西藏多不杂斑岩铜矿床辉钼矿Re-Os和锆石U-Pb SHRIMP测年及地质意义

多不杂矿床是班公湖-怒江缝合带上发现的第一处大型斑岩铜矿床.该矿床位于班公湖-怒江缝合带的北侧,羌塘地块的南缘.含矿斑岩体属花岗闪长斑岩,其SiO2含量为61.3796-67.73%,平均为65.16%;稀土元素总量为(41.4-94)× 10~(-6),LREE>HREE,属轻稀土元素富集型;微量元素特征表现为富集大离子不相容元素Rb、K、Th、Ba、La、Ce、Sr,亏损高场强元素Nb、Ta、P、Ti.含矿斑岩的稀土元素和微量元素特点反映出岛弧带的岩浆作用特征.含矿斑岩中锆石的U-Pb SHRIMP测年获得(120.9±2.4)Ma(MSWD=4.3)谐和年龄,代表了含矿斑岩的形成时代.6个辉钼矿样品的Re-Os模式年龄范围非常一致,其变化范围为(117.6±1.3)～(118.5±1.4)Ma,等时线年龄为(118.0±1.5)Ma(MSwD=0.30),代表了该矿床的成矿年龄.该矿床的形成时代对应于班公湖.怒江早白垩世期间的多岛弧-盆系演化时期,其形成环境类似于东南亚的多岛弧-盆系统.     

西藏雄梅铜矿区含矿斑岩与非含矿斑岩成因对比研究

西藏雄梅铜矿床是近年来在班公湖_怒江成矿带中段新发现的一处斑岩铜矿床,该矿床的发现使得班公湖_怒江成矿带真正具备了"带"的概念,大大地拓宽了找矿远景。文章通过对雄梅铜矿区斑岩体的LA_ICP_MS锆石U_Pb定年,发现矿区存在2套斑岩:一套是前人测定的年龄为106.7 Ma的含矿斑岩;另一套是本文测定的非含矿斑岩,3个年龄分别是(121.8±2.3)Ma(MSWD=0.32)、(122.8±2.1)Ma(MSWD=1.16)、(121.5±2.5)Ma(MSWD=0.54)。两套斑岩的岩性虽然都是花岗闪长斑岩,但非含矿斑岩比含矿斑岩含有更多的钾长石,矿化强度大大减弱。岩石地球化学分析结果表明,两套斑岩虽然都富集大离子亲石元素(LILE)Rb、Ba、Th、U、K、Pb,亏损高场强元素(HFSE)Nb、Ta、Ti,具有碰撞后岩浆作用的共同特征,但在岩浆源区和成因上显示出明显的差异。含矿斑岩和非含矿斑岩均属于强过铝质S型花岗岩,然而前者源区组成为杂砂岩,后者源区则以泥质岩为主。岩浆分异过程中,含矿斑岩受斜长石和钾长石的分离结晶控制,非含矿斑岩则受钾长石和黑云母的分离结晶控制。     

西藏班公湖—怒江成矿带斑岩-浅成低温热液型矿床岩浆作用与成矿:以改则县东窝东铜多金属矿床为例

西藏改则县东窝东铜多金属矿床位于西藏多龙矿集区东部,是近年来班公湖—怒江成矿带上新发现的铜多金属矿。对区内花岗闪长斑岩和花岗斑岩进行了LA-ICP-MS锆石U-Pb年代学测试显示,成岩年龄为(121.0±1.2)Ma和(121.5±1.0)Ma,与多龙矿集区内成岩成矿年龄相近。研究区含矿斑岩显示了富集轻稀土和大离子亲石元素,亏损重稀土和高场强元素,中等Eu负异常,高铝、低镁、低钛,高Sr、低Y及Yb的岛弧岩浆岩特征,暗示矿区含矿岩浆与多龙矿集区含矿岩浆具备相同的岩浆源区。矿区含矿斑岩的锆饱和温度介于779.6~844.5℃,地球化学数据显示高Sr低Nd及低εNd(t)值特征;含矿斑岩εHf(t)为+3.4~+11.1,两阶段模式年龄T2DMC为467~963 Ma;表明其与多龙矿区含矿斑岩具备相似的Sr-Nd-Hf同位素特征,暗示了矿区含矿斑岩是班公湖—怒江特提斯洋洋壳向北俯冲消减背景下,由玄武质新生下地壳在较高温度条件下部分熔融形成的产物,指示班公湖—怒江洋盆于早白垩世晚期尚未关闭。野外地质调查发现,矿区发育典型斑岩铜矿蚀变分带;具备与多龙矿集区的岩石组成、矿化及蚀变、成岩成矿时代、构造环境和物质来源相类似的特征,且空间位置相近,暗示两者受控于统一的构造-岩浆成矿系统。综合分析认为,东窝东地区为多龙矿集区东延部分,具有寻找斑岩-浅成低温热液型铜(金)矿床隐伏矿体的良好潜力。     

