对富铝型豆荚状铬铁矿矿床成因的新认识一一以新疆萨尔托海铬铁矿矿床为例

萨尔托海铬铁矿矿床产于萨尔托海蛇绿岩块的地幔橄榄岩中,属于富铝型豆荚状铬铁矿床。该矿床与一套橄长岩和辉长岩类岩石紧密伴生,矿体周围常被一薄的绿泥石壳所包裹。本区铬铁矿的形成包括两个阶段:第一阶段是原始地幔岩经高度熔融形成富铬铬铁矿;第二阶段形成富铝铬铁矿。交代作用伴随着新生单斜辉石和斜长石的形成。原始地幔岩的高度熔融以及基性熔体在地幔橄榄岩中的形成和存在是萨尔托海铬铁矿形成的先决条件。     

玉石沟铬铁矿床的成因

玉石沟铬铁矿床产于北祁连蛇绿岩型超镁铁岩中，可分为产于堆积超镁铁岩中的堆积铬铁矿床和产于地幔橄榄岩中的豆荚状铬铁矿床两种类型。堆积铬铁矿床由玄武岩浆分离结晶作用形成，位于辉长岩下约２０ｍ处的纯橄岩或辉石岩中；豆荚状铬铁矿床由地幔岩部分熔融作用形成，产于地幔橄榄岩上部或顶部基性程度最高的纯橄岩或纯橄岩－斜辉辉橄岩杂岩带，位于堆积杂岩下约２００～１７００ｍ范围内。     

内蒙古苏尼特左旗乌兰敖包基性-超基性岩的成因及其对含矿性的指示

乌兰敖包基性-超基性岩位于阿拉善北缘兴蒙造山带,由方辉橄榄岩、辉绿岩、辉长岩组成。地球化学分析表明:蛇纹石化橄榄岩为地幔橄榄岩,辉绿岩和辉长岩为拉斑玄武岩系列岩石,均具有与N-MORB相似的微量元素特征,但区别于N-MORB,3种岩石共同组成了蛇绿混杂岩。矿物学分析表明蛇纹石化橄榄岩中橄榄石为地幔橄榄岩中镁橄榄石(Fo=91.10~91.81),铬铁矿为铬尖晶石,具有高的Cr~#和Mg~#值分别为61.04~64.44、50.40~56.37)。单斜辉石出现在方辉橄榄岩、辉长岩及辉绿岩中,而斜方辉石只出现在方辉橄榄岩中,其中方辉橄榄岩中单斜辉石为顽透辉石,辉长岩中为普通辉石,而辉长岩中为次透辉石、贫钙普通辉石、普通辉石,斜方辉石均为斜顽辉石。辉长岩U-Pb年龄为344.5±1.5 Ma,表明该蛇绿混杂岩形成于早石炭世。地球化学及矿物学特征表明乌兰敖包蛇绿岩形成于俯冲早期的弧前环境中,属于SSZ型蛇绿岩。蛇绿混杂岩成因提供铬铁矿形成的有利条件,因此应围绕铬铁矿进行找矿工作。     

内蒙古贺根山蛇绿岩型铬铁矿中固体包裹体矿物化学成分研究

内蒙古贺根山蛇绿岩型(豆荚型)铬铁矿矿床分布于内蒙古-大兴安岭海西褶皱带的蛇绿岩套内的贺根山岩块中。该蛇绿岩块主要由地幔橄榄岩、堆积岩和基性熔岩组成。铬铁矿矿体主要赋存于地幔橄榄岩相内的纯橄岩脉内,或被薄层的纯橄岩(数厘米到数米)外壳包围,矿体成群和成带分布。 在铬铁矿矿石中发现多种固体包裹体矿物,如橄榄石、斜方辉石、单斜辉石、角闪石、韭闪石、硬玉、钠长石、钛钠金云母等。这种特殊的固体包裹体矿物组合反映了铬铁矿矿床的成因或形成环境。     

冀东新太古代蛇绿岩套基本特征的初步报道

在冀东遵化新太古代构造带内首次识别出了东湾子蛇绿岩套残片，它具备严格意义上蛇绿岩套层序，从顶部到底部依次为变形枕状溶岩和变沉积岩，席状岩墙杂岩，斜长花岗岩，辉长岩杂岩，镁铁质－超镁铁质杂岩堆积岩，超镁铁质构造岩。其中，席状岩墙杂岩规律巨大，由密集分布的基性岩墙组成，并显示特征的单向冷凝边，岩浆构造及层序指示该蛇绿岩套向西掀斜，并因构造变形使层序重复，根据已有的2．67－2．79Ga的Sm-Nd全岩等时线年龄，及其被奥长花岗岩体（锆石U－Pd2501＋18／－16Ma)侵位，可以认为东湾子蛇绿岩套形成于新太古代。它的发现对于早期板块的构造的研究意义重大。     

