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1.
The isotope-oxygen composition of ice wedges, ground ice, ice of the intrusive-segregated seasonal mound, and segregated ice of Eastern Chukotka near Koolen Lake, the settlement of Lavrentiya on the Chul’kheveem River, the settlement of Lorino, and the city of Anadyr on the Onemen Bay coast was studied. The comparison of isotopic diagrams showed that the variations in δ18O of the Holocene ice wedges of Eastern Chukotka did not exceed 2‰, which indicates the insignificant variability of climatic winter conditions in the late Holocene. The long-term mean-January temperature values varied less than 3°C according to calculations from the equations of interrelation between air temperature and the isotopic composition of the wedges.  相似文献   

2.
Stable isotope composition of syngenetic and epigenetic ice wedges, radiocarbon age, and pollen spectra of the surrounding deposits were studied during long term investigations at the "Belyi Klyuch" site on the first(6-8 m height) terrace of the Chara River(720 m.a.s.l.) in northern Transbaikalia to assess climatic conditions during ice-wedge formation. It was revealed that Holocene ice wedges had been formed from 10 to 7.5 ka 14 C BP. The isotope composition(δ~(18)O, δ~2 H) of relict ice wedges is the lightest and amounts-23‰ and-185‰, correspondingly. The isotopic compositions of ice lenses from sandy loam above ice wedges are-15.7‰, and-133‰; of small ice wedge in peat and sand are-15.3‰ and-117.9‰, accordingly.Interpretation of the ice wedge isotope composition has yielded that mean winter temperatures during cold stages of Holocene optimum were lower than today, during warm stages they were close to modern ones. During the coldest stages of Holocene optimum the total annual freezing index varied from-5100 to-5700 ℃ degree days, i.e. 300-600 ℃ degree days colder than during extremely severe modern winters. The total annual thawing index varied from 1300 to 1800 ℃ degree days, which was slightly higher than modern ones.  相似文献   

3.
Twenty three groups of thermomineral springs in eastern Chukotka with the discharge temperature of 2 to 97°C and mineralization of 1.47 to 37.14 g/l are studied and compared with surface freshwater from their localities. The δD and δ18O values in surface waters vary from ?121.4 to ?89.5‰ and from ?16.4 to ?11.1‰, respectively, while respective values in thermomineral waters range from ?134.2 to ?92.5‰ and from ?17.6 to ?10.5‰. The δD value in surface waters decreases from the east to west, i.e., toward interior areas of the peninsula. Hydrothermal springs most depleted in deuterium (δD < ?120‰) are localized in the geodynamically active Kolyuchinskaya-Mechigmen Depression. According to the proposed formation model of Chukotka thermomineral waters, their observed chemical and isotopic characteristics could result from the mixing (in different proportions) of surface waters with the deep-sourced isotopically light mineralized component (δD ≈ ?138‰, δ18O ≈ ?19‰, M = 9.5?14.7 g/l). The latter originates most likely from subpermafrost waters subjected to slight cryogenic metamorphism.  相似文献   

4.
Abstract

The nature of the substrate below the northern Lachlan Orogen and the southern Thomson Orogen is poorly understood. We investigate the nature of the mid- to lower-crust using O and Lu–Hf isotope analyses of zircons from magmatic rocks that intrude these regions, and focus on the 440–410 Ma time window to minimise temporal effects while focussing on spatial differences. Over the entire region, weighted mean δ18O values range from 5.5 to 9.8‰ (relative to VSMOW, Vienna Standard Mean Oceanic Water), and weighted mean ?Hft range from ?8.8 to +8.5. In the northern Lachlan Orogen and much of the southern Thomson Orogen, magmatic rocks with unradiogenic ?Hft (~?7 to ?4) and elevated δ18O values (~9 to 10‰) reflect a supracrustal source component that may be common to both orogens. Magmatic rocks intruding the Warratta Group in the western part of the Thomson Orogen also have unradiogenic ?Hft (~?9 to ?6) but more subdued δ18O values (~7‰), indicating a distinct supracrustal source component in this region. Some regions record radiogenic ?Hf and mantle-like δ18O values, indicative of either a contribution from arc-derived rocks or a direct mantle input. In the northeast Lachlan Orogen Hermidale Terrane, magmatic rocks record mixing of the supracrustal source component with input from a infracrustal or mantle source component (?Hft as high as +8.5, δ18O values as low as 5.5‰), possibly of Macquarie Arc affinity. Samples in the west-southwestern Thomson Orogen also record some evidence of radiogenic input (?Hft as high as ?0.5, δ18O values as low as 6.4‰), possibly from the Mount Wright Arc of the Koonenberry Belt. Overall, our results demonstrate a strong spatial control on isotopic compositions. We find no isotopic differences between the bulk of the Lachlan Orogen and the bulk of the Thomson Orogen, and some indication of similarities between the two.  相似文献   

