In-water and remote measurements of ocean color

Spectral measurements of downwelling irradiance, E _d(), above the surface, and of upwelling irradiance just below the surface, E _u(), allow computation of spectral values of the diffuse reflectance R() = E _u()/E _d(); this yields full information about the true color and brightness of the ocean. Typical results are presented and interpreted for waters very different in turbidity and phytoplankton content. Conversely, the possibility of infering the water content from R() data at selected wavelengths is examined in terms of the respective number of equations and unknowns. The necessary use of assumptions and of empirical laws is emphasized.The magnitude of the useful signal emerging from the water, and the magnitude of the additional signals due to specular reflexion at the interface and to atmospheric scattering, are compared on the basis of spectroradiometric measurements performed within and above the sea, from different altitudes. These unwanted signals are dominant, causing a drastic change in the spectral composition of the light received by a remote sensor. The evaluation of the atmospheric effect must be very precise in order to recover the marine signal with a sufficient accuracy for a meaningful application of any kind of algorithm.This work was supported in part by the Centre National d'Exploitation des Océans (under contract CNEXO 77/1695) and in part by the Centre National de la Recherche Scientifique (RCP 247 & ERA 278).     

Uncoupled multi-layer model for the transfer of sensible and latent heat flux densities from vegetation

The sensible heat flux density C and the latent heat flux density E are coupled in the case of a multi-layer model of vegetation. Therefore two linearly independent combinations of C and E, the enthalpy flux density H and the saturation heat flux density J, are introduced. Two electrical analogues, for H and J, are designed. They are equivalent to the resistance scheme for C and E, but uncoupled. Penman's formulas for C and E, which are applicable only to single-layer models, can be expressed equivalently in terms of H and J. This version of Penman's formulas can be extended easily to multi-layer canopies.     

Synchronous Scan and Excitation-Emission Matrix Fluorescence Spectroscopy of Water-Soluble Organic Compounds in Atmospheric Aerosols

Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (_Exc/_Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at _Exc/_Em240/405 nm and _Exc/_Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.     

On the correlation between turbulent velocity and temperature derivatives in the atmospheric surface layer

Velocity and temperature derivatives were obtained at a height of 4 m in the atmospheric surface layer above land. With the assumption of local isotropy, these measurements are used to obtain some statistics of the turbulent energy and scalar dissipation fields. These statistics include the variances of the logarithms of the scalar and velocity dissipation fields and the correlation between these logarithms. When used in conjunction with the hypotheses for fluctuations in turbulent dissipation rates of Obukhov and Kolmogorov, the statistics suggest that the dependence of the flatness factor of temperature derivative on the turbulent Rynolds number R is not as large as that which had been previously reported in the literature. The experimental data indicate a R ^0.5 dependence for the kurtosis of the temperature derivative and a R ^0.15 variation for the strain rate-scalar dissipation correlation.     

Der Umkehreffekt von Götz Messungen des Zenithimmelslichtes mit dem Multiplier

Zusammenfassung Bisher wurde der Umkehreffekt vonGötz nur mittels Photozelle oder Zählrohr untersucht. Die Anwendung des Multipliers als Meßinstrument bietet wegen dessen wesentlich größerer Empfindlichkeit viele Vorteile. So kann damit noch bei Zenitdistanzen der Sonnez>90° bei kleineren Wellenlängen als bisher und bei engerem Spalt des Spektrometers (bessere Monochromasie) gemessen werden.Resultate: 1. Die Verschiebung der Minima der Umkehrkurven,i _n /i _m =f(z), erfolgtgleichsinnig mit abnehmender Wellenlänge _n nach kleineren Zenitdistanzen (entgegen den Angaben vonSchein undStoll, aber in Übereinstimmung mit der Theorie nachGötz undDobson). 2. Zum ersten Mal beziehen sich hier die Angaben aufeffektive Wellenlängen, die ihrerseits noch eine Funktion vonz sind. 3. Aus den Messungen bei den kleinsten, bisher noch nicht zugänglichen Wellenlängen folgt, daß deren Streuniveaus bei tiefen Sonnenständen oberhalb der Schichten größten Ozongehaltes liegen müssen.

