温度对马尾藻及其油页岩混合物热解产气特性的影响

【目的】研究马尾藻及其油页岩混合物在不同温度下的热解产气特性。【方法】利用燃烧烟气污染物测试实验台,测量马尾藻及其油页岩混合物在温度区间400℃至800℃下CO和H_2的排放特性,包括峰值浓度、峰值时间和平均浓度。【结果】马尾藻以及其油页岩混合物的热解过程可分为慢速析出、快速析出和降速三个阶段。马尾藻单独热解实验中,排放的CO体积分数峰值达到10 367×10~(-6)。温度的升高有利于马尾藻在热解中CO和H_2的析出,反应的开始时间和完成时间均有所提前。在马尾藻与油页岩混合物的热解中,H2的析出在700℃时达到最高(体积分数峰值为1 254×10~(-6))。油页岩的加入迟滞了CO和H_2的排放时间。【结论】油页岩的加入有效减少马尾藻热解过程中CO的排放并缩短反应时间,提高效率节省能源,马尾藻与油页岩的混合热解具有良好的应用前景。     

山东泰莱凹陷姚庄地区油页岩特征及成因分析

为评价泰莱凹陷姚庄地区油页岩资源潜力,开展了6口地质井的钻探、二维地震勘探和多项油页岩的样品分析测试工作。根据油页岩分析测试资料,结合录井、测井、地震、沉积等研究成果,总结了油页岩主要特征,对该区油页岩成因进行了初步分析。结果表明:泰莱凹陷姚庄地区油页岩主要发育在大汶口组中段沉积时期的湖相沉积中,大汶口组中段油页岩矿层与地层产状一致,走向277°,倾向7°,倾角4°~5°,矿层顶板埋深108.40m,矿层底板埋深272.06m,厚度0.80~2.29m,平均岩石密度为1.90t/m^3,含油率3.12%~4.07%,平均含油率3.48%。     

黑龙江省油页岩资源特征及成矿条件研究

黑龙江省侏罗系、白垩系及第三系沉积盆地比较发育,具有形成油页岩的良好地质条件。油页岩是十分重要的油气资源替代产品,勘查开发油页岩资源作为补充能源,发展油页岩工业,培育矿业经济新的增长点,带动地方经济长足发展,具有十分重要的现实和战略意义。     

我省油页岩资源开发利用状况浅析

一、资源现状 我省针对油页岩矿产的地质调查和勘查程度很低,从我省油页岩地质工作情况看,历史上还没有对全省油页岩特征、分布、成因及资源潜力做过系统评价。     

昌乐五图煤田油页岩地质特征及质量分析

五图煤矿油页岩广泛分布于李家崖组的B段、C段和D段,以C段为主体,探明储量2.72亿t,是褐煤的伴生矿种。C段油页岩层密集,厚度大;D段上部含油页岩,但厚度小。油页岩焦油产率最高16.25%,最低5.43%,平均8.36%。基准发热量最高8.72MJ/kg,最低6.16MJ/kg,平均6.91MJ/kg。油页岩作为固态燃料,是汽油的替代能源,五图煤田油页岩资源的开发和利用前景广阔。     

原位开采油页岩技术获进展

吉林省开展的油页岩开发技术攻关日前取得进展。在扶余市三骏乡苗胜村,从地下300米处提取的棕褐色页岩油成功点火,标志着＂原位压裂化学干馏提取油页岩油气＂试验项目获得初步成功。据介绍,该技术解决了当前油页岩地上干馏工艺技术带来的环境污染问题,适合扶余地区埋藏深、岩层薄、品位低的油页岩开采。同时,该技术填补了我国原位开采油页岩技术空白。     

山东省油页岩资源特征及开发利用前景

随着石油资源可用量的不断减少,页岩气、油页岩、油砂与稠油作为一种新能源,近年来备受人们的重视。山东省存在着丰富的油页岩资源。近年来笔者通过收集前人相关资料、野外地质填图、钻探编录、典型矿区考察、关键样品化验分析等手段对其进行了初步研究,初步认识了山东地区油页岩的资源特征及其形成环境,对未来山东地区油页岩矿的预测及潜力的评价具有一定的指导与借鉴作用。     

铜川—延安地区油页岩资源评价获优

正中国地质调查局日前组织专家对"鄂尔多斯盆地南部铜川—延安地区三叠系油页岩资源调查评价"成果报告进行了审查。专家组对该成果报告综合评分93分,为优秀级。该项目是中国地质调查局下达的矿产资源调查评价工作项目,主要以油页岩及伴生矿资源潜力综合评价为目标,通过地质调查与油页岩钻探、油页岩地球物理探测(电法剖     