5.
An investigation using environmental isotopes (δ18O and δD) was conducted to gain insight into the hydrological processes of the Ganga Alluvial Plain, northern India. River-water, shallow-groundwater and lake-water samples from the Gomati River Basin were analyzed. During the winter season, the δ18O and δD compositions of the Gomati River water ranged from ?1.67 to ?7.62 ‰ and ?25.08 to ?61.50 ‰, respectively. Deuterium excess values in the river water (+0.3 to ?13 ‰) and the lake water (?20 ‰) indicate the significance of evaporation processes. Monthly variation of δ18O and δD values of the Gomati River water and the shallow groundwater follows a similar trend, with isotope-depleted peaks for δ18O and δD synchronized during the monsoon season. The isotopically depleted peak values of the river water (δ18O?=??8.30 ‰ and δD?=??57.10 ‰) can be used as a proxy record for the isotopic signature of the monsoon precipitation in the Ganga Alluvial Plain.  相似文献   

6.
Palaeotemperature estimates from the oxygen‐isotope compositions of belemnites have been hampered by not knowing ancient seawater isotope compositions well enough. We have tackled this problem using Mg/Ca as a proxy for temperature and here, we present a ~2 Ma record of paired Mg/Ca and δ18O measurements of Jurassic (Early Pliensbachian) belemnites from the Asturian basin as a palaeo‐proxy of seawater oxygen‐isotope composition. From the combined use of the two approaches, we suggest a δ18Ow composition of about ?0.1‰ for the Jamesoni–Ibex zones. This value may have been increased by about 0.6‰ during the Davoei Zone due to the effect of waters with a different δ18Ow composition. These findings illustrate the inaccuracy of using a globally homogeneous ice‐free value of δ18Ow = ?1‰ for δ18Ocarb‐based palaeotemperature reconstructions. Our data suggest that previous palaeotemperatures calculated in the region from δ18O values of belemnites may have been underestimated as the seawater oxygen isotopic composition could have been higher.  相似文献   

7.
The oxygen isotope signature (δ18O) of stalagmite SI3 collected from Shizi Cave in north‐east Sichuan Province provides an Asian Summer Monsoon (ASM) record in Central China for the period 54–46 ka. The SI3 δ18O record clearly shows a negative δ18O excursion centred around 49.4 ka, which was reported in Hulu Cave in East China but not identified in the speleothem records from South‐west China. As a whole, this record displays a higher coherence with the two Hulu records from East China than with the speleothem δ18O records from South‐west China, suggesting that at 54–46 ka, Central China was influenced more by the East Asian Summer Monsoon than by the Indian Summer Monsoon. It also displays a significant negative δ18O excursion at 47.5–46.6 ka, which is not clearly documented in two other speleothem δ18O records previously reported from South‐west China. This suggests that details of the Greenland interstadial 12 warrant further investigations in future in monsoonal China. The SI3 δ18O record displays more significant centennial‐scale variations than the other four speleothem δ18O records from East and South‐west China, which may be due to the fact that the study site is closer to the north‐west boundary of the ASM and more sensitive to variations of the ASM than East and South‐west China. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

8.

The aim of the work was to perform paleotemperature reconstructions for the Late Pleistocene and Holocene of Kotelny Island according to oxygen isotope analysis of syngenetic ice wedges. Variations of δ18O in the Late Pleistocene ice wedges formed on Kotelny Island are significant, exceeding 8‰ (from –30‰ to –22.9‰), while they are insignificant at –1.5‰ (from –23.1‰ to –21.6‰) for those in the Holocene. Reconstructions showed that the mean January temperature in the Late Pleistocene changed over 8 to 13°C. The mean annual temperature of frozen soils was about –19 or –20°C in the Late Pleistocene, and about –13 to –15°C in the Holocene, while the current temperature is about –14°C.