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Summary Until now the Umkehr-effect of Götz (inversion of intensity-ratio in zenith-scattered sunlight) has been investigated only by means of photocells or Geiger counters. The application of the multiplier as measuring instrument is of greater advantage because of its much higher sensitivity. Measurements can be made with it even with the sun's zenith distancesz>90° at shorter wave-lengths and with a narrower slit of the spectrometer (better monochromasy).Results: (1) The shift of the minima of the Umkehr-curvesi _n /i _m =f(z), erfolgtgleichsinnig mit abnehmender Wellenlänge _n shows the same sense with decreasing wave-length _n to shorter zenith distances (in opposition to the assertions ofSchein andStoll, but in agreement with the theory ofGötz andDobson). (2) For the first time the statements refer here to effective wave-lengths which in their turn are a function ofz. (3) From measurements of the shortest wave-lengths which until now have not yet been accessible, it can be concluded that at low sun heights the scattering level is situated above the layers with the greatest ozone content.

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Résumé Jusqu'à présent le «Umkehreffect» deGötz, c. à d. l'effet d'inversion des relations d'intensité dans le rayonnement solaire zénithal diffus, n'a été étudié qu'au moyen de cellules photo-électriques ou de compteurs Geiger. En utilisant le multiplicateur comme instrument de mesure on obtient l'avantage d'une bien plus grande sensibilité. Ainsi il est possible de mesurer encore à des distances zénithales du soleil dez>90° par longueurs d'ondes plus courtes que jusqu'ici et avec une fente du spectromètre plus étroite, ce qui nous garantit une meilleure monochromasie.Résultats: 1) Le déplacement des minima des courbes d'inversioni _n /i _m =f(z), erfolgtgleichsinnig mit abnehmender Wellenlänge _n s'effectue dans le même sens que la diminution des longuers d'ondes _n , par distances zénithales plus petites (contrairement aux assertions deSchein et deStoll, mais en concordance avec la théorie selonGötz etDobson). — 2) Pour la première fois les données se rapportent ici à des longueurs d'ondes effectives qui, de leur côté, sont encore fonctions dez. — 3) Il ressort des mesures des plus courtes longueurs d'ondes, qui, jusqu'ici, restaient hors d'atteinte, que pour des hauteurs du soleil basses, leur niveau de fiffusion se trouve au-dessus des couches ayant le plus grand contenu d'ozone.

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Mit 9 Textabbildungen     

Numerical simulation of turbulent convective flow over wavy terrain

By means of a large-eddy simulation, the convective boundary layer is investigated for flows over wavy terrain. The lower surface varies sinusoidally in the downstream direction while remaining constant in the other. Several cases are considered with amplitude up to 0.15H and wavelength ofH to 8H, whereH is the mean fluid-layer height. At the lower surface, the vertical heat flux is prescribed to be constant and the momentum flux is determined locally from the Monin-Obukhov relationship with a roughness lengthz _o=10^–4 H. The mean wind is varied between zero and 5w _*, wherew _* is the convective velocity scale. After rather long times, the flow structure shows horizontal scales up to 4H, with a pattern similar to that over flat surfaces at corresponding shear friction. Weak mean wind destroys regular spatial structures induced by the surface undulation at zero mean wind. The surface heating suppresses mean-flow recirculation-regions even for steep surface waves. Short surface waves cause strong drag due to hydrostatic and dynamic pressure forces in addition to frictional drag. The pressure drag increases slowly with the mean velocity, and strongly with /H. The turbulence variances increase mainly in the lower half of the mixed layer forU/w _*>2.     

