The late Quaternary limnological history of Lake Kinneret (Sea of Galilee), Israel

The freshwater Lake Kinneret (Sea of Galilee) and the hypersaline Dead Sea are remnant lakes, evolved from ancient water bodies that filled the tectonic depressions along the Dead Sea Transform (DST) during the Neogene-Quartenary periods. We reconstructed the limnological history (level and composition) of Lake Kinneret during the past ∼40,000 years and compared it with the history of the contemporaneous Lake Lisan from the aspect of the regional and global climate history. The lake level reconstruction was achieved through a chronological and sedimentological investigation of exposed sedimentary sections in the Kinnarot basin trenches and cores drilled at the Ohalo II archeological site. Shoreline chronology was established by radiocarbon dating of organic remains and of Melanopsis shells.The major changes in Lake Kinneret level were synchronous with those of the southern Lake Lisan. Both lakes dropped significantly ∼42,000, ∼30,000, 23,800, and 13,000 yr ago and rose ∼39,000, 26,000, 5000, and 1600 yr ago. Between 26,000 and 24,000 yr ago, the lakes merged into a unified water body and lake level achieved its maximum stand of ∼170 m below mean sea level (m bsl). Nevertheless, the fresh and saline water properties of Lake Kinneret and Lake Lisan, respectively, have been preserved throughout the 40,000 years studied. Calcium carbonate was always deposited as calcite in Lake Kinneret and as aragonite in Lake Lisan-Dead Sea, indicating that the Dead Sea brine (which supports aragonite production) never reached or affected Lake Kinneret, even during the period of lake high stand and convergence. The synchronous level fluctuation of lakes Kinneret, Lisan, and the Holocene Dead Sea is consistent with the dominance of the Atlantic-Mediterranean rain system on the catchment of the basin and the regional hydrology. The major drops in Lake Kinneret-Lisan levels coincide with the timing of cold spells in the North Atlantic that caused a shut down of rains in the East Mediterranean and the lakes drainage area.     

Magnetic and Gravity Investigations of Lisan Peninsula-Dead Sea(Jordan)

The Lisan Peninsula is located within the Dead Sea basin which represents the plate boundary between African and Arabian plates. This basin constitutes a good example of a pull-apart basin because of its large dimensions, its structural simplicity and its active subsidence . The gravity data reveal that the Dead Sea basin can be divided into segments, each of them about 30 km long in N-S direction , where the Lisan Peninsula represents the deepest one (9 km thick Pleistocene sediments ), overlying about 6 km thick Mesozoic sediments . In addition , 20 km of extension was predicted along the Dead Sea basin, which indicates that the Dead Sea basin should be about 3.3 Ma in age . Furthermore, the Precambrian basement under the Lisan area is characterized by high susceptibility contrast that is related to continuous tectonic activity in the region.     

Primary carbonates and Ca-chloride brines as monitors of a paleo-hydrological regime in the Dead Sea basin

Lakes Samra, Lisan and the Dead Sea occupied the Dead Sea basin during the Last Interglacial (∼140–75 ka BP), last glacial (∼70–14 ka BP) and Holocene periods, respectively. The age of Lake Lisan and Samra was determined by U–Th dating of primary aragonites comprising parts of the lacustrine sedimentary sequences. The lakes have periodically deposited sequences of layered calcitic marls (Lake Samra) or laminated primary aragonite (Lake Lisan). The deposition of aragonite as the primary carbonate phase reflects the contribution of the incoming freshwater (loaded with bi-carbonate) and high Mg-, Ca-chloride brine that originated from the subsurface vicinity of the Dead Sea basin. Deposition of calcitic marls suggests a minor effect of the brines. The Ca-chloride subsurface brine has been migrating in and out of the wall rocks of the Dead Sea basin, reflecting the regional hydrological conditions. During most of the last glacial period and during the late Holocene, sufficient precipitation above the Judea Mountains pushed the subsurface Ca-chloride brines into the lakes causing the deposition of aragonite. During the Last Interglacial period the rain that precipitated above the Judea Mountains was insufficient to induce brine flow toward Lake Samra. It appears that sporadic floods provided calcium, bicarbonate and detritus to produce the Samra calcitic marls. Travertines deposited at the Samra–Lisan boundary indicate the early stage in the resumption of groundwater (springs) activity that led to the resurgence of Ca-chloride brine and rise of Lake Lisan. Similar variations in the regional rain precipitation and hydrological activity probably characterized the long-term geochemical evolution of Pleistocene lacustrine water-bodies in the Dead Sea basin, enabling the use of the carbonates as paleo-hydrological monitors.     

