Measurements of solar radiation and estimation of optical depth in the high Andes of Peru

Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (_wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (_ray) and ozone (_oz) optical depths were obtained from published tabulations. Subtracting _ray, _oz, and _wv from yielded estimates of aerosol optical depth _aer. The components _ray and _oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; _aer also decreases towards the higher elevations. Particularly pronounced is the decrease of _aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures     

The behaviour of aerosol optical depth during clear summer days in Athens,Greece

Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s^–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures     

The von Kármán constant determined by large eddy simulation

The present study explores the extent to which the logarithmic region of the adiabatic atmospheric boundary layer can be modeled using a three-dimensional large eddy simulation. A value of the von Kármán constant (_LES) is obtained by determining the slope of a logarithmic portion of the velocity profile. Its numerical value is found to be dependent on the value of the Smagorinsky-Model Reynolds number, Re_SM: the value of _LES increases with Re_SM. Results indicate that _LES approaches a value of 0.35 as Re_SM reaches about 7.75 × 10⁵ for the largest domain. The sensitivity of _LES to the profile region over which it is evaluated has been tested. Results show that _LES is not sensitive to the depth of this evaluation region when we employ five grids above the sub-grid buffer layer where sub-grid-scale effects dominate. The maximum _LES is obtained when the lower boundary of the evaluation region is just above the top of the sub-grid-scale buffer layer. This result is consistent with modelled mean speed and resolved-scale shear stress profiles.     

On the similarity in atmospheric fluctuations of carbon dioxide,water vapor and temperature over vegetated fields

This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)^-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.     

The use of σ T as a temperature scale in the atmospheric surface layer

The standard deviation of temperature _T is proposed as a temperature scale and as a velocity scale to describe the behaviour of turbulent flows in the Atmospheric Surface Layer (ASL), instead of _* andu _* of the Monin—Obukhov similarity theory, and ofT _f andU _f used for free convection stability conditions. On the basis of experimental evidence reported in the literature, it is shown that _T T _f andv _* U _f in the free convection region, and _{T *} andv _* U _* in nearneutral and stable conditions. This implies that the proposed scales can be applied for all stabilities. Furthermore, a new length scale is proposed and its relation with Obukhov length is given. Also, a simple semi-empirical expression is presented with which _T andv _* can be evaluated in a rather simple way. Some examples of practical applications are given, e.g., a stability classification for unstable conditions.     

Occurrence of roll circulations in a shallow boundary layer

Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z _i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.     

The source area influencing a measurement in the Planetary Boundary Layer: The “footprint” and the “distribution of contact distance”