Three-dimensional modeling of synthetic cold fronts approaching the Alps

Summary A numerical model was used to study the behaviour of prototype cold fronts as they approach the Alps. Two fronts with different orientations relative to the Alpine range have been considered. One front approaches from west, a second one from northwest. The first front is connected with southwesterly large-scale air-flow producing pre-frontal foehn, whereas the second front is associated with westerly largescale flow leading to weak blocking north of the Alps.Model simulations with fully represented orography and parameterized water phase conversions have been compared with control runs where either the orography was cut off or the phase conversions were omitted. The results show a strong orographic influence in case of pre-frontal foehn which warms the pre-frontal air and increases the cross-frontal temperature contrast leading to an acceleration of the front along the northern Alpine rim. The latent heat effect was found to depend much on the position of precipitation relative to the surface front line. In case of pre-frontal foehn precipitation only falls behind the surface front line into the intruding cold air where it partly evaporates. In contrary, precipitation already appears ahead of the front in the case of blocking. Thus, the cooling effect of evaporating rain increases the cross-frontal temperature difference only in the first case causing an additional acceleration of the front.List of symbols C _pd specific heat capacity of dry air at constant pressure (C _pd =1004.71 J kg^–1 K^–1) - C _pv specific heat capacity of water vapour at constant pressure (C _pv =1845.96 J kg^–1 K^–1) - C _f propagation speed of a front - x, y horizontal grid spacing (cartesian system) - , horizontal grid spacing (geographic system) - t time step - E turbulent kinetic energy - f Coriolis parameter - g gravity acceleration (g=9.81 ms^–1) - h terrain elevation - H height of model lid (H=9000 m) - k Karman constant (k=0.4) - K _Mh horizontal exchange coefficient of momentum - K _Hh horizontal exchange coefficient of heat and moisture - K _Mz vertical exchange coefficient of momentum - K _Hz vertical exchange coefficient of heat and moisture - l mixing length - l _c specific condensation heat (l _c =2500.61 kJ kg^–1) - l _f specific freezing heat (l _f =333.56 kJ kg^–1) - l _s specific sublimation heat (l _s =2834.17 kJ kg^–1) - longitude - m ₁,m ₂,m ₃ metric coefficients - p pressure - Exner function - Pr Prandtl number - latitude - _M profile function - q _v specific humidity - q _c specific content of cloud droplets - q _i specific content of cloud ice particles - q _R specific content of rain drops - q _S specific content of snow - R _d gas constant of dry air (R _d =287.06 J kg^–1 K^–1) - R _v gas constant of water vapour (R _v =461.51 J kg^–1 K^–1) - r _E radius of earth (r _E =6371 km) - Ri _F flux Richardson number - density of dry air - t time - T temperature - _dia period of diastrophy - potential temperature - _v virtual potential temperature - _e equivalent potential temperature - U relative humidity - u, v, w cartesian wind components - u _F ,v _F front-normal and front-parallel wind components - x, y, z cartesian coordinates - w ^* transformed vertical wind component - W _R speed of falling rain - W _S speed of falling snow - z ^* transformed vertical coordinate Abbreviations GND (above) ground level - MSL (above) mean sea level With 12 Figures     

Turbulence Reynolds number and the turbulent kinetic energy balance in the atmospheric surface layer

The relation between the turbulence Reynolds numberR and a Reynolds numberz* based on the friction velocity and height from the ground is established using direct measurements of the r.m.s. longitudinal velocity and turbulent energy dissipation in the atmospheric surface layer. Measurements of the relative magnitude of components of the turbulent kinetic energy budget in the stability range 0 >z/L 0.4 indicate that local balance between production and dissipation is maintained. Approximate expressions, in terms of readily measured micrometeorological quantities, are proposed for the Taylor microscale and the Kolmogorov length scale .     