Stromatolites in caves of the Dead Sea Fault Escarpment: implications to latest Pleistocene lake levels and tectonic subsidence

A varied assemblage of algal stromatolites was encountered in caves along the northern section of the Dead Sea Fault Escarpment. The caves are situated at the lower part of the escarpment at altitudes ?310 to ?188 m relative to mean sea level (m.s.l.), i.e. ca 110–230 m above the present Dead Sea level. The cave stromatolites are mainly composed of aragonite yielding U–Th ages of ～75–17 ka. The altitude, mineralogy and ages, as well as comparison with previously documented stromatolite outcrops in the area, ascribe the cave stromatolites to the aragonite-precipitating hypersaline Lake Lisan—the Late Pleistocene predecessor of the Dead Sea.The stromatolites are used as a lake level gauge, based on the algae being reliant upon the light of the upper water layer. Preservation of the original structure and aragonite mineralogy of the stromatolites, suggests a closed system regarding the radioactive elements, enabling reliable U–Th dating. A curve of Lake Lisan levels is constructed based on the stromatolite ages and cave elevations. The following points are noted: (1) Lake levels of ?247 m relative to m.s.l., are recorded at ～75–72.5 ka; (2) relatively high lake levels above ?220 m relative to m.s.l., are achieved at ～41.5 ka, and are still recorded at ～17 ka; (3) the peak level is ?188 m relative to m.s.l., at ～35.5–29.5 ka. These results indicate lake stands up to 80 m higher than previously accepted, for large parts of the Lake Lisan time span. This difference is explained by tectonic subsidence of up to 2.2 m/ka within the Dead Sea depression since the latest Pleistocene. This subsidence rate is in the same order of magnitude with previously calculated subsidence rates for the Dead Sea depression [Begin, Z.B., Zilberman, E., 1997. Main Stages and Rate of the Relief Development in Israel. Geological Survey of Israel report, Jerusalem]. Unlike previous Lake Lisan level estimations, the new curve is measured at the relatively stable shoulders of the Dead Sea depression.     

Leaching of Lisan Marl and its consequences on the engineering behavior of dikes,studied by finite elements modeling

Leaching of Lisan Marl, Dead Sea, Jordan increased the soil compressibility and cohesion intercept. Back analysis using the Plaxis finite element code was successfully implemented. The Finite element modeling of dike construction showed a significant increase of total settlement and negligible effect on the strength as calculated by the φ/c reduction method. The height of dikes to be constructed on Lisan Marl as foundation material, should be optimized to account for the effect of soluble salts leaching. For this to take place, an accurate calculation of settlement is crucial.     

The role of volcanic eruptions in blocking the drainage leading to the Dead Sea formation

The shrinkage of the Lisan Lake (LL) to form the recent Dead Sea (DS) was mainly a result of the reduction of the catchment area from around 157,000 km² during Late Pleistocene to 43,000 km² presently. The reduction in the catchment area resulted from the eruption and spread of the basalt flows of Jabal Arab-Druz (JAD), which together with the resulting deposition of thick rock debris and gravels occupied the drainage system. The filling of the pre-basalt drainage system, which used to feed the Dead Sea, with basalts and alluvial sediments blocked the inflows from reaching the Dead Sea. Local base levels along the basalt flow boarders such as Azraq Oasis, Sirhan Basin and Damascus Oasis, and numerous pools and mud flats were created.     