西昆仑库地蛇绿岩地质、地球化学及其成因研究

西昆仑库地蛇绿混杂岩由方辉橄榄岩和纯橄榄岩等地幔变质橄榄岩、豆荚状铬铁矿、堆晶橄榄岩、堆晶辉石岩和辉长岩、辉绿岩墙、块状和枕状玄武岩等组成。强亏损方辉橄榄岩为主的地幔岩组合,二辉石的低Al含量和铬尖晶石的高Cr^#,以及岩石的富Mg、Ni和贫Al、Ca特征一致表明地幔橄榄岩类是经较高程度部分熔融后的地幔残余,与消减带之上蛇绿岩中的同类岩石相近。岩石富Rb、Ba、U、Th、LREE,说明地幔残余岩石受到了来自消减带的洋壳重熔组分的混染。堆晶岩以辉石岩和辉长岩为主,可能属PPG系列,指示岩浆是在消减带环境和含水条件下熔融的。辉长岩为低Ti蛇绿岩型,代表洋内弧后盆地早期环境或弧前环境。辉绿岩和玄武岩为洋中脊拉斑玄武岩和岛弧拉斑玄武岩的过渡类型;玄武岩和辉绿岩相比富Ba、Th、LREE,贫Ta,指示玄武岩较辉绿岩更多地受到来自消减带洋壳重熔组分的影响。库地蛇绿岩形成时的古构造环境是消减带之上的弧间或弧后盆地。     

东天山色尔特能豆荚状铬铁矿的发现及意义

色尔特能镁铁质-超镁铁质岩位于东天山小热泉子构造带和觉罗塔格构造带结合部位,由纯橄岩-辉橄岩-辉石岩和辉长岩组成。2020年发现一条铬铁矿体,长2 m,宽1 m,走向110°,豆荚状,Cr2O3品位40.71%。通过野外地质特征分析与成矿理论研究,认为其属蛇绿岩型豆荚状铬铁矿。该类型矿产的发现在康古尔断裂带一带尚属首次,表明色尔特能镁铁质-超镁铁质岩为蛇绿岩,非基性-超基性侵入岩。证明东天山康南-东恰特尕力-色尔特能蛇绿岩带的存在,大大拓展了东天山铬铁矿勘查潜力,具有重要理论和现实意义。     

对大道尔吉铬铁矿床成因的新认识

大道尔吉岩体为一肢解的蛇绿岩残片,由两个单元组成,一为堆晶杂岩,另一为地幔橄榄岩。堆晶杂岩包括三个岩浆旋回,每一旋回均表现出由超镁铁质向镁铁质演化的特点。工业铬铁矿产于堆晶杂岩第三旋回底部的纯橄岩-含辉纯橄岩中,而产于地幔橄榄岩中的铬铁矿为数甚微。矿体主要由各种浸染状的铬铁矿石组成。矿体的围岩为纯橄岩且两者逐渐过渡。副矿物铬尖晶石与造矿铬尖晶石的成分相似。上述特征表明大道尔吉铬铁矿床系堆积成因,明显地区别于地幔橄榄岩中的豆荚状铬铁矿。大道尔吉铬铁矿床为我国一个与蛇绿岩堆晶杂岩有关的典型铬铁矿床。     

西藏丁青地区与玻镁安山岩类有关的蛇绿岩的矿物学特征

西藏丁青蛇绿岩的东杂岩体是一种与玻镁安山岩(Boninite)有关的特殊的蛇绿岩类型。其 堆晶斜方辉石岩、辉长岩和辉绿岩的岩石化学、微量元素以及稀土元素的地球化学特征均与西太平洋诸岛(伊豆—马利亚纳、巴布亚新几内亚、新喀里多尼亚等)的玻镁安山岩相似。此外,超镁铁质构造岩中的橄榄石和顽火辉石富镁,指示残余地幔具强烈亏损的性质。尖晶石的Cr含量中等至较高,与深海橄榄岩及大洋中脊玄武岩中的尖晶石不同。堆晶岩和辉长岩中的古铜辉石富镁,斜长石富钙,也明显不同于典型大洋中脊环境的特征,表明丁青东蛇绿岩形成的环境不像大洋中脊或弧后盆地,而可能是在洋内俯冲带之上的岛弧底部。     

