胶北晚中生代煌斑岩的岩石地球化学特征及其成因研究

胶北煌斑岩分别采自龙口、烟台和威海地区，包括拉辉煌斑岩、斜闪正煌岩和角闪煌斑岩，煌斑岩K—Ar全岩年龄变化于89．3～169．5Ma，为晚中生代岩浆活动的产物。在岩石化学组成上，SiO2=42．02％～54．95％，以钙碱性系列为主．岩石以富集大离子亲石元素（LILE）（Ba，U，K，Th）和LREE，亏损高场强元素（HFSE）（Nb，Ta和Ti）为特征，Mg^#=33．9～53．9，Eu／Eu^＊=0．71～0．89，^87Sr／^86Sr初始比值0．707642～0．709791，εNd（t）为-17．6～-10．4，^206Pb／^204Pb=37．588～38．431，^207Pb／^204Pb=15．423～15．531，^206Pb／^204Pb=17．204～18．179。表明煌斑岩源自俯冲陆壳（扬子下地壳）在地幔源区发生交代作用时形成的富集型地幔的部分熔融体．考虑到煌斑岩具有大陆边缘弧玄武岩的特征，我们认为煌斑岩在成因上同样与古大洋板块的俯冲作用有关，为碰撞后弧岩浆作用形成的脉岩。     

南秦岭中段西乡群火山岩岩石成因

南秦岭中段新元古代中期（730-845Ma）西乡群（自下而上包括孙家河组、大石沟组和白勉峡组）火山岩喷发于大陆板内裂谷环境。它们极有可能与导致Rodinia超大陆裂谷化裂解的地幔柱活动有关。根据岩石地球化学数据．南秦岭中段新元古代中期西乡群裂谷基性熔岩总体上属于低Ti／Y（LT,Ti／Y〈500）岩浆类型。LT熔岩又可进一步划分为LT1和LT2等2个亚类。LT1熔岩以高Nb／La（0．87～0．98）、低Thw／NbN（≈1）、缺乏Nb—Ta和Ti的亏损、具有“大隆起”式微量元素原始地幔标准化分配型式、（^87SrSr^86Sr）（t）=0．703869、εNd（t）=4．83为特征,属于拉斑玄武质岩浆系列;LT2熔岩以低Nb／La（〈0．75）、高ThN／NbN（〉1．4）、Nb—Ta和Ti亏损明显和Sr—Nd同位索比值变化较大为特征。元素和同位素数据表明,西乡群裂谷火山岩的化学变化不是由一个共同的母岩浆结晶分异作用所产生。孙家河组、大石沟组和自勉峡组中TiO2含量大于1．09％的火山岩的母岩浆经受了辉长岩质结晶分离作用。而白勉峡组中TiO2含量小于0．69％的基性熔岩的化学演化则是受控于单斜辉石（cpx）±橄榄石（ol）结晶分离作用。西乡群火山岩系中,基性、中性和酸性熔岩间为分异结晶关系。南秦岭中段新元古代中期西乡群裂谷火山岩系极有可能是源于共同的地幔柱,该地幔柱组分的成分为;εNd（t）≈＋5,^87Sr／^86Sr（t）≈0．704,La／Nb≈0．7。南秦岭中段新元古代中期西乡群裂谷基性熔岩存在空间上的地球化学变化：LT1熔岩的母岩浆,没有受到明显的大陆岩石圈混染,保存了鲜明的地幔柱信号;而大陆地壳或大陆岩石圈混染作用对于LT2熔岩的形成则有着重要贡献。研究揭示,南秦岭中段新元古代中期西乡群裂谷基性熔岩的母岩浆总体上产生于上涌地幔柱上部层位（地幔柱头）3GPa?     

西天山石炭纪火山岩岩石学及Sr-Nd同位素地球化学研究

西天山石炭纪火山岩连续从玄武岩、粗面质玄武安山岩、粗面安山岩、粗面岩一直演化到流纹岩。不同地区火山岩的同位素组成差别很大。出露在拉尔敦达坂一带的晚石炭世粗面安山岩-粗面岩具有较高的εNd（t）值（＋2、68～＋4．29）和较高的初始^87Sr／^86Sr值（0、7015～0．7051）。新源城南的早石炭世粗面安山岩．流纹岩具有相对较低的εNd（t）值（-0．22～＋0．87）和变化较大的初始^87Sr／^86Sr值（0．7045～0．7068）。早石炭世玄武岩的初始^87Sr／^86Sr值较低且变化范围较小（0．7045～0．7058），εNd（t）值高且变化范围大（＋0．89～＋3．04）。本文的同位素地球化学资料以及前期的年代学研究表明，西天山晚泥盆-早石炭世岛弧自西向东逐渐消亡，取而代之的是晚石炭世碰撞后富钾岩浆的喷发。     