The geochemical evolution of the Pleistocene Lake Lisan-Dead Sea system

The geochemical history of Lake Lisan, the Pleistocene precursor of the Dead Sea, has been studied by geological, chemical and isotopic methods.Aragonite laminae from the Lisan Formation yielded (equivalent) Sr/Ca ratios in the range 0.5 × 10^?2?1 × 10^?2, Na/Ca ratios from 3.6 × 10^?3 to 9.2 × 10^?3, $\text{δ}{}^{18}\text{O}{}_{\mathrm{PDB}}$ values between 1.5 and 7%. and $\text{δ}{}^{13}\text{C}{}_{\mathrm{PDB}}$ from ?7.7 to 3.4%..The distribution coefficient of Na⁺ between aragonite and aqueous solutions, $\text{λ}{}^{\mathrm{A}}{}_{\mathrm{Na}}$, is experimentally shown to be very sensitive to salinity and nearly temperature independent. Thus, Na/Ca in aragonite serves as a paleosalinity indicator.Sr/Ca ratios and $\text{δ}{}^{18}\text{O}$ values in aragonite provide good long-term monitors of a lake's evolution. They show Lake Lisan to be well mixed, highly evaporated and saline. Except for a diluted surface layer, the salinity of the lake was half that of the present Dead Sea (15 vs 31%).Lake Lisan evolved from a small, yet deep, hypersaline Dead Sea-like, water body. This initial lake was rapidly filled-up to its highest stand by fresh waters and existed for about 40,000 yr before shrinking back to the present Dead Sea. The chemistry of Lake Lisan at its stable stand represented a material balance between a Jordan-like input, an original large mass of salts and a chemical removal of aragonite. The weighted average depth of Lake Lisan is calculated, on a geochemical basis, to have been at least 400, preferably 600 m.The oxygen isotopic composition of Lake Lisan water, which was higher by at least 3%. than that of the Dead Sea, was probably dictated by a higher rate of evaporation.Na/Ca ratios in aragonite, which correlate well with $\text{δ}{}^{13}\text{C}$ values, but change frequently in time, reflect the existence of a short lived upper water layer of varying salinity in Lake Lisan.     

Sea-rain-lake relation in the Last Glacial East Mediterranean revealed by δO-δC in Lake Lisan aragonites

We investigated the Sea-Rain-Lake relation during the Last Glacial-Holocene in the East Mediterranean region by comparing the δ¹⁸O and δ¹³C records of authigenic aragonite deposited in Lake Lisan, the Dead Sea, Mediterranean foraminifera, and speleothems. The Lisan Formation data display long- and short-term variations of δ¹⁸O, representing steady-state conditions of the lake (e.g., 5.6‰ ± 0.5‰ and 4.5‰ ± 1‰ in the Upper and Lower Members of the Lisan Formation, respectively), and short-term excursions reflecting large floods and droughts. The long-term (steady-state) δ¹⁸O values of the Lisan aragonites show similarity to the corresponding time-equivalent records of the Eastern Mediterranean foraminifera and Judea Mountain speleothems: The Last Glacial deposits are in all of them 2‰-3‰ heavier than the Holocene ones. We interpret this similarity as reflecting the significance of the source effect on the long-term behavior of isotopic reservoirs: Speleothem δ¹⁸O is strongly influenced by the marine reservoir that contributes its vapor to rain formation; the lake δ¹⁸O is dominated by the composition of the inflowing water. Short-term variations in the isotopic composition of rainfall are dominated by the amount effect and the temperature and those of the Lake’s upper water mass by the lake’s water balance.δ¹³C values are more variable than δ¹⁸O in the same Lisan sequences (e.g., δ¹³C in the Lower Member is 1.0‰ ± 1.7‰, whereas δ¹⁸O is 4.6‰ ± 0.7‰) and are 1‰ to 1.5‰ higher in the Upper Member than in the Lower and Middle Members of the Lisan Formation. These variations reflect significant increase in primary productivity of the lake and algal bloom activity. It appears that the hypersaline-saline lakes were not as “dead” as the Dead Sea is and that algal activity had an important impact upon the geochemistry of Lake Lisan.The δ¹⁸O data combined with independent geochemical and limnologic information (e.g., level fluctuations) indicate that Lisan time was characterized by high precipitation-high lake stands-high atmospheric humidity, whereas the Holocene Dead Sea shows the opposite behavior. This paleoclimatic reconstruction is consistent with independent evidence for significantly wetter conditions in the East Mediterranean region during the Last Glacial period.     