新疆达拉布特超镁铁岩成因——来自铬尖晶石的证据

通过研究西准噶尔达拉布特蛇绿混杂岩中方辉橄榄岩和橄榄辉石岩的岩石学特征,分析方辉橄榄岩广泛发育的铬尖晶石和斜方辉石构成的蠕虫状共生连晶结构的成因,得出结论认为:这种共生连晶结构不是前人所认为的文象结构或者石榴石的后成合晶,而是原始地幔岩熔融形成富铬岩浆的演化产物。这种富铬岩浆高度分异形成铬铁矿块体(即萨尔托海铬铁矿矿床)后,熔体进入地幔岩中结晶形成铬尖晶石和斜方辉石的蠕虫状共生连晶结构。因此,铬尖晶石与辉石的共生连晶结构可以作为豆荚状铬铁矿的重要找矿标志。方辉橄榄岩中的斜方辉石发育铬尖晶石出溶结构,出溶棒的成分特点表明,该结构是达拉布特蛇绿岩在快速就位过程中环境氧逸度突然升高诱发变质反应的结果。     

藏北羌塘中部桃形湖早古生代蛇绿岩的岩石学特征

桃形湖早古生代蛇绿岩是龙木错－双湖板块缝合带近期的重要发现。通过对桃形湖蛇绿岩进行详细的野外地质调查和岩石学、年代学、地球化学的研究发现,桃形湖早古生代蛇绿岩各单元出露齐全,由下到上分别为变质橄榄岩、超基性堆晶杂岩、堆晶辉长岩、基性岩墙群和枕状玄武岩,在堆晶岩中有不同规模的斜长花岗岩（层）脉体。桃形湖堆晶辉长岩的时代为中奥陶世,并具有大洋中脊型的地球化学特点。桃形湖早古生代蛇绿岩的发现说明龙木错－双湖板块缝合带中存在完整的蛇绿岩组合,同时也是古特提斯洋早期裂解的重要证据。     

西昆仑造山带东端新C-2013-198航磁异常处含钴镍矿化超镁铁质岩的发现及其找矿意义

新C-2013-198号航磁异常位于西昆仑造山带东端黄羊滩地区,苏巴什构造结合带南侧。三级查证工作表明,该异常对应地质体为含钴镍矿化超镁铁质岩,由辉橄岩和辉石岩组成。其中辉橄岩Ni含量分布在0.15%～0.32%,Co 0.012%～0.016%,Ni平均品位0.21%,Co 0.014%;辉石岩Ni含量为0.10%～0.19%,Co 0.007%～0.010%,Ni平均品位0.14%,Co 0.008%。含钴镍矿化仅赋存于超镁铁质岩石中,具明显岩浆控矿特征。赋矿超镁铁质岩与伴生辉长岩、斜长花岗岩构成蛇绿岩岩石组合,为西昆仑造山带苏巴什蛇绿岩的一部分。综合分析认为,含钴镍矿化成矿类型为与蛇绿岩有关的岩浆硫化物矿床,具煎茶岭式镍矿成矿特征。推断新疆南部西昆仑地区具有寻找煎茶岭式镍矿的找矿前景。     

新疆西准噶尔地区蛇绿岩与豆荚型铬铁矿床的成因研究

本文将西准噶尔地区蛇绿岩分为两类:一类是变质橄榄岩+辉石岩+辉长岩组合(简称PPG系列),它们遵循富Ca的演化趋势,发育冶金型铬铁矿床;另一类是变质橄榄岩+橄长岩+辉长岩组合(简称PTG系列),它们遵循富Al的演化趋势,发育耐火型铬铁矿床。两类蛇绿岩中变质橄榄岩的成因机制是上地幔岩的部分熔融,而铬铁矿及纯橄岩的出现则是高度熔融的残余;堆积杂岩中出现辉石岩+辉长岩和橄长岩+辉长岩的不同组合则与岩浆房的出露深度和氧化状态有关。     