西藏铁格隆南超大型铜(金、银)矿含矿斑岩岩石成因及其对多龙地区早白垩世成矿动力学机制的启示

铁格隆南是西藏多龙矿集区新发现的超大型斑岩-浅成低温热液型铜(金、银)矿床。作为班公湖-怒江成矿带西段早白垩世重大成矿事件的典型代表,铁格隆南矿床以及整个多龙矿集区的含矿斑岩岩石成因及成矿动力学机制仍存在明显争议。本文以铁格隆南矿床为核心,基于详细的矿床地质特征和岩石学特征,利用锆石的SHRIMP U-Pb年代学厘定花岗闪长斑岩侵位时代为121. 2±2. 4Ma,与区域早白垩世含矿斑岩岩浆侵位时间一致。同时,详细的岩石地球化学分析表明,铁格隆南矿床及多龙矿集区,含矿斑岩以花岗闪长斑岩为主,含少量闪长玢岩和花岗斑岩,属于高钾-钙碱性或钾玄岩系列,富集轻稀土和大离子亲石元素(Rb、Ba、U),亏损重稀土及高场强元素(Nb、Ta、Ti),具典型的弧岩浆特征。此外,其岩石地球化学特征及Sr-Nd-Pb-Hf同位素组成揭示,含矿斑岩的岩浆源区可能与俯冲板片流体交代的富集岩石圈地幔部分熔融有关。最后,详细的岩石学"探针"及区域岩浆活动特征表明,多龙矿集区白垩世重大成矿作用动力学机制与班公湖-怒江洋北向俯冲板片的折返(130～110Ma)有关。     

西藏青草山斑岩铜金矿床含矿斑岩锆石U-Pb年代学及岩石成因

西藏青草山Cu-Au矿床是班公湖-怒江缝合带北侧新发现的具有大型远景的斑岩型矿床,但该矿床含矿斑岩的年龄、成因及源区一直未得到有效的约束.对青草山花岗闪长岩以及含矿花岗岩闪长斑岩进行了锆石年代学、Hf同位素以及岩石地球化学研究.结果显示,花岗闪长岩与含矿花岗闪长斑岩的侵入时代分别为131.2±0.3 Ma与117.9±0.8 Ma,代表了班公湖-怒江缝合带早期的成岩作用以及斑岩Cu-Au成矿作用.二者具有相似的地球化学特征,表明二者可能具有相同的岩浆源区,是不同时期同源岩浆活动的产物.结合含矿花岗闪长斑岩锆石Hf同位素组成,认为青草山含矿斑岩形成于班公湖-怒江洋壳向北俯冲过程中,是下地壳部分熔融的产物,受到了少量地幔物质的混合.      

西藏班公湖-怒江成矿带荣嘎斑岩型钼矿床的发现及意义

西藏班公湖-怒江成矿带为近十年来找矿突破明显的一个矿带,矿床类型主要包括斑岩-浅成低温热液型和斑岩-矽卡岩型,矿种以铜金为主,总体研究程度尚低.荣嘎矿床位于班公湖-怒江缝合带南缘西段,为2016年新发现的首例具大型远景的斑岩型钼矿床,其辉钼矿Re-Os同位素加权平均年龄为99.3±0.1 Ma（MSWD=0.2,n=8）,等时线年龄为99.2±0.4 Ma（MSWD=0.2,n=8）,表明该矿床成矿时代为晚白垩世早期,成矿发生在班公湖-怒江洋盆闭合后的拉萨-羌塘地体碰撞造山阶段.该矿床的发现丰富了班-怒带成矿理论认识,填补了该带钼矿资源的空白,对已有的成矿模型提出了新的挑战,预示着班-怒缝合带还存在一期斑岩钼成矿事件,并为该带进一步寻找相似的钼矿床提供了例证及理论支撑.      

黑龙江铁力鹿鸣斑岩型钼矿床埃达克岩的发现及其地质意义

鹿鸣钼矿是伊春-延寿成矿带内近年发现的大型斑岩钼矿,矿区主要出露含矿的二长花岗岩、花岗斑岩,不含矿的花岗闪长岩及似斑状花岗闪长岩四种岩性。二长花岗岩与花岗斑岩具有相似的低Sr高Y等地球化学特征,形成于194.8±0.7Ma~184Ma前后的早侏罗世,是斑岩型矿床的赋矿围岩。花岗闪长岩及似斑状花岗闪长岩含有暗色岩包体,主要为高钾钙碱性系列岩石,但以高Sr、低Y及富Na为特征,部分地球化学指标与中国东部埃达克岩极为相似,形成于176.2±2.1Ma并与辉钼矿Re-Os法获得的成矿年龄一致,被认定为斑岩型矿床的成矿母岩。高Sr和低Sr两类花岗岩形成于不同的构造背景,与中生代时期中国东部及其邻区几次重大地质事件密切相关。鹿鸣斑岩型钼矿床与中侏罗世太平洋板块俯冲在高氧逸度条件下熔融形成的埃达克质岩浆高侵位有关。鹿鸣矿区埃达克岩的发现表明中侏罗世太平洋板块已经发生了萎缩与消减,与之相关的岩浆作用及成矿应该具有广泛的区域性,扎实的岩石学工作可为区域更多斑岩型矿床的发现提供线索。     

