Diagenetic haematite and sulfate assemblages in Valles Marineris

Previous orbital mapping of crystalline gray haematite, ferric oxides, and sulfates has shown an association of this mineralogy with light-toned, layered deposits on the floor of Valles Marineris, in chaos terrains in the canyon’s outflow channels, and in Meridiani Planum. The exact nature of the relationship between ferric oxides and sulfates within Valles Marineris is uncertain. The Observatoire pour la Mineralogie, l’Eau, les Glaces et l’Activite (OMEGA) spectrometer initially identified sulfate and ferric oxides in the layered deposits of Valles Marineris. The Thermal Emission Spectrometer (TES) has also mapped coarse (gray) haematite in or at the base of these deposits. We use Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) spectra and Context Camera (CTX) and High Resolution Imaging Science Experiment (HiRISE) imagery from the Mars Reconnaissance Orbiter (MRO) to explore the mineralogy and morphology of the large layered deposit in central Capri Chasma, part of the Valles Marineris canyon system that has large, clear exposures of sulfate and haematite. We find kieserite (MgSO₄·H₂O) and ferric oxide (often crystalline red haematite) in the lower bedrock exposures and a polyhydrated sulfate without ferric oxides in the upper bedrock. This stratigraphy is duplicated in many other basinal chasmata, suggesting a common genesis. We propose the haematite and monohydrated sulfate formed by diagenetic alteration of a sulfate-rich sedimentary deposit, where the upper polyhydrated sulfate-rich, haematite-poor layers either were not buried sufficiently to convert to a monohydrated sulfate or were part of a later depositional phase. Based on the similarities between the Valles Marineris assemblages and the sulfate and haematite-rich deposits of Meridiani Planum, we hypothesize a common evaporite and diagenetic formation process for the Meridiani Planum sediments and the sulfate-bearing basinal Interior Layered Deposits.     

The nature of coarse-grained crystalline hematite and its implications for the early environment of Mars

The Thermal Emission Spectrometer (TES) on the Mars Global Surveyor spacecraft has detected deposits of coarse-grained, gray crystalline hematite in Sinus Meridiani, Aram Chaos, and Vallis Marineris. We argue that the key to the origin of gray hematite is that it requires crystallization at temperatures in excess of about 100 °C. We discuss thermal crystallization (1) as diagenesis at a depth of a few kilometers of sediments originally formed in low-temperature waters, or (2) as precipitation from hydrothermal solution. In Aram Chaos, a combination of TES data, Mars Orbiter Camera images, and Mars Orbiter Laser Altimeter (MOLA) topography suggests that high concentrations of hematite were formed in planar strata and have since been exposed by erosion of an overlying light-toned, caprock. Lesser concentrations of hematite are found adjacent to these strata at lower elevations, which we interpret as perhaps due to accumulation from physical weathering. The topography and the collapsed nature of the chaotic terrain favor a hydrothermally charged aquifer as the original setting where the hematite formed. Concentration of iron into such an ore-like body would be chemically favored by saline, Cl-rich hydrothermal fluids. An alternative sedimentary origin requires post-depositional burial to a depth of ∼3-5 km to induce thermally driven recrystallization of fine-grained iron oxides to coarse-grained hematite. This depth of burial and re-exposure is difficult to reconcile with commonly inferred martian geological processes. However, shallow burial accompanied by post-burial hydrothermal activity remains plausible. When the hematite regions originally formed, redox balance requires that much hydrogen must have been evolved to complement the extensive oxidation. Finally, we suggest that the coexistence of several factors required to form the gray hematite deposits would have produced a favorable environment for primitive life on early Mars, if it ever existed. These factors include liquid water, abundant electron donors in the form of H₂, and abundant electron acceptors in the form of Fe³⁺.     