Microwave vegetation optical depth and inverse modelling of soil emissivity using Nimbus/SMMR satellite observations

Summary A radiative transfer model has been used to determine the large scale effective 6.6 GHz and 37 GHz optical depths of the vegetation cover. Knowledge of the vegetation optical depth is important for satellite-based large scale soil moisture monitoring using microwave radiometry. The study is based on actual observed large scale surface soil moisture data and observed dual polarization 6.6 and 37 GHz Nimbus/SMMR brightness temperatures over a 3-year period. The derived optical depths have been compared with microwave polarization differences and polarization ratios in both frequencies and with Normalized Difference Vegetation Index (NDVI) values from NOAA/AVHRR. A synergistic approach to derive surface soil emissivity from satellite observed brightness temperatures by inverse modelling is described. This approach improves the relationship between satellite derived surface emissivity and large scale top soil moisture fromR ²=0.45 (no correction for vegetation) toR ²=0.72 (after correction for vegetation). This study also confirms the relationship between the microwave-based MPDI and NDVI earlier described and explained in the literature.List of Symbols f frequency [Hz] - f _i(p) fractional absorption at polarizationp - h surface roughness - h h cos² - H horizontal polarization - n _i complex index of refraction - p polarization (H orV) - R _s microwave surface reflectivity - T _B(p) brightness temperature at polarizationp - T ^* normalized brightness temperature - T polarization difference (T _v-T _H) - T _s temperature of soil surface - T _c temperature of canopy - T _max daily maximum air temperature - T _min daily minimum air temperature - V vertical polarization - soil moisture distribution factor; also used for the constant to partition the influence of bound and free water components to the dielectric constant of the mixture - empirical complex constant related to soil texture - microwave transmissivity of vegetation (=e ^–) - ^* effective transmissivity of vegetation (assuming =0) - microwave emissivity - _s emissivity of smooth soil surface - _rs emissivity of rough soil surface - _vs emissivity of vegetated surface - soil moisture content (% vol.) - K dielectric constant [F·m^–1] - K _fw dielectric constant of free water [F·m^–1] - K _ss dielectric constant of soil solids [F·m^–1] - K _m dielectric constant of mixture [F·m^–1] - K _o permittivity of free space [8.854·10^–12 F·m^–1] - high frequency limit ofK _wf [F·m^–1] - wavelength [m] - incidence angle [degrees from nadir] - polarization ratio (T _H/T _V) - b soil bulk density [gr·cm^–3] - s soil particle density [gr·cm^–3] - R surface reflectivity in red portion of spectrum - NIR surface reflectivity in near infrared portion of spectrum - _eff effective conductivity of soil extract [mS·cm^–1] - vegetation optical depth - _6.6 vegetation optical depth at 6.6 GHz - ₃₇ vegetation optical depth at 37 GHz - ^* effective vegetation optical depth (assuming =0) - single scattering albedo of vegetation With 12 Figures     

Influences on surface energy fluxes in simulated present and doubled CO2 climates

The surface energy fluxes simulated by the CSIRO9 Mark 1 GCM for present and doubled CO₂ conditions are analyzed. On the global scale the climatological flux fields are similar to those from four GCMs studied previously. A diagnostic calculation is used to provide estimates of the radiative forcing by the GCM atmosphere. For 1 × CO₂, in the global and annual mean, cloud produces a net cooling at the surface of 31 W m^–2. The clear-sky longwave surface greenhouse effect is 311 W m^–2, while the corresponding shortwave term is –79 W m^–2. As for the other GCM results, the CSIRO9 CO₂ surface warming (global mean 4.8°C) is closely related to the increased downward longwave radiation (LW ). Global mean net cloud forcing changes little. The contrast in warming between land and ocean, largely due to the increase in evaporative cooling (E) over ocean, is highlighted. In order to further the understanding of influences on the fluxes, simple physically based linear models are developed using multiple regression. Applied to both 1 × CO₂ and CO₂ December–February mean tropical fields from CSIRO9, the linear models quite accurately (3–5 W m^–2 for 1 × CO₂ and 2–3 W m^–2 for CO₂) relate LW and net shortwave radiation to temperature, surface albedo, the water vapor column, and cloud. The linear models provide alternative estimates of radiative forcing terms to those from the diagnostic calculation. Tropical mean cloud forcings are compared. Over land, E is well correlated with soil moisture, and sensible heat with air-surface temperature difference. However an attempt to relate the spatial variation of LWt within the tropics to that of the nonflux fields had little success. Regional changes in surface temperature are not linearly related to, for instance, changes in cloud or soil moisture.     

