太行山中段石湖金矿区石英闪长玢岩脉LA-ICP-MS锆石U-Pb年龄、地球化学特征及成矿意义

石湖金矿大地构造位置上位于华北克拉通太行山中段,与石英闪长玢岩脉存在密切的成因联系。通过对矿区内石英闪长玢岩脉锆石进行激光等离子体质谱LA-ICP-MS单颗粒锆石微区U-Pb同位素测年,获得了年龄为(130.5±1.4)Ma(MSWD=1.8,N=34),时代为早白垩世。该岩石具高硅、富碱、富铝等特征,属钙碱性系列,具有弱的Eu正异常,富集大离子亲石元素K、Cs、Rb等,亏损高场强元素和重稀土元素Nb、Ta、Zr、Hf、Y、Yb等。具有高Sr低Y、Yb的特征,以及较高的Sr/Y、(La/Yb)_N比值,具有类似于加厚下地壳部分熔融形成的埃达克质岩石特征,埃达克质岩石与金矿密切相关。因此,太行山中段埃达克质石英闪长玢岩脉与金矿具有重要成因联系。     

徐淮地区早白垩世丰山和蔡山高镁埃达克质岩:拆沉下地壳熔融的熔体与地幔橄榄岩的反应

徐淮地区丰山花岗闪长斑岩和蔡山石英闪长玢岩的岩石地球化学、Sr-Nd-Hf同位素和石榴石的矿物化学研究对探讨华北克拉通东南缘早白垩世高镁埃达克质岩的岩石成因和构造演化具有重要意义。结果表明,丰山花岗闪长斑岩和蔡山石英闪长玢岩具高SiO_2(60.98%～67.88%)、富Al_2O_3(14.37%～15.04%)以及高的Na_2O/K_2O比值(1.58～2.24)和Mg~#值(57～66)的特征;富集LILE(Rb、Ba、Sr)和LREE,亏损HFSE(Nb、Ta、Ti)和HREE,具有Pb正异常和弱的Eu异常;结合高的Sr含量(579×10~(-6)～778×10~(-6))以及Sr/Y(33～69)和(La/Yb)_N比值(8.63～13.7),低的Y(10.5×10~(-6)～17.8×10~(-6))和Yb含量(0.74×10~(-6)～1.17×10~(-6)),暗示它们属于高镁埃达克质岩。丰山和蔡山埃达克质岩石的初始~(87)Sr/~(86)Sr比值介于0.7079～0.7086之间,ε_(Nd)(t)值变化于-10.77～-7.18之间,t_(DM2)=1504～1793Ma;岩浆锆石的ε_(Hf)(t)值为-14.2～-5.3,t_(DM2)=2101～2898Ma。徐淮地区早白垩世利国、班井、夹沟高镁埃达克质岩石中岩浆锆石的ε_(Hf)(t)值分别介于-13.4～-7.0、-13.4～-7.9和-15.9～-4.5之间,它们的t_(DM2)分别变化于2248～2825Ma、2331～2824Ma和2030～3048Ma之间。徐淮地区丰山和蔡山高镁埃达克质岩的Sr-Nd-Hf同位素组成和丰山花岗闪长斑岩中铁铝榴石残留晶的存在,结合它们高的Pb同位素组成和继承锆石U-Pb年代学暗示,丰山和蔡山高镁埃达克质岩浆主要起源于俯冲断离的扬子克拉通石榴辉石岩相下地壳物质熔融的熔体与地幔橄榄岩的反应,同时有拆沉的华北克拉通基底物质的参与,形成于华北克拉通东部岩石圈减薄的伸展构造背景。     

