Evaporation effects on the formation of martian gullies

In order to investigate the formation of martian gullies and the stability of fluids on Mars, we examined about 120 gully images. Twelve HiRISE images contained a sufficient number of Transverse Aeolian Ridges (TARs) associated with the gullies to make the following measurements: overall gully length, length of the alcove, channel and apron, and we also measured the frequency of nearby TARs. Six of the 12 images examined showed a statistically significant negative correlation between overall gully length (alcove, channel and apron length) and TAR frequency. Previous experimental work from our group has shown that at temperatures below ∼200 K, evaporation rate increases by about an order of magnitude as wind speed increases from 0 to ∼15 m/s. Thus the negative correlations we observe between gully length and dune frequency can be explained by formation at temperatures below ∼200 K where wind speed/evaporation is a factor governing gully length. In these cases evaporation of the fluid carving the gully was a constraint on their dimensions. Cases where there is no correlation between gully length and TAR frequency, can be explained by formation at temperatures >200 K. The temperatures are consistent with Global Circulation Model and Thermal Emission Spectrometer (TES) data for these latitudes. The temperatures suggested by these trends are consistent with the fluid responsible for gully formation being a strong brine, such as Fe₂(SO₄)₃ which has a eutectic temperature of ∼200 K. We also find that formation timescales for gullies are 10⁵-10⁶ years.     

Eutectic Brines on Mars: Origin and Possible Relation to Young Seepage Features

If the recently observed young gullies on Mars represent seeps or outflows of aqueous fluid, that fluid must be highly concentrated brine to be even moderately stable under current martian surface conditions. Such brines are to be expected in the megaregolith if an initial saline hydrosphere underwent evapoconcentration via water escape from the atmosphere, evolved into subsurface CaCl₂-enriched brines by chemical interaction with mafic rocks, and then froze until eutectic compositions were reached. Although most such brines would tend to sink deep into the megaregolith, they could be preserved locally at relatively high elevations as aquifers (or frozen paleoaquifers) perched between ground ice and crystalline salts.     

Gully formation on Mars: Two recent phases of formation suggested by links between morphology, slope orientation and insolation history

The unusual 80 km diameter Noachian-aged Asimov crater in Noachis Terra (46°S, 5°E) is characterized by extensive Noachian-Hesperian crater fill and a younger superposed annulus of valleys encircling the margins of the crater floor. These valleys provide an opportunity to study the relationships of gully geomorphology as a function of changing slope orientation relative to solar insolation. We found that the level of development of gullies was highly correlated with slope orientation and solar insolation. The largest and most complex gully systems, with the most well-developed fluvial landforms, are restricted to pole-facing slopes. In contrast, gullies on equator-facing slopes are smaller, more poorly developed and integrated, more highly degraded, and contain more impact craters. We used a 1D version of the Laboratoire de Météorologie Dynamique GCM, and slope geometries (orientation and angle), driven by predicted spin-axis/orbital parameter history, to assess the distribution and history of surface temperatures in these valleys during recent geological history. Surface temperatures on pole-facing slopes preferential for water ice accumulation and subsequent melting are predicted to occur as recently as 0.5-2.1 Ma, which is consistent with age estimates of gully activity elsewhere on Mars. In contrast, the 1D model predicts that water ice cannot accumulate on equator-facing slopes until obliquities exceed 45°, suggesting they are unlikely to have been active over the last 5 Ma. The correlation of the temperature predictions and the geological evidence for age differences suggests that there were two phases of gully formation in the last few million years: an older phase in which top-down melting occurred on equator-facing slopes and a younger more robust phase on pole-facing slopes. The similarities of small-scale fluvial erosion features seen in the gullies on Mars and those observed in gullies cut by seasonal and perennial snowmelt in the Antarctic Dry Valleys supports a top-down melting origin for these gullies on Mars.     