Geological features indicative of processes related to the hematite formation in Meridiani Planum and Aram Chaos, Mars: a comparison with diagenetic hematite deposits in southern Utah, USA

In order to understand the formation of the few but large, hematite deposits on Mars, comparisons are often made with terrestrial hematite occurrences. In southern Utah, hematite concretions have formed within continental sandstones and are exposed as extensive weathered-out beds. The hematite deposits are linked to geological and geomorphological features such as knobs, buttes, bleached beds, fractures and rings. These terrestrial features are visible in aerial and satellite images, which enables a comparison with similar features occurring extensively in the martian hematite-rich areas. The combination of processes involved in the movement and precipitation of iron in southern Utah can provide new insights in the context of the hematite formation on Mars. Here we present a mapping of the analogue geological and geomorphological features in parts of Meridiani Planum and Aram Chaos. Based on mapping comparisons with the Utah occurrences, we present models for the formation of the martian analogues, as well as a model for iron transport and precipitation on Mars. Following the Utah model, high albedo layers and rings in the mapped area on Mars are due to removal or lack of iron, and precipitation of secondary diagenetic minerals as fluids moved up along fractures and permeable materials. Hematite was precipitated intraformationally where the fluid transporting the reduced iron met oxidizing conditions. Our study shows that certain geological/geomorphological features can be linked to the hematite formation on Mars and that pH differences could suffice for the transport of the iron from an orthopyroxene volcanoclastic source rock. The presence of organic compounds can enhance the iron mobilization and precipitation processes. Continued studies will focus on possible influence of biological activity and/or methane in the formation of the hematite concretions in Utah and on Mars.     

Mars Reconnaissance Orbiter observations of light-toned layered deposits and associated fluvial landforms on the plateaus adjacent to Valles Marineris

We have used data from the Mars Reconnaissance Orbiter to study 30-80 m thick light-toned layered deposits on the plateaus adjacent to Valles Marineris at five locations: (1) south of Ius Chasma, (2) south of western Melas Chasma, (3) south of western Candor Chasma, (4) west of Juventae Chasma, and (5) west of Ganges Chasma. The beds within these deposits have unique variations in brightness, color, mineralogy, and erosional properties that are not typically observed in light-toned layered deposits within Valles Marineris or many other equatorial areas on Mars. Reflectance spectra indicate these deposits contain opaline silica and Fe-sulfates, consistent with low-temperature, acidic aqueous alteration of basaltic materials. We have found valley or channel systems associated with the layered deposits at all five locations, and the volcanic plains adjacent to Juventae, Ius, and Ganges exhibit inverted channels composed of light-toned beds. Valleys, channels, and light-toned layering along the walls of Juventae and Melas Chasmata are most likely coeval to the aqueous activity that affected the adjacent plateaus and indicate some hydrological activity occurred after formation of the chasmata. Although the source of water and sediment remains uncertain, the strong correlation between fluvial landforms and light-toned layered deposits argues for sustained precipitation, surface runoff, and fluvial deposition occurring during the Hesperian on the plateaus adjacent to Valles Marineris and along portions of chasmata walls.     

Ages of Valles Marineris (Mars) landslides and implications for canyon history

The chronology of landslides of Valles Marineris, the equatorial trough system of Mars, has been investigated by a crater population study. Valles Marineris landslides have widespread debris aprons which offer a remarkable opportunity to study the crater population with high resolution images from Mars Orbiter Camera (MOC) and from Mars Odyssey Thermal Emission Imaging System (THEMIS). Sixty-six ages were determined within Valles Marineris including 56 landslide ages and 10 ages of the canyon floor. Results reveal that landslides of Valles Marineris system of canyons occurred during a widespread period of time between 3.5 Gy and 50 My. In some locations, the canyon floor has an apparent age of 3.5 Gy suggesting that at least locally within Valles Marineris no major refreshing processes have occurred for 3.5 Gy. The temporal repetitivity of landslides implies that the triggering mechanisms of the landslides are reproducible in time. Landslides have the same features whatever their age. The dynamic of these landslides is probably the same either with intervention of water up to recently (the last 100 My) or without water since 3.5 Gy.     

