Geochemical and hydrogeological contrasts between shallow and deeper aquifers in two villages of Araihazar, Bangladesh: Implications for deeper aquifers as drinking water sources

Sediment and groundwater profiles were compared in two villages of Bangladesh to understand the geochemical and hydrogeological factors that regulate dissolved As concentrations in groundwater. In both villages, fine-grained sediment layers separate shallow aquifers (< 28 m) high in As from deeper aquifers (40-90 m) containing < 10 μg/L As. In one village (Dari), radiocarbon dating indicates deposition of the deeper aquifer sediments > 50 ka ago and a groundwater age of thousands of years. In the other village (Bay), the sediment is < 20 ka old down to 90 m and the deeper aquifer groundwater is younger, on the order of hundreds of years. The shallow aquifers in both villages that are high in As contain bomb-³H and bomb-¹⁴C, indicating recent recharge. The major and minor ion compositions of the shallow and deeper aquifers also differ significantly. Deeper aquifer water is of the Na⁺-HCO₃^- type, with relatively little dissolved NH₄⁺ (76 ± 192 μmol/L), Fe (27 ± 43 μmol/L) and Mn (3 ± 2 μmol/L). In contrast, shallow aquifer water is of the Ca²⁺-Mg²⁺-HCO₃^- type, with elevated concentrations of dissolved NH₄⁺ (306 ± 355 μmol/L), Fe (191 ± 73 μmol/L), and Mn (27 ± 43 μmol/L). In both villages, the quantity of As extractable from deeper aquifer sands with a 1 mol/L phosphate solution (0.2 ± 0.3 mg/kg, n = 12; 0.1 ± 0.1 mg/kg, n = 5) is 1 order of magnitude lower than P-extractable As from shallow deposits (1.7 ± 1.2 mg/kg, n = 9; 1.4 ± 2.0 mg/kg, n = 11). The differences suggest that the concentration of P-extractable As in the sediment is a factor controlling the concentration of As in groundwater. Low P-extractable As levels are observed in both deeper aquifers that are low in As, even though there is a large difference in the time of deposition of these aquifers in the two villages. The geochemical data and hydrographs presented in this study suggest that both Holocene and Pleistocene deeper aquifers that are low in As should be a viable source of drinking water as long as withdrawals do not exceed recharge rates of ∼1 cm/yr.     

Direct evidence for nitrogen isotope discrimination during sedimentation and early diagenesis in Lake Kasumigaura, Japan

Sediment core samples from the center of Lake Kasumigaura, Japan, were collected from 1979 to 2007 at intervals of 1 month to 5 yr. We evaluated the degree of modification in N isotope composition during sedimentation and diagenesis. We estimated the degree of isotope discrimination during diagenesis by comparing historical changes in N isotope composition of the surface sediment (top 2 cm) against the vertical profile of the isotope composition of sediment core samples (15 cm depth). The degree of ¹⁵N enrichment during sedimentation appeared to be significant under the preferential N decomposition that occurred in the periods with low C/N ratio values of suspended particulate organic matter. We documented ¹⁵N depletion in sediment deeper than approximately 3 cm during diagenesis. The contrasting directions of N isotope discrimination during sedimentation and diagenesis suggest changing mechanisms of isotopic shift across an oxidation-reduction boundary.     

Vertical sediment fluxes and wave-induced sediment resuspension in a shallow-water coastal lagoon