鲁西临朐铁寨杂岩体锆石U-Pb年代学、地球化学特征及其地质意义

鲁西临朐铁寨杂岩体主要由石英二长玢岩和石英二长斑岩组成。为了精确厘定杂岩体的成岩时代和地球化学特征,对石英二长玢岩和石英二长斑岩进行了锆石U-Pb定年、全岩地球化学研究。结果表明,石英二长玢岩的锆石U-Pb年龄为(129.0±1.7) Ma,其含有的继承锆石年龄为(2 520±30) Ma;石英二长斑岩的锆石年龄为(125.0±1.6) Ma。两种侵入岩均具有富硅、富碱和低钙镁的特征,石英二长玢岩比石英二长斑岩的Mg^#值高;稀土总量较低,轻重稀土分馏明显,Eu基本无异常;Sr、Ba含量高,Nb、Ta和Ti等高场强元素负异常。岩石地球化学特征表明:鲁西铁寨杂岩体来源为富集地幔部分熔融、同化混染了部分古老的地壳物质,两种岩性的Mg^#值差异是磁铁矿分离结晶的结果。早白垩世滞留在地幔过渡带的太平洋板片脱水是岩石圈减薄的诱因,期间产生大量的岩浆岩,表明早白垩世是华北克拉通岩石圈减薄的峰期。     

华北克拉通中部早白垩世岩石圈地幔性质：来自狐偃山科头钾质正长岩年代学、同位素的限制

华北克拉通东部中生代岩石圈减薄已经取得了大量进展,相比之下对克拉通中部岩石圈演化认识不足。本文对华北克拉通中部狐偃山杂岩体中科头正长岩进行了锆石U-Pb年代学、主量和微量元素、Sr-Nd-Hf同位素地球化学研究。LA-ICP-MS锆石U-Pb定年结果显示,科头正长岩侵位于早白垩世晚期(～111Ma)。岩石样品均为钾质—超钾质,属于碱性系列岩石。这些岩石相对富集轻稀土,亏损重稀土和中稀土,具有明显的正Eu异常(Eu/Eu~*=1.22～1.96)、富集大离子亲石元素LILE(Rb、Sr、Ba),亏损高场强元素HFSE(Nb、Ta、Ti)。所有岩石样品具有相对高的初始~(87)Sr/~(86)Sr比值(0.7058～0.7062)和低的ε_(Nd)(t)(-10.4～—11.1),ε_(Hf)(t)介于—12.2～—5.2之间。详细的元素和同位素地球化学研究表明科头正长岩的原始岩浆可能来源于富集岩石圈地幔中富金云母的尖晶石二辉橄榄岩源区的部分熔融,岩浆演化过程中经历了地壳混染与结晶分异(AFC)过程。结合华北克拉通中部岩浆资料,将华北克拉通中部早白垩世岩浆作用分为早晚两期:早期(123～135Ma)为岩浆作用高峰期,晚期(～114Ma)为最后一期弱的岩浆期;华北克拉通中部陆下岩石圈地幔是富集的、不均一的,其至少在早白垩世(138～111Ma)一直处于减薄状态。     

河南舞阳南部张士英岩体的地球化学与成因及其构造意义

张士英岩体岩石类型以石英二长岩、石英正长岩为主。岩体属于准铝质的高钾-钾玄岩系列(Al2O3为14.8%～16.7%,A/CNK=0.77～1.02,K2O/Na2O在1.00～1.43之间),稀土元素总量在261.7～381.0μg/g之间,轻稀土元素相对富集,稀土元素球粒陨石标准化模式呈右倾平滑曲线,(La/Yb)N比值为28～50,具有轻微的Eu负异常,Eu/Eu?比值在0.73～0.87之间。微量元素组成上表现为Sr、Ba、Nb、Ta的亏损,而Th、U相对富集。(87Sr/86Sr)i初始平均值为0.709,εNd(t)值为-13.9～-19.9,Nd的模式年龄为1.48～2.10Ga。岩体锆石LA-ICP-MSU-Pb年龄为(124.2±0.5)Ma,为早白垩世岩浆作用的产物。岩体侵位的区域地质背景为华北克拉通白垩纪大规模岩石圈转型和减薄时期,岩石的微量元素及同位素特征表明,岩体主要来源于下地壳物质的部分熔融,但有年轻地幔物质的加入。反映在区域强烈伸展拉张和岩石圈减薄背景下,软流圈地幔岩浆底侵所造成的下地壳部分熔融及壳幔混合过程。     