This paper considers the ground area which affects the properties of fluid parcels observed at a given spot in the Planetary Boundary Layer (PBL). We examine two source-area functions; the footprint, giving the source area for a measurement of vertical flux: and the distribution of contact distance, the distance since a particle observed aloft last made contact with the surface. We explain why the distribution of contact distance extends vastly farther upwind than the footprint, and suggest for the extent of the footprint the inequalities: % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqaqpepeea0xe9qqVa0l% b9peea0lb9Lq-JfrVkFHe9peea0dXdarVe0Fb9pgea0xa9W8qr0-vr% 0-viWZqaceaabiGaciaacaqabeaadaqaaqaaaOabaeqabaGaamyvam% aalaaabaGaamiAaaqaaiabeo8aZnaaBaaaleaacaWGxbaabeaakiaa% cIcacaWGObGaaiykaaaacqGH8aapcaWG4bGaeyipaWJaamyvaKazaa% iadaGabaqaamaaDaaajqwaacqaaiaadIgacaGGVaGabmOEayaacaGa% aiilaiaabccacaGGVbGaaiiDaiaacIgacaGGLbGaaiOCaiaacEhaca% GGPbGaai4CaiaacwgaaeaacaWGubWaaSbaaKazcaiabaGaamitaaqa% baqcKfaGaiaacIcacaWGObGaaiykaiaabYcacaqGGaGaaeiAaiaabc% cacaGGHbGaaiOyaiaac+gacaGG2bGaaiyzaiaabccacaGGZbGaaiyD% aiaackhacaGGMbGaaiyyaiaacogacaGGLbGaeyOeI0IaaiiBaiaacg% gacaGG5bGaaiyzaiaackhaaaaajqgaacGaay5EaaaakeaaaeaacaGG% 8bGaamyEaiaacYhacqGH8aapcqaHdpWCdaWgaaWcbaGaamODaaqaba% GccaGGOaGaamiAaiaacMcadaWcaaqaaiaadIhaaeaacaWGvbaaaaaa% aa!7877!\[\begin{array}{l} U\frac{h}{{\sigma _W (h)}} < x < U\left\{ {_{h/\dot z,{\rm{ }}otherwise}^{T_L (h){\rm{, h }}above{\rm{ }}surface - layer} } \right. \\ \\ |y| < \sigma _v (h)\frac{x}{U} \\ \end{array}\] where U is the mean streamwise (x) velocity, h is the observation height, _L is the Lagrangian timescale, _v and _w are the standard deviations of the cross-stream horizontal (y) and vertical (z) velocity fluctuations, and is the Lagrangian Similarity prediction for the rate of rise of the centre of gravity of a puff released at ground.Simple analytical solutions for the contact-time and the footprint are derived, by treating the PBL as consisting of two sub-layers. The contact-time solutions agree very well with the predictions of a Lagrangian stochastic model, which we adopt in the absence of measurements as our best estimate of reality, but the footprint solution offers no improvement over the above inequality.     

A Comparative Analysis of Transpiration and Bare Soil Evaporation

Transpiration E^v and bare soil evaporation E^b processes are comparatively analysed assuming homogeneous and inhomogeneous areal distributions of volumetric soil moisture content . For a homogeneous areal distribution of we use a deterministic model, while for inhomogeneous distributions a statistical-deterministic diagnostic surface energy balance model is applied. The areal variations of are simulated by Monte-Carlo runs assuming normal distributions of .The numerical experiments are performed for loam. In the experiments we used different parameterizations for vegetation and bare soil surface resistances and strong atmospheric forcing. According to the results theE^v()-^Eb() differences are great, especially in dry conditions. In spite of this, the available energy flux curves of vegetation A^v() and bare soil A^b() surfaces differ much less than the E^v() and ^Eb() curves. The results suggest that E^v is much more non-linearly related to environmental conditions than ^Eb. Both E^v and ^Eb depend on the distribution of , the wetness regime and the parameterization used. With the parameterizations, ^Eb showed greater variations than E^v. These results are valid when there are no advective effects or mesoscale circulation patterns and the stratification is unstable.     

The spectral velocity tensor for homogeneous boundary-layer turbulence

We have postulated a simple model for the spectral tensor _ij (k) of an anisotropic, but homogeneous turbulent velocity field. It is a simple generalization of the spectral tensor _inf ^{ij piso}(k) for isotropic turbulence and we show how in the limit of isotropy, _ij (k) becomes equal to _inf ^{ij piso}(k). Whereas _inf ^{ij piso}(k) is determined entirely by one scalar function of k = ¦k¦, namely the energy spectrum, we need three independent scalar functions of k to specify _ij (k). We show how it is possible by means of the three stream-wise velocity component spectra to determine the three scalar functions in _ij (k) by solving two uncoupled, ordinary linear differential equations of first and second order. The analytic form of the component spectra each has a set of three parameters: the variance and the integral length scale of the velocity component and a dimensionless parameter, which governs the curvature of the spectrum in the transition domain from the inertial subrange towards lower wave numbers. When the three sets of parameters are the same, the three spectra correspond to isotropic turbulence and they are all interrelated and related to the energy spectrum. We show how it is possible to obtain these spectral forms in the neutral surface layer and in the convective boundary layer from data reported in the literature. The spectral tensor is used to predict the lateral coherences for all three velocity components and these predictions are compared with coherences obtained in two experiments, one using three masts at a horizontally homogeneous site in Denmark and one employing two aircraft flying in formation over eastern Colorado. Comparison shows reasonable agreement although with considerable experimental scatter.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Scavenging Efficiency of ‘Aerosol Carbon’ and Sulfate in Supercooled Clouds at Mt. Sonnblick (3106 m a.s.l., Austria)

Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (_SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (_AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both _SO and _AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, _SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m³. In the case of aerosol carbon, we obtained a more gradual increase of _AC up to an LWC of 0.5 g/m³. At higher LWCs, _{_} remained relatively constant at 0.60. As the differences between _SO and _A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.     

Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2

The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O₂ of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O₂ versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(H_{decomposition}–H_{O 2 reaction}), between these two reactions pathways. For (H)[22–0.5(H_{O 2 reaction})], alkoxy radical decomposition dominates over the reaction with O₂ at room temperature and atmospheric pressure of air, while for (H)[25-0.5(H_{O 2 reaction})], the O₂ reaction dominates over decomposition (where the units of H are in kcal mol^–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.     

On the mean monthly equivalent potential temperature and rainfall in West Africa

Summary Rainfall in West Africa is examined in relation to monthly mean equivalent potential temperature ( _e )at the earth's surface. The study revealed that monthly mean equivalent potential temperature ( _e ) and monthly rainfall (R) generally decreased northwards from the equator.A good relationship existed betweenR and _e in the northern zone of West Africa (i.e., north of 7.5° N). No definite relationship existed in the southern zone. In the northern zone, the departure of _e from its annual mean ( ) first became positive about a month before the onset of the rains. Positive departures from ) generally resulted in more than normal (or average) rainfall in this zone. In general, little or no rainfall occurred in West Africa whenever _e was less than 320 K.

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Zusammenfassung Der Niederschlag (MonatssummeR) in Westafrika wird in Zusammenhang mit der mittleren monatlichen Äquivalent-temperatur ( _e ) an der Erdoberfläche untersucht. Es zeigte sich, daß die Monatswerte beider Elemente im allgemeinen vom Äquator nach Norden abnehmen.ZwischenR und _e ergab sich für das nördliche Westafrika (nördlich von 7.5° N) eine gute, für die südliche Zone jedoch keine beweisbare Übereinstimmung. In der nördlichen Zone übertraf _e das Jahresmittel erstmals etwa einen Monat vor Beginn der Regenzeit. Positive Abweichungen vom mittleren _e hatten immer übernormalen Niederschlag in dieser Zone zur Folge. Dagegen gab es wenig oder keinen Niederschlag in Westafrika, wenn _e unter 320 K lag.

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With 7 Figures     

Temperature distribution and current system in a convectively mixed lake

During spring and autumn, many lakes in temperate latitudes experience intensive convective mixing in the vertical, which leads to almost isothermal conditions with depth. Thus the regime of turbulence appears to be similar with that characteristic of convective boundary layers in the atmosphere. In the present paper a simple analytical approach, based on boundary-layer theory, is applied to convective conditions in lakes. The aims of the paper are firstly to analyze in detail the temperature distribution during these periods, and secondly to investigate the current system, created by the horizontal temperature gradient and wind action. For these purposes, simple analytical solutions for the current velocities are derived under the assumption of depth-constant temperatures. The density-induced current velocities are shown to be small, in the order of a few mm/sec. The analytical model of wind-driven currents is compared with field data. The solution is in good qualitative agreement with observed current velocities under the condition that the wind field is steady for a relatively long time and that residual effects from former wind events are negligible.The effect of the current system on an approximately depth-constant temperature distribution is then checked by using the obtained current velocity fields in the heat transfer equation and deriving an analytical solution for the corrected temperature field. These temperature corrections are shown to be small, which indicates that it is reasonable to describe the temperature distribution with vertical isotherms.Notation T temperature - t time - x, y, z cartesian coordinates - molecular viscosity - _h , _v horizontal and vertical turbulent viscosity - K _h ,K _v horizontal and vertical turbulent conductivity - Q heat flux through the water surface - D depth - u, v, w average current velocity components inx, y andz directions - f Coriolis parameter - p pressure - density - g gravity acceleration - a constant in the freshwater state equation - h _s deviation from the average water surface elevation - L _*,H _* length and depth scale - U _*,W _* horizontal and vertical velocity scale - T temperature difference scale - bottom slope - u _* friction velocity at the water surface - von Karman constant - L Monin-Obukhov length scale - buoyancy parameter - l turbulence length scale - C ₁,C ₂,C ₃ dimensionless constants in the expressions for the vertical turbulent viscosity - , dimensionless vertical coordinate and dimensionless local depth - angle between surface stress direction andx-axis - T _bx ,T _by bottom stress components - c bottom drag coefficient     