Degradation of mid-latitude craters on Mars

Recent geomorphic, remote sensing, and atmospheric modeling studies have shown evidence for abundant ground ice deposits in the martian mid-latitudes. Numerous potential water/ice-rich flow features have been identified in craters in these regions, including arcuate ridges, gullies, and small flow lobes. Previous studies (such as in Newton Basin) have shown that arcuate ridges and gullies are mainly found in small craters (∼2-30 km in diameter). These features are located on both pole-facing and equator-facing crater walls, and their orientations have been found to be dependent on latitude. We have conducted surveys of craters >20 km in diameter in two mid-latitude regions, one in the northern hemisphere in Arabia Terra, and one in the southern hemisphere east of Hellas basin. In these regions, prominent lobes, potentially ice-rich, are commonly found on the walls of craters with diameters between ∼20-100 km. Additional water/ice-rich features such as channels, valleys, alcoves, and debris aprons have also been found in association with crater walls. In the eastern Hellas study region, channels were found to be located primarily on pole-facing walls, whereas valleys and alcoves were found primarily on equator-facing walls. In the Arabia Terra study region, these preferences are less distinct. In both study regions, lobate flows, gullies, and arcuate ridges were found to have pole-facing orientation preferences at latitudes below 45° and equator-facing orientation preferences above 45°, similar to preferences previously found for gullies and arcuate ridges in smaller craters. Interrelations between the features suggest they all formed from the mobilization of accumulated ice-rich materials. The dependencies of orientations on latitude suggest a relationship to differences in total solar insolation along the crater walls. Differences in slope of the crater wall, differences in total solar insolation with respect to wall orientation, and variations in topography along the crater rim can explain the variability in morphology of the features studied. The formation and evolution of these landforms may best be explained by multiple cycles of deposition of ice-rich material during periods of high obliquity and subsequent modification and transport of these materials down crater walls.     

The role of arcuate ridges and gullies in the degradation of craters in the Newton Basin region of Mars

A survey of craters in the vicinity of Newton Basin, using high-resolution images from Mars Global Surveyor and Mars Odyssey, was conducted to find and analyze examples of gullies and arcuate ridges and assess their implications for impact crater degradation processes. In the Phaethontis Quadrangle (MC-24), we identified 225 craters that contain these features. Of these, 188 had gullies on some portion of their walls, 118 had arcuate ridges at the bases of the crater walls, and 104 contained both features, typically on the same crater wall. A major result is that the pole-facing or equator-facing orientation of these features is latitude dependent. At latitudes >44° S, equator-facing orientations for both ridges and gullies are prevalent, but at latitudes <44° S, pole-facing orientations are prevalent. The gullies and arcuate ridges typically occupy craters between ∼2 and 30 km in diameter, at elevations between −1 and 3 km. Mars Orbiter Laser Altimeter (MOLA) elevation profiles indicate that most craters with pole-facing arcuate ridges have floors sloping downward from the pole-facing wall, and some of these craters show asymmetry in crater rim heights, with lower pole-facing rims. These patterns suggest viscous flow of ice-rich materials preferentially away from gullied crater walls. Clear associations exist between gullies and arcuate ridges, including (a) geometric congruence between alcoves and sinuous arcs of arcuate ridges and (b) backfilling of arcuate ridges by debris aprons associated with gully systems. Chronologic studies suggest that gullied walls and patterned crater floor deposits have ages corresponding to the last few high obliquity cycles. Our data appear consistent with the hypothesis that these features are associated with periods of ice deposition and subsequent erosion associated with obliquity excursions within the last few tens of millions of years. Arcuate ridges may form from cycles of activity that also involve gully formation, and the ridges may be in part due to mass-wasted, ice-rich material transported downslope from the alcoves, which then interacts with previously emplaced floor deposits. Most observed gullies may be late-stage features in a degradational cycle that may have occurred many times on a given crater wall.     

