“北祁连蛇绿岩及其构造背景野外研讨会”在甘肃举行

别鲁阿嘎希花岗闪长岩－石英闪长岩带与金矿化有十分密切的关系。锆石Ｕ－Ｐｂ法测得别鲁阿嘎希石英闪长岩年龄为３６９Ｍａ。斜长石环带成分振荡，与黑云母共生的角闪石成分显示为富镁。岩石地球化学特征表明，这些岩石为幔源的拉斑玄武岩岩浆和地壳部分熔融形成岩浆混合后的产物。     

西藏冈底斯带始新世曲水岩基的岩浆混合作用:来自斜长石阴极发光特征和成分变化的证据

斜长石作为主要造岩矿物,是研究岩石成因、示踪岩浆演化和岩浆混合过程的有效工具.对冈底斯带曲水岩基始新世花岗闪长岩、二长花岗岩、闪长岩脉和暗色包体中的斜长石进行了阴极发光图像结构特征、电子探针主量元素和LA-ICP-MS微量元素成分的分析,揭示了斜长石复杂环带的成因和相关的岩浆过程.该区斜长石的阴极发光图像呈现出多种颜色且与其An值相对应,随着An值降低依次为绿色、蓝色和暗灰色或暗红色等,并发育补丁状环带、筛状环带、韵律环带等.花岗闪长岩、二长花岗岩中斜长石的An值具有相似的变化范围(20~55),而闪长岩脉和暗色包体中An值的变化范围较大(25~85),表明曲水岩基经历了复杂的开放过程.微量元素结果表明:花岗闪长岩与闪长岩脉和暗色微粒包体具有相同的Sr含量范围(600×10^-6~1 100×10^-6);而二长花岗岩的Sr含量(1 000×10^-6~2 400×10^-6)整体高于前者.以上研究表明,花岗闪长岩中阴极发光呈现绿色的核部或幔部是偏中性岩浆注入寄主岩岩浆混合的结果;具有高Sr含量的二长花岗岩认为是高Sr含量的岩浆结晶形成的;闪长岩脉和暗色微粒包体中的筛状结构斜长石为寄主岩捕掳晶.     

河西堡花岗岩体中闪长质包体与岩浆混合作用

河西堡花岗岩体为阿拉善地块西南缘早古生代中酸性岩浆活动的产物，其中产出一些闪长岩，石英闪长岩甚至玄武岩的暗色包体，这些包体的岩相学特征间示它们是曾经与寄主花岗岩处于同一熔融状态的基性岩浆相分的结晶产物，矿物温压计估算的结果表明，包体与寄主岩的再平衡结晶温压条件十分接近，寄主花岗岩的岩石化学，稀土元素及锶同位素组成也表现出基性组分与酸性组分混合的特点，采用Ｃ＾混＝ＫＣ＾基＋（１－Ｋ）Ｃ＾酸混合定量模     

西准噶尔别鲁阿嘎希花岗闪长岩年代学、地球化学特征及岩石成因

为更深入了解西准噶尔晚古生代岩浆活动和构造背景,对位于西准噶尔中部的别鲁阿嘎希岩体开展了年代学、地球化学以及Sr-Nd同位素研究,讨论了岩石成因、源区性质和构造背景.别鲁阿嘎希花岗闪长岩为钙碱性系列岩石,岩浆锆石结晶年龄为318.7±3.3 Ma.其具相对高的MgO(Mg#=49~59)、Ni、Cr含量,富集大离子亲石元素(如K、Rb、Sr和Ba)、亏损高强场元素(如Nb、Ta、Ti),轻重稀土元素分异不明显.Sr-Nd同位素特征显示,其有较低的初始Sr比值(0.704 297~0.704 399),较高的ε_Nd(t)值(5.8~6.5).通过综合分析,认为在晚石炭世早期,达尔布特洋壳(板片)俯冲至地幔楔下部,俯冲洋壳板片脱水所产生的流体在上升过程中与地幔楔共同作用,底侵加热由亏损地幔形成不久的年轻地壳(由洋壳和岛弧组成),使其部分熔融形成了别鲁阿嘎希分异I型花岗岩.      

