黑龙江争光金矿床方铅矿黄铁矿Rb-Sr年龄及地质意义

争光金矿床位于兴安地块东缘黑龙江省多宝山铜钼-金矿集区南东端,矿体产于早奥陶世闪长岩与下奥陶统多宝山组地层接触带及多宝山组中,为大型金矿.因缺乏精确的成矿年代学研究,其成矿时代一直存在争议.本文在争光金矿床地质背景和岩石矿物学研究的基础上,对矿区内12件矿石样品中共生矿物方铅矿和黄铁矿进行Rb-Sr同位素年代学研究.结...     

Isotopic equilibrium/disequilibrium in granites, metasedimentary rocks and migmatites (Damara orogen, Namibia)—a consequence of polymetamorphism and melting

The overwhelming part of the continental crust in the high-grade part of the Damara orogen of Namibia consists of S-type granites, metasedimentary rocks and migmatites. At Oetmoed (central Damara orogen) two different S-type granites occur. Their negative ε_Nd values (− 3.3 to − 5.9), moderately high initial ⁸⁷Sr/⁸⁶Sr ratios (0.714–0.731), moderately high ²⁰⁶Pb/²⁰⁴Pb (18.21–18.70) and ²⁰⁸Pb/²⁰⁴Pb (37.74–37.89) isotope ratios suggest that they originated by melting of mainly mid-Proterozoic metasedimentary material. Metasedimentary country rocks have initial ε_Nd of − 4.2 to − 5.6, initial ⁸⁷Sr/⁸⁶Sr of 0.718–0.725, ²⁰⁶Pb/²⁰⁴Pb ratios of 18.32–18.69 and ²⁰⁸Pb/²⁰⁴Pb ratios of 37.91–38.45 compatible with their variation in Rb/Sr, U/Pb and Th/Pb ratios. Some migmatites and residual metasedimentary xenoliths tend to have more variable ε_Nd values (initial ε_Nd: − 4.2 to − 7.1), initial Sr isotope ratios (⁸⁷Sr/⁸⁶Sr: 0.708–0.735) and less radiogenic ²⁰⁶Pb/²⁰⁴Pb (18.22–18.53) and ²⁰⁸Pb/²⁰⁴Pb (37.78–38.10) isotope compositions than the metasedimentary rocks. On a Rb–Sr isochron plot the metasedimentary rocks and various migmatites plot on a straight line that corresponds to an age of c. 550 Ma which is interpreted to indicate major fractionation of the Rb–Sr system at that time. However, initial ⁸⁷Sr/⁸⁶Sr ratios of the melanosomes of the stromatic migmatites (calculated for their U–Pb monazite and Sm–Nd garnet ages of c. 510 Ma) are more radiogenic (⁸⁷Sr/⁸⁶Sr: 0.725) than those obtained on their corresponding leucosomes (⁸⁷Sr/⁸⁶Sr: 0.718) implying disequilibrium conditions during migmatization that have not lead to complete homogenization of the Rb–Sr system. However, the leucosomes have similar Nd isotope characteristics than the inferred residues (melanosomes) indicating the robustness of the Sm–Nd isotope system during high-grade metamorphism and melting. On a Rb–Sr isochron plot residual metasedimentary xenoliths show residual slopes of c. 66 Ma (calculated for an U–Pb monazite age of 470 Ma) again indicating major fractionation of Rb/Sr at c. 540 Ma. However, at 540 Ma, these xenoliths have unradiogenic Sr isotope compositions of c. 0.7052, indicating depleted metasedimentary sources at depth. Based on the distinct Pb isotope composition of the metasedimentary rocks and S-type granites, metasedimentary rocks similar to the country rocks are unlikely sources for the S-type granites. Moreover, a combination of Sr, Nd, Pb and O isotopes favours a three-component mixing model (metasedimentary rocks, altered volcanogenic material, meta-igneous crust) that may explain the isotopic variabilty of the granites. The mid-crustal origin of the different types of granite emphasises the importance of recycling and reprocessing of pre-existing differentiated material and precludes a direct mantle contribution during the petrogenesis of the orogenic granites in the central Damara orogen of Namibia.     

