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临沧锗矿含碳硅质灰岩的成因及其与锗成矿的关系 总被引:5,自引:1,他引:5
临沧锗矿是我国近年发现的具有独立开采价值且接近超大型规模的锗矿床,其富锗含煤段中存在薄层含碳硅质灰岩,深入研究含碳硅质灰岩的成因对于揭示锗矿床的成因具有重要的意义。通过对薄层含碳硅质灰岩岩石化学、微量元素、稀土元素和碳、氧同位素的系统研究,并与典型的陆相热水沉积物进行对比,得出以下初步认识:(1)含碳硅质灰岩属陆相热水沉积成因;(2)含碳硅质灰岩的微量元素和稀土元素可能主要来自基底的二云母花岗岩;(3)煤中锗主要由形成含碳硅质岩等热水沉积岩的热水带来。 相似文献
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临沧锗矿床的微量元素地球化学 总被引:6,自引:0,他引:6
采用ICP-MS测定了临沧锗矿中51个含矿煤、5个无矿煤、9个硅质岩样品的微量元素含量,并与基底二云母花岗岩进行对比,探讨了含矿煤与无矿煤的微量元素地球化学及其与锗超常富集的关系,得出几点认识: a 含矿煤、无矿煤和硅质岩中的大多数微量元素来自基底的二云母花岗岩; b 热水携带了成矿所必需的锗; c Nb可作为锗矿化的指示元素 相似文献
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云南临沧是我国重要的Ge资源基地,大田河煤矿是近年来所发现的具有锗成矿条件的矿床。对矿区内主要出露的含锗煤、泥沙质细砾岩及黑云二长花岗岩稀土元素组成进行了系统研究和对比,结果表明,该矿床的稀土元素表现为LREE富集的右倾型,且负Eu异常明显,而Ce异常程度较弱。其中,含锗煤和泥沙质细砾岩与三叠世黑云二长花岗岩具有较一致的稀土元素标准化配分模式,且ΣREE和δEu等参数从黑云二长花岗岩→泥沙质细砾岩→含锗煤呈逐渐降低的趋势,此外,含锗煤在ΣREE-δEu和ΣREE-δCe关系图上显示与三叠世黑云二长花岗岩关系密切,而与矿区外围二叠世黑云母花岗岩关系较小。结合该矿床产出地质特征,本文认为含锗煤和泥沙质细砾岩可能继承了黑云二长花岗岩的稀土元素,矿床中Ge主要来自于三叠世黑云二长花岗岩,Ge的超常富集与三叠世岩浆侵入热液活动有关,并形成于相对还原的环境。 相似文献
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对煤中锗矿化若干问题的思考——以临沧锗矿为例 总被引:8,自引:0,他引:8
本文在综述煤中锗矿化国内外研究现状的基础上,以临沧锗矿为例,深入讨论了在煤系地层中形成超大型独立锗矿床的特殊条件。结果表明,煤是锗成矿极有利的围岩,煤能否富集锗主要取决于有无富锗流体与煤相互作用。 相似文献
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热水沉积电气石岩稀土元素地球化学特征 总被引:7,自引:0,他引:7
阐述了辽东元古宙大陆型裂谷内层状硫化物矿床中伴生的电气岩稀土元素特征。含矿建造内的电气石岩具有REE总量低,较强的Eu正异常和Ce负异常,稀土元素属(LREE/HREE)N>1.3的富集型,为热水沉积的产物。纹层状电气石岩的REE研究证明,成矿流体来自富含挥发份的深源。 相似文献
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《地学前缘》2016,(3):113-123
锗元素是研究得最多也是开发利用最好的煤中可利用伴生元素。在自然界中所有的煤都含有锗,但是能富集成锗矿床的只是极少数,多数煤中锗含量甚微。中国目前已发现的具有开采价值的煤-锗矿床有两个,分别是位于云南西部的新生代盆地的临沧煤-锗矿床和内蒙古的中生代盆地的乌兰图嘎煤-锗矿床。但这两个煤锗矿床地质因素各有不同,文中对其不同点进行了比较。中国云南省煤中含锗的情况最为丰富多样,其研究程度较高,处于成熟开发阶段。云南省西部含有富锗煤的新生代盆地的基底都是可提供丰富锗源的花岗岩。盆地内煤中锗分布不均一与两类花岗岩提供的锗源有一定关系。内蒙古胜利煤田内富锗煤矿床正处于开发阶段。矿产地西部附近出露二长花岗岩和闪长岩为主要的锗源供给。胜利煤田和伊敏煤田煤中锗的赋存状态和地质条件与临沧的差异较大。二连盆地群与煤油气相关的地质研究成果较为丰富,如果进一步开展普查找矿工作,将有可能发现新的矿点。 相似文献
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通过矿床地质地球化学、煤岩学、有机地球化学及成矿模拟实验的研究,首次阐明临沧盆地大寨超大型煤中锗(铀)的有机成矿机理:初始锗来源于赋锗的花岗岩风化产物;在泥炭化阶段通过微生物对陆生高等植物降解和改造,经有机质吸附和生成锗络合物等环节构成富锗泥炭层。当富锗泥炭层形成褐煤时,未成熟有机质从含锗的粒间孔隙水中富集锗形成褐煤锗矿层;在表生氧化阶段中,褐煤锗矿层中锗被含氧地下水淋滤、迁移、叠加再造形成富大锗矿体。为进一步探讨锗矿的有机成矿机理进行了包括浸出、吸附、络合的锗矿预富集,以及锗重新迁移和聚集实验,来表述和证明上述有机成矿机理。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引:4,自引:0,他引:4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
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正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
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正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
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正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
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正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献