胶莱盆地晚白垩世玄武岩的年代学和地球化学特征及其对华北岩石圈减薄-增生的制约

已有研究认为华北岩石圈减薄的时空不均一是显著的,主要表现在软流圈来源的岩浆最早出现的时间呈现南北差异。本文通过40Ar-39Ar法获得胶莱盆地西官庄拉斑玄武岩的年龄为96±3Ma,属于青山群火山岩的一部分,早于王氏群大西庄碱性玄武岩(73Ma)。两套岩石均缺乏Nb、Ta负异常,分别具有与E-MORB和OIB类似的微量元素配分特征。西官庄拉斑玄武岩((87Sr/86Sr)t=0.7058,εNd(t)=0.37～0.57)和大西庄碱性玄武岩((87Sr/86Sr)t=0.7040,εNd(t)=5.5～5.7)的同位素组成特征均显示软流圈的印记。前者为软流圈熔体与古老富集岩石圈地幔相互反应的产物,而后者是软流圈部分熔融的产物。研究区岩浆的εNd(t)值随年龄的降低而逐渐增大,暗示古老岩石圈减薄过程中软流圈的上涌,说明研究区晚白垩世-早新生代岩石圈仍在经历减薄作用。类似的岩浆演化趋势在辽西和辽东地区也有发现,不过演化的时间分别为120～100Ma和80～60Ma,再次证明华北岩石圈减薄作用的时空不均一性。     

安徽黄梅尖地区基性脉岩年代学和地球化学特征

对庐枞盆地黄梅尖岩体内发育的辉绿玢岩开展了K-Ar法定年和系统的岩石地球化学特征研究。研究表明,辉绿玢岩形成年龄为107Ma±,属于晚白垩世产物。岩石出现2种辉石(单斜辉石和斜方辉石),w(SiO_2)介于51.93%～58.87%之间,具有富碱、高钾、贫钛等特征,岩石富集LREE、大离子亲石元素和强不相容元素,无Eu亏损现象,显示出洋岛玄武岩(OIB)相似的稀土元素和微量元素配分曲线。锶同位素初始值(I_(Sr))介于0.70575～0.70588,DSr值介于57.46～58.80,(~(143)Nd/~(144)Nd)_i介于0.512124～0.512188,εNd(t)值范围为-6.1～-7.3。我们认为黄梅尖辉绿玢岩属钾玄岩,其源区性质表现出富集地幔(EMI型)特征,庐枞盆地岩浆作用形成和演化与扬子陆块-华北陆块间陆陆碰撞后的伸展环境及软流圈物质上涌导致富集地幔部分熔融有关。黄梅尖钾玄岩限定了岩石圈减薄的时限,推测岩石圈减薄动力学演化过程可能对热液型铀成矿有重要的制约作用。     

吉林南部晚三叠世蚂蚁河岩体的成因:锆石U-Pb年代学和地球化学证据

蚂蚁河岩体主要由辉长闪长岩-花岗闪长岩-二长花岗岩构成。辉长闪长岩和二长花岗岩中的锆石呈自形晶,发育细微振荡生长环带,显示高的Th/U值(0.14～2.56),表明了锆石的岩浆成因。锆石LA-ICP-MSU-Pb定年结果表明,辉长闪长岩中锆石206Pb/238U年龄集中于219～227Ma,其加权平均年龄为(224±4)Ma(n=8);二长花岗岩中锆石年龄为217～241Ma,206Pb/238U加权平均年龄为(226±3)Ma(n=19)。岩石地球化学分析结果表明,蚂蚁河岩体具有双峰式岩石组合特征,辉长闪长岩具有较低的SiO2,较高的TiO2、MgO和CaO,以及富集大离子亲石元素(LILEs)和轻稀土元素(LREEs),亏损高场强元素(HFSEs)特征,其87Sr/86Sr初始值和εNd(t)值分别为0.7037和3.45～3.82。上述特征暗示岩浆起源于亏损岩石圈地幔;相反,花岗闪长岩和二长花岗岩具有较高的SiO2,较低的TiO2、MgO和CaO,以及强烈富集Rb、Th、U,亏损Nb、Ta、P、Ti、Ba、Sr的地球化学属性,其87Sr/86Sr初始值和εNd(t)值分别为0.7053～0.7058和-0.73～-3.40,暗示了岩浆的壳源成因。蚂蚁河岩体双峰式岩石组合的存在反映了伸展的构造背景,结合区域构造研究成果,其成因应与扬子和华北克拉通之间俯冲碰撞后的伸展环境有关,华北克拉通东部中生代岩石圈减薄或破坏始于晚三叠世,减薄或破坏空间范围应包括吉南地区。     