Isotopic evidence of middle proterozoic magmatism from bombay high field: Implications to crustal evolution of western offshore of India

Precambrian granitic basement rocks obtained from well BH-36 of Bombay High Field, western offshore of India has been studied both by Rb-Sr and K-Ar dating methods. Seven basement samples chosen from two cores have yielded whole rock Rb-Sr isochron age of 1446 ± 67 Ma with an initial⁸⁷Sr/⁸⁶Sr ratio of 0.7062 ± 0.0012. This age has been interpreted as the formation/emplacement time of the granite. Two biotite fractions of different grain size separated from a sample CC6B2T have yielded Rb-Sr mineral isochron age of 1385 ± 21 Ma. However, these fractions when studied by K-Ar dating method have yielded slightly higher but mutually consistent ages of 1458 ± 43 Ma and 1465 ± 43 Ma, respectively. Further, two biotites separated from additional samples CC5B9T and CC6B3B have yielded K-Ar ages of 1452 ± 42 Ma and 1425 ± 40 Ma with an overall mean age of 1438 ± 19 Ma. This mean K-Ar age is indistinguishable from whole rock Rb-Sr isochron as well as mineral isochron age within experimental error. The similarity in the whole rock and biotite ages obtained by different isotopic methods suggests that no thermal disturbance has occurred in these rocks after their emplacement/formation around 1450 Ma ago. The present study provides the evidence for the existence of an important Middle Proterozoic magmatic event around 1400-1450 Ma on the western offshore of India which, hitherto, was thought to be mainly confined to the eastern Ghats, Satpura and Delhi fold belt of India. This finding may have an important bearing on the reconstruction of Proterozoic crustal evolution of western Indian shield.     

Mineral isotope evidence for the contemporaneous process of Mesozoic granite emplacement and gneiss metamorphism in the Dabie orogen

Kinetics of isotopic equilibrium in the mineral radiometric systems of igneous and metamorphic rocks is an important issue in geochronology. It turns out that temperature is the most important factor in dictating isotopic equilibrium or disequilibrium with respect to diffusion mechanism. Contemporaneous occurrence of Mesozoic granites and gneisses in the Dabie orogen of China allows us to evaluate the thermal effect of magma emplacement and associated metamorphism on mineral radiometric systems. Zircon U-Pb, mineral Rb-Sr and O isotope analyses were carried out for a Cretaceous granite and its host gneiss (foliated granite) from North Dabie. Zircon U-Pb dating gave consistently concordant ages of 127 ± 3 Ma and 128 ± 2 Ma for the granite and the gneiss, respectively. A direct correspondence in equilibrium state is observed between the O and Rb-Sr isotope systems of both granitic and gneissic minerals. Mineral O isotope temperatures correlate with O diffusion closure temperatures under conditions of slow cooling, indicating attainment and preservation of O isotope equilibrium in these minerals. The mineral Rb-Sr isochron of granite, constructed by biotite, feldspar, apatite and whole-rock with the O isotope equilibrium, yields a meaningful age of 118 ± 3 Ma, which is in accordance with the mineral Rb-Sr isochron age of 122 ± 1 Ma for the host gneiss. The consistency in both U-Pb and Rb-Sr ages between the granite and the gneiss suggests a contemporaneous process of crystallizing the zircons and resetting the Rb-Sr radiometric systems during magma emplacement and granite foliation. Whereas the zircon U-Pb ages for both granite and gneiss are interpreted as the timing of magma crystallization, the young Rb-Sr isochron ages record the timing of Sr diffusion closure during the slow cooling. Protolith of the gneiss crystallized shortly before intrusion of the granite, so that it was able to be foliated by voluminous emplacement of coeval mafic to felsic magmas derived by anatexis of orogenic lithospheric keel. Therefore, extensional collapse of collision-thickened crust at Early Cretaceous is suggested to trigger the post-collisional magmatism, which in turn serves as an essential driving force for the contemporaneous high-T deformation/metamorphism.     