辽西新太古代钓鱼台花岗岩成因及演化过程:来自岩石组构的证据

辽西兴城钓鱼台地区分布一套花岗质杂岩,是新太古代"绥中花岗岩"的重要组成部分。花岗质杂岩以似斑状花岗闪长岩和石英闪长岩为主,少量细粒黑云闪长岩(包体)及脉状花岗岩,各类岩石接触关系明确,本文定义为"钓鱼台花岗岩"。锆石U-Pb同位素测试结果显示似斑状花岗闪长岩、石英闪长岩、脉状花岗岩的形成年龄分别为2538±20Ma、2476±56Ma、2470±18Ma,同为新太古代末期热事件的产物。通过该花岗岩组合的宏观-微观组构解析表明,似斑状花岗闪长岩表现为均匀块状构造,具有深熔花岗质岩浆的典型堆晶结构;细粒黑云闪长岩为细粒结构,呈小型暗色包体分布在似斑状花岗闪长岩中,包体的塑性变形、捕掳晶、淬冷边及反向脉等组构发育,具有铁镁质基性岩浆加入同深熔花岗闪长岩并快速冷却的特征;暗色的石英闪长岩主要分布在似斑状花岗闪长岩之下,接触带附近似斑状花岗闪长岩中的钾长石变斑晶明显增多,显示闪长质岩浆"底垫"侵位加热的特征;脉状花岗岩同时穿切似斑状花岗闪长岩和石英闪长岩,具有熔体富集脉体的结构特征。各类岩石中变形组构均不发育。钓鱼台花岗岩记录了新太古代末期地壳深熔和壳幔相互作用过程,岩石组构研究表明新太古代地壳再造作用是一个"静态"多期次的缓慢深熔过程,伴有同期幔源基性物质加入并混合,以及随后大规模的基性岩浆底侵。由此推断钓鱼台花岗岩形成的构造背景为幔源岩浆垂向底侵过程,可能是与俯冲带关联不明显的岩浆弧环境。     

北太行紫荆关基性岩体的成因: 岩石学和地球化学证据

通过对北太行紫荆关晚中生代基性岩体的岩石学和地球化学特征研究, 讨论其岩浆源区特征及成因.结果表明, 紫荆关岩体主要由橄榄二辉石岩、角闪辉长岩和闪长岩等岩石组成.橄榄二辉石岩具有明显的堆晶结构, 可能是堆晶成因, 而角闪辉长岩和闪长岩可能是堆晶形成之后的残余岩浆的结晶.闪长岩中的斜长石显示复杂的结构和成分环带, 相对富钠的核部见富钙斜长石叠加, 后者又向富钠斜长石演化.闪长岩中的单斜辉石也显示复杂的成分环带, 主要是最边部的MgO含量比紧邻的内侧辉石更高.这表明在闪长岩形成过程中有新的幔源高温富镁的岩浆注入.以上各岩石类型具有类似的地球化学性质, 包括较强的稀土分异((La/Yb)_N比值为5.76~23.13), 高Sr/Y比值(50.95~146.13), 富集K、Sr、Ba等大离子亲石元素和LREE, 亏损Nb、Zr、Ti等高场强元素和HREE, Eu异常不明显.都显示富集的Sr-Nd同位素特征, I_Sr=0.7058~0.7066, ε_Nd(t) =-13.8~-18.2.这些特征表明紫荆关基性岩体的母岩浆来源于EM1型富集地幔的部分熔融.橄榄辉石岩和角闪辉长岩具有类似的Nd同位素成分(主要为ε_Nd(t) =-15.0~-16.6), 但形成较晚的闪长岩的ε_Nd(t) 值却比较高(-13.8~-14.6), 也支持新的幔源岩浆在晚期的注入.      