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9.
This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ18Odiatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ18Odiatom values range from +29.8 to +35.0‰, and relatively higher δ18Odiatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ18Odiatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ18Odiatom values, whereas lower lake levels cause higher δ18Odiatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ18Odiatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ18Odiatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.  相似文献   

10.
The aim of this work is to obtain the vertical isotopic profile of the thick Pestsovoe pingo ice core in the southern part of the Tazovsky Peninsula, to determine the oxygen and hydrogen isotopic composition of the ice, and to reveal its formation conditions. Two trends were identified for the isotopic profile of the pingo ice: an insignificant increase of the δ18O (~1.5‰) and δD (~9‰) values at depths of 12–15 m and a gradual decrease of isotopic values by 3.8 and 23‰ for δ18O and δD, respectively, at a depth of 15–26 m. The formation of the pingo ice core in the semiclosed system resulted in fractionation of the isotopic composition of oxygen and hydrogen by more than 4 and 20‰, respectively.  相似文献   

11.
Shells of the helicid Cepaea nemoralis were studied using taphonomic, isotopic and morphometric measurements to estimate late glacial–Holocene (~ 12.1–6.3 cal ka BP) environmental conditions in northern Spain. Higher taphonomic alteration among Holocene shells suggests lower sedimentation rates or higher shell-destruction rates than during glacial conditions. Shells preserved the aragonitic composition despite differing degree of skeleton damage. Shell δ13C values were ? 10.3 ± 1.1‰, ? 8.2 ± 2.3‰, and ? 7.3 ± 1.6‰ for modern, Holocene and late-glacial individuals, respectively. Higher δ13C values during the late-glacial and some Holocene periods imply higher water stress of C3 plants and/or higher limestone contribution than today. Intrashell δ13C values were higher during juvenile stages suggesting higher limestone ingestion to promote shell growth. Shell δ18O values were ? 1.1 ± 0.7‰, ? 0.9 ± 0.8‰ and ? 0.1 ± 0.7‰ for modern, Holocene and late-glacial specimens, respectively. A snail flux-balance model suggests that during ~ 12.1 ? 10.9 cal ka BP conditions were drier and became wetter at ~ 8.4 ? 6.3 cal ka BP and today. Intrashell δ18O profiles reveal that glacial individuals experienced more extreme seasonality than interglacial shells, despite possible larger hibernation periods. Shell size correlated positively with δ18O values, suggesting that growth rates and ultimate adult size of C. nemoralis may respond to climate fluctuation in northern Spain.  相似文献   

12.
REE-fluorocarbonates as major REE minerals in the Bayan Obo deposit,the largest REE deposit in the world,were analyzed for their stable isotopic compositions,The δ^13 C and δ^18 O values of huanghoite,cebaite and bastnaesite from late-stage veins vary in the ranges of 7.8--4.0‰ and 6.7-9.4‰,respectively,These data are relatively similar to those of bastnaesites from banded ores:δ^13C-5.6--5.2‰ andδ^18O3.6-5.5‰.The REE fluorocarbonates from both late-staege veins and banded ores are characterized by lower δ^13 C and δ^18O values,especially the δ^18O values of bastnaesites from banded ores.Compared with them,the disseminated bastnaesits the dolomite-type ores possess rather highδ^13 C and δ^18O values,i.e.,-2.1-0.4‰ and 8.6-12.9‰ respectively.The high values are typical of the sedimentary host dolomite rocks as well as of the dolomite-type-ores.The carbon and oxygen isotopic characteristics of REE fluorocarbonate minerals provide new evidence for the hypothesis on the origin of Bayan Obo deposit-epigenetic hydrothermal metasomatism.  相似文献   

13.
The extent of denitrification in a small agricultural area near a river in Yangpyeong, South Korea, was determined using multiple isotopes, groundwater age, and physicochemical data for groundwater. The shallow groundwater at one monitoring site had high concentrations of NO3-N (74–83 mg L?1). The δ15N-NO3 values for groundwater in the study area ranged between +9.1 and +24.6‰ in June 2014 and +12.2 to +21.6‰ in October 2014. High δ15N-NO3 values (+10.7 to +12.5‰) in both sampling periods indicated that the high concentrations of nitrate in the groundwater originated from application of organic fertilizers and manure. In the northern part of the study area, some groundwater samples showed elevated δ15N-NO3 and δ18O-NO3 values, which suggest that nitrate was removed from the groundwater via denitrification, with N isotope enrichment factors ranging between ?4.8 and ?7.9‰ and O isotope enrichment factors varying between ?3.8 and ?4.9‰. Similar δD and δ18O values of the surface water and groundwater in the south appear to indicate that groundwater in that area was affected by surface-water infiltration. The mean residence times (MRTs) of groundwater showed younger ages in the south (10–20 years) than in the north (20–30 years). Hence, it was concluded that denitrification processes under anaerobic conditions with longer groundwater MRT in the northern part of the study area removed considerable amounts of nitrate. This study demonstrates that multi-isotope data combined with physicochemical data and age-dating information can be effectively applied to characterize nitrate contaminant sources and attenuation processes.  相似文献   