超高压变质岩的放射性同位素体系及年代学方法

深刻理解同位素在超高压变质及退变质过程中的地球化学行为对获得超高压变质岩准确并有明确意义的年龄值是非常重要的。对 Sm-Nd,Rb-Sr 同位素体系,只有变质矿物同位素体系达到平衡才能给出精确有意义的等时线年龄。研究表明,与副变质岩互层的细粒榴辉岩的高压变质矿物之间,或者强退变质岩石的退变质矿物之间,其 Nd,Sr 同位素可以达到平衡;然而高压变质矿物与退变质矿物之间 Nd,Sr 同位素不平衡。由于全岩样品总是含有数量不等的退变质矿物,因此石榴石 全岩 Sm-Nd 法或多硅白云母 全岩 Rh-Sr 法将有可能给出无地质意义的年龄。通常低温榴辉岩的高压变质矿物之间存在Nd 同位素不平衡。超高压变质岩多硅白云母所含过剩 Ar 主要源于榴辉岩原岩中角闪石在变质分解时释放出来的放射成因 Ar。因此,不含榴辉岩的花岗片麻岩多硅白云母基本不含过剩 Ar。对变质锆石成因的准确判断是正确理解锆石 U-Ph 年龄意义的关键。本文对不同成因锆石的判别标志及年龄意义做了总结,并指出将阴极发光图形,锆石痕量元素组成及矿物包裹体鉴定相结合是进行锆石成因鉴定的有效方法。高压变质或退变质增生锆石组成单一,是理想变质定年对象。然而变质重结晶锆石域常是重结晶锆石和继承晶质锆石的混合区,因而给出混合年龄。只有完全变质重结晶锆石才能给出准确变质时代。     

河北平泉光头山碱性花岗岩体的形成时代

光头山碱性花岗岩体位于河北省与内蒙古自治区交界处的平泉县北部,地理坐标为东经118°27′北纬41°17′。岩体出露面积约20km²,四周为太古代变质岩(图1)。岩石为灰白色中细粒花岗结构,含椭圆状、次圆状的细粒暗色包体,还有晚期的含碱性矿物的伟晶囊状体。主要造岩矿物有碱性长石、石英、钠铁闪石、霓辉石,副矿物主要有钠铁非石(Aenigmatite)、羟铁云母、硅铈铁矿、褐帘石、星叶石等。     

中亚盆地钾盐矿床盐类矿物Rb-Sr同位素体系研究及其意义

中亚盆地钾盐矿床的形成时代目前被限定为晚侏罗世至早白垩世,较为宽泛.盐类矿物沉积之后若未被改造,可测定其形成时代;若被改造则可利用同位素测年研究其沉积后作用.为了得到中亚盆地钾盐矿床的形成时代和/或了解盐类矿物受到的后期改造过程,利用Rb-Sr同位素定年对矿床中的盐类矿物进行了测定.结果表明,无法形成可靠的Rb-Sr等...     

Re-Os Dating of Sulfides from the Volcanogenic Massive Sulfide Deposit at Gacun, Southwestern China

Abstract. The Re-Os isotopic compositions of sulfide ores were analyzed for the Gacun, a volcanogenic massive sulfide deposit in southwestern China, to constrain the timing of mineralization. Sulfide ores from the deposit have a wide range of Re and Os concentrations, varying from 80.2 to 1543.2 ppb and from 0.307 to 8.83 ppb, respectively, and yielded a limited field of high ¹⁸⁷Re/¹⁸⁸Os and high ¹⁸⁷Os/188Os ratios, ranging from 1452 to 3309 and from 5.77 to 13.24, respectively. All sulfide samples yielded an isochron with an age of 217±28 Ma and an initial ¹⁸⁷Os/¹⁸⁸Os ratio of around 0.52±0.73. The Re-Os isochron age agrees with ages previously constrained by the other isotopic dating of the host rocks and fossil strata for the deposit. The rhythmic variation in ¹⁸⁷Os/¹⁸⁸Os and ¹⁸⁷Re/¹⁸⁸Os ratios within massive sulfide zone records a complicated process for ore-forming fluids episodically vented into the brine pool on the Mesozoic seafloor.     

A 3.1 billion year old marble and the 87Sr/86Sr of late-Archean seawater

A marble band in the ≈ 2.75 Gyr old Ramagiri schist belt in the Dharwar craton of south India gave a Pb–Pb age of 3.075 ± 0.095 Gyr. The geochemical data, including high Sr and low Ba and Mn indicate seawater origin for the parent rock, and that there was insignificant geochemical exchange between the marble and the surrounding rocks. The calculated initial Nd isotopic composition and μ₁ indicate an older continental crustal source for the Nd and Pb. The initial ⁸⁷Sr/⁸⁶Sr of the marble is 0.70128, which is higher than the calculated mantle value at ≈ 3 Ga. Although pre-3 Gyr old marine carbonate rocks are thought to be buffered by mantle Sr, the Ramagiri marble contains evolved, crustal Sr. Despite this, the marble has the lowest measured ⁸⁷Sr/⁸⁶Sr among carbonates and represents one of the least radiogenic periods in seawater Sr isotope composition.     