Surface renewal analysis for sensible and latent heat flux density

High frequency temperature measurements were recorded at five heights and surface renewal (SR) analysis was used to estimate sensible heat flux density (H) over 0.1 m tall grass. Traces of the temperature data showed ramp-like structures, and the mean amplitude and duration of these ramps were used to calculate H using structure functions. Data were compared with H values measured with a sonic anemometer. Latent heat flux density (E) was calculated using an energy balance and the results were compared with E computed from the sonic anemometer data. SR analysis provided good estimates of H for data recorded at all heights but the canopy top and at the highest measurement level, which was above the fully adjusted boundary layer.     

Turbulence measurements above a pine forest

Eddy fluxes of momentum, sensible and latent heat, and turbulence spectra measured over the Thetford Forest during 10 days in the Spring of 1973 are described. The measured total heat flux (H + E) for 122 20-min periods agreed closely on average with independent estimates from an energy balance method. There was evidence that the energy balance data gave small systematic overestimates of available energy during the hours before noon, compensated by slight underestimates for the remainder of the day. A comparison of measured wind speeds and friction velocities in neutral stability confirmed the validity of the aerodynamic method for estimating momentum fluxes at heights of a few roughness lengths above the canopy. In stable conditions the log-linear wind profileU = (u _*/k)(ln ((z -d)/z _o) + (z -d -z _o)/L) with = 3.4 ± 0.4 provided a good fit to the data. Spectra in unstable conditions were generally more sharply peaked than those measured by other workers over smoother terrain: differences were less marked in the case of vertical velocity in stable conditions. Temperature spectra in these stable conditions showed high energy at relatively low wavenumbers, andwT cospectra showed a cospectral gap; both of these results were associated with an intermittent sawtooth structure in the temperature fluctuations.Now at the Meteorological Office, Bracknell     

The turbulent heat flux from arctic leads

The turbulent transfer of heat from Arctic leads in winter is one of the largest terms in the Arctic heat budget. Results from the AIDJEX Lead Experiment (ALEX) suggest that the sensible component of this turbulent heat flux can be predicted from bulk quantities. Both the exponential relation N = 0.14R _x ^0.72 and the linear relation N = 1.6 × 10^–3 R _x+ 1400 fit our data well. In these, N is the Nusselt number formed with the integrated surface heat flux, and R _x is the Reynolds number based on fetch across the lead. Because of the similarity between heat and moisture transfer, these equations also predict the latent heat flux. Over leads in winter, the sensible heat flux is two to four times larger than the latent heat flux.The internal boundary layer (IBL) that develops when cold air encounters the relatively warm lead is most evident in the modified downwind temperature profiles. The height of this boundary layer, , depends on the fetch, x, on the surface roughness of the lead, z ₀ and on both downwind and upwind stability. A tentative, empirical model for boundary layer growth is % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4baFfea0dXde9vqpa0lb9% cq0dXdb9IqFHe9FjuP0-iq0dXdbba9pe0lb9hs0dXda91qaq-xfr-x% fj-hmeGabaqaciGacaGaaeqabaWaaeaaeaaakeaadaWcaaqaaiabes% 7aKbqaaiaadQhadaWgaaWcbaGaaGimaaqabaaaaOGaeyypa0JaeqOS% di2aaeWaaeaacqGHsisldaWcaaqaaiaadQhadaWgaaWcbaGaaGimaa% qabaaakeaacaWGmbaaaaGaayjkaiaawMcaamaaCaaaleqabaGaaGim% aiaac6cacaaI4aaaaOWaaeWaaeaadaWcaaqaaiaadIhaaeaacaWG6b% WaaSbaaSqaaiaaicdaaeqaaaaaaOGaayjkaiaawMcaamaaCaaaleqa% baGaaGimaiaac6cacaaI0aaaaaaa!472D!\[\frac{\delta }{{z_0 }} = \beta \left( { - \frac{{z_0 }}{L}} \right)^{0.8} \left( {\frac{x}{{z_0 }}} \right)^{0.4} \] where L is the Obukhov length based on the values of the momentum and sensible heat fluxes at the surface of the lead, and is a constant reflecting upwind stability.Velocity profiles over leads are also affected by the surface nonhomogeneity. Besides being warmer than the upwind ice, the surface of the lead is usually somewhat rougher. The velocity profiles therefore tend to decelerate near the surface, accelerate in the mid-region of the IBL because of the intense mixing driven by the upward heat flux, and rejoin the upwind profiles above the boundary layer. The profiles thus have distinctly different shapes for stable and unstable upwind conditions.     