Radial clastic dykes formed by a salt diapir in the Dead Sea Rift, Israel

ABSTRACT Fanning structures radiating from a central perturbation are known in various geological environments, where different processes have produced similar geometry. The present contribution describes and analyses fanning clastic dykes in the Dead Sea Rift, a new example of diapir-related deformation. The dykes are opening-mode fractures exposed in lacustrine varved marl of the Lisan Formation, deposited 70–15 ka. They are arranged mainly in a radial and tangential geometry. The radial traces converge at the 'Black Hill' structural dome. The geometry of the fractures is consistent with stresses exerted by the rise of a salt diapir located underneath the Black Hill. The estimated extension of the radial fractures is in good agreement with the present topographic elevation of the hill. The absence of fractures in the overlying Holocene alluvium probably indicates that either the rise of the Black Hill salt diapir paused or is associated now with a different style of deformation.     

Origin of high bromide concentration in the water sources in Jordan and in the Dead Sea water

The Dead Sea is worldwide a major bromine provider for industry with an average concentration of 5.2 g/l of bromide compared to 0.065 mg/l in seawater and with a Cl/Br weight ratio in the Dead Sea water of about 42 compared to around 300 in oceanic water. The origin of the high bromide concentration in the Dead Sea has not yet been adequately clarified. In the course of this study, the bromide concentrations in the different surface and groundwater bodies in Jordan were analyzed and the types of rocks with which these waters were in contact were identified. Analyses carried out up to about 30 years ago and recent analyses confirm the natural origin of bromide in the water and also confirm that the analyzed sources are not polluted by anthropogenic bromide sources. It was found that a variety of these surface and groundwater sources contain high concentrations of bromide which discharges into the Dead Sea and contribute to its high bromide concentration. The present study concludes that the late Cretaceous early Tertiary oil shale deposits form the major source of the bromine species in the surface and groundwater feeding the Dead Sea. Some bromide is also contributed by the Triassic and Jurassic rocks containing evaporate salts containing bromides. Phosphate rocks of late Upper Cretaceous age contribute also with appreciable amounts of bromine species to the different water sources and hence to the Dead Sea water. At present, dissolution and erosion of bromide-rich sediments laid down by the predecessor water bodies of the present Dead Sea such as the Lisan Lake are being transported into the Dead Sea and contribute relatively large amounts of secondary bromide to the Dead Sea water.     

Gypsum as a monitor of the paleo-limnological–hydrological conditions in Lake Lisan and the Dead Sea

The isotopic composition and mass balances of sources and sinks of sulfur are used to constrain the limnological–hydrological evolution of the last glacial Lake Lisan (70–14 ka BP) and the Holocene Dead Sea. Lake Lisan deposited large amounts of primary gypsum during discrete episodes of lake level decline. This gypsum, which appears in massive or laminated forms, displays δ³⁴S values in the range of 14–28‰. In addition, Lake Lisan’s deposits (the Lisan Formation) contain thinly laminated and disseminated gypsum as well as native sulfur which display significantly lower δ³⁴S values (−26 to 1‰ and −20 to −10‰, respectively). The calculated bulk isotopic compositions of sulfur in the sources and sinks of Lake Lisan lacustrine system are similar (δ³⁴S ≈ 10‰), indicating that freshwater sulfate was the main source of sulfur to the lake. The large range in δ³⁴S found within the Lisan Formation (−26 to +28‰) is the result of bacterial sulfate reduction (BSR) within the anoxic lower water body (the monimolimnion) and bottom sediments of the lake.