天山北部石炭纪埃达克岩-高镁安山岩-富Nb岛弧玄武质岩：对中亚造山带显生宙地壳增生与铜金成矿的意义

新疆天山北部地区存在有石炭纪的埃达克岩-高镁安山岩-富Nb玄武质岩组合，并且其中许多岩石与铜（金）矿床伴生（如达巴特、阿希、土屋-延东、赤湖，等等）。埃达克岩富钠、高Sr但亏损Y与Yb，无明显Eu-正Eu异常以及正Sr异常与Nb、Ti亏损。高镁安山（闪长）岩是本次研究首次报道的，这些岩石无明显Eu-正Eu异常以及Nb、Ti亏损，普遍具有高的MgO和Cr、Ni含量，其中阿希金矿区一些样品类似于日本西南新生代Setouchi弧火山岩带中的赞岐岩类。富Nb玄武质岩富钠贫钾，具有微弱负．正Ba、Nb和Ti异常以及高的Nb／La比值，不同于大多数正常岛弧玄武岩。天山北部地区石炭纪埃达克岩具有高的8Nd（t）（＋3．4-＋9．0）和低的（^87Sr／^86Sr）i（0．7032—0．7043）。富Nb玄武质岩具有变化的εNd（t）（＋3．6-＋11．6）和（^87Sr／^86Sr）；（0．7007—0．7067）。我们的研究表明，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合可能是“埃达克岩交代的岛弧岩浆岩系列”。埃达克岩最有可能由石炭纪北天山洋的年轻洋壳在俯冲过程中熔融形成。另外，俯冲板片产生的熔体以及所释放的少量流体在上升过程中可能交代地幔楔橄榄岩或与其发生反应：一方面，触发地幔楔橄榄岩发生熔融形成富Nb岛弧玄武质岩；另一方面，地幔组分迅速进入到板片熔体中，导致其地幔组分增加，乃至形成高镁安山岩。因此，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合表明：（1）天山北部地区石炭纪可能为岛弧环境而非裂谷环境；（2）天山地区石炭纪的地壳生长可能以侧向增生为主；（3）除了亏损地幔之外，俯冲洋壳的熔融可能也在地壳的生长中发挥了重要的作用；（4）俯冲板片产生的埃达克质岩浆具有高的氧逸度，而其与地幔楔橄榄岩的强烈相互作用将导致地幔中的金属硫化物分解，成矿金属元素进入到岩浆中。这可能是新疆北部铜金矿化与一些埃达克岩、高镁安山（闪长）岩或富Nb岛弧玄武质岩密切共生的基本原因。     

天山石炭-二叠纪大火成岩省裂谷火山作用与地幔柱

中国西北部石炭纪-早二叠世喷发的天山裂谷火山岩系构成了一个大火成岩省。该火山岩系的组成以玄武质熔岩为主，其次有中性和酸性熔岩及火山碎屑岩。根据岩石学、主元素、微量元素和Sr—Nd—Pb同位素数据，天山玄武岩可分为两个主要岩浆类型：①高Ti／Y（HT）类型，以高Ti／Y（〉500）、高Ce／Y（〉3）和相对低Nb／Zr（〈0．11）、低εNd（t）为特征；②低Ti／Y（LT）类型，以低Ti／Y（〈500）为特征。LT熔岩又可以进一步分为两个亚类：LT1熔岩以低Nb／Zr（〈0．15）和高εNd（t）（＋3．1～＋9．7）为特征；LT2熔岩具有较高的Nb／Zr值（〉0．16）和较低的εNd（t）值（-0．98～-2．91）。元素和同位素数据表明，HT和LT熔岩的化学变异不是由一个共同母岩浆的结晶分异作用所产生。它们极有可能是源于一种似洋岛玄武岩源的幔源（^87St／^86Sr（t）≈0．7045，εNd（t）≈＋4，^206Pb／^204Pb（t）≈18．35．^207Pb／^204Pb（t）≈15．66，^208Pb／^204Pb（t）≈38．25．La／Nb≈0．7），且具有不同的熔融条件和经受了不同的分异和混染。以碱性熔岩为主的HT熔岩是产生于幔源石榴子石稳定区的低度部分熔融，其化学变异受控于单斜辉石（Cpx）[士橄榄石（O1）]分离作用。相反，LT类型的母岩浆则是形成于幔源的尖晶石一石榴子石过渡带：碱性LT2亚类的母岩浆是产生于部分熔融程度较低的条件下；而以拉斑玄武质为主的LT1亚类的母岩浆则是产生于部分熔融条件较高的条件下：它们经受了浅层辉长岩质分离作用，化学变异较大。天山玄武岩可能是产生于地幔柱头。HT和LT岩浆的岩石成因又进一步为地壳和岩石圈地幔的混染作用所复杂化。我们的研究揭示，天山大火成岩省的火山岩中存在空间上的岩石地球化学变化。天山东段的LT1火山岩系的厚度最大．它们记录了玄武岩侵位的主幕，该处可能是地幔柱或地幔熔融异常的中心位置。相反，厚度较小的HT和LT2玄武岩则可能是意味着地幔柱活动影响的减弱。事实上，HT和LT2玄武岩也是该大火成岩省边缘部分的主要岩浆类型。HT和LT2熔岩的地幔熔融程度较低，可能是与地幔柱边部的岩石圈相对较厚和地热较低有关。     