Regional-Scale Heat and Water Vapour Fluxes in an Agricultural Landscape: An Evaluation of CBL Budget Methods at OASIS

This paper evaluates convective boundary layer (CBL) budget methods as a tool for estimating regionally averaged sensible and latent heat fluxes for the study region used in OASIS (Observations at Several Interacting Scales). This is an agricultural region of mixed cropping and grazing extending about 100 km west of the town of Wagga Wagga, NSW, Australia.The analysis proceeds in three stages: first, a simpleone-dimensional model of the well-mixed layer (the CBL slab model), forced with measurements of the surface heat and evaporation fluxes, is evaluated by comparing measured and modelled CBL temperature, humidity and depths. A comparison of several entrainment schemes shows that a simple model, where the entrainment kinetic energy is parameterised as a fraction (₃) of the surface sensible heat flux, works well if is set to 0.5. Second, the slab model is coupled to a Penman–Monteith model of surface evaporation to predict regional scale evaporation and thence heat fluxes. Finally, the integral CBL budget approach, which is an inverse method using theone-dimensional slab model, is used to infer regional heat and evaporation fluxes from measured time series of CBL temperature and humidity.We find that the simple CBL slab model works reasonably well for predicting CBL depth and very well for CBL temperature, especially if approximate estimates of subsidence velocity and warming due to advection are included. Regional sensible heat fluxes estimated from the integral CBL method match those measured, although the method is very sensitive to measurement errors. Measurement-model differences were larger for short integration times, because the well-mixed assumptions are violated at particular times of the day. The corollary is that `whole-day' (0530–1530 h) estimates are in reasonable agreement with measured values. Integral methods could not be used to infer the regional evaporation flux directly because CBL humidity profiles were complex and often not well mixed until mid-afternoon. We recommend that regional evaporation fluxes be predicted either from a coupled Penman–Monteith – CBL slab model, or inferred as a residual term from estimates of the regionally averaged available energy and sensible heat flux. Furthermore, we show that inferring fluxes via integral methods will always be difficult when the scalar concentrations have either a large surface source and free atmosphere sink (in the case of water vapour and methane), or a large surface sink and upper level source (in the case of CO₂).     

The Gas Phase Reaction of Unsaturated Oxygenates with Ozone: Carbonyl Products and Comparison with the Alkene-Ozone Reaction