Short-Term Variability of Atmospheric DMS and Its Oxidation Products at Amsterdam Island during Summer Time

A one-month experiment was performed at Amsterdam Island in January 1998, to investigate the factors controlling the short-term variations of atmospheric dimethylsulfide (DMS) and its oxidation products in the mid-latitudes remote marine atmosphere. High mixing ratios of DMS, sulfur dioxide (SO₂) and dimethylsulfoxide (DMSO) have been observed during this experiment, with mean concentrations of 395 parts per trillion by volume (pptv) (standard deviation, = 285, n = 500), 114 pptv ( = 125, n = 12) and 3 pptv ( = 1.2, n = 167), respectively. Wind speed and direction were identified as the major factors controlling atmospheric DMS levels. Changes in air temperature/air masses origin were found to strongly influence the dimethylsulfoxide (DMSO)/DMS and SO₂/DMS molar ratios, in line with recent laboratory data. Methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO₄ ^2–) mean concentrations in aerosols during this experiment were 12.2± 6.5 pptv (1, n=47) and 59 ± 33 pptv (1, n=47), respectively. Evidence of vertical entrainment was reported following frontal passages, with injection of moisture-poor, ozone-rich air. High MSA/ nss-SO₄ ^2– molar ratios (mean 0.44) were calculated during these events. Finally following frontal passages, few spots in condensation nuclei (CN) concentration were also observed.     

Numerical integration errors in calculated tropospheric photodissociation rate coefficients

Tropospheric photodissociation rate coefficients (J values) were calculated for NO₂, O₃, HNO₂, CH₂O, and CH₃CHO using high spectral resolution (0.1 mm wavelength increments), and compared to the J values obtained with numerically degraded resolution (=1, 2, 4, 6, 8, and 10 nm, and several commonly used nonuniform grids). Depending on the molecule, substantial errors can be introduced by the larger increments. Thus for =10 nm, errors are less than 1% for NO₂, less than 2% for HNO₂, +6.5% to -16% for CH₂O, -6.9% to +24% for CH₃CHO, and -24% to +110% for O₃. The errors for CH₂O arise from the fine structure of its absorption spectrum, and are prevalently negative (underestimate of J). The errors for O₃, and to a lesser extent for CH₃CHO, arise mainly from under-resolving the overlap of the molecular action spectrum and the tropospheric actinic flux in the wavelength region of stratospheric ozone attenuation. The sign of those errors depends on whether the actinic flux is averaged onto the grid before or after the radiative transfer calculation. In all cases studied, grids with 2 nm produced errors no larger than 5%.     

Synchronous Scan and Excitation-Emission Matrix Fluorescence Spectroscopy of Water-Soluble Organic Compounds in Atmospheric Aerosols

Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (_Exc/_Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at _Exc/_Em240/405 nm and _Exc/_Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.     