The present study describes variations in the vertical fluxes measured concurrently with sediment traps at both a shallow water (4 m) and a deeper water (7.5 m) position in a coastal lagoon in April 1995. A tripod equipped with five sediment traps (trap openings at 0.35 m, 0.75 m, 1.05 m, 1.40 m, and 1.80 m above the seabed) was placed at the shallow water position. This tripod was deployed three times during the study period and deployment periods varied between 2 d and 5 d. The second sediment trap, placed at the deep water position in the central part of the lagoon, measured vertical flux for intervals of 12 h at 1.4 m above the seabed. The horizontal distance between the sediment traps was 8 km. The average maximum vertical flux at the shallow water position reached 27.9 g m⁻² d⁻¹ during a period of high, westerly wind speeds, and a maximum vertical flux of 16.9 g m⁻² d⁻¹ was reached at the deep water position during a period of high, easterly wind speeds. Both strong resuspension events were closely related to increased wave shear stress derived from surface waves. Maximum wave-induced resuspension rate was 10 times higher at the shallow water position and 3.8 times higher at the deep water position compared with the net sedimentation rate in the lagoon. Small resuspension events occurred at the shallow water position during periods of increased current shear stress, Estimations of conditions for transport of sediment between shallow water and deep water showed that particles must be resuspended to a height between 3 m and 4 m and that current speeds must be higher than about 0.1 m s⁻¹. An average sedimentation rate of 3.8 g m⁻² d⁻¹ was obtained at the shallow water position during a period without wave shear stress and low current shear stress. This rate measured by sediment traps is similar to a net sedimentation rate in the lagoon of 4.4 g m⁻² d⁻¹, which was determined by radiocarbon dating of a sediment core (Kristensen et al. 1995).     

Progradation and retrogradation of the Medjerda delta during the 20th century (Tunisia,western Mediterranean)

The aim of this study is the reconstitution of the recent morpho-sedimentary evolution of the Medjerda River delta. We examine the spatio-temporal evolution of the Medjerda shoreline between 1936 and 2016 using satellite images, complemented by sedimentological and geochemical analyses and ²¹⁰Pbex and ¹³⁷Cs radiometric data. The general tendency of the shoreline evolution shows an increasing progradation (300 ± 12 m) between 1936 and 2016. Yet the mesoscale Net Shoreline Movement position (NSM) and the End Point Rate (EPR) reveal an erosion pattern estimated to be −20 m ± 0.15 m/yr during the period 1988–1999.The sedimentological analyses reveal four main lithostratigraphic units. The fine sand substratum layer (Md = 0.08 mm) decreases toward clay and silt facies (Md < 0.063 mm), rich in continental plant debris. The geochemical results reveal gradual incoming of the terrigenous component instead of marine deposits. The ¹³⁷Cs/²¹⁰Pbex radiometric dating confirms the functioning of the new river flow by the 1950s with the highest sedimentation rate being 3.3 cm/yr. Our results show that the Sidi-Salem dam impoundment (1981) led to a dramatic reduction of sediment discharge, a decrease of the grain size with nearly no more sand reaching the coast, and the shoreline retreat.     

Suspended sediment transport,sedimentation, and resuspension in Lake Houston,Texas: Implications for water quality

Lake Houston is a man-made reservoir located northeast of Houston, Texas. The purpose of this investigation was to document suspended sediment transport, sedimentation, and resuspension in the lake with a view towards estimating the influence of sedimentation on water quality. Sediment traps were placed in strategic locations in the lake to collect suspended sediments. Samples were analyzed for bulk density, grain size, organic carbon, and a number of trace elements. These data were analyzed along with meteorological data to examine those factors which regulate suspended sediment input and dispersal, and the role of suspended sediments in controlling water quality within the lake. Sediment input to the lake depends primarily on the intensity of rainfall in the watershed. Sediment movement within the lake is strongly influenced by wave activity, which resuspends sediments from shallow areas, and by wind-driven circulation. The increased residence time of suspended sediments due to resuspension allows greater decomposition of organic matter and the release of several trace elements from sediments to the water column. Virtually all samples from sediment traps suspended between 1 and 5 m above the lake bottom contain medium to coarse silt, and even some very fine sand-sized material. This implies that circulation in Lake Houston is periodically intense enough to transport this size material in suspension. During winter, northerly winds with sustained velocities of greater than 5 m/sec provide the most suitable condition for rapid (<1 d) transport of suspended sediment down the length of the lake. Fluctuations in current velocities and the subsequent suspension/deposition of particles may explain variations in the abundance of coliform bacteria in Lake Houston.     