Carbonyl products have been identified and their formation yields measured in the gas phase reaction of ozone with unsaturated oxygenates in experiments carried out at ambient T, p = 1 atm. of purified humid air (RH = 50%) and with sufficient cyclohexane added to scavenge the hydroxyl radical. The compounds studied are the esters methyl acrylate, vinyl acetate and cis-3-hexenyl acetate, the carbonyl crotonaldehyde, the hydroxy-substituted diene linalool, the ether ethylvinyl ether and the keto-ether trans-4-methoxy-3-buten-2-one. The alkene 1-pentene was included for comparison. The nature and formation yields of the carbonyl products from this study and those measured in earlier work under the same conditions are compared to those of alkenes and are supportive of a reaction mechanism that is similar to that for the reaction of ozone with alkenes, i.e. O₃ + R₁R₂C=CR₃X (R₁COR₂ + R₃XCOO) + (1 – )(R₃COX + R₁R₂COO), where R_i are the alkyl substituents, X is the oxygen-containing substituent (–CHO for aldehydes; –C(O)R for ketones; –C(O)OR and –OC(O)R for esters; –OH and hydroxyalkyl for alcohols; and –OR for ethers), R₁COR₂ is the primary carbonyl, R₃COX is the other primary product and R₁R₂COO and R₃XCOO are the carbonyl oxide biradicals. The biradicals lead to carbonyls in reactions that are also analogous to those involved in carbonyl formation from biradicals in the ozone-alkene reaction. These features make it possible to predict the nature and formation yields of the major carbonyl products of the reaction of ozone with unsaturated oxygenates that may be components of biogenic emissions.     

Heat energy exchange over a large water body under stable atmospheric conditions

The surface heat budget over the Riband reservoir covering 300 km² is investigated making use of hydrometeorological data collected at a number of stations during May and June 1983. The observations had to be restricted to 0800–1400 hr for operational reasons in this remote part of India. The winds were weaker, and in general the temperature and humidity gradients were stronger at that time of day than during the afternoon.The mean albedo between 0700–1200 hr is found to be about 34% which could be due to the high turbidity of the water. A simple relation of the form, R = (1 – )Q _i – 85 is proposed to estimate net radiation over the water body from the global radiation. This relation is useful for the computation of net radiation since it avoids the computation of effective back radiation, which requires data on humidity, cloud amount and surface water temperature. The overall means of net radiation, latent and sensible heat fluxes were found to be 420, 96 and -11 W/m², respectively. A net heat gain of about 335 W/m² was observed during the study period. The measured effective back radiation agreed reasonably well with the value computed from the theoretical formula.     

Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.     

Spectral Characteristics and Correction of Long-Term Eddy-Covariance Measurements Over Two Mixed Hardwood Forests in Non-Flat Terrain

We present turbulence spectra and cospectra derived from long-term eddy-covariancemeasurements (nearly 40,000 hourly data over three to four years) and the transferfunctions of closed-path infrared gas analyzers over two mixed hardwood forests inthe mid-western U.S.A. The measurement heights ranged from 1.3 to 2.1 times themean tree height, and peak vegetation area index (VAI) was 3.5 to 4.7; the topographyat both sites deviates from ideal flat terrain. The analysis follows the approach ofKaimal et al. (Quart. J. Roy. Meteorol. Soc. 98, 563–589, 1972) whose results were based upon 15 hours of measurements atthree heights in the Kansas experiment over flatter and smoother terrain. Both thespectral and cospectral constants and stability functions for normalizing and collapsingspectra and cospectra in the inertial subrange were found to be different from those ofKaimal et al. In unstable conditions, we found that an appropriate stabilityfunction for the non-dimensional dissipation of turbulent kinetic energy is of the form ₍₎ = (1 - b^-)^-1/4 - c^-, where representsthe non-dimensional stability parameter. In stable conditions, a non-linear functionG_xy() = 1 + b_xy^c _xy (c_xy < 1) was found to benecessary to collapse cospectra in the inertial subrange. The empirical cospectralmodels of Kaimal et al. were modified to fit the somewhat more (neutraland unstable) or less (stable) sharply peaked scalar cospectra observed over forestsusing the appropriate cospectral constants and non-linear stability functions. Theempirical coefficients in the stability functions and in the cospectral models varywith measurement height and seasonal changes in VAI. The seasonal differencesare generally larger at the Morgan Monroe State Forest site (greater peak VAI) andcloser to the canopy.The characteristics of transfer functions of the closed-path infrared gas analysersthrough long-tubes for CO₂ and water vapour fluxes were studied empirically. This was done by fitting the ratio between normalized cospectra of CO₂ or watervapour fluxes and those of sensible heat to the transfer function of a first-order sensor.The characteristic time constant for CO₂ is much smaller than that for water vapour. The time constant for water vapour increases greatly with aging tubes. Three methods were used to estimate the flux attenuations and corrections; from June through August, the attenuations of CO₂ fluxes are about 3–4% during the daytime and 6–10% at night on average. For the daytime latent heat flux (Q_E), the attenuations are foundto vary from less than 10% for newer tubes to over 20% for aged tubes. Correctionsto Q_E led to increases in the ratio (Q_H + Q_E)/(Q^* - Q_G) by about 0.05 to0.19 (Q_H is sensible heat flux, Q^* is net radiation and Q_G is soil heat flux),and thus are expected to have an important impact on the assessment of energy balanceclosure.     