南天山北部巴音布鲁克早古生代火成岩的地球化学特征与岩石成因

南天山北部上志留统巴音布鲁克组火山岩系以中基性喷出岩为主,并有辉长岩侵入,其矿物组合中都含有角闪石,岩层中爆发相火山碎屑岩极为发育。各种火山-侵入岩的LREE和LILE强烈富集、HFSE相对亏损,出现明显的Ta、Nb负异常,（La／Yb）N：2．92～5．21,Nh／La=0．22—0．33,具有岛弧岩浆岩的特征。zr／Nb=26～47、Hf／Ta=11．9—19．9,暗示其源区为类似于N—MORB的亏损地幔;高的Th、LREE含量和高于正常弧火山岩、低于洋岛玄武岩（OIB）的HFSE绝对丰度,较小的εNd（t）值（＋3．23～＋6．15）、较大的（^87Sr/^86Sr）。值（0．7044—0．7063）,εNd（t）与（^87Sr／^86Sr）。间呈明显的线性负相关关系,并且分别与LILE／HFSE之间呈负相关和正相关关系。上述特征反映出巴音布鲁克火成岩的岩石成因中既有俯冲洋壳板片流体-沉积物的加入,也有板片熔体组分的贡献,在地球化学上具有正常岛孤玄武岩（IAB）与富铌岛弧玄武岩（NEAB）之间过渡系列的特征。该套火成岩与中天山南缘蛇绿混杂岩带紧邻,地层时代也与南天山洋俯冲-消减时代相当,它应当是南天山洋盆于晚志留世时发生的俯冲-消减所引发的岛弧火山-岩浆作用的地质记录。     

松辽盆地早白垩世火山岩地球化学特征及其构造意义

松辽盆地早白垩世发育基性岩类的橄榄玄武岩、玄武岩,中性岩类的玄武安山岩、安山岩、粗安岩,酸性岩类的粗面岩、粗面英安岩、英安岩和流纹岩。早白垩世火山岩都具有大离子亲石元素(LILE)、轻稀土元素(LREE)相对富集的特征,并具有较低的(~(87)Sr/~(86)Sr)_i值和较高的(~(143)Nd/~(144)Nd)_i值。基性岩类Ce/Nb=1.92～8.31,Th/Nb=0.08～0.44,(~(87)Sr/~(86)Sr)_i=0.7031～0.7047,ε_(Nd)(t)=+1.7～+5.2;中性岩类Ce/Nb=3.70～15.80,Th/Nb=0.34～2.58,(~(87)Sr/~(86)Sr)_i=0.7040～0.7054,ε_(Nd)(t)=0～+3.0;酸性岩类Ce/Nb=4.29～15.80,Th/Nb=0.11～1.02,(~(87)Sr/~(86)Sr)_i=0.7038～0.7066,ε_(Nd)(t)=+1.0～+3.3。基性岩类岩浆主要来自被富集了的亏损地幔源的部分熔融,受混染程度很小;中性岩类岩浆源于年轻地壳组分被来自亏损地幔岩浆的再次部分熔融;酸性岩类浆岩可能主要来自源于亏损地幔的初生地壳部分熔融,并受到了上地壳的混染。晚侏罗世-早白垩世,由于蒙古-鄂霍次克洋关闭引发强烈的挤压造山后,发生的岩石圈拆沉作用致使来自亏损地幔的岩浆熔融上涌导致岩石圈主动伸展拉张,地表则表现出大规模的裂谷断陷作用和大范围的火山活动。这个阶段的伸展拉张以主动拉张为主。     