Paleozoic migmatites affected by high-grade tertiary metamorphism in the central Alps (Valle Bodengo,Italy)

The Lepontine Gneiss Complex of southern Switzerland and northern Italy is characterized by high-grade metamorphism and intensive deformation of Alpine age with migmatites prevalent in the area with the highest metamorphic grade. Petrological and structural observations are generally inconclusive but indicate in some places an Alpine age for the migmatite formation. To determine the time of migmatite formation a geochronologic study was undertaken in one of the best exposed areas, the Valle Bodengo, Italy. Rb-Sr whole-rock errorchrons of intrusive migmatite phases and of two rather homogeneous granitoid gneiss bodies yield apparent ages between 280 and 350 m.y. They suggest a Hercynian or older igneous history for these rocks. The U-Pb ages of the euhedral zircons are highly discordant, but they do point to the presence of zircon components more than 450 m.y. old. The concordia-intercept ages are incompatible with the Rb-Sr data and the low initial ⁸⁷Sr/⁸⁶Sr ratios of about 0.706. These low initial ratios suggest that either the bulk of the granitoid material is not much older than Hercynian, or older crustal material was isotopically homogenized on a regional scale with rocks that had low Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios (e.g. the lower crust or upper mantle) during a Hercynian metamorphism. Rb-Sr small-scale whole-rock isochrons and tie lines of adjacent, lithologically different rock phases give Alpine ages, the best isochron yielding 22 m.y. This coincides with concordant U-Pb ages of monazites of 23 to 24 m.y. Rb-Sr mineral isoohrons (muscovite, biotite, feldspars, apatite) give ages of 18–21 m.y. Our interpretation is that this age pattern resulted due to rapid cooling after the climax of the last phase of the Alpine metamorphism and we conclude that high-grade metamorphic conditions existed during the upper Oligocene or early Miocene. Other investigators have suggested that the Alpine metamorphism had a climax 35–40 m.y. ago and that the younger mineral ages are a result of simple continuous cooling due to uplift. Based on this study and other recent geochronological studies in the Lepotine Gneiss Complex we suggest that there had to be a thermal maximum at about 20–25 m.y. The example of Valle Bodengo demonstrates that the areal coincidence of the zone of highest-grade metamorphism with the occurrence of migmatites does not necessarily mean that metamorphism and migmatite formation were coeval and related to each other.     

Dating the events of metamorphism and granitic magmatism in the Alpine orogen of Naxos (Cyclades,Greece)

An isotopic dating investigation (66 K-Ar and 34 Rb-Sr analyses) provided the geochronological framework for the Alpine events of metamorphism and granitic magmatism on Naxos. The oldest phase of high-pressure/medium-temperature metamorphism, M1, was dated by Rb-Sr and K-Ar analyses of paragonites, phengitic muscovites and muscovites at 45±5 Ma (Middle Eocene). Most of the record of the M1 phase has been eraded by a second phase of medium-pressure/high-temperature metamorphism, M2, which induced a metamorphic zonation with anatectic melting in the highest-grade part, the migmatite dome. Most K-Ar dates of M2 hornblendes, muscovites, biotites and tourmalines range from about 21 Ma in the lower-grade part (biotite-chloritoid zone) to about 11 Ma in the migmatite dome. From the pattern of K-Ar mineral dates it is concluded that the M2 phase took place 25±5 Ma ago (Late Oligocene/Early Miocene) and was followed by a prolonged cooling history until about 11 Ma ago (Late Miocene), when the ambient temperature in the migmatite dome had decreased to below 400–360 °C. A Rb-Sr whole-rock isochron analysis of a granodioritic mass dated the intrusion (and the associated M3 phase of contact-metamorphism) at 11.1±0.7 Ma (Late Miocene), with an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7112 ±0.0001. A local phase of low-grade retrograde metamorphism, M4, probably related to Late Alpine overthrusting, was dated at about 10 Ma (Late Miocene).     