Recent and subrecent sedimentary conditions in the southern part of the North Sea–Baltic Sea transition

The recent rate of net sedimentation (0–5mm/yr) in the southern Kattegat is to a high degree governed by resuspension. In shallow areas (10–25 m) there is no or very little sedimentation. Sediments here are sandy lag sediments with a low content of organic matter (0.5–3.0%), nitrogen (0–0.1%) and phosphorus (0.01–0.05%). In deep water (30–60 m) the sediments are clays or fine silts and generally have high contents of organic matter (3.0–10.8%), nitrogen (0.1–0.34%) and phosphorus (0.05–0.10%). Shallow water sediments are relatively well sorted because of resuspension of fine material, which is transported to deeper water. Here the sorting becomes poor because relatively coarser material is supplied during exceptional storm events. Discrimination on erosion/transport bottoms and on depositional bottoms was based on resuspension calculations, grain-size parameters and Passegas (1964) CM diagrams. The IG/N ratio was an useful additional tool. From the sediment content of CaCO₃ it is suggested that recent sedimentation in the deeper parts of southern Kattegat is less influenced by contributions from the North Sea than it was during the early Holocene.     

Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study

The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m^?2d^?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited.     

Radiocarbon Geochemistry of Modern and Ancient Arctic Lake Systems, Baffin Island, Canada

The accuracy of Arctic lake chronologies has been assessed by measuring the¹⁴C activities of modern carbon sources and applying these isotopic mass balances to dating fossil lake materials. Small (<1 km²) shallow (<25 m) Arctic lakes with watersheds <12 km²have soil and peat stratigraphic sections with¹⁴C activities ranging from 98 to 51% Modern. The¹⁴C activity of particulate organic carbon, dissolved organic carbon, and dissolved inorganic carbon from lake and stream waters ranges from 121 to 95% Modern. The sediment–water interface of the studied lakes shows consistent¹⁴C ages of ∼1000¹⁴C yr, although the¹⁴C activity of living aquatic vegetation is 115% Modern. Radiocarbon measurements of components of the lacustrine carbon pool imply that the ∼1000¹⁴C yr age of the sediment–water interface results from deposition of¹⁴C-depleted organic matter derived from the watershed.     

Rates of sediment accumulation in pollen cores from small lakes and mires of eastern North America

Data from 291 small lakes and mires in eastern North America provide information on the natural variability of rates of sediment accumulation in these environments over the last 18,000 yr. Accumulation rates were calculated by linear interpolation between radiocarbon and biostratigraphic dates from sediment cores taken for pollen analysis. Within the data set, the rates were lognormally distributed with a mean accumulation rate of 91 cm/10³ yr, and a range from less than 1 to over 3500 cm/10³ yr. The accumulation rate data were divided into five subsets that were temporally or spatially distinct and therefore represent different geomorphic and climatic conditions at the time of deposition. Sediments deposited in basins north of 50°N, south of 40°N, and before 10,000 yr B.P. accumulated at much slower rates than sediments accumulating in midlatitude basins (between 40° and 50°N) between 10,000 and 330 yr B.P. Sediment accumulation over the last 330 yr has, on average, been at rates four to five times faster than any time previously. Inorganic sediments that could be radiocarbon-dated have accumulated at significantly lower rates than organic sediments, reflecting differences in depositional processes. For midlatitude basins during the Holocene, the most likely rate of continuous sediment accumulation within our data set is 65 cm/10³ yr. Rates below 10 cm/10³ yr are likely to be associated with nonconstant processes of sediment accumulation.     

Sediment-water oxygen and nutrient exchanges along the longitudinal axis of Chesapeake Bay: Seasonal patterns,controlling factors and ecological significance