胶莱盆地晚白垩世不同地幔源区的两种基性岩浆——诸城玄武岩和胶州玄武岩的对比

采用全岩K-Ar法获得山东省胶莱盆地诸城玄武岩的形成年龄为76M，胶州玄武岩的形成年龄为72Ma，代表了发生在晚白垩世的地幔岩浆事件，但两地岩浆产物具有不同的地球化学性质。诸城玄武岩主要为粗面玄武岩，富集轻稀土元素（LREE），微量元素组成类似于洋岛玄武岩（OIB），（^87Sr/^86Sr）t=0．7060-0．7080，εNd（t）=-3．0--5．1，介于洋岛玄武岩和中生代富集的岩石圈地幔之间，表明软流圈来源的岩浆中混入了富集岩石圈地幔来源的岩浆，是软流圈地幔与岩石圈地幔相互作用的结果。胶州玄武岩主要为碱性玄武岩，比诸城玄武岩更富集轻稀土元素，微量元素组成类似于诸城玄武岩，但Nb、Ta、Ti等高场强元素不显示亏损，Sr-Nd同位素组成也存在明显差别，（^87Sr/^86Sr）t=0、70350-0．70355，εNd（t）=5．4-5．8，与山东省新生代火山岩的地球化学特征类似，类似于洋岛玄武岩（OIB），表明岩浆起源于亏损的软流圈地幔。研究显示出晚白垩世以来胶莱盆地软流圈地幔不均匀上涌和逐渐成为玄武岩浆主要源区的趋势。     

三江地区古特提斯火山岩源区物质的Nd-Sr-Pb同位素体系特征

Nd-Sr-Pb同位素体系对三江地区古特提斯火山岩的示踪结果表明，古特提斯时期三江地区存在亏损和近原始两种地幔储库。亏损地幔的Isr＝0．7041～0．7077，εNd（t）＝＋2．87～＋7．24；近原始地幔的Isr＝0．7039～0．7079，εNd（t）＝－0．95～＋5．41。它们均属南半球地幔域。亏损地幔和近原始地幔分别是三江地区MORB和OIB的源区物质。金沙江洋内弧火山岩继承了MORB的源区物质，Isr＝0．7060～0．7066，εNd（t）＝＋6．24～＋7．54；碰撞弧火山岩的源区物质是陆壳重融物，Isr＝0．7203～0．7235，εNd（t）＝－8．80～－10．76；滞后弧山岩的源区物质是陆壳重融物与少量地幔柱熔融物的混合物，Isr＝0．7077～0．7099，εNd（t）＝－2．56～－9．93。澜沧江陆缘弧火山岩的源区物质是洋壳、大洋沉积物和陆壳物质的混合物，Isr＝0．7052～0．7111，εNd（t）＝＋0．61～－7．26。Sr-Pb同位素联合示踪还表明，三江地区存在Dupal异常，其△Sr＞40，△8／4＞60和△7／4＞7。     

辽西北票早侏罗世兴隆沟组英安岩的地球化学特征

辽西北票早侏罗世兴隆沟组英安岩具有埃达克岩的地球化学特征。它们具有较高的SiO2（≥63．93％）、Al2O3（≥15．40％）、Na2O（≥3．65％）和MgO（≥2．32％，Mg^#=0．48～0．61）含量，较高的Sr（〉463μg／g）、Cr（〉119μg／g）、Ni（〉75μg／g）含量，较低的Yb（〈1．70μg／g）、Y（〈17μg/g）含量，高的La／Yb（〉18）、Sr／Y（〉34）值和低Rb／Sr（≤0．31）比值，稀土元素强烈分馏，弱的负铕异常（Eu／Eu^＋=0．80～0．87）．它们的Nd同位素（^143Nd/^144Nd=0．512414～0．512502．εND（t）=-2．10～-0．38，TDM：0．89～1．02Ga），Sr同位素（^87Sr／^86Sr=0．7073～0．7075，8Sr（t）=11．16～13．78）和Pb同位素（^206Pb／^204Pb=18．28～18．40，^207Pb／^204Pb=15．42～15．53，^208Ph／^204Pb=38．08～38．27）组成与华北陆块古老的岩石圈地幔及其中的中晚侏罗世和早白垩世火山岩不同。这表明兴隆沟组英安岩可能是古亚洲洋壳残片部分熔融形成的，熔体在上升过程中与地幔楔发生过强烈的混染作用。据此，推测古亚洲洋曾向华北陆块发生过俯冲作用。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.