山东五图煤田古近纪李家崖组油页岩品质特征分析

为了查明昌乐县五图煤田古近纪李家崖组油页岩的分布及其品质特征,从沉积学、油气地质学等方面开展研究。五图煤田古近纪李家崖组可划分为4部分:上部含煤段(A),中部含煤段(B)、油页岩段(C)和下部含煤段(D)。该组油页岩主要发育在淡水湖相沼泽环境,油页岩发育层数较多,可达80余层,但单层厚度不大。基于对大量钻孔的油页岩厚度统计及相关的化验测试,研究发现:李家崖组油页岩总厚度在研究区中部靠近南侧F3断裂处厚度最大,向四周减薄;灰分平均含量60%左右,靠近北侧F1断裂处灰分较高;焦油产率平均约8.36%,靠近南部F3断裂附近产率较高;硫分平均含量2.14%,水分平均含量4.2%,硫分和水分含量整体表现为东南部高西北部低。综合研究可以发现,研究区中南部靠近F3的地区,油页岩厚度大、品质好,是五图煤田油页岩资源潜力区。     

巴彦扎嘎朗盆地下白垩统巴颜俄尔和图组油页岩沉积特征

文章通过巴彦扎嘎朗盆地下白垩统巴颜俄尔和图组油页岩赋矿层的沉积构造、生物化石等特征,对该组的沉积相进行划分,建立了沉积模式,并探讨了断陷盆地的形成以及盆地沉积相与油页岩生成的关系.     

测井技术在泰安姚庄油页岩勘探中的识别应用

油页岩是一种很有前景的油气资源,测井技术是油页岩矿勘探开发的关键技术。该文依托姚庄地区油页岩矿钻孔的测井工作,通过对典型钻孔zk002的测井资料进行分析对比,得出测井曲线的变化与岩层有机质含量的关系,识别出地层岩性,并定出含油页岩层厚度,其结果与地质岩心钻探结果基本一致,因此,测井技术能较好地识别含油页岩层。     

Design of database management system of oil shale resource evaluation based on GIS

Base on the oil shale data model,the authors analyz the four main data types and their mutual relations,grasped the focus on the oil shale data management,established UML visual demand model for oil shale resources in the field of evaluation,constructed three-tier system and developed oil shale resource evaluation database management system. The system can be used for managing oil shale data storage,enhancing the efficiency and quality of the oil shale resource evaluation.     

气测录井在页岩气勘查中的应用——以潍北凹陷昌页参1井为例

潍北凹陷是昌潍坳陷的次一级凹陷盆地,也是传统油气开采区。潍北凹陷孔店组二段沉积了较厚的暗色泥岩、泥页岩,多为良好的烃源岩,也是凹陷内页岩气的主要生、储层位。通过分析昌页参1井气测录井数据,并结合现场解析实验数据,系统阐述了应用录井采集数据综合判别油气层的方法,以及该方法在实际油、气层判别中的应用情况。研究表明,利用该方法可对页岩气富集层段含油气情况作出较为准确的判断。     

Test method and experimental research on resistance of oil shale under high temperature

Heating the oil shale by current underground to accomplish in-situ transformation process, is a viable direction. The electrical properties of oil shale under different temperatures, especially the resistance, become important. Charging oil shale underground to heat oil shale till kerogen’s decomposition temperature, then crude oil and other gases can be generated. The resistance of the oil shale samples was measured by Direct Current (DC) quadripole method to find out the variation rules of resistance value. In the experiments, oil shale presented its semiconductor property. When heated till 350℃-450℃, its resistance changed greatly, optional for heating and cracking. The porosity, oil content, media and composition affected the resistance largely.     

Application of sedimentary pyrite in paleo-environment:a case study of Meihe Formation

The indices related to sedimentary pyrite are widely used in paleo-environmental studies;however its application principles and flaws have not been presented in detail so far , therefore it is necessary to review the controlling factors of them .In this study the authors described the application principles in detail , including py-rite morphology, C/S ratio, DOP, size distribution, sulfur isotope, and further discussed the C-S-Fe system in oil shale in Meihe Formation which indicates oxic or suboxic conditions during oil shale deposition .The concen-tration of TOC and S in the oil shale in Meihe Formation is more than that in background mudstone , and the py-rite formation is limited by sulfate .Therefore studying the indices related to pyrite proves to be of great impor-tance.     

Highlights of the Messel Oil Shale

The Messel oil shale, Germany, was deposited in a maar crater that formed 47 million years ago. Since 1975 the Senckenberg Research Institute in Frankfurt am Main, has conducted systematic scientific excavations of this oil shale with much success. Besides plants and insects, more than 130 species of well-preserved fossil vertebrates like reptiles, fishes, birds and mammals have been found and have made Messel world-famous. Some examples of these vertebrates are presented.     

Highlights of the Messel Oil Shale

The Messel oil shale, Germany, was deposited in a maar crater that formed 47 million years ago. Since 1975 the Senckenberg Research Institute in Frankfurt am Main, has conducted systematic scientific excavations of this oil shale with much success. Besides plants and insects, more than 130 species of well - preserved fossil vertebrates like reptiles, fishes, birds and mammals have been found and have made Messel worldfamous. Some examples of these vertebrates are presented.