Sediment-water oxygen and nutrient (NH₄ ⁺, NO₃ ^?+NO₂ ^?, DON, PO₄ ^3?, and DSi) fluxes were measured in three distinct regions of Chesapeake Bay at monthly intervals during 1 yr and for portions of several additional years. Examination of these data revealed strong spatial and temporal patterns. Most fluxes were greatest in the central bay (station MB), moderate in the high salinity lower bay (station SB) and reduced in the oligohaline upper bay (station NB). Sediment oxygen consumption (SOC) rates generally increased with increasing temperature until bottom water concentrations of dissolved oxygen (DO) fell below 2.5 mg l^?1, apparently limiting SOC rates. Fluxes of NH₄ ⁺ were elevated at temperatures >15°C and, when coupled with low bottom water DO concentrations (<5 mg l^?1), very large releases (>500 μmol N m^?2 h^?1) were observed. Nitrate + nitrite (NO₃ ^?+NO₂ ^?) exchanges were directed into sediments in areas where bottom water NO₃ ^?+NO₂ ^? concentrations were high (>18 μM N); sediment efflux of NO₃ ^?+NO₂ ^? occurred only in areas where bottom water NO₃ ^?+NO₂ ^? concentrations were relatively low (<11 μM N) and bottom waters well oxygenated. Phosphate fluxes were small except in areas of hypoxic and anoxic bottom waters; in those cases releases were high (50–150 μmol P m^?2 h^?1) but of short duration (2 mo). Dissolved silicate (DSi) fluxes were directed out of the sediments at all stations and appeared to be proportional to primary production in overlying waters. Dissolved organic nitrogen (DON) was released from the sediments at stations NB and SB and taken up by the sediments at station MB in summer months; DON fluxes were either small or noninterpretable during cooler months of the year. It appears that the amount and quality of organic matter reaching the sediments is of primary importance in determining the spatial variability and interannual differences in sediment nutrient fluxes along the axis of the bay. Surficial sediment chlorophyll-a, used as an indicator of labile sediment organic matter, was highly correlated with NH₄ ^?, PO₄ ^3?, and DSi fluxes but only after a temporal lag of about 1 mo was added between deposition events and sediment nutrient releases. Sediment O:N flux ratios indicated that substantial sediment nitrification-denitrification probably occurred at all sites during winter-spring but not summer-fall; N:P flux ratios were high in spring but much less than expected during summer, particularly at hypoxic and anoxic sites. Finally, a comparison of seasonal N and P demand by phytoplankton with sediment nutrient releases indicated that the sediments provide a substantial fraction of nutrients required by phytoplankton in summer, but not winter, especially in the mid bay region.     

Diagenetic cycling of arsenic in the sediments of eutrophic Baldeggersee,Switzerland

Sedimentation and benthic release of As was determined in Baldeggersee, a eutrophic lake in central Switzerland. Sediment traps recorded As sedimentation during 1994, including a flood event in spring. Diagenetic processes were studied using porewater profiles at the sediment–water interface and in deeper sediment strata deposited in the mesotrophic lake (before 1885). Sediment cores were used to calculate the accumulation and to construct the balance of sedimentation and remobilisation. The results showed that the lake sediment acts as an efficient sink for As. Only 22% of the particulate As flux reaching the sediment surface was remobilised at the sediment–water interface. The As accumulation in the recent varved section of the eutrophic lake was 40 mg As m⁻² a⁻¹. Iron reduction in older sediment caused a remobilisation of 1.2 mg As m⁻² a⁻¹. This upward flux from the deeper sediment was quantitatively immobilised in the recent sulfidic sediments. The flood event in spring contributed about 34% of the yearly sediment load and led to distinct peak profiles of dissolved As in the porewater. This evidence for rapid remobilisation disappeared within months.     

Early to mid-Holocene Atlantic water influx and deglacial meltwater events, Beaufort Sea slope, Arctic Ocean

Holocene high-resolution cores from the margin of the Arctic Ocean are rare. Core P189AR-P45 collected in 405-m water depth on the Beaufort Sea slope, west of the Mackenzie River delta (70°33.03′N and 141°52.08′W), is in close vertical proximity to the present-day upper limit of modified Atlantic water. The 5.11-m core spans the interval between ∼6800 and 10,400 ¹⁴C yr B.P. (with an 800-yr ocean reservoir correction). The sediment is primarily silty clay with an average grain-size of 9 φ. The chronology is constrained by seven radiocarbon dates. The rate of sediment accumulation averaged 1.35 mm/yr. Stable isotopic data (δ¹⁸O and δ¹³C) were obtained on the polar planktonic foraminifera Neogloboquadrina pachyderma (s) and the benthic infaunal species Cassidulina neoteretis. A distinct low-δ¹⁸O event is captured in both the benthic and planktonic data at ∼10,000 ¹⁴C yr B.P.—probably recording the glacial Lake Agassiz outburst flood associated with the North Atlantic preboreal cold event. The benthic foraminifera are dominated in the earliest Holocene by C. neoteretis, a species associated with modified Atlantic water masses. This species decreases toward the core top with a marked environmental reversal occurring ∼7800 ¹⁴C yr B.P., possibly coincident with the northern hemisphere 8200 cal yr B.P. cold event.     