14.
The ice-rich core formation within the core of the lithalsa in the Sentsa River valley (West Buryatia) was studied. The concentrations of stable oxygen and hydrogen isotopes in the ice were determined, the plant residues in the enclosing deposits were aged. It was found that the lacustrine loams enclosing the ice body were accumulated about 4700–7000 years ago. The ice core of the lithalsa was characterized by δD values from 141.9 to–159.8‰, δ18O from–19.52 to–21‰, and d exc within 4.1–17.29‰. Small variations in the isotope composition of the ice–soil material within the lithalsa core point to its formation in an open system with water inflow from outside. The values of δ18O and δD were much closer to those for recent middle-winter and late-autumn atmospheric precipitation, as well as for riverine water, which pointed to a Holocene age of the ice.  相似文献   

15.
As a result of the scarcity of isotopic reference waters for daily use, a new secondary isotopic reference material for international distribution has been prepared from ice‐core water from the Amundsen–Scott South Pole Station. This isotopic reference material, designated as USGS49, was filtered, homogenised, loaded into glass ampoules, sealed with a torch, autoclaved to eliminate biological activity and measured by dual‐inlet isotope‐ratio mass spectrometry. The δ2H and δ18O values of USGS49 are ?394.7 ± 0.4 and ?50.55 ± 0.04 mUr (where mUr = 0.001 = ‰), respectively, relative to VSMOW, on scales normalised such that the δ2H and δ18O values of SLAP reference water are, respectively, ?428 and ?55.5 mUr. Each uncertainty is an estimated expanded uncertainty (= 2uc) about the reference value that provides an interval that has about a 95% probability of encompassing the true value. This isotopic reference material is intended as one of two isotopic reference waters for daily normalisation of stable hydrogen and oxygen isotopic analysis of water with an isotope‐ratio mass spectrometer or a laser absorption spectrometer. It is available by the case of 144 glass ampoules or as a set of sixteen glass ampoules containing 5 ml of water in each ampoule.  相似文献   

16.
Ice core from Greenland was melted, filtered, homogenised, loaded into glass ampoules, sealed, autoclaved to eliminate biological activity, and calibrated by dual‐inlet isotope‐ratio mass spectrometry. This isotopic reference material (RM), USGS46, is intended as one of two secondary isotopic reference waters for daily normalisation of stable hydrogen (δ2H) and stable oxygen (δ18O) isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The measured δ2H and δ18O values of this reference water were ?235.8 ± 0.7‰ and ?29.80 ± 0.03‰, respectively, relative to VSMOW on scales normalised such that the δ2H and δ18O values of SLAP reference water are, respectively, ?428 and ?55.5‰. Each uncertainty is an estimated expanded uncertainty (= 2uc) about the reference value that provides an interval that has about a 95‐percent probability of encompassing the true value. This reference water is available in cases containing 144 glass ampoules that are filled with either 4 ml or 5 ml of water per ampoule.  相似文献   

17.
In the Muskeg Trough of northcentral Alberta the Gilwood Member contains widespread carbonate deposits that formed within terrigenous mudstone and sandstone hosts. Stratigraphic, depositional and petrographic relationships indicate that these carbonates represent calcretes and dolocretes. Calcretes, observed best with cathodoluminescence, display microcrystalline alpha fabrics, circumgranular cracks, root networks, displacive growth fabrics, elongate channel voids and rare coloform growths with flower spar. Similarly, dolocretes have microcrystalline alpha fabrics, brecciation, gradational contacts with host mudstones, extensive layered nodular horizons and are associated with anhydrite and pyrite. δ13C values range between ?7‰ to +1‰ and –6‰ to +3‰ for calcretes and dolocretes, respectively. Oxygen isotopes are more variable and differ with host lithologies. δ18O of calcretes ranges between ?11‰ to ?8‰ for sandstones and ?8‰ to ?3‰ for mudstones, whereas δ18O of dolocretes ranges between ?3‰ to 1‰ for marine mudstones and ?6‰ to ?2‰ for pedogenic mudstones. Regional mapping indicates that calcretes thicken towards the deepest parts of the Muskeg Trough. Widespread dolocretes extend beyond the eastern and western limits of Muskeg Trough and are useful marker intervals for regional correlations. Dolocretes of restricted lateral extent are found within gleyed palaeosol mudstones next to calcretized channel sandstones. Calcrete isotopic values are interpreted as indicative of carbonate precipitation from waters with meteoric water input. However, the higher δ18O values in dolocretes are indicative of a contribution from an isotopically heavier source such as seawater. Stratigraphically, calcretes are most common along the western and northern edges of Muskeg Trough; thus, calcrete accumulation was further controlled by meteoric water in-flow from the highland to the west and sluggish groundwater flow in Muskeg Trough. In contrast, regionally widespread dolocrete horizons appear to have formed from mixing of fresh waters derived from the highland to the west and seawaters introduced from the east. Regionally restricted dolocretes which are found next to channel sandstones formed from groundwater out-flow from the permeable channel sandstones which resulted in calcretization in channel proximal mudstones and dolomitization in channel distal mudstones.  相似文献   