The formation and evolution of youthful gullies on Mars: Gullies as the late-stage phase of Mars’ most recent ice age

Gullies are extremely young erosional/depositional systems on Mars that have been carved by an agent that was likely to have been comprised in part by liquid water [Malin, M.C., Edgett, K.S., 2000. Evidence for recent groundwater seepage and surface runoff on Mars. Science 288, 2330-2335; McEwen, A.S. et al., 2007. A closer look at water-related geologic activity on Mars. Science 317, 1706-1709]. The strong latitude and orientation dependencies that have been documented for gullies require (1) a volatile near the surface, and (2) that insolation is an important factor for forming gullies. These constraints have led to two categories of interpretations for the source of the volatiles: (1) liquid water at depth beneath the melting isotherm that erupts suddenly (“groundwater”), and (2) ice at the surface or within the uppermost layer of soil that melts during optimal insolation conditions (“surface/near-surface melting”). In this contribution we synthesize global, hemispheric, regional and local studies of gullies across Mars and outline the criteria that must be met by any successful explanation for the formation of gullies. We further document trends in both hemispheres that emphasize the importance of top-down melting of recent ice-rich deposits and the cold-trapping of atmospherically-derived H₂O frost/snow as important components in the formation of gullies. This provides context for the incorporation of high-resolution multi-spectral and hyper-spectral data from the Mars Reconnaissance Orbiter that show that (1) cold-trapping of seasonal H₂O frost occurs at the alcove/channel-level on contemporary Mars; (2) gullies are episodically active systems; (3) gullies preferentially form in the presence of deposits plausibly interpreted as remnants of the Late Amazonian emplacement of ice-rich material; and (4) gully channels frequently emanate from the crest of alcoves instead of the base, showing that alcove generation is not necessarily a product of undermining and collapse at these locations, a prediction of the groundwater model. We interpret these various lines of evidence to mean that the majority of gullies on Mars are explained by the episodic melting of atmospherically emplaced snow/ice under spin-axis/orbital conditions characteristic of the last several Myr.     

Evidence of gully formation by regional groundwater flow in the Gorgonum-Newton region (Mars)

The discovery of gullies on Mars suggests liquid water activity near the surface of the planet in recent times. Since liquid water is unstable under the present-day P-T martian conditions, the formation mechanisms of the gullies, and the source of the putative water, have been a matter of debate for the last years. To provide new insights into these matters, we have approached the problem studying the gullies in relation to their regional setting. A major point in our study relates to the geographic orientation of gullies, an aspect that has been previously regarded as a crucial matter in different models, and has profound implications regarding their origin. We present a comprehensive and detailed survey of the Gorgonum-Newton region, and a study of the Dao and Nirgal Vallis regions. The survey was carried out with the aid of 965 high-resolution MOC images (752 for Gorgonum-Newton, 102 for Nirgal Vallis and 111 for Dao Vallis regions), and MOLA-derived DEMs. We found that gullies display a clear regional pattern, geographically and topographically consistent with a decreasing regional slope. We interpret the results in terms of the existence of several groundwater flow systems operating at different scales, which ultimately may have led to gully formation by seepage at the slopes of craters and canyons. We suggest that aquifers discharging at gully systems may have recharged from the surface, in response to the melting of young partially eroded ice-rich deposits.     

Sorted clastic stripes, lobes and associated gullies in high-latitude craters on Mars: Landforms indicative of very recent, polycyclic ground-ice thaw and liquid flows