U-Series Chronology of Lacustrine Deposits in Death Valley, California

Uranium-series dating on a 186-m core (DV93-1) drilled from Badwater Basin in Death Valley, California, and on calcareous tufas from nearby strandlines shows that Lake Manly, the lake that periodically flooded Death Valley during the late Pleistocene, experienced large fluctuations in depth and chemistry over the last 200,000 yr. Death Valley has been occupied by a long-standing deep lake, perennial shallow saline lakes, and a desiccated salt pan similar to the modern valley floor. The average sedimentation rate of about 1 mm/yr for core DV93-1 was punctuated by episodes of more-rapid accumulation of halite. Arid conditions similar to the modern conditions prevailed during the entire Holocene and between 120,000 and 60,000 yr B.P. From 35,000 yr B.P. to the beginning of the Holocene, a perennial saline lake existed, over 70 m at its deepest. A much deeper and longer lasting perennial Lake Manly existed from about 185,000 to 128,000 yr B.P., with water depths reaching about 175 m, if not 330 m. This lake had two significant “dry” excursions of 10²–10³yr duration about 166,000 and 146,000 yr B.P., and it began to shrink to the point of halite precipitation between 128,000 and 120,000 yr B.P. The two perennial lake periods correspond to marine oxygen isotopic stages (OIS) 2 and 6. Based on the shoreline tufa ages, we do not rule out the possible existence 200,000 yr ago of yet a third perennial lake comparable in size to the OIS 6 lake. The²³⁴U/²³⁸U data suggest that U in tufa owes its origin mainly to Ca-rich springs fed by groundwater that emanated along lake shorelines in southern Death Valley, and that an increase of this spring-water input relative to the river-water input apparently occurred during OIS 6.     

Hydrodynamics and sediment dynamics of The Wash embayment, eastern England

Water and sediment movement in The Wash embayment has been determined from an extensive set of data, consisting of tidal current readings and suspended sediment concentration measurements. Instantaneous and residual currents in the embayment show a distinct lateral inhomogeneity, whereas vertically the water column is almost homogenous. The central deep water area (30–40 m) of the embayment is dominated by a residual landward water movement, whilst on the margins, the residual movement is seaward. Sediment is supplied predominantly in suspension from the north, through the northern extremity of Boston Deep. Suspended sediment pathways are coincident with the spring tide water movements and the subtidal channels act as the main conduits. Approximately 6·8 × 10⁶ tonnes yr^?1 of suspended sediments are supplied to the embayment from offshore areas. Bedload sediment supply is of lesser importance, ～ 1·4 × 10⁴ tonnes yr^?1. Whereas suspended sediment movement appears to be the dominant mode of transport throughout the embayment, bedload transport is important in reforming the sea bed into a variety of bedforms which are particularly well developed on the margins of channels and shoals.     

A study on the hydrogeology and hydrogeochemistry of groundwater from different depths in a coastal aquifer: Annamalai Nagar,Tamilnadu, India

Chemical characterization of groundwater is essential to bring out its nature and utility. Samples from shallow and deep ground water of the same location were collected and studied for their geochemical characteristics following standard procedures (APHA 1998). Sediment samples from different depths were collected and analysed for minerals using FTIR and SEM. Resisitivity logging was carried out in the bore well to understand the variations in depth to fresh water potential. The shallow ground water is dominated by Na–Cl–HCO₃–SO₄ and deeper groundwater by Na–HCO₃–SO₄–Cl types. It is observed that there is a significant ionic variation with depth. The ionic strength of the deeper samples is lesser than in the shallower samples. Wide pH variations in the shallow water samples are due to ion exchange process. Thermodynamic stability plot was used to identify the state of stability. It is inferred that there is no major significant difference in the thermodynamic state of stability in the shallow and the deeper aquifers as the aquifer matrix for the shallow and deeper aquifers are almost similar. Saturation index of Gibbsite, Kaolinite, Calcite, Dolomite and anhydrite, were studied for shallow and deep aquifers, to identify the difference in hydro chemical signatures. The Si/Al ratios of shallow samples are less when compared with the deeper samples. Leaching of secondary salts was the chief mechanism controlling the ground water chemistry of the region.     