18.
The unidirectional solidification textures (UST) quartz is generally thought to form from fluids exsolved from shallow intrusions and/or magma chambers, but such an idea is still poorly constrained from the evidence of stable isotopes. In this study, we report for the first time the δ18O of quartz that shows UST from the Qulong Cu–Mo and the Yechangping Mo porphyry deposits in China. The analysis results show that the UST quartz samples from the Qulong deposit have δ18O values ranging from +6.2 ‰ to +7.6 ‰, which are similar to that of quartz phenocrysts (+6.7 ‰ to +7.8 ‰). In contrast, the UST quartz samples from the Yechangping porphyry Mo deposit yield a high δ18O value (+10.0 ‰). The δ18Owater value of Yechangping UST quartz (+8.5 ‰) is also higher than that of Qulong (+4.6 ‰ to +5.8 ‰). Hydrothermal biotite from potassic alteration and sericite from early phyllic alteration at Qulong have similar δ18O values to UST quartz, suggesting the involvement of magmatic fluids during this stage of deposit evolution.  相似文献   

19.
The skarn‐type tungsten deposit of the Date‐Nagai mine is genetically related to the granodiorite batholith of the Iidateyama body. Skarn is developed along the contact between pelitic hornfels and marble that remains as a small roof pendant body directly above the granodiorite batholith. Zonal arrangement of minerals is observed in skarn. The zonation consists of wollastonite, garnet, garnet‐epidote, and vesuvianite‐garnet zones, from marble to hornfels. Sheelite is included in garnet, garnet‐epidote, and vesuvianite‐garnet zones. The oxygen isotope values of skarn minerals were obtained as δ18O = 4.2–7.7‰ for garnet, 5.9–6.9‰ for vesuvianite, ?0.3–3.4‰ for scheelite, 6.0–10.9‰ for quartz, and 8.2‰ for muscovite. The temperature of skarn‐formation was calculated from oxygen isotopic values of scheelite‐quartz pairs to be 288°C. Calculated oxygen isotope values of fluid responsible for skarn minerals were 6.1–9.5‰ for garnet, 1.2–4.8‰ for scheelite, ?1.3‐3.6‰ for quartz, and 4.5‰ for muscovite. Garnet precipitated from the fluids of different δ18O values from scheelite, quartz, and muscovite. These δ18O values suggest that the origin of fluid responsible for garnet was magmatic water, while evidence for the presence of a meteoric component in the fluids responsible for middle to later stages minerals was confirmed.  相似文献   

20.
Mangerud, J., Gulliksen, S. & Larsen, E. 2009: 14C‐dated fluctuations of the western flank of the Scandinavian Ice Sheet 45–25 kyr BP compared with Bølling–Younger Dryas fluctuations and Dansgaard–Oeschger events in Greenland. Boreas, 10.1111/j.1502‐3885.2009.00127.x. ISSN 0300‐9483. We present 32 accelerator mass spectrometry (AMS) 14C dates obtained on well‐preserved bones from caves in western Norway. The resulting ages of 34–28 14C kyr BP demonstrate that the coast was ice‐free during the so‐called Ålesund Interstadial. New AMS 14C dates on shells aged 41–38 14C kyr BP are evidence of an earlier (Austnes) ice‐free period. The Ålesund Interstadial correlates with Greenland interstadials 8–7 and the Austnes Interstadial with Greenland interstadials 12–11. Between and after the two interstadials, the ice margin reached onto the continental shelf west of Norway. These events can be closely correlated with the Greenland ice core stratigraphy, partly based on identification of the Laschamp and Mono Lake palaeomagnetic excursions. We found that the pattern of the NGRIP δ18O curves for the two periods Greenland Interstadial (GI) 8 to Greenland Stadial (GS) 8 and GI 1–GS 1 (Bølling–Younger Dryas) were strikingly similar, which leads us to suggest that the underlying causes of these climate shifts could have been the same. We therefore discuss some aspects of glacial fluctuations during the Bølling–Younger Dryas in order to elucidate processes during Dansgaard–Oeschger events.  相似文献   

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