花岗质岩浆起源和多次岩浆混合的标志：包体：—以北京周口店岩体为例

北京周口店岩株,主要由两次侵入的石英二长闪长岩和花岗闪长岩组成,其中包体广泛分布。在岩体南缘的关坻变质岩中,零星出露了一种块状的闪长质岩石。关坻闪长岩与主岩体同期侵入的岩浆结晶产物,角闪石质包体的形成是二长辉长岩浆结晶—再平衡的结果,富云包体系花岗闪长岩浆源区的耐熔残余。通过二长辉长岩与花岗闪长岩两种岩浆简单混合可形成细粒石英二长质包体,由二长辉长岩、关坻闪长岩和花岗闪长岩3种岩浆混合形成了微粒闪长质包体。主岩体的成分变异,也与岩浆混合有关。     

新疆尾亚矿区3期岩浆混合作用的初步研究

新疆东天山的尾亚钒钛磁铁矿矿区，发育3期岩浆混合作用。第一期为辉长质与花岗质岩浆混合．并生成闪长质岩石；第二期为闪长质与花岗质岩浆的混合，生成了石英二长质岩浆；第三期为石英二长岩浆与闪长质岩浆的混合。在各类岩石氧化物对SiO2的哈克图解上，尾亚3期岩浆混合岩石的投影点分别呈相关的线性关系。在稀土和微量元素方面，3期岩浆混合作用形成的岩石分别表现出相近的地球化学特征。配分曲线形态各自相似．形成的过渡岩石——岩浆混合岩类与各自的端元岩石具有继承关系。3期岩浆混合作用之间具有明显的继承性：第一期形成的岩浆混合岩，成分相当于闪长岩，与第二期岩浆混合的基性端元属同类岩石．且与第二期各类岩石具有相似的地球化学特征；第二期形成的石英二长闪长岩，与第三期的端元岩石石英二长斑岩体完全可以对比。尾亚地区的3期岩浆混合作用表明，混合作用可以是多阶段、多期次的，本区火成岩类最初的母岩浆是酸性的陆壳硅铝质和基性的幔源铁镁质岩浆。岩浆混合作用反映了本区壳幔相互作用的本质。     

措勤盆地冈底斯构造带侵入岩岩石地球化学特征及构造成因分析

冈底斯构造带为措勤盆地－主要Ⅱ级构造单元。该带中、新生代岩浆活动异常强烈，形成从中性闪长岩到酸性花岗岩完整的中酸性花岗岩侵入岩带。通过对侵入岩体的岩石类型、岩石化学特征、岩石地球化学特征研究，认为该岩浆岩带侵入岩体主要为花岗闪长岩、二长花岗岩、石英二长岩等，属钙碱性岩石系列，具“Ⅰ”型花岗岩的特征，是新特提斯洋壳沿雅鲁藏布江断裂带向北俯冲引起下地壳物质熔融向上侵入所致，为燕山晚期－喜山早期岩浆活动的产物。     

岩浆混合作用与火成岩多样性的耦合关系:以东昆仑造山带白日其利长英质岩体为例

壳-幔岩浆相互作用如何影响长英质火成岩的岩石学多样性是当前岩石学研究的焦点问题之一.以岩石类型丰富的东昆仑白日其利长英质岩体和暗色微粒包体为研究对象,开展系统的锆石U-Pb年代学、矿物学、全岩元素地球化学和Sr-Nd-Hf同位素研究,探讨和解析这一重要科学问题.LA-ICPMS锆石U-Pb年代学研究表明,暗色微粒包体（247.8±2.0 Ma）与二长花岗岩（247.5±1.4 Ma）、花岗闪长岩（248.8±2.1 Ma）和石英闪长岩（248.8±1.5 Ma）均侵位结晶于早三叠世.岩相学和矿物学研究表明,白日其利长英质岩石与包体的成因机制与壳-幔岩浆的机械或化学混合作用密切相关.元素地球化学和Sr-Nd-Hf同位素组成研究揭示,幔源镁铁质岩浆端元起源于受俯冲板片流体交代的富集地幔熔融,而壳源长英质岩浆端元则起源于东昆仑古老的变质杂砂岩基底.岩石成因分析揭示,幔源镁铁质岩浆侵入长英质晶粥岩浆房,促使长英质晶粥发生活化,随后壳-幔岩浆端元以不同比例和不同方式发生机械和化学混合等相互作用,从而形成镁铁质岩墙、包体、石英闪长岩和花岗闪长岩等多种岩石类型.晶粥状态下壳-幔岩浆相互作用是控制东昆仑长英质火成岩多样性和大陆地壳生长演化的重要方式.      

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).