Self-organised patterns of stone stripes, polygons, circles and clastic solifluction lobes form by the sorting of clasts from fine-grained sediments in freeze-thaw cycles. We present new High Resolution Imaging Science Experiment (HiRISE) images of Mars which demonstrate that the slopes of high-latitude craters, including Heimdal crater - just 25 km east of the Phoenix Landing Site - are patterned by all of these landforms. The order of magnitude improvement in imaging data resolution afforded by HiRISE over previous datasets allows not only the reliable identification of these periglacial landforms but also shows that high-latitude fluviatile gullies both pre- and post-date periglacial patterned ground in several high-latitude settings on Mars. Because thaw is inherent to the sorting processes that create these periglacial landforms, and from the association of this landform assemblage with fluviatile gullies, we infer the action of liquid water in a fluvio-periglacial context. We conclude that these observations are evidence of the protracted, widespread action of thaw liquids on and within the martian regolith. Moreover, the size frequency statistics of superposed impact craters demonstrate that this freeze-thaw environment is, at least in Heimdal crater, less than a few million years old. Although the current martian climate does not favour prolonged thaw of water ice, observations of possible liquid droplets on the strut of the Phoenix Lander may imply significant freezing point depression of liquids sourced in the regolith, probably driven by the presence of perchlorates in the soil. Because perchlorates have eutectic temperatures below 240 K and can remain liquid at temperatures far below the freezing point of water we speculate that freeze-thaw involving perchlorate brines provides an alternative “low-temperature” hypothesis to the freeze-thaw of more pure water ice and might drive significant geomorphological work in some areas of Mars. Considering the proximity of Heimdal crater to the Phoenix Landing Site, the presence of such hydrated minerals might therefore explain the landforms described here. If this is the case then the geographical distribution of martian freeze-thaw landforms might reflect relatively high temperatures (but still below 273 K) and the locally elevated concentration of salts in the regolith.     

Indications of brine related local seepage phenomena on the northern hemisphere of Mars

Springtime low albedo features, called Dark Dune Spots, on the seasonal frost covered dunes on Mars between 77°N and 84°N latitude have been analyzed. Two groups of these spots have been identified: “small” and “large” ones, where large spots have diameters above 4 m, and complex internal structure. From these “large” spots branching seepage-like features emanate and grow on the steep slopes. They show a characteristic sequence of changes: first only wind-blown features emanate from them, while later a bright circular and elevated ring forms, and dark seepage-features start from the spots. These streaks grow with a speed between 0.3 m/day and 7 m/day respectively, first only from the spots, later from all along the dune crest.During this “seepage period” the temperature is between 150 K and 180 K at a 3-9 km spatial resolution scale, indicating that CO₂ ice-free parts must be present at the observed dark spots. Around the receding northern seasonal CO₂ cap, an annulus of water ice lags behind, which is probably present in the spots too where the CO₂ frost has sublimated. Our model estimates show in the present work and in Kereszturi et al. (Kereszturi, A., Möhlmann, D., Berczi, Sz., Ganti, T., Kuti, A., Sik, A., Horvath, A. [2009b]. Icarus 201, 492-503) that the warming driven by solar insolation may produce not only interfacial water, but also bulk brines around the dune grains. The brine can support the movement of liquids and dune grains, enhances the sublimation of CO₂ frost, and produce the dark features, as well as liquid modifies the optical properties of the surface.Signs of movement of dune material after the total defrosting of the terrain is also visible but it is uncertain because of the limit of resolution. In our previous work (Kereszturi et al., 2009b) we showed that resembling seepage-like streaks at the southern hemisphere might have been formed by ephemeral interfacial water, as well as these northern features. Such wet environments may have astrobiological importance too.     

Observations of martian gullies and constraints on potential formation mechanisms

The discovery of presumably geologically recent gully features on Mars (Malin and Edgett, 2000, Science 288, 2330-2335) has spawned a wide variety of proposed theories of their origin including hypotheses of the type of erosive material. To test the validity of gully formation mechanisms, data from the Mars Global Surveyor spacecraft has been analyzed to uncover trends in the dimensional and physical properties of the gullies and their surrounding terrain. We located 106 Mars Orbiter Camera (MOC) images that contain clear evidence of gully landforms, distributed in the southern mid and high latitudes, and analyzed these images in combination with Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) data to provide quantitative measurements of numerous gully characteristics. Parameters we measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, orientations, and present-day characteristics that affect local ground temperatures. We find that the number of gully systems normalized to the number of MOC images steadily declines as one moves poleward of 30° S, reaches a minimum value between 60°-63° S, and then again rises poleward of 63° S. All gully alcove heads occur within the upper one-third of the slope encompassing the gully and the alcove bases occur within the upper two-thirds of the slope. Also, the gully alcove heads occur typically within the first 200 meters of the overlying ridge with the exception of gullies equatorward of 40° S where some alcove heads reach a maximum depth of 1000 meters. While gullies exhibit complex slope orientation trends, gullies are found on all slope orientations at all the latitudes studied. Assuming thermal conductivities derived from TES measurements as well as modeled surface temperatures, we find that 79% of the gully alcove bases lie at depths where subsurface temperatures are greater than 273 K and 21% of the alcove bases lie within the solid water regime. Most of the gully alcoves lie outside the temperature-pressure phase stability of liquid CO₂. Based on a comparison of measured gully features with predictions from the various models of gully formation, we find that models involving carbon dioxide, melting ground ice in the upper few meters of the soil, dry landslide, and surface snowmelt are the least likely to describe the formation of the martian gullies. Although some discrepancies still exist between prediction and observation, the shallow and deep aquifer models remain as the most plausible theories. Interior processes involving subsurface fluid sources are generally favored over exogenic processes such as wind and snowfall for explaining the origin of the martian gullies.     