Precipitation of primary gypsum from the Ca-chloride solution of Lake Lisan is limited by sulfate concentration, which could not exceed 3000 mg/l. The Upper Gypsum Unit, deposited before ca. 17–15 ka, is the thickest gypsum unit in the section and displays the highest δ³⁴S values (25–28‰). Yet, our calculations indicate that no more than a third of this Unit could have precipitated directly from the water column. This implies that during the lake level decline that instigated the precipitation of the Upper Gypsum Unit, significant amounts of dissolved sulfate had to reach the lake from external sources. We propose a mechanism that operated during cycles of high-low stands of the lakes that occupied the Dead Sea basin during the late Pleistocene. During high-stand intervals (i.e., Marine Isotopic Stages 2 and 4), lake brine underwent BSR and infiltrated the lake’s margins and adjacent strata. As lake level dropped, these brines, carrying ³⁴S-enriched sulfate, were flushed back to the shrinking lake and replenished the water column with sulfate, thereby promoting massive gypsum precipitation.

The Holocene Dead Sea precipitated relatively small amounts of primary gypsum, mainly in the form of thin laminae. δ³⁴S values of these laminae and disseminated gypsum are relatively constant (15 ± 0.7‰) and are close to present-day lake composition. This reflects the lower supply of freshwater to the lake and the limited BSR activity during the arid Holocene time and possibly during former arid interglacials in the Levant.     

Palaeoseismic Events in Karst Terrains along the Northern Bulgarian Black Sea Coast

The study of the palaoseismic events in the karst terrains of the Bulgarian Black Sea coast is a very important up-to-date problem. The investigated region is one of the highest-energy regions in Bulgaria with established and recorded catastrophic historic and contemporary earthquakes. The terrain is subjected to the influence not only of its own earthquake foci but also of those in Romania and Russia. The palaeoearthquakes that caused considerable disturbances in the karst terrains along the Northern Bulgarian Black Sea coast have left significant traces. They caused disturbances in the environment and the relief (rearrangement of the surface and ground water karst basins, partially or entirely collapsed caves, deformed caves, oil, gas and salt intrusions and gravitationally formed caves). The ecological consequences in historic and contemporary aspects were catastrophic. The palaeoseismic dislocations were formed as a result of global, regional and local geodynamic events related with the destruction     

Asymmetry and basin migration in the dead sea rift

The Dead Sea depression sensu stricto, forms the deepest continental part of the Dead Sea rift, a transfer which separates the Levanthine and Arabian plates. It is occupied by three distinct sedimentary bodies, deposited in basins whose depocenters are displaced northward with time. They are: the continental red beds of the Hazeva Formation (Miocene), the Bira-Lido-Gesher marls and the exceptionally thick rocksalt of the Sedom Formation (Pliocene—Early Pleistocene), and the successive Amora, Lisan and Dead Sea evaporites and clastics (Early Pleistocene—Recent). Lengthwise and crosswise asymmetries of these sedimentary basins and their respective depocenters are due to: leftlateral shear combined with anticlockwise rotation of the Arabian (eastern) plate; steeper faulting of the crustal eastern margin than of the western sedimentary margin, and modification of depositional pattern by twice filling up of basins, by Hazeva red beds during Late Miocene pause of shear and by Sedom rocksalt during Pliocene marine ingression.     