青藏高原中部阿索蛇绿岩岩石学与同位素年龄

阿索蛇绿岩位于尼玛县阿索乡西南,大地构造上归属于狮泉河-永珠-嘉黎蛇绿岩带中段。蛇绿岩以岩片形式混杂在晚侏罗世—早白垩世复理石中,岩石组合较齐全,由下至上为蛇纹岩、辉石岩、堆晶辉长岩、席状岩墙及火山熔岩,同时存在蛇绿岩上覆沉积岩系。辉长岩获得LA-ICP-MS锆石U-Pb谐和年龄为117.5±0.5Ma,时代为早白垩世。狮泉河-永珠-嘉黎蛇绿岩带中的蛇绿岩形成于晚三叠世—早白垩世,主要分布在219~178Ma、165~149Ma和117~114Ma三个年龄段,代表了大洋演化的扩张、俯冲、弧后拉张3个阶段。     

Geochemistry and SHRIMP U‐Pb Zircon Dating of Mafic Rocks North of Zunhua City,Eastern Hebei,North China Craton: Paleoproterozoic Gabbro rather than Neoarchean Ophiolite

Abundant mafic-ultramafic blocks and dikes occur in the area north of Zunhua City, eastern Hebei Province, and were previously suggested to be part of a late Archean ophiolitic assemblage. We employed SHRIMP zircon dating and a geochemical study on these mafic and surrounding rocks to test the ophiolite hypothesis. The SHRIMP data suggest that three metagabbro samples were metamorphosed at ～1.8 Ga. Numerous ～2.5 Ga zircons display strong oscillatory zoning, characteristic of zircons from granitoid rocks but not from gabbro, so we suggest that these are xenocrystic grains. The age of these xenocrystic zircons and their metamorpbic rims suggests that these mafic blocks formed in Paleoproterozoic. The surrounding gneiss of intermediate composition also contains 2.5 Ga zircons with oscillatory zoning and 1.8 Ga metamorphic rims. Fractionated REE patterns and Nb, Ta, Zr, Hf negative anomalies to variable extent were observed in the mafic blocks and surrounding rocks, also supporting a significant difference in the chemistry of ophiolitic rocks. Our data suggest that many mafic blocks in northern Zunhua are not part of a late Archean ophiolite complex but part of a tectonically dismembered Paleoproterozoic intrusive gabbro complex. This study shows that late Paleoproterozoic metamorphism occurred in the western part of eastern Hebei Province.     

北祁连山中段早中奥陶世蛇绿岩中席状岩墙杂岩的发现及其地质意义

作为蛇绿岩套重要组成部分之一的席状岩墙杂岩(Sheeted dyke complex)近来在北祁连山中段肃南县大岔大坂北坡的早中奥陶世蛇绿岩中被发现。这一发现对于祁连山早古生代蛇绿岩来说尚属首次,而且对于研究蛇绿岩的发展演化及探讨奥陶纪时洋底扩张都有重要意义。席状岩墙杂岩由一系列具单向冷凝边的辉绿岩墙组成,以一墙挨一墙的形式产出,岩墙间无任何填充物。席状岩墙杂岩在矿物组合上,常量元素、稀土元素及痕量元素地球化学特征和配分模式,甚至金属硫化物矿化作用方面都有类似之处。这些证据表明席状岩墙杂岩是连通其下岩浆房与其上枕状熔岩的通道。席状岩墙的单向冷凝边为岩浆上升方式和扩张洋脊的存在提供了令人信服的证据。根据Zr/Y—Zr关系图式,得出该区洋脊的扩张速率大约为2cm/a。     

内蒙古北山地区月牙山蛇绿质构造混杂岩带地质特征、形成时代及大地构造意义

月牙山蛇绿质构造混杂岩带位于红柳河—洗肠井蛇绿岩带东部的月牙山一带。月牙山蛇绿岩套出露较完整,自下而上由超基性杂岩、辉长岩、层状玄武岩、枕状玄武岩及放射虫硅质岩组成。蛇绿岩套北侧发生了强烈的构造混杂作用,形成蛇绿质构造混杂岩带,由强糜棱岩化、强蛇纹石化的辉橄岩、玄武岩基质和辉石岩、堆晶辉长岩、斜长花岗岩、橄榄岩、橄辉岩、角闪石岩、白云岩、放射虫硅质岩、蚀变玄武岩等岩块组成。通过对蛇绿岩套中辉石岩、辉长岩、斜长花岗岩、辉长闪长岩及蛇绿岩套北侧斜山——东七一山火山弧中的安山岩、花岗闪长岩等开展锆石U-Pb同位素测年研究,确定月牙山蛇绿岩套形成时代约为530Ma,相当于早寒武世;洋盆发生大规模自南向北俯冲作用的时间为421.0±15~442.4±1.5Ma,相当于志留纪。通过对蛇绿岩带两侧地层形成环境及蛇绿岩带对两侧地层单位的限定意义等研究认为,红柳河—洗肠井蛇绿岩带是代表古大洋闭合的板块缝合带,以该带为界,北侧为哈萨克斯坦板块,南侧为塔里木板块。     