Astronomical tuning of the Tortonian 87Sr/86Sr curve in the Mediterranean basin

ABSTRACT This work presents a detailed ⁸⁷Sr/⁸⁶Sr isotope curve for the interval 7.5–9.7 Ma obtained by a high-resolution analysis (sampling spacing of about 40 kyr) of an astronomically calibrated land-based sedimentary sequence exposed in the central Mediterranean area (Gibliscemi section, southern Sicily). The main aim is to verify a synchronous response of the Mediterranean seawater Sr isotope record to the oceanic forcing on the basis of multiple comparisons of the Gibliscemi record with published coeval ⁸⁷Sr/⁸⁶Sr curves. A good correlation with the ⁸⁷Sr/⁸⁶Sr data from the ODP site 926 (equatorial Atlantic ocean), considered to be the Sr chemostratigraphic reference section for the Late Miocene, and from the Pacific DSDP site 590B was registered. Conversely, the comparison of the Gibliscemi Sr isotope data with ⁸⁷Sr/⁸⁶Sr ratios from the coeval segment of the land-based Sardella section (eastern Mediterranean) shows important differences highlighting a local control on the seawater Sr isotope changes in semi-isolated subbasins within the Late Miocene Mediterranean.     

Electron microprobe dating of monazite from high-T shear zones in the São José de Campestre Massif, NE Brazil

The easternmost domain of the Borborema Province, northeastern Brazil, presents widespread, extensional-related high-temperature metamorphism during the Brasiliano (=Pan-African) orogeny. This event reached the upper amphibolite to granulite facies and provoked generalized migmatization of Proterozoic metapelitic rocks of the Seridó Group and tonalitic to granodioritic orthogneisses of the Archean to Paleoproterozoic basement. We report new geochronological data based on electron microprobe dating of monazite from metapelitic migmatite and leuconorite within the high-T shear zones that make up the eastern continuation of the huge E–W Patos shear belt. These data were also constrained by using the Sm–Nd isotopic systematic on garnet from a syntectonic alkaline granite and two garnet-bearing leucosomes. The results suggest an age of about 578 to 574 Ma for the peak of the widespread high-T metamorphism. This event is best recorded by Sm–Nd garnet-whole rock ages. The U–Th–Pb isotopes on monazite of the metapelitic migmatite show a younger thermal event at 553 ± 10 Ma. When compared to the Sm–Nd garnet-whole rock ages, the U–Th–Pb electron probe monazite ages seem to record an event of slightly lower temperatures after the peak of the high-T metamorphism. This may reflect the difference in the isotopic behavior of the geochronological methods employed. Otherwise, the U–Th–Pb ages on monazites could indicate an event not yet very well defined. In anyway, this paper reveals the partial or even complete re-opening and resetting of the U–Th–Pb isotopic system produced by the action of low-T Ca-rich fluid.     

Dating the exhumation of UHP rocks and associated crustal melting in the Norwegian Caledonides

U–Pb and Rb–Sr dating was undertaken in combination with P–T estimates to (1) constrain the time of ultrahigh-pressure (UHP) eclogite formation in the Stadlandet UHP province of Norway, (2) date later crustal melting–migmatization of the eclogite country gneisses, and (3) temporally trace post-migmatite cooling and retrogression under amphibolite facies metamorphic conditions. In contrast to earlier U–Pb studies which used accessory minerals from the gneisses, we focused on the direct dating of minerals defining the HP assemblage. For the eclogite, rutile and omphacite fractions were analyzed for U–Pb, and from an adjacent migmatite leucosome titanites and K-feldspar. For Rb–Sr dating, phengite was measured for the eclogite, and biotite for two leucosome layers of the migmatite–eclogite complex. A U–Pb age of 389±7 (2σ) Ma is obtained if the full set of 12 rutile and five omphacite analyses is regressed (MSWD: 16), and 389±2 Ma for those nine data which strictly satisfy isochron conditions (MSWD: 0.78). The 389-Ma age is interpreted to date equilibration and freezing of the eclogite paragenesis at maximum temperatures of 770 °C, reached during decompression to 1.8 GPa. Decompression from 2.8 to 1.8 GPa occurred in the partial melting domain of granitic crust, with the migmatites being dated at 375±6 Ma by titanite and K-feldspar from an eclogite-adjacent granitic leucosome. This titanite age also shows that the U–Pb chronometer in rutile is very robust to high temperatures—it remained a closed system for at least 14 million years, at temperatures in excess to 650 °C. After decompression and migmatization, exhumation is accompanied by rapid cooling to reach the 300 °C isograde by 357± 9 Ma, determined by a biotite isochron for a leucosome in a slightly shallower structural level. In considering that the time of maximum pressure is bracketed by early zircon crystallization during subduction and later omphacite–rutile equilibration in the eclogites, an exhumation rate of 5 mm/year is deduced for initial exhumation, occurring between 394 and 389 Ma. For subsequent cooling from 770 to 600 °C, we obtain a rate of 2.3±1.3 mm/year. First stages of exhumation most likely occurred under an overall compressional regime, whereas Devonian basin formation is associated to detachment movements during 389–375 Ma exhumation. This period of extension is followed by a much younger, decoupled thermal phase at 327±5 Ma, occurring under static conditions within very restricted zones, most likely in association with the circulation of fluid phases along old discontinuities. Initial isotopic signatures of Sr and Pb substantiate Paleo- to Meso-Proterozoic crust formation times of the Stadlandet UHP province precursor lithologies.     