Landslides in Valles Marineris (Mars): A possible role of basal lubrication by sub-surface ice

There is much interest on the occurrence of water and ice in the past history of Mars. Because landslides on Mars are much better conserved than their terrestrial counterparts, a physical examination and morphological analysis can reveal significant details on the depositional environment at the instant of failure. A study of the landslides in Valles Marineris based on their physical aspect is presented and the velocity of the landslides is calculated with a stretching block model. The results show that the landslides were subject to strong basal lubrication that made them travel at high speed and to long distances. We use physical analysis to explore the four alternative possibilities that the natural lubricant of the landslides in Valles Marineris was either ice, deep water, a shallow carpet of water, or evaporites. Examination of the furrows present on the surface of the landslide deposits shows that either sub-surface ice or evaporites were likely present on the floor of Valles Marineris during the mass failures.     

Fresnel modeling of hematite crystal surfaces and application to martian hematite spherules

The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm⁻¹ feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm⁻¹ feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.     

Mars: Evidence for dynamic processes from mariners 6 and 7

Mariners 6 and 7 photographs of the equatorial region of Mars document a three-stage evolution of that part of the Martian surface: (1) High- and intermediate-albedo cratered terrains in Meridiani Sinus, Margaritifer Sinus-Thymiamata, Deucalionis Regio-Sabaeus Sinus, and Hellespontus; (2) low-albedo moderately cratered terrain and dark crater fill in Meridiani Sinus, Thymiamata, and Deucalionis Regio-Sabaeus Sinus and possible volcanism in the Hellas-Hellespontus border; and (3) high-albedo surficial deposits, banked-up crater fill, a possible bright-ray crater in Meridiani Sinus, chaotic terrain on the edge of the Margaritifer Sinus mesa, featureless terrain in Hellas and Edom, sinuous channel-like reentrants on scarps at the Hellas-Hellespontus boundary. Regional faulting seems to have occurred following formation of the old cratered plains and prior to formation of low-albedo plains in Meridiani Sinus and also prior to formation of canyon-like reentrants and featureless terrain along the Hellas-Hellespontus boundary.Mars has had a complex history of dynamic evolution, possibly analogous to the more stable regions of Earth. Its geochemical differentiation and thermal regime should account for long-term postaccretional tectonic and volcano-tectonic processes as well as for fluid media on its surface sufficient to cause erosion, including the cutting of large canyons.     

New insights into the mineralogy and weathering of the Meridiani Planum meteorite,Mars

Meridiani Planum is the first officially recognized meteorite find on the surface of Mars. It was discovered at and named after the landing site of the Mars Exploration Rover Opportunity. Based on its composition, it was classified as a IAB complex iron meteorite. Mössbauer spectra obtained by Opportunity are dominated by kamacite (α‐Fe‐Ni) and exhibit a small contribution of ferric oxide. Several small features in the spectra have been neglected to date. To shed more light on these features, five iron meteorite specimens were investigated as analogs to Meridiani Planum with a laboratory Mössbauer setup. Measurements were performed on (1) their metallic bulk, (2) troilite (FeS) inclusions, (3) cohenite ((Fe,Ni,Co)₃C) and schreibersite ((Fe,Ni)₃P), and (4) corroded rims. In addition to these room‐temperature measurements, a specimen from the Mundrabilla IAB‐ungrouped meteorite was measured at Mars‐equivalent temperatures. Based on these measurements, the features in Meridiani Planum spectra can be explained with the presence of small amounts of schreibersite and/or cohenite and iron oxides. The iron oxides can be attributed to a previously reported coating on Meridiani Planum. Their presence indicates weathering through the interaction of the meteorite with small amounts of water.     