Reevaluation of the lake-sediment chronology in the Dead Sea basin, Israel, based on new Th/U dates

The Dead Sea is surrounded by chemical and detrital sediments that were deposited in its larger precursor lakes, Lake Samra and Lake Lisan. The sedimentary history of these lakes was recon-structed by means of ²³⁰Th/²³⁴U ages of 30 samples, mostly of argonite laminae, from 8 columnar sections up to 110 km apart. The general validity of the ages was demonstrated by subjecting them to tests of internal isotopic consistency, agreement with stratigraphic order, and concordance with ¹⁴C ages. In the south, only the part of the Samra Formation older than 170,000 yr is exposed, while the aragonite-detritus rhythmites found in the central and northern region are generally younger than 120,000 yr. The Lisan Formation started accumulating about 63,000 yr B.P., with the clay and aragonite beds in the south-central area reflecting a rise in water level to at least −280 m. The upper part of the Lisan Formation, the aragonite-rich White Cliff Member, started accumulating about 36,000 yr B.P. The lake probably reached its highest level sometime after this, based on the ages of Lisan sediments preserved in the southernmost reaches of the basin.     

Clastic dikes in the Dead Sea basin as indicators of local site amplification

Natural Hazards - Early Holocene seismic activity triggered fluidization and clastic-dike emplacement within Late Pleistocene lacustrine Lisan Formation sediments in the Dead Sea basin (DSB)....     

Structural control of sinkholes and subsidence hazards along the Jordanian Dead Sea coast

For about four decades, the Dead Sea (DS) level and the surrounding water table has been dropping dramatically. At least from the eighties, the direct vicinity of the Lisan Peninsula (LP), Jordan, has been facing high rates of subsidence and sinkhole hazards. Between 2000 and 2002, the Arab Potash Company (APC) lost two salt evaporation ponds resulting in a loss of $70 million. In the fertile plain of Ghor al Haditha (GAH), three deep and wide bowl-shaped subsidence areas threaten human activities and infrastructures. Over the part of the Lisan Peninsula that emerged before the 1960s, relict fossil sinkholes occurred everywhere, whereas new collapses constantly appear in the southern area only. In this paper, we have integrated 15 years of field observations related to sinkholes and subsidence with interpretation of space borne radar interferometric outputs, aerial photographs and satellite images. This has helped to place hazardous areas in their geological context and to clarify them within the framework of the general tectonic setting of the area.     

The role of hydrogeological base level in the formation of sub-horizontal caves horizons, example from the Dead Sea Basin, Israel

This paper deals with the hydrogeological relationship between base levels of saline lakes and the formation of sub-horizontal caves. The mechanism presented here suggests that many horizontal cave levels in carbonate sequences are created adjacent to the saline lakes shorelines because of the converging of the groundwater flow above the fresh–saline water interface. The main factors that control enhanced carbonate dissolution and cave formation are high groundwater flow velocities in the shallow phreatic zone during a relative long steady state of the water table. High groundwater flow velocities are evident close to the Dead Sea due to the convergent fast flows above the shallow interface adjacent to the shoreline. The same could prevail in the case of previous paleo-lakes that existed in the basin. The synergetic combination of the above preconditions for enhanced cave formation seems to be responsible for the formation of elevation-controlled alignment of paleo-near shore cave levels in the central and southern (Dead Sea) portion of the study area. These are found on the western fault escarpment and basin margin in different stratigraphic horizons of carbonate lithology. Many of the cave levels can be linked to late Quaternary–Holocene lake levels obtained from dated lake sediments within the basin. The most common cave’s elevation was found to be around 200 m below sea level which was the elevation of the Lisan Lake during part of its history. On the other hand, the Hula Basin in the northern part of the Dead Sea Basin was not occupied by saline water bodies since its formation as a base level, and thus the above preconditions for enhanced cave formation did not prevail. Indeed, this is evident by the lack of horizontal cave levels on its western carbonate margins unlike the situation in the south.     