Geochronology of Archaean gneisses and tonalites from north of the Frederikshåbs isblink,S.W. Greenland

The main rock types in the area north of the Frederikshåbs isblink are streaky gneisses, massive tonalites and ‘supracrustals’. The gneisses are thought to be the parent rocks of the tonalite and can be seen to merge into tonalite across a narrow zone of nebulite. Rb-Sr whole rock points from samples of gneiss and tonalite fall on a common isochron with an age of 2662 ± 116 m.y. (2σ) and initial ratio of 0.7032 ± 0.0008 (2σ) (half-life of ⁸⁷Rb = 50 b.y.). The uncertainties in the isochron could mask small age and initial ratio differences between the gneiss and tonalite. However, our present interpretation is that the isochron reflects a homogenization of Sr isotopes within and between the two rock types. The presence of two out of four K-feldspar points on the whole rock isochron is interpreted as evidence that the K-feldspar became closed to Sr isotope migration at the same time as the whole rocks. Subsequent local isotopic disturbance has resulted in a minor loss of radiogenic strontium from two of the samples. The interpretation of the K-feldspar as a product of the epidoteamphibolite facies metamorphism allows the conclusion that the whole rock-K-feldspar isochron is recording a Sr isotopic homogenization during this event and is not related to the formation of the gneiss or the tonalite. Rb-Sr closure ages of ca. 2515 m.y. for muscovite and ca. 1950 m.y. for biotite could be recording separate isotopic disturbances or the cessation of strontium isotope migration as the minerals cooled through their characteristic blocking temperatures. Zircons from both the gneiss and the tonalite have igneous morphological features. Their U-Pb systems are complex, however, and suggest a multistage history of isotopic disturbance. Whereas the zircon U-Pb and whole rock Rb-Sr results suggest a maximum age of approximately 3000 m.y. for the parent rocks of the gneiss and tonalite they do not entirely exclude the possibility that the rocks represent older crust in which the isotopic systems have been almost completely reset ca. 2700 m.y. ago.     

硫化物Rb-Sr同位素定年研究进展

针对金属矿床成矿年代确定混乱的问题,国内外许多矿床学家和同位素地球化学家对金属矿物常规同位素定年方法进行了有益的探索研究,尤其是对于矿石矿物以闪锌矿、方铅矿和黄铁矿为主的铅锌矿床,硫化物矿物Rb-Sr同位素定年方法显示出了其独特的优势。结合近几年开展的工作,总结国内外硫化物Rb-Sr同位素定年研究取得的成果、闪锌矿中Rb、Sr的赋存状态与定年机理以及定年适应性问题。采用闪锌矿Rb-Sr同位素组成数据拟合成等时线源自热液流体与闪锌矿之间Rb和Sr的不同分异作用,但并不是所有的闪锌矿均适合该定年技术。要成功获得年龄,需结合野外地质特征采集代表性的矿石样品,并在镜下鉴定基础上挑选合适的单矿物;在分析测试过程中,需尽可能去除次生包裹体和粘土矿物。     

A Gold-bearing Alkaline Pluton in Eastern Linxi District, Inner Mongolia: Its Geochemistry and Metallogenic Significance