Radar altimetry of South Tharsis,Mars

Martian altitudes were measured by radar during the oppositions of 1971 and 1963 using the 64-m antenna at Goldstone (California). The resultant topographic profiles substantiate a zonal classification of the volcanic flows blanketing the south flanks of Arsia Mons, and they confirm the existence of a secondary, parasitic shield attached from the SSW to the main Arsia shield. The secondary shield is about 400 km in diameter at its base and at least 4 km high at its center. South of Valles Marineris, the Tharsis plateau is bounded by the approximate longitudes of 80° in the east and 140° in the west. In the Sinai Planum, closely adjacent to Coprates Chasma, another rise has been detected, bounded by longitudes of 55° in the east and 80° in the west. A volcanic shield of diameter 80 km, capped with a 22 km caldera has been identified near the crest of the rise. Topographic highs of about 1 km are associated with heavily faulted tracts such as Claritas Fossae. The distribution and orientation of the lunar-mare-like ridges in Sinai Planum appear to be independent of the regional gradients. Segments of the chaotic terrain at the eastern terminus of Valles Marineris are located as much as 6 km below the level of the surrounding plains.     

Layering stratigraphy of eastern Coprates and northern Capri Chasmata, Mars

Distinct competent layers are observed in the slopes of eastern Coprates Chasma, part of the Valles Marineris system on Mars. Our observations indicate that the stratigraphy of Coprates Chasma consists of alternating thin strong layers and thicker sequences of relatively weak layers. The strong, competent layers maintain steeper slopes and play a major role in controlling the overall shape and geomorphology of the chasmata slopes. The topmost competent layer in this area is well preserved and easy to identify in outcrops on the northern rim of Coprates Chasma less than 100 m below the southern Ophir Planum surface. The volume of the topmost emplaced layer is at least 70 km³ and may be greater than 2100 km³ if the unit underlies most of Ophir Planum. The broad extent of this layer allows us to measure elevation offsets within the north rim of the chasma and in a freestanding massif within Coprates Chasma where the layer is also observed. Rim outcrop morphology and elevation differences between Ophir and Aurorae Plana may be indicative of the easternmost extent of the topmost competent layer. These observations allow an insight into the depositional processes that formed the stratigraphic stack into which this portion of the Valles Marineris is carved, and they present a picture of some of the last volcanic activity in this area. Furthermore, the elevation offsets within the layer are evidence of significant subsidence of the massif and surrounding material.     

Evidence for Amazonian acidic liquid water on Mars—A reinterpretation of MER mission results

The Mars Exploration Rover (MER) missions have confirmed aqueous activity on Mars. Here we review the analyses of the field-based MER data, and conclude that some weathering processes in Meridiani Planum and Gusev crater are better explained by late diagenetic water-rock interactions than by early diagenesis only. At Meridiani, the discovery of jarosite by MER-1 Opportunity indicates acidic aqueous activity, evaporation, and desiccation of rock materials. MER-based information, placed into the context of published data, point to local and limited aqueous activity during geologically recent times in Meridiani. Pre-Amazonian environmental changes (including important variations in the near-surface groundwater reservoirs, impact cratering, and global dust storms and other pervasive wind-related erosion) are too extreme for pulverulent jarosite to survive over extended time periods, and therefore we argue instead that jarosite deposits must have formed in a climatically more stable period. Any deposits of pre-existent concretionary jarosite surviving up to the Amazonian would not have reached completion in the highly saline and acidic brines occurring at Meridiani. MER-2 Spirit has also revealed evidence for local and limited Amazonian aqueous environmental conditions in Gusev crater, including chemical weathering leading to goethite and hematite precipitation, rock layering, and chemical enhancement of Cl, S, Br, and oxidized iron in rocks and soils. The estimated relative age of the impact crater materials in Gusev indicates that these processes have taken place during the last 2 billion years. We conclude that minor amounts of shallow acidic liquid water have been present on the surface of Mars at local scales during the Amazonian Period.     