新疆西准噶尔地区两类蛇绿岩的地质特征及其成因研究

本文将西准噶尔地区蛇绿岩分为两类:一类是变质橄榄岩 橄长岩 辉长岩岩石组合(简称PTG系列);另一类则是变质橄榄岩 辉石岩 辉长岩岩石组合(简称PPG系列)。前者以达拉布特、和布克赛尔蛇绿岩带为代表,后者以唐巴勒、玛依勒山蛇绿岩带为代表。PTG系列遵循富Al的演化趋势,而PPG系列则遵循富Ca的演化趋势;从而造成两类蛇绿岩之间在岩石组合、矿物学、岩石化学、稀土元素等地球化学以及所含铬铁矿床的种属上均有明显的差异。 两类蛇绿岩中变质橄榄岩的成因机制是上地幔岩部分熔融,两者之间的差异则是由部分熔融程度决定的。而壳层岩石(指堆积杂岩、岩墙杂岩、熔岩)则是由岩浆结晶作用形成的;堆积杂岩中出现辉石岩 辉长岩和橄长岩 辉长岩的不同岩石组合则与堆积岩岩浆房出露的深度和氧化状态有关。     

The Khan-Taishir ophiolitic complex of Western Mongolia,its petrology,origin and comparison with other ophiolitic complexes

The Khan-Taishir ophiolitic complex is situated within Early Caledonian structures of Western Mongolia. It consists (from below upward) of strongly differentiated ultramafics (dunites and harzburgites), pyroxenites and gabbro, sheeted dikes, pillow lavas and sediments, including in their uppermost part archaeocyatic limestones of Lower Cambrian age. Geological, petrochemical and geochemical data indicate that the ultramafics are turn off from the overlying ophiolitic sequence. Igneous rocks of the ophiolitic complex, except the ultramafics, were formed by two-stage differentiation of mantle magma of quartz-tholeiitic composition exhausted in potassium and titanium. Pyroxenites and gabbro with an anorthositic trend of differentiation were generated during the first stage, and sheeted dikes and pillow lavas with a quartz trend of differentiation were formed during the second one. Ophiolites of the Khan-Taishir complex petrochemically and geochemically differ strongly from mafic and ultramafic rocks of midoceanic ridges. Together with ophiolites of the Troodos complex (Cyprus) and Macquarie Island (eastern Indian Ocean) they constitute the special type of ophiolite peculiar rather to slip boundaries of lithosphere plates. The other type of ophiolite, including complexes like the Dzolen complex of south Mongolia, contains poorly differentiated ultramafics and does not contain sheeted dikes; while the igneous rocks are very similar to mafic and ultramafic rocks dredged from midoceanic and formed probably in midoceanic ridge environments as well.     

Geochemical constraints on the origin of the Hegenshan Ophiolite,Inner Mongolia,China

The Hegenshan ophiolite in Inner Mongolia is a remnant of oceanic lithosphere of probable Devonian age. The ophiolite consists of several blocks composed chiefly of serpentinized ultramafic rocks with lesser amounts of troctolite and gabbro, and sparse lavas and dikes. The ultramafic rocks consist chiefly of depleted harzburgite and minor dunite and are interpreted as mantle tectonites. In the Hegenshan block dunite is relatively abundant and is typically associated with podiform chromitite. Both the chromite ore and the residual chromites in this body are relatively aluminous with average Cr numbers of 44–54. A few small chromite bodies and some of the residual chromites have much higher Cr numbers (72–76). Several blocks have well-layered cumulate sequences of gabbro and troctolite. Sheeted dikes are absent but small mafic dikes are common in some of the ultramafic sections. Most of the mafic dikes have flat chondrite-normalized REE patterns and are strongly depleted in incompatible elements, similar to depleted tholeiites from immature island arcs. The basaltic lavas of the Hegenshan ophiolite have two distinctly different chemical signatures—one similar to the mafic dikes and one similar to ocean island basalts. The entire complex was probably formed within an island arc–marginal basin system that was later accreted to the southern margin of the Siberian Altaids.