Abstract: The Biliutai pluton, as the host of a small gold deposit, containing dark-gray enclaves, intruded into the Lower Permian volcanic-sedimentary formations in east Inner Mongolia, China. The host rocks and enclaves formed simultaneously at about 200 Ma (Rb–Sr isochron age with initial ⁸⁷Sr/⁸⁶Sr of 0.704). The _Nd (T) values for the enclaves (from +4.4 to +4.6) are similar to their host rocks (+3.2 to +4.8), although the values for the host rocks are relatively variable. Both enclaves and host rocks are enriched in large ion lithosphere elements and light rare earth elements but depleted in high field strength elements and heavy rare earth elements. These observations suggest that the magma was produced from subduction-modified mantle sources. The age of the mantle enrichment event, evaluated using depleted mantle Nd model ages, is 0.61 - 0.83 Ga. These geochemical characteristics constrain the metallogeny of the Biliutai pluton, and imply that the ore-forming materials probably were derived from lithospheric mantle.     

Geology and geochronology of the Arunta complex north of Ormiston Gorge,Central Australia

A major west‐trending lineament marked by a wide belt of highly deformed rocks (the Redbank Zone), lies in the Arunta Complex, north of the Amadeus Basin. Along its southern margin the Zone has been progressively affected by, and is hence older than, migmatization and granite intrusion. The migmatization event yields a Rb‐Sr isochron age of 1076 ± 50 m.y. Within the migmatite complex, relicts of a pre‐migmatite metasedimentary sequence around the Chewings Range yield a Rb‐Sr isochron age of 1620 ± 70 m.y. The migmatites are unconformably overlain by the basal unit of the Amadeus Basin sequence, the Heavitree Quartzite. The 1076 ± 50 m.y. date thus provides a maximum age for the start of sedimentation along the northern margin of the Basin. The existence of a major zone of weakness in the basement probably exerted a strong control on basement and cover deformation during the Palaeozoic Alice Springs Orogeny.     

Application of Laser Ablation ICP-MS to U-Th-Pb Dating of Monazite

Recent advances in laser ablation ICP-MS techniques allow accurate U-Th-Pb age dating of monazites that are as young as several tens of million years to a precision better than 2%. Accuracy of the age determinations has been improved by true real-time mass bias correction via nebulisation of a solution containing enriched ²³³U and natural Tl isotopes. The Tl-U tracer solution eliminates possible effects of variable sample matrices on the precision and accuracy of measured isotopic ratios. Mass bias corrections based on measured ²⁰⁵Tl/²³³U ratios in the tracer solution allow direct measurement of ²³⁵U in monazite. Combined with high-sensitivity laser ablation ICP-MS measurements, direct measurement of ²³⁵U particularly improves the precision of U-Pb dating of young monazites. Correction for laser-induced Pb/U and Pb/Th elemental fractionation is based on a mathematical treatment of time resolved count-rate data that is independent of laser ablation characteristics, does not require external standardisation and allows variable laser pit size or raster patterns for each measurement. The new procedures make the LA ICP-MS technique more flexible for in situ U-Th-Pb analysis.     

Strontium Isotope Analysis of Kimberlitic Groundmass Perovskite via LA-MC-ICP-MS

Strontium isotopic composition is a potentially powerful tracer in studies of kimberlitic rocks but the results from even the most carefully collected and stringently prepared bulk-rock samples are still hampered by contamination and alteration effects. Here we describe a LA-MC-ICP-MS technique which can obtain accurate, high precision Sr_i ratios from 50–150 μm kimberlitic groundmass perovskite without requiring time-consuming mineral separation procedures. Since perovskite is a robust magmatic phase with an extremely low Rb/Sr ratio, the effects of late-stage crustal contamination, post-emplacement alteration and age correction are minimised and results are more representative of primary melt compositions, while additionally preserving powerful grain-scale spatial and textural information. We demonstrate that the adopted protocol overcomes isobaric interferences from Kr⁺, Rb⁺, Er²⁺ and Yb²⁺, and that Ca dimers and Ca argides do not detectably affect the quality of ⁸⁷Sr/⁸⁶Sr ratios produced. To illustrate the utility of the technique, contrasting bulk-rock and in situ perovskite results from eleven Proterozoic kimberlites are documented.