Related Magma-Ice Interactions: Possible Origins of Chasmata, Chaos, and Surface Materials in Xanthe, Margaritifer, and Meridiani Terrae, Mars

We examine here the close spatial and temporal associations among several unique features of Xanthe and Margaritifer Terrae, specifically the Valles Marineris troughs or chasmata and their interior deposits, chaotic terrain, the circum-Chryse outflow channels, and the subdued cratered material that covers Xanthe, Margaritifer, and Meridiani Terrae. Though previous hypotheses have attempted to explain the origin of individual features or subsets of these, we suggest that they may all be related. All of these features taken together present a consistent scenario that includes the processes of sub-ice volcanism and other magma/ice interactions, results of intrusive events during Late Noachian to Early Amazonian times.     

Martian landslides in Valles Marineris: Wet or dry?

The objective of this paper is to determine whether martian landslides in Valles Marineris were wet or dry and place constraints on the availability of liquid water in Valles Marineris during the Amazonian, when the landslides occurred. We, thus, statistically compare the power-law relationship between the volume and runout distance of landslides on Earth with those in Valles Marineris, Mars. The exponent of the power-law for martian landslides is similar to that for dry landslides and volcanic flows on Earth, and differs significantly from wet debris flows on Earth. The constant of proportionality in the observed power-law relationship for martian flows is linearly proportional to gravity, as predicted from physical modeling of dry flows in which the dissipation occurs in a layer of uniform thickness. Conversion of gravitational potential energy to heat is insufficient to generate more than a few weight percent of liquid water in the landslide. We thus conclude that water did not significantly influence the dynamics of landslides in Valles Marineris. This implies predominantly dry conditions in Valles Marineris during the Amazonian.     

Formation of an Hesperian-aged sedimentary basin containing phyllosilicates in Coprates Catena,Mars

The extensive light-toned deposits in canyons and troughs in Valles Marineris provide evidence of formation through water-related processes. As such, these deposits offer a window to past conditions on Mars. We study a small outcrop of light-toned deposits in a closed trough in Coprates Catena, a chain of collapse pits to the south-east of the main Valles Marineris system. A well-exposed sequence of deposits on the base of the north wall of the trough offers a 220 m section for geochemical and morphologic analysis. Using CRISM data we identify the presence of both phyllosilicates and sulfates and/or opaline silica in the light toned deposits, which vary in relative strength with elevation. We observe a trend in the dominant mineralogical signal, with Al phyllosilicates occurring near the base of the deposits, both below and above a band of Fe/Mg phyllosilicates, before a transition to more sulfate- or opaline silica-rich material near the top of the section. This trend likely reflects a change in the chemistry of the water in which the deposits formed. Using a HiRISE Digital Elevation Model, we find that the layers in the light-toned deposits on both sides of the trough dip gently towards the center of the trough, with a dip direction that aligns with the strike of the trough, suggesting that the light-toned deposits formed after the trough. Our general morphologic and mineralogical observations fit well with significant amounts of water in the trough. The deposits are too small to be dated using crater counting techniques, however, our crater analysis suggests that the plains in which the trough formed are probably Late Hesperian in age. If the chemistry of the light-toned deposits reflects the primary depositional mineralogy, then this and other small troughs in Coprates Catena might provide evidence of limited phyllosilicate formation in this region towards the end of the Hesperian era on Mars.     

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.     

Morphology and geology of the ILD in Capri/Eos Chasma (Mars) from visible and infrared data