Effects of sediment slurry enrichment on salt marsh rehabilitation: Plant and soil responses over seven years

In deltaic marshes, mineral sediment promotes positive elevation change and counters subsidence and sea level rise. In many such marshes sediment deficits result in wetland loss. One new way to address sediment deficiency is to supply marshes with sediments in a slurry that deposits the sediment in a thin layer over a large area. The long-term effects of this strategy are poorly understood. In a rapidly submerging,Spartina alterniflora salt marsh, we tested how different amounts of sediment ameliorated the effects of sea level rise and subsidence over 7 yr (1992–1998). Sediment slurry enrichment likely affected plants and soils by two mechanisms. It increased elevation and soil bulk density, leading to increased plant vigor and soil condition. These effects were long lasting, such that by 1998 areas receiving moderate amounts of sediment (5–12 cm relative elevation) had better plant vigor and soil condition compared to areas not receiving sediment (55% cover versus 20%; bulk densities of 0.4–1.0 g cm⁻³ versus 0.2 g cm⁻³; 0 mM hydrogen sulfide versus > 1.0 mM). The sediment slurry also had high nutrient content, which resulted in a pulse of growth, especially in areas receiving the most sediment (areas > 12 cm relative elevation initially had >90% cover and canopy heights >1.6 m). This nutrient-induced growth spurt was short lived and faded after 3 yr, at which point the long lasting effects of increased elevation probably became the dominant factor promoting plant vigor and soil condition. Moderate levels of sediment generated the most beneficial and long lasting effects to the vegetation and soils. This degree of sediment slurry addition countered the effects of subsidence and sea level rise, but not so much as to surpass the intertidal position to whichS. alterniflora is best adapted.     

Climate change in southern Illinois, USA, based on the age and δC of organic matter in cave sediments

Matrix-supported diamicton and uniform to laminated, silty, fine-grained sediment deposited from about 42,500 to 27,600 cal yr B.P. under slackwater conditions nearly filled two caves in southwestern Illinois. At some point, most of the sediment was flushed from the caves and from about 22,700 to 4000 cal yr B.P., floods deposited a drape of sandy and silty sediment on remnant slackwater successions, cobbly alluvium, and bedrock (especially from 7700 to 4000 cal yr B.P.). Clay mineral analyses of the slackwater cave sediment reveal a provenance of chiefly Petersburg Silt, a smectite- and illite-rich proglacial lacustrine unit present in the overlying Illinois Episode glacial succession. Today, remnants of the ancient subterranean slackwater deposits nearly fill several secondary passages and, in at least two locations, cover a cobble-mantled strath terrace 1.3 to 1.5 m above active stream channels. Slumping and sinkhole formation appear to have been important mechanisms for deposition of the ancient subterranean deposits. Slumping of these surficial deposits and associated vegetation can occur along the flanks of sinkholes (in addition to sinkhole formation) and enter caves; however, the finer organics, some of them comminuted during transport into the caves, become part of the cave alluvium. This finer organic fraction is the modern analog of the humified organic matter disseminated in slackwater sediment dated in this investigation by radiocarbon methods. Twenty-four ¹⁴C ages on humified organic matter provide chronologic control. The δ¹³C values of the organic matter reflect the proportion of C₄-type to C₃-type vegetation growing in and around swallets and sinkholes at the time of redeposition. Drought-tolerant C₄-type vegetation was more prevalent relative to C₃-type vegetation from 42,500 to 31,200 cal yr B.P. compared to conditions from 28,800 cal yr B.P. to the present. The δ¹³C values are consistent with the results from other investigations of speleothems and organic matter from loessial paleosols.     

Anthropogenic marker evidence for accelerated sedimentation in Lake Illawarra,New South Wales,Australia