Meteorological results of MONSOON-88 expedition (pre-monsoon period)

Mean atmospheric circulation, moisture budget and net heat exchange were studied during a pre-monsoon period (18th March to 3rd May, 1988), making use of the data collected on board Akademik Korolev in the central equatorial and southern Arabian Sea region. The net heat exchange (R _n ) is found to be about 20 W m^–2 for a small area (0–4° N; 55–60° E), 50% less than the dimatological value. The mean value of net radiation (140 W m^–2) is less than the climatological value, which was due to higher cloud amount. The higher SST enhanced both the latent and sensible heat fluxes.The mean atmospheric circulation obtained from the upper air data is quite convincing. The mean exchange coefficient (C _e ) estimated from the moisture budget is about 1.0 × 10^–3 for a wind speed of 4 m s^–1. This value is slightly lower than that obtained by the usual methods.National Institute of Oceanography, RC, 52-Kirlampudi layout, Visakhapatnam — 530 023.India Meteorological Department, Gauhati.     

Analysis and trends of atmospheric turbidity parameters over Cairo

Summary This work deals with the Linke turbidity factor, based on total spectrum observations of the direct solar beam and aerosol turbidity parametersa _a , , and based on observations in broad spectral bands. Diurnal and seasonal variations of these turbidity parameters were analyzed for the period 1975 to 1991.Annual variations of these parameters show low values in winter and high values in both spring and summer. The extinction coefficients decrease with increase of both wavelength and optical airmass. Trend analysis shows an increase in aerosol extinction coefficient below 0.63 m, and a slight decrease for longer wave-lengths.Linear regression relations are also constructed to estimate botha _a and whenT _L is available. The relations show thata _a can be estimated with errors below 20%. The relation with the parameter, may give better results when it is estimated by assigning a fixed value of .Nomenclature AV Monthly and total average of the measured parameter - a Atmospheric optical thicknes - a _a Aerosol optical thickness - a _r Mean value of optical thickness of. Rayleigh atmosphere over all wavelengths - a _o Ozone optical thickness - a _o Ozone absorption coefficient - a _w Water vapor optical thickness - COR Correlation coefficient of the linear relation in percentage - Ex₁, Ex₂, Ex₃ Aerosol extinction coefficients in the bands .2–.53, .53–.63, .63–.695, respectively - I _(o) Normal incident direct solar radiation, under clear sky condition - I _o Extraterrestrial insolation at normal incidence - m _r Relative (optical) air mass - NO Number of the observations used in either making the relation or the verification - RMSE Root mean square error of the linear relation - RMSE% Percentage value of the root mean square error relative to the average measured value AV - T _L Linke turbidity factor - T Dry bulb temperature in °C - u _o Ozone layer thickness, cm - Z Zenith angle - Ångström wavelength exponent - Ångström turbidity coefficient - Wavelength - Y The year number after 1975 With 5 Figures