河北省涞源县龙门斑岩型钼矿床锆石U-Pb和辉钼矿Re-Os年龄及其地质意义

龙门钼矿床是太行山北段成矿带内近些年探明的一个大型钼矿床,钼矿体主要产于花岗斑岩、闪长岩和新太古代片麻岩中,以角砾岩型矿石为主.矿区内辉钼矿化主要类型为浸染状、薄膜状、细脉状,发育钾长石化、硅化、绢云母化、黄铁矿化蚀变,类似典型的斑岩型矿床的矿化和蚀变特征.文章对龙门钼矿床的闪长岩和花岗斑岩进行了LA-ICP-MS锆石U-Pb同位素测年,获得闪长岩的锆石谐和年龄为(138.1±0.6)Ma(MSWD=0.6,n=21),花岗斑岩的锆石谐和年龄为(137.0±0.7)Ma(MSWD=1.03,n=17),结合地质特征,显示花岗斑岩晚于闪长岩形成.对主要矿石类型中的辉钼矿进行了Re-Os同位素测年,获得辉钼矿的Re-Os等时线年龄为(136.5±1.5)Ma,与赋矿的花岗斑岩的侵位年龄相一致,二者应为同一岩浆-流体活动的产物.龙门钼矿床辉钼矿样品的w(Re)为13.1×10-6～59.3×10-6,表明其成矿物质来源于壳幔混源.龙门矿区及太行山北段成矿带内的隐爆角砾岩体是下一步找矿勘查的方向.     

藏西班公湖斑岩铜矿带的形成时代与成矿构造环境

通过对藏西班公湖斑岩铜矿带多不杂和尕尔穷2个大、中型斑岩铜矿床含矿斑岩的研究,初步查明了该铜矿带的形成时代、含矿斑岩性质及成矿构造环境.锆石SHRIMP U-Pb定年结果给出2个铜矿床含矿斑岩的时代分别为127.8Ma±2.6Ma和112.0Ma±2.3Ma,处于造山带演化的碰撞后阶段(班公湖-怒江洋盆的闭合时间为145Ma).岩石地球化学分析表明,该铜矿带的含矿斑岩属钾玄岩-高钾钙碱性岩系,以富集Rb、K、Sr、Pb等大离子不相容元素和亏损Nb、Ta、Ti等高场强元素为特点,与冈底斯斑岩铜矿带的含矿斑岩相似.所不同的是,班公湖斑岩铜矿带含矿岩浆生成深度较浅,构造环境上处于碰撞后地壳隆升阶段,而冈底斯斑岩铜矿带则处于地壳上升到最大高度后的伸展塌陷阶段.     

西藏班公湖-怒江成矿带上的碰撞后铜矿床

地处藏北高原的班公湖-怒江铜矿带是继藏东的玉龙斑岩铜矿带和藏南的冈底斯斑岩铜矿带之后,在青藏高原上发现的第三条铜矿带。与前两条斑岩铜矿带不同的是,班公湖-怒江铜矿带的铜矿床类型具有多样性,包括:1多龙、雄梅斑岩型铜金矿床;2尕尔穷-嘎拉勒斑岩-矽卡岩型铜金矿床;3拨拉扎斑岩型铜钼矿床;4舍索矽卡岩型铜(铅锌)多金属矿床。不同类型铜矿床的成矿时代集中在120~90 Ma之间,约30 Ma间隔内。文章通过沉积岩岩相学、火成岩岩石地球化学以及锆石U-Pb与辉钼矿Re-Os同位素年代学的综合研究,指出班公湖-怒江中特提斯洋盆的闭合时间为早白垩世初(140~130 Ma之间),班公湖-怒江成矿带上的铜矿床都形成于碰撞后造山环境。该成矿带与铜矿化有关的侵入岩主要为花岗闪长(斑)岩和石英闪长(玢)岩,在岩石地球化学上,富集大离子亲石元素(Rb、Th、U、Ba、K、Pb),亏损高场强元素(Nb、Ta、Ti),显示出俯冲组分对岩浆生成过程产生的重要影响,与碰撞后岩浆作用特征相吻合。除了班公湖-怒江铜矿带外,青藏高原上的另外两条斑岩铜矿带(即藏东的玉龙斑岩铜矿带和藏南的冈底斯斑岩铜矿带),也是形成于洋盆闭合之后的造山带碰撞后环境,因此,青藏高原可以说是地球上碰撞后铜矿床的天堂。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.