Carbon dioxide and the δ18O record of late-Quaternary climatic change: a global model

A dynamical model for the late-Quaternary global variations of ¹⁸O, mean ocean surface tempeature , ice mass I, deep ocean temperature , and atmospheric carbon dioxide concentration , is constructed. This model consists of two diagnostic equations (for ¹⁸O and ), and three prognostic equations (for I, , and ) of a form studied extensively in previous articles. The carbon dioxide equation includes forcing by a representation of the Milankovitch earth-orbital radiation effects, and contains a basic instability that drives a free oscillation of period near 100,000 years. The system is constrained to conserve mass and energy, contain physically plausible feedbacks including a system time constant no greater than 10.000 years, and be robust (i. e., structurally stable in the presence of expected noise levels and uncertainties in values of coefficients). Within the limits of these constraints, coefficients are chosen such that (i) the solution gives a good fit to the observed SPECMAP ¹⁸O variations, and (ii) the ice mass variations are qualitatively similar to the ¹⁸O variations. The predicted long term variations of sea surface temperature and atmospheric carbon dioxide are in reasonably good agreement with the limited observational evidence available for these quantities, while the predicted variations of deep ocean temperature remain to be verified when paleoclimatic estimates of this quantity become available. The relative contributions of ice mass changes and surface water temperature changes to the variations of ¹⁸O at any time are given by the model.     

Effects of heat and water vapor transport on eddy covariance measurement of CO2 fluxes

Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO₂ concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO₂, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO₂. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= _cw for CO₂, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux _c w. Thus, when the net flux of CO₂ is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., _c w = – _c w. Corrections for the mean convective flux are particularly significant for CO₂ because _cw and _c w are often of similar magnitude. The correct measurement of the net CO₂ flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.     

Numerical studies of heat island circulations

A two dimensional model has been set up to investigate the circulation induced by an urban heat island in the absence of synoptic winds. The boundary conditions need to be formulated carefully and due to difficulties arising here, we restrict our attention to cases of initially stable thermal stratification. Heat island circulations are allowed to develop from rest and prior to the appearance of the final symmetric double cell pattern, a transitional multi-cell pattern is observed in some cases. The influence on the steady state circulation of various parameters is studied, among which are eddy transfer coefficients, the heat island intensity, the initial temperature stratification and the heat island size. Some results are presented for a case in which differential surface cooling beneath an initially stable atmosphere produces a circulation and an unstable layer capped by an elevated inversion over the city. It is hoped that this case is vaguely representative of the night-time heat island with no geostrophic wind.Notation c_p Specific heat at constant pressure - g Acceleration due to gravity - H Top of integration region - K_z Vertical eddy transfer coefficient - K_x, K_xH, K_xm Horizontal eddy transfer coefficients for heat and momentum - l ixing length - p Pressure - p₀ Reference surface pressure (1000 mb) - P_H (x, t) Pressure at z = H - R Specific gas constant for dry air - t Time - u, w Horizontal and vertical velocities - x, z Horizontal and vertical coordinates - x₁, x₂ Positions of discontinuities in surface temperature field (see Figure 2) - x_a Heat island half-width - x_b Boundary of integration region - Parameter in formula for eddy coefficients (variable-K case) = 18.0 - _s Intensity of heat island - Potential temperature field - Reference absolute temperature (variable-K case) - _r Reference temperature (° C) - _s Surface temperature - Q Air density     

The carbon isotopic ratio of atmospheric carbon dioxide at Tsukuba,Japan

To find out the secular and seasonal trends of the ¹³C value and CO₂ concentration in the surface air and the determination of the ¹³C in the atmospheric CO₂ collected at Tsukuba Science City was carried out during the period from July 1981 to October 1983. The monthly average of the ¹³C value of CO₂ in the surface air collected at 1400 LMT ranged from -7.52 to \s-8.45 with an average of -7.96±0.25 and the CO₂ concentration in the air varied from 334.5 l 1^-1 to 359 l 1^-1 with an average of 347.2±6.3 l 1^-1. The ¹³C value is high in summer and low in winter and is negatively correlated with the CO₂ concentration. In general, the relationship between the ¹³C and the CO₂ concentration is explainable by a simple mixing model of two different constant carbon isotopic species but the relationship does not always follow the model. The correlation between the ¹³C value and the CO₂ concentration is low during the plant growth season and high at other times. The observed negative deviation of the ¹³C value from the simple mixing model in the plant growth season is partly due to the isotopic fractionation process which takes place in the land biota.