C extremes because the highest water temperature lags the maximum number of sunshine hours. Records of the extreme high temperature observed in the northern South China Sea between Oct. 1987 and Sep. 1988, and the extraordinary low temperature from Oct. 1992 to Feb. 1993 are also preserved in the coralline isotope signals. However, when the water temperature becomes too high the coral growth seems to stop.     

Relationships between δ18O in summer precipitation and temperature and moisture trajectories at Muztagata, western China

Based on summer observations of stable isotope of precipitation at Muztagata, western China, during 2002-2003, this paper presents the relationship between δ ¹⁸O in precipitation and air temperature, and discusses the effect of moisture transport on δ ¹⁸O in precipitation. Results show that air temperature correlates positively with δ ¹⁸O in precipitation, and the temperature effect controls the δ ¹⁸O of precipitation in this area. The Muztagata region exhibits high δ ¹⁸O values in summer precipitation, similar to those shown at stations in adjacent regions. According to the results of our model set up to trace the moisture trajectories, the westerlies and local moisture circulation contribute to variations of oxygen isotopes in precipitation. In addition, the impacts of the moisture transport distance, the moisture transport level, and the incursion of the polar air mass also influence the variations of δ ¹⁸O in precipitation. The moisture origins and transport mechanisms also contribute to the variation of δ ¹⁸O in precipitation at Muztagata.     

Variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O in precipitation from the Muztagata Glacier,East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ ¹⁸O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ ¹⁸O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ ¹⁸O and temperature suggests that δ ¹⁸O can be used as an indicator of temperature in this region. The δ ¹⁸O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.     

Microgastropod records in paleoceanographical environment of southern shelf of South China Sea since 14 ka

Very diversified and abundant benthic microgastropods and planktonic microgastropods (pteropods) from core NS93-12-25 could provide a glance of change of the sea level in the south continental shelf of the South China Sea since last 14 ka. Research shows that general sea level changes of this sea area were rising and later rising after a short period of falling in this period. In the range from the bottom of the core to the core depth of 200 cm, individuals in big size are common in microgastropods and Turritella filiola is very rich, signifying the environment of the inner continental shelf in the last deglaciation stage. In the core depth range of 200–150 cm the continuously getting light of the δ¹⁸O, the regularly decreasing of the percentage content of T. filiola and the high diversification of microgastropods indicate the rising of the sea level. Especially at the core depth range of 175–150 cm the pteropods became dominant, making sure the fact that the high sea level possibly occurred in the early Holocene. Channels of surrounding straits connecting the adjacent sea thus were opened. But at the core depth of about 100 cm T. filiola became very rich again. This possibly implies that there was a short term of the sea level falling, resulting in the temporal closure of the channels. In the core depth range of 55–50 cm the Scaliola’s representatives relatively develop and this may be inferred to the cooling of climate.     

Climatic significance of δ <Superscript>18</Superscript>O records from an 80.36 m ice core in the East Rongbuk Glacier,Mount Qomolangma (Everest)

The δ ¹⁸O variations in an 80.36 m ice core retrieved in the accumulation zone of the East Rongbuk Glacier, Mount Qomolangma (Everest), is not consistent with changes of air temperature from both southern and northern slopes of Himalayas, as well as these of the temperature anomalies over the Northern Hemisphere. The negative relationship between the δ ¹⁸O and the net accumulation records of the ice core suggests the “amount effect” of summer precipitation on the δ ¹⁸O values in the region. Therefore, the δ ¹⁸O records of the East Rongbuk ice core should be a proxy of Indian Summer Monsoon intensity, which shows lower δ ¹⁸O values during strong monsoon phases and higher values during weak phases.