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1.
研究区的碳氧同位素组成表明,矿化灰岩和细晶灰岩的δ^13C为正值,其δ^18O值变化于-6.4‰~-21‰之间;而绝大多数矿石中碳酸盐矿物的δ^13C为负值,只有少数为正值,与其对应的δ^18O值为-12.3‰~-12.5‰。根据δ^13C-δ^18O图解分析,区分出了3种不同类型的碳同位素:(1)三叠纪海洋生物碳;(2)海相碳酸盐的碳与热卤水中碳的过渡类型;(3)深部热卤水中CO2的碳。研究发现  相似文献   

2.
高温高压模拟实验气态产物碳同位素演化特征   总被引:3,自引:0,他引:3  
对泥炭、褐煤样品进行了高压(0.1~2GPa)、高温(200~800℃)模拟实验,并用微量气体同位素测定系统(GC-C-MS)测定了气态产物的碳同位素值。在400℃的温度条件下,乙烷、丙烷、正丁烷碳同位素值有随压力升高而变重的趋势,并出现了碳同位素局部反序的特征(δ^13C2〉δ^13C3);在600℃、1GPa和1.5GPa的温压条件下,甲烷和乙烷的δ^13(PDB)值偏重,分别约为-15.0‰  相似文献   

3.
段毅  吴应忠  赵阳 《地质学报》2016,90(5):1030-1039
系统采集了位于青藏高原东北部的尕海湖淡水湖泊沉积物,对沉积物中正构烷烃及其氢同位素进行了分析,研究了沉积物中正构烷烃及其氢同位素组成,探讨了它们的来源。研究结果表明,尕海湖沉积物中正构烷烃分布反映了它们来自水生和陆生植物。尕海湖沉积正构烷烃氢同位素组成平均值为-221.9‰~-190.5‰。C_(21)~C_(33)奇碳数正构烷烃δD值明显地将样品划分为两种类型。类型Ⅰ样品的C_(21)~C_(33)奇碳数正构烷烃平均δD值明显地高于类型Ⅱ样品。类型Ⅰ沉积正构烷烃δD值分布特征反映了它们主要来自尕海湖水生植物;类型Ⅱ沉积物中正构烷烃δD值特征指示了它们主要来自研究区陆生草本植物。提出了具有δD值低、丰度高和CPI值低的中等链长正构烷烃起源于改造陆源草本植物的细菌。研究成果证实了沉积正构烷烃δD值可以作为指示有机质源的地球化学指标。  相似文献   

4.
扬子地台震旦纪海水碳同位素的变化   总被引:15,自引:1,他引:15  
本文测定了湖北宜昌三峡剖面震旦系海相碳酸盐岩样品的碳同位素组成。研究表明:震旦纪扬子区海水的δ^13C值显示出大幅度变化,南沱冰期δ^13C为低值(-4‰);陡山沱早期δ^13C值迅速上升,达到5-6‰,陡山沱期δ^13C值一般在0-5‰之间;灯影期δ^13C值较平稳,一般在2.0-3.4%之间,导致震旦经水δ^13C值大幅度变化的原因主要是由于以疑在和近岸为藻类等光合作用的海洋植物群体为主体的大  相似文献   

5.
我国煤的稳定同位素组成特征   总被引:2,自引:0,他引:2  
总结了煤及其煤化作用产物稳定同位素地球化学研究成果。煤的δ^13C值主要在-22.5‰~-25.5‰之间,中值为-24.4‰。煤化作用及地质年代影响极微,但煤岩显微组分对δ^13C值有明显影响,壳质组含量增加,煤的δ^13C值变轻。煤的热模拟演化产物δ^13C值;甲烷在液态烃产出峰值处有最烃的碳同位素组成,液态烃与煤有相似的δ^13C值,其族组分中烷烃部分随温度增高,δ^13C值有变重的趋势。煤的  相似文献   

6.
林清  彭平安  刘荣谟 《地球化学》2000,29(5):425-430
鄂陵湖浅层学2m的冻结湖相沉积物中埋藏植物屑保存完好,植物屑均来源于同一种沉水植物-龙须眼子菜(Potamogeton pectinatus)。碳同位素分析结果表明,剖面中该植物屑的δ^13C值在-17.67‰ ̄-11.39‰间变化,比该地生长的陆生植物高。根据δ^13C值的变化特征,将湖相沉积分为三个阶段,相应δ^13C平均值分别为-16.68‰、-14.48‰和-12.28‰,由下而上呈降低的  相似文献   