Layered deposits have been observed in different locations at the surface of Mars, as crater floors and canyons systems. Their high interest relies in the fact they imply dynamical conditions in their deposition medium. Indeed, in opposition to most of the rocks of the martian surface, which have a volcanic origin, bright layered deposits seems to be sedimentary outcrops.Capri Chasma, a canyon located at the outlet of Valles Marineris, exhibits such deposits called Interior Layered Deposits (ILD). A large array of visible and infrared spacecraft data were used to build a Geographic Information System (GIS). We added HiRiSE images, from the recent MRO mission, which offer a spatial resolution of 25 cm per pixel. It allowed the mapping and the analysis of morphologies in the canyon. We highlighted that the ILD are several kilometers thick and flat-top stratified deposits. They overlap the chaotic floor. They are surrounded and cut by several flow features that imply that liquid water was still acting after the formation of these stratified deposits. The density of crater on the floor of Capri Chasma was quantified. The current topography was aged to 3 Gyr. All these morphological information allow us to suggest a plausible geological history for Capri Chasma. We propose that the Interior Layered Deposits have formed during the Hesperian, during or after the opening of the canyon. Some observations argue that water discharges have happened at several times before and just after the formation of the ILD. Liquid water must have played a major role in the formation of these deposits after 3.5 Gyr, implying that it was present in surface at least locally and temporarily. If this can be applied to ILD in others canyons of Valles Marineris, it would imply that liquid water was stable in surface or sub-surface during the Hesperian. Or in the actual conditions, with a cold and dry martian surface, long-term standing water bodies are not possible. Thus we suggest that either the climate at the Hesperian was cold, but wetter, or as warm as the Noachian climate, what is less likely. Nevertheless, the global climate change which has occurred at the beginning of Mars history may have been later than announced.     

Morphology and geometry of Valles Marineris landslides

The walls of the Valles Marineris canyons are affected by about 45 landslides. The study of these landslides provides a test of the hypothesis of processes having affected Martian wallslopes after their formation. The dynamics of Valles Marineris landslides are controversial : either the landslides are interpreted as large debris flows or as dry rock avalanches. Their morphology and their topography are basic parameters to understand their dynamics. From topographic MOLA data and remote sensing images acquired with different spatial resolutions (Viking, THEMIS, MOC), the 3D geometry of 45 landslides of Valles Marineris has been studied. The landslides have been classified in 3 geomorphologic classes from the topography of the landslide deposits: the “chaotic” landslides without well identified structures, the “structured deposit without debris aprons” landslides with tectonic structures and small roughness at the deposit front and the “structured deposit with debris aprons” which display circular normal faults at the back of the deposit and several debris aprons at the front of the landslide. The spatial distribution of the three morphological types is in relation with the confinement of the canyons. The initial volume and the total deposited volume were also measured to compute volume balances. The deposited volumes range from 50 to . All volume balances display a maximum deficit ranging from 5% to 70%. The landslides with the largest deficits take place within an enclosed-canyon (Hebes Chasma). Lacking material exportation, these deficits could be interpreted as reflecting the porosity of the landslide source. This fact is in agreement with the hypothesis of a karstic origin of these enclosed-canyons. The Valles Marineris landslides have large mobilities (length/vertical drop) ranging from 1.8 to 12 implying low coefficients of friction and so fluidization mechanisms. The possible filling up of the porosity by volatile could be compatible with the fluidization patterns of Valles Marineris landslides.     

Evidence for ponding and catastrophic floods in central Valles Marineris, Mars

The Valles Marineris canyon system of Mars is closely related to large flood channels, some of which emerge full born from chaotic terrain in canyon floors. Coprates Chasma, one of the largest Valles Marineris canyons, is connected at its west end to Melas Chasma and on its east end to chaotic terrain-filled Capri and Eos Chasmata. The area from central Melas to Eos Chasmata contains a 1500 km long and about 1 km deep depression in its floor. Despite the large volumes of groundwater that likely discharged from chaotic terrain in this depression, no evidence of related fluvial activity has thus far been reported. We present an analysis of the regional topography which, together with photogeologic interpretation of available imagery, suggests that ponding due to late Hesperian discharge of water possibly produced a lake (mean depth 842 m) spanning parts of the Valles Marineris depression (VMD). Overflow of this lake at its eastern end resulted in delivery of water to downstream chaos regions and outflow channels. Our ponding hypothesis is motivated primarily by the identification of scarp and terrace features which, despite a lateral spread of about 1500 km, have similar elevations. Furthermore, these elevations correspond to the maximum ponding elevation of the region (−3560 m). Simulated ponding in the VMD yields an overflow point at its eastern extremity, in Eos Chasma. The neighborhood of this overflow point contains clear indicators of fluvial erosion in a consistent east-west orientation.