Subsidence hazards due to evaporite dissolution in the United States

Evaporites, including gypsum (or anhydrite) and salt, are the most soluble of common rocks; they are dissolved readily to form the same type of karst features that typically are found in limestones and dolomites, and their dissolution can locally result in major subsidence structures. The four basic requirements for evaporite dissolution to occur are: (1) a deposit of gypsum or salt; (2) water, unsaturated with CaSO₄ or NaCl; (3) an outlet for escape of dissolving water; and (4) energy to cause water to flow through the system. Evaporites are present in 32 of the 48 contiguous states of the United States, and they underlie about 35–40% of the land area. Karst is known at least locally (and sometimes quite extensively) in almost all areas underlain by evaporites, and some of these karst features involve significant subsidence. The most widespread and pronounced examples of both gypsum and salt karst and subsidence are in the Permian basin of the southwestern United States, but many other areas also are significant. Human activities have caused some evaporite–subsidence development, primarily in salt deposits. Boreholes may enable (either intentionally or inadvertently) unsaturated water to flow through or against salt deposits, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures above the cavity can cause land subsidence or catastrophic collapse.     

Stratigraphy, depositional environments and level reconstruction of the last interglacial Lake Samra in the Dead Sea basin

In this paper we describe the stratigraphy and sediments deposited in Lake Samra that occupied the Dead Sea basin between ∼ 135 and 75 ka. This information is combined with U/Th dating of primary aragonites in order to estimate a relative lake-level curve that serves as a regional paleohydrological monitor. The lake stood at an elevation of ∼ 340 m below mean sea level (MSL) during most of the last interglacial. This level is relatively higher than the average Holocene Dead Sea (∼ 400 ± 30 m below MSL). At ∼ 120 and ∼ 85 ka, Lake Samra rose to ∼ 320 m below MSL while it dropped to levels lower than ∼ 380 m below MSL at ∼ 135 and ∼ 75 ka, reflecting arid conditions in the drainage area. Lowstands are correlated with warm intervals in the Northern Hemisphere, while minor lake rises are probably related to cold episodes during MIS 5b and MIS 5d. Similar climate relationships are documented for the last glacial highstand Lake Lisan and the lowstand Holocene Dead Sea. Yet, the dominance of detrital calcites and precipitation of travertines in the Dead Sea basin during the last interglacial interval suggest intense pluvial conditions and possible contribution of southern sources of wetness to the region.     

Copper-bearing encrustations: a tool for age dating and constraining the physical–chemical regime during the late Quaternary in the Wadi Araba, southern Jordan

The alluvial–fluvial drainage system in the Wadi Araba, southern Jordan, incised into Cambrian clastic sedimentary and felsic igneous rocks giving rise to a disseminated Cu–(Mn) mineralization of diagenetic and epigenetic origin along the southern branch of the Dead Sea Transform Fault (=DSTF). During the Late Pleistocene and Holocene, the primary Cu sulfides were replaced by secondary minerals giving rise to hypogene to supergene encrustations, bearing Cu silicates, Cu carbonates, Cu oxychlorides and cupriferous vanadates. They occur in fissures, coat walls and developed even-rim/meniscus and blocky cements in the arenites near the surface. The first generation cement has been interpreted in terms of freshwater vadose hydraulic conditions, while the second-generation blocky cement of chrysocolla and malachite evolved as late cement. The Cu–Si–C fluid system within the Wadi Araba drainage system is the on-shore or subaerial facies of a regressive lacustrine regime called the “Lake Lisan Stage”, a precursor of the present-day Dead Sea. Radiocarbon dating (younger than 27,740 ± 1,570 years), oxygen-isotope-based temperature determination (hot brine-related mineralization at 60–80 °C, climate-driven mineralization at 25–30 °C) and thermodynamical calculations let to the subdivision of this secondary Cu mineralization into four stages, whose chemical and mineralogical composition was controlled by the variation of the anion complexes of silica and carbonate and the chlorine contents. The acidity of the pore water positively correlates with the degree of oxidation. The highest aridity and most intensive evaporation deduced from the thermodynamical calculations were achieved during stage 3, which is coeval with late Lake Lisan. Geogene processes causing Cu-enriched encrustations overlap with man-made manganiferous slags. The smelter feed has been derived mainly from Cu ore which developed during Late Pleistocene in the region.