7.
一个未成熟褐煤抽提物中,高等植物生源化合物的同位素值在全煤碳同位素组成(δ13C值-27.0‰)的±2‰范围内,表明相似成煤植物对这些化合物的贡献,或者其成煤植物经历过相似的生物合成分馏效应。所检测的萜烃类按同位素差异分为两组:二萜类(δ13C值-25.0±1.4‰)和倍半萜类(δ13C值-25.9±1.5‰)平均较全煤样富集1~2%。13C,而奥利烷-乌散烷-羽扇烷型衍生物(δ13C值-29.0±0.8‰)平均比全煤样减少1~2‰13C。C15~C35正烷烃δ13C平均值-32.4±0.6‰,据此表明C17~C22和C22~C33正烷烃的同位素值与上述平均值没有明显差异。与全煤样相比较,该煤样抽提物的藿烷衍生物13C值则减少8~34‰,标志在成煤过程中甲烷的细菌循环起着作用。  相似文献   

8.
为认识低纬度亚热带地区湖泊沉积物中正构烷烃氢同位素组成特征及其与母源输入和生态环境的关系,本文利用气相色谱-高温热转变-同位素比值质谱议(GC-TC-IRMS),对系统采集的抚仙湖沉积物样品中正构烷烃氢同位素进行了测定。抚仙湖沉积正构烷烃δD值分布在-219.3‰~-142.5‰之间,样品中平均值为-208.1‰~-154.5‰,并且奇碳数正构烷烃δD值明显地将样品划分为两种类型。类型Ⅰ样品中正构烷烃平均δD值明显地高于类型Ⅱ样品,反映了它们生物源存在明显差别。沉积物与水生植物和陆生植物中正构烷烃氢同位素组成对比结果指示了沉积C_(17)、C_(21)~C_(25)奇碳数正构烷烃来自水生植物,C_(27)和C_(29)奇碳数正构烷烃主要来自木本植物,C31和C33正构烷烃来自水生和陆生草本植物的混合。对比研究结果表明,湖泊地区生态环境是控制湖泊沉积正构烷烃氢同位素组成的重要因素之一,在利用沉积正构烷烃氢同位素研究古水文学特征时,还要考虑研究区古生态环境对沉积正构烷烃氢同位素的影响,并且结合沉积正构烷烃ACL值和Qw值,才能对沉积有机质中正构烷烃氢同位素组成及变化作出合理的解释。  相似文献   

9.
李儒峰  刘本培 《地球科学》1996,21(3):261-266
结合碳酸盐岩层序地层分析,首次系统测定了马平组碳,氧同位素值,并对其演化规律与层序地层的关系进行了探讨,研究结果表明:马平组内δ^13C,δ^18O值变化范围分别是-2.56‰~+3.89‰和-8.16‰~-6.02‰(PDB)准层序为δ^13C值向上逐渐减小,海进体系域(TST)和高水位体系域(HST)内δ^13C值分别呈增加和减小的趋,层序界面处δ^13C,δ^18O值均表现为负异常,控制层序  相似文献   

10.
不同沉积环境凝析油的分子有机地球化学特征   总被引:3,自引:0,他引:3  
马柯阳 《甘肃地质》1995,4(1):82-90
对中国10个盆地不同沉积环境的42个凝析油进行的GC、GC-MS、GC-AED及碳、氢同位素分析表明:海相、淡水、微咸水湖泊相、半成水湖泊相、咸水湖泊相凝析油以及沼泽相凝析油具有不同的有机分子和生物标记化合物组合以及碳氢同位素分布。海相凝析油富含异构烷烃和烷基环戊烷轻烃系列、硫芴及降姥鲛烷;贫二环倍半萜尤其是升锥满烷;Σ烷基环己烷/Σ正构烷烃值较大,具有较重的δD值和较轻的δ ̄(13)C值,前者平均-29.8‰;后者平均-119.7‰。陆相咸水、半咸水湖相凝析油富含含硫化合物尤其是硫芴;Σ烷基环己烷/Σ正构烷烃值略小于海相凝析油;具明显植烷优势;具有较重的δ ̄(13)C值和δD值,平均值分别为-25.5‰和-121.2‰,全烃色谱具继承性微弱奇偶优势。微咸水、淡水湖相凝析油相对富含二环倍半萜尤其是锥满烷和升锥满烷及芴。沼泽相凝析油富含甲苯、甲基环己烷(轻烃)、二环倍半萜及氧芴;尚检出有按叶油烷等陆相生标化合物;Σ烷基环己烷/Σ正构烷烃值较小,具有姥鲛烷优势;δ ̄(13)C值较重,平均值为-26.5‰。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

17.
18.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

19.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

20.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

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