The chronology of near-surface sediments in Lake Illawarra has been investigated using radiocarbon dating and anthropogenically derived substances including trace metals, ash, and¹³⁷Cs. Sediments at depths about 1 m below the water-sediment interface ranged in age from Modern to 786 calendar years bp on the basis of radiocarbon dating ofNotospisula trigonella valves. Multiple marker (for example ash-trace metals) depth-concentration sediment profiles yielded estimates of sedimentation rate ranging from 3 to 5 mm yr^–1 at Griffins Bay to more than 16 mm yr^–1 at Macquarie Rivulet. Sedimentation rates of approximately 10 mm yr^–1 appeared to be typical of the western and southwestern portions of the lagoon. Rates of sediment accretion, prior to catchment clearing, urbanization, and industrialization have been estimated at less than 1 mm yr^–1, thus indicating a general tenfold increase in sediment accumulation adjacent to the western foreshore caused by catchment development. Accelerated sedimentation in shallow coastal lagoons constitutes significant environmental impacts including shoaling, degradation of seagrass beds, and increased turbidity with consequent loss of aesthetic appeal. Management policy should be directed at attempts to reduce the amount of sediment input by the construction of strategically placed sediment retention ponds. Siltation within the shallow embayments of Lake Illawarra could be ameliorated by a carefully planned program of dredging.     

Oxygen Consumption in Permeable and Cohesive Sediments of the Gulf of Aqaba

Oxygen profiles were measured in the sediments of the Gulf of Aqaba (Red Sea), an oligotrophic marine system affected by episodic seasonal flash floods and intense aeolian dry deposition. Sediment cores were retrieved from shallow (15–45 m), intermediate (250–561 m) and deep (700 m) water sites of south–north and east–west transects. Dissolved oxygen concentrations were measured simultaneously by using microelectrodes and microoptodes immediately after sampling and after transportation. Oxygen penetration depths were found to increase from 2 to 5 mm at the shallow water sites with sandy permeable sediments to 10–21 mm at the deeper sites with cohesive muddy sediments. This increase corresponds to decrease in oxygen diffusive fluxes at the sediment–water interface and oxygen consumption rates with depth. Oxygen consumption rates exhibit local maxima at the oxic–anoxic sediment boundary, which may be attributed to oxygen reduction coupled to oxidation of dissolved Fe(II) and Mn(II) at deep and intermediate water sites and of hydrogen sulfide at shallow water sites. Microelectrodes and microoptodes measurements of cohesive sediments from deep and intermediate water sites yielded similar results. By comparison, the microoptodes displayed more robust measurements than microelectrodes in sandy near-shore sediments. This was attributed to their flexible fiber structure that is less likely to break or to abruptly displace sand particles. After transportation of sediment cores from Eilat to Beer Sheva followed by ≤?24-h storage, no changes in oxygen fluxes and consumption rates were detected.     

Trace metals and radionuclides reveal sediment sources and accumulation rates in Jordan Cove, Connecticut

Many small estuaries are influenced by flow restrictions resulting from transportation rights-of-way and other causes. The biogeochemical functioning and history of such systems can be evaluated through study of their sediments. Ten long and six short cores were collected from the length of Jordan Cove, Connecticut, a Long Island Sound subestuary, and analyzed for stratigraphy, radionuclides (¹⁴C, ²¹⁰Pb, ²²⁶Ra, ¹³⁷Cs, and ⁶⁰Co), and metals (Ag, Cd, Cu, Pb, Zn, Fe, and Al). For at least 3,800 yr, rising sea level has gradually inundated Jordan Cove, filling it with mud similar to that currently being deposited there. Long-term sediment accumulation in the cove averaged close to 0.1 cm yr⁻¹ over the last three millennia. Recent sediment accumulation rates decrease inland from 0.84 cm yr⁻¹ to 0.40 cm yr⁻¹, and are slightly faster than relative sea-level rise at this site (0.3 cm yr⁻¹). Similarity of depth distributions of trace metals was used to confirm relative sediment accumulation rates. ⁶⁰Co and Ag are derived from sources outside the cove and its watershed, presumably the Millstone nuclear power plant and regional contaminated sediments, respectively. The combined data suggest that Long Island Sound is an important source of sediment to the cove; a minor part of total sediment is supplied from the local watershed. Trace metal levels are strongly correlated with Fe but not with either organic matter or Al. Sediment quality has declined in the cove over the past 60 yr, but only slightly. Cu, Pb, and Zn data correlate strongly with Fe but not with either organic matter or aluminum. Ratios of Ag to Fe and to trace metals suggest that Ag in the cove is derived almost entirely from Long Island Sound. This result supports the notion that Fenormalized Ag can serve as a better tracer of some kinds of contamination than more common and abundant metals, like Cu, Pb, and Zn. *** DIRECT SUPPORT *** A01BY085 00008