鲁西沂南铜井闪长质岩体锆石U-Pb年龄、元素及同位素地球化学特征

对鲁西沂南铜井岩体的中生代闪长玢岩进行了主量元素、微量及稀土元素、Sr-Nd-Pb同位素以及锆石U-Pb年龄、Hf同位素研究,结果表明,铜井闪长玢岩SiO2含量为54.68%～63.01%,富Na,Na2O/K2O为0.93～4.46,Mg#较高,为55～66,为中钾-高钾钙碱性系列,TiO2含量较低,0.2%～0.71%。样品具有显著的LREE富集[(La/Yb)n=10～15]以及高场强元素Nb、Ta和Ti的负异常,Eu基本无异常,Sr、Ba含量高(分别为241×10-6～711×10-6和554×10-6～822×10-6)的特征。ISr和εNd(t)值分别为0.706473～0.708867和-15.13～-9.18,与鲁西方城玄武岩和前人所研究的沂南辉长岩结果有所差异,显示其源区具有多端员混合特征,除了富集岩石圈地幔外,亏损地幔和地壳物质的贡献也很重要,Pb同位素也显示其源区有扬子克拉通物质的贡献,佐证了华北克拉通中生代富集岩石圈地幔的形成与扬子克拉通的俯冲有关。闪长岩中锆石具有典型的岩浆锆石特征,U-Pb年龄为128～129Ma,锆石εHf(t)值主要在-13～-8(平均值为-10.3)范围内,暗示了岩浆来源于富集岩石圈地幔,但受到亏损地幔物质的混染。沂南铜井闪长玢岩岩浆源区的多元性以及亏损地幔物质参与程度的逐渐增强,说明该地区中生代岩石圈减薄已达到最大,岩浆源区的差异可能也是该地区与胶东地区成矿性差异的主要原因之一。     

华北克拉通东部中生代岩石圈减薄的过程与机制:中生代火成岩和深源捕虏体证据

基于最新的同位素年代学资料 ,华北克拉通东部中生代的岩浆作用可划分成四个阶段 ,即晚三叠世 ( 2 0 5～ 2 2 5Ma)碱性岩浆作用 ;中晚侏罗世 ( 1 5 5～ 1 6 0Ma)花岗质岩浆作用 ;早白垩世 ( 1 1 2～ 1 32Ma)双峰式岩浆作用和晚白垩世 ( 92～ 73Ma)碱性玄武质岩浆作用。徐淮地区中生代侵入岩中榴辉岩捕虏体的发现及其地质年代学资料 ( 2 1 9Ma)表明 ,华北克拉通东部中生代早期曾发生过一次重要的陆壳加厚过程。俯冲板片的断离以及高压—超高压变质岩的快速折返和晚三叠世 ( 2 0 5～ 2 2 5Ma)的碱性岩浆作用的存在均暗示 ,华北克拉通中生代岩石圈减薄已经开始。拆沉作用则是引起中生代早期岩石圈减薄的主要机制。中、晚侏罗世 ( 1 5 5～ 1 6 0Ma)花岗质岩浆作用形成于造山期后的伸展环境 ,代表了中生代岩石圈减薄的继续和发展。早白垩世 ( 1 1 2～ 1 32Ma)双峰式岩浆作用表明中生代岩石圈减薄达到了峰期。而幔源纯橄岩捕虏体中富硅质熔体的交代作用和玄武岩的高87Sr/ 86Sr值、低ε(Nd ,t)值特征表明 ,软流圈对岩石圈底部的化学侵蚀可能是导致该阶段岩石圈减薄的主导机制。晚白垩世 ( 92～ 73Ma)碱性玄武质岩浆作用和“海洋型”地幔捕虏体的存在代表了等温面的下降和岩石圈地幔的增生     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

正~~     

GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)