Interfacial liquid water on Mars and its potential role in formation of hill and dune gullies

Gullies are among the most intriguing structures identified on the surface of Mars. Most common are gullies located on the slopes of craters which are probably formed by liquid water transported by shallow aquifers (Heldmann, J.L., Carlsson, E., Johansson, H., Mellon, M.T., Toon, O.B. [2007]. Icarus 188, 324-344). Two particular types of gullies are found on slopes of isolated hills and dunes. The hill-slope gullies are located mostly at 50°S, which is at the high end of latitudes of bulk of the gullies found so far. The dune gullies are found in several locations up to 65°S (Reiss, D., Jaumann, R., Kereszturi, A., Sik, A., Neukum, G. [2007]. Lunar Planet. Sci. XXXVIII. Abstract 1993), but the best known are those in Russel crater at 54°S. The hill and dune gullies are longer than others making the aquifers explanation for their formation unlikely (Balme, M., Mangold, N., Baratoux, D., Costard, F., Gosselin, M., Masson, P., Pnet, P., Neukum, G. [2006]. J. Geophys. Res. 111. doi:10.1029/2005JE002607). Recently it has been noted that thin liquid films of interfacial water can play a role in rheological processes on the surface of Mars (Moehlmann, D. [2008]. Icarus 195, 131-139. Kereszturi, A., Moehlmann, D., Berczi, Sz., Ganti, T., Kuti, A., Sik, A., Horvath, A. [2009]. Icarus 201, 492-503.). Here we try to answer the question whether interfacial liquid water may occur on Mars in quantities large enough to play a role in formation of gullies. To verify this hypothesis we have calculated thermal models for hills and dunes of various steepness, orientation and physical properties. We find that within a range of average expected values of parameters it is not possible to have more than a few monolayers of liquid water at depths greater than a centimeter. To create subsurface interfacial water film significantly thicker and hence to produce conditions for the slope instability, parameters have to be chosen to have their extreme realistic values or an additional source of surface heating is needed. One possibility for additional heating is a change of atmospheric conditions due to a local dust storm. We conclude that if interfacial water is responsible for the formation of the hill-slope gullies, our results may explain why the hill gullies are rare.     

Investigating gully flow emplacement mechanisms using apex slopes

The origin of the martian gullies has been much debated since their discovery by the Mars Orbiter Camera (MOC, Malin, M.C., Edgett, K.S. [2000]. Science 288, 2330-2335). Several previous studies have looked at slope gradients in and around gullies, but none have used Digital Elevation Models (DEMs) from the High Resolution Imaging Science Experiment (HiRISE, McEwen, A.S., and 14 colleagues [2007]. J. Geophys. Res. 112 (E05), E0505S02), which has a pixel scale down to 25 cm/pixel. We use five 1 m/post HiRISE DEMs to measure gully apex slopes, the local channel gradient at the upslope extent of the gully debris apron, which marks a shift from erosion to deposition. The apex slope provides information about whether a flow was likely a typical dry granular flow (begins depositing on slopes ∼21°) or fluidized by some extra mechanism (depositing on shallower slopes). We find that 72% of the 75 gully fans studied were likely emplaced by fluidized flows. Relatively old gullies appear more likely to have hosted fluidized flows than relatively fresh gullies. This suggests a time and location dependent fluidizing agent, possibly liquid water produced in a different climate as previously proposed. Our results do not provide evidence for water-rich flows in gullies today.     

A cold and wet Mars

Water on Mars has been explained by invoking controversial and mutually exclusive solutions based on warming the atmosphere with greenhouse gases (the “warm and wet” Mars) or on local thermal energy sources acting in a global freezing climate (the “cold and dry” Mars). Both have critical limitations and none has been definitively accepted as a compelling explanation for the presence of liquid water on Mars. Here is considered the hypothesis that cold, saline and acidic liquid solutions have been stable on the sub-zero surface of Mars for relatively extended periods of time, completing a hydrogeological cycle in a water-enriched but cold planet. Computer simulations have been developed to analyze the evaporation processes of a hypothetical martian fluid with a composition resulting from the acid weathering of basalt. This model is based on orbiter- and lander-observed surface mineralogy of Mars, and is consistent with the sequence and time of deposition of the different mineralogical units. The hydrological cycle would have been active only in periods of dense atmosphere, as having a minimum atmospheric pressure is essential for water to flow, and relatively high temperatures (over ∼245 K) are required to trigger evaporation and snowfall; minor episodes of limited liquid water on the surface could have occurred at lower temperatures (over ∼225 K). During times with a thin atmosphere and even lesser temperatures (under ∼225 K), only transient liquid water can potentially exist on most of the martian surface. Assuming that surface temperatures have always been maintained below 273 K, Mars can be considered a “cold and wet” planet for a substantial part of its geological history.     

Observations of martian gullies and constraints on potential formation mechanisms: II. The northern hemisphere

The formation process(es) responsible for creating the observed geologically recent gully features on Mars has remained the subject of intense debate since their discovery. We present new data and analysis of northern hemisphere gullies from Mars Global Surveyor data which is used to test the various proposed mechanisms of gully formation. We located 137 Mars Orbiter Camera (MOC) images in the northern hemisphere that contain clear evidence of gully landforms and analyzed these images in combination with Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) data to provide quantitative measurements of numerous gully characteristics. Parameters we measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, orientations, and present-day characteristics that affect local ground temperatures. Northern hemisphere gullies are clustered in Arcadia Planitia, Tempe Terra, Acidalia Planitia, and Utopia Planitia. These gullies form in craters (84%), knobby terrain (4%), valleys (3%), other/unknown terrains (9%) and are found on all slope orientations although the majority of gullies are equator-facing. Most gullies (63%) are associated with competent rock strata, 26% are not associated with strata, and 11% are ambiguous. Assuming thermal conductivities derived from TES measurements as well as modeled surface temperatures, we find that 95% of the gully alcove bases with adequate data coverage lie at depths where subsurface temperatures are greater than 273 K and 5% of the alcove bases lie within the solid water regime. The average alcove length is 470 m and the average channel length is 690 m. Based on a comparison of measured gully features with predictions from the various models of gully formation, we find that models involving carbon dioxide, melting ground ice in the upper few meters of the soil, dry landslide, and surface snowmelt are the least likely to describe the formation of the martian gullies. Although some discrepancies still exist between prediction and observation, the shallow and deep aquifer models remain as the most plausible theories. Interior processes involving subsurface fluid sources are generally favored over exogenic processes such as wind and snowfall for explaining the origin of the martian gullies. These findings gleaned from the northern hemisphere data are in general agreement with analyses of gullies in the southern hemisphere [Heldmann, J.L., Mellon, M.T., 2004. Icarus 168, 285-304].     

Erosional modification and gully formation at Meteor Crater, Arizona: Insights into crater degradation processes on Mars

Hydrogeological modification of Meteor Crater produced a spectacular set of gullies throughout the interior wall in response to rainwater precipitation, snow melting, and possible groundwater discharge. The crater wall has an exceptionally well-developed centripetal drainage pattern consisting of individual alcoves, channels, and fans. Some of the gullies originate from the rim crest and others from the middle crater wall where a lithologic transition occurs; broad gullies occur along the crater corner radial faults. Deeply incised alcoves are well developed on the soft Coconino Sandstone exposed on the middle crater wall, beneath overlying dolomite. In general, the gully locations are along crater wall radial fractures and faults, which are favorable locales of erosion due to preferential rock breakup from faulting, and groundwater flow/discharge; these structural discontinuities are also the locales where the surface runoff from rain precipitation and snow melting can preferentially flow, causing erosion and crater degradation. Channels are well developed on the talus deposits and alluvial fans on the periphery of the crater floor. Caves exposed on the lower crater level point to percolation of surface runoff and selective discharge through fractures on the crater wall. In addition, lake sediments on the crater floor provide significant evidence of a past pluvial climate, when the water table was higher, and groundwater may have seeped from springs on the crater wall. Although these hydrological processes continue at Meteor Crater today, conditions at the crater are much more arid than they were soon after impact, reflecting a climatic shift. This climate shift and the hydrological modifications observed at Meteor Crater provide insights for landscape sculpturing on Mars during various parts of its history.     

Annual survey of water vapor behavior from the OMEGA mapping spectrometer onboard Mars Express

We present here the annual behavior of atmospheric water vapor on Mars, as observed by the OMEGA spectrometer on board Mars Express during its first martian year. We consider all the different features of the cycle of water vapor: temporal evolution, both at a seasonal and at a diurnal scale; longitudinal distribution; and the vertical profile, through the variations in the saturation height. We put our results into the context of the current knowledge on the water cycle through a systematic comparison with the already published datasets. The seasonal behavior is in very good agreement with past and simultaneous retrievals both qualitatively and quantitatively, within the uncertainties. The average water vapor abundance during the year is ∼10 pr. μm, with an imbalance between northern and southern hemisphere, in favor of the first. The maximum of activity, up to 60 pr. μm, occurs at high northern latitudes during local summer and shows the dominance of the northern polar cap within the driving processes of the water cycle. A corresponding maximum at southern polar latitudes during the local summer is present, but less structured and intense. It reaches ∼25 pr. μm at its peak. Global circulation has some influence in shaping the water cycle, but it is less prominent than the results from previous instruments suggest. No significant correlation between water vapor column density and local hour is detected. We can constrain the amount of water vapor exchanged between the surface and the atmosphere to few pr. μm. This is consistent with recent results by OMEGA and PFS-LW. The action of the regolith layer on the global water cycle seems to be minor, but it cannot be precisely constrained. The distribution of water vapor on the planet, after removing the topography, shows the already known two-maxima system, over Tharsis and Arabia Terra. However, the Arabia Terra increase is quite fragmented compared with previous observations. A deep zone of minimum separates the two regions. The saturation height of water vapor is mainly governed by the variations of insolation during the year. It is confined within 5-15 km from the surface at aphelion, while in the perihelion season it stretches up to 55 km of altitude.     

Adsorptive fractionation of HDO on JSC MARS-1 during sublimation with implications for the regolith of Mars

A chamber was constructed to simulate the boundary between the ice table, regolith and atmosphere of Mars and to examine fractionation between H₂O and HDO during sublimation under realistic martian conditions of temperature and pressure. Thirteen experimental runs were conducted with regolith overlying the ice. The thickness and characteristic grain size of the regolith layer as well as the temperature of the underlying ice was varied. From these runs, values for the effective diffusivity, taking into account the effects of adsorption, of the regolith were derived. These effective diffusivities ranged from 1.8 × 10⁻⁴ m² s⁻¹ to 2.2 × 10⁻³ m² s⁻¹ for bare ice and from 2.4 × 10⁻¹¹ m² s⁻¹ to 2.0 × 10⁻⁹ m² s⁻¹ with an adsorptive layer present. From these, latent heats of adsorption of 8.6 ± 2.6 kJ mol⁻¹ and 9.3 ± 2.8 kJ mol⁻¹ were derived at ice-surface temperatures above 223 ± 8 K and 96 ± 28 kJ mol⁻¹ and 104 ± 31 kJ mol⁻¹ respectively for H₂O and HDO were derived at colder temperatures. For temperatures below 223 K, the effective diffusivity of HDO was found to be lower than the diffusivity of H₂O by 40% on average, suggesting that the regolith was adsorptively fractionating the sublimating gas with a fractionation factor of 1.96 ± 0.74. Applying these values to Mars predicts that adsorbed water on the regolith is enriched in HDO compared to the atmosphere, particularly where the regolith is colder. Based on current observations, the D/H ratio of the regolith may be as high as 21 ± 8 times VSMOW at 12°S and L_S = 357° if the regolith is hydrated primarily by the atmosphere, neglecting any hydration from subsurface ice.     

Extension of atmospheric dust loading to high altitudes during the 2001 Mars dust storm: MGS TES limb observations

Mars Global Surveyor (MGS) visible (solarband bolometer) and thermal infrared (IR) spectral limb observations from the Thermal Emission Spectrometer (TES) support quantitative profile retrievals for dust opacity and particle sizes during the 2001 global dust event on Mars. The current analysis considers the behavior of dust lifted to altitudes above 30 km during the course of this storm; in terms of dust vertical mixing, particle sizes, and global distribution. TES global maps of visible (solarband) limb brightness at 60 km altitude indicate a global-scale, seasonally evolving (over 190-240° solar longitudes, L_S) longitudinal corridor of vertically extended dust loading (which may be associated with a retrograde propagating, wavenumber 1 Rossby wave). Spherical radiative transfer analysis of selected limb profiles for TES visible and thermal IR radiances provide quantitative vertical profiles of dust opacity, indicating regional conditions of altitude-increasing dust mixing ratios. Observed infrared spectral dependences and visible-to-infrared opacity ratios of dust scattering over 30-60 km altitudes indicate particle sizes characteristic of lower altitudes (cross-section weighted effective radius, ), during conditions of significant dust transport to these altitudes. Conditions of reduced dust loading at 30-60 km altitudes present smaller dust particle sizes . These observations suggest rapid meridional transport at 30-80 km altitudes, with substantial longitudinal variation, of dust lifted to these altitudes over southern hemisphere atmospheric regions characterized by extraordinary (m/s) vertical advection velocities. By L_S=230° dust loading above 50 km altitudes decreased markedly at southern latitudes, with a high altitude (60-80 km) haze of fine (likely) water ice particles appearing over 10°S-40°N latitudes.     

Limits on the trapping of atmospheric CH4 in martian polar ice analogs

Recent detection of methane (CH₄) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH₄ on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH₄ gas. The ices were monitored for spectroscopic evidence of CH₄ trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH₄ in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH₄ was observed in the ice analogs studied at warmer temperatures (140 K for H₂O and CO₂ clathrate, 90 K for CO₂ snow) with approximately 10 mTorr CH₄ in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH₄. If it is assumed that the trapping mechanism is linear with CH₄ partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH₄ plume, and therefore does not represent a significant sink for CH₄.     

MARCI and MOC observations of the atmosphere and surface cap in the north polar region of Mars

We used MGS-MOC and MRO-MARCI daily mapping images of the North Polar Region of Mars from 16 August 2005 (L_s = 270°) to 21 May 2009 (L_s = 270°), covering portions of three consecutive martian years (MY 27-MY 29), to observe the seasonal behavior of the polar ice cap and atmospheric phenomena. The rate of cap regression was similar in MY 28 and MY 29, but was advanced by 3.5° of L_s (∼7-8 sols) in MY 29. The spatial and temporal behaviors of dust and condensate clouds were similar in the two years and generally in accord with prior years. Dust storms (>100 km²) were observed in all seasons, with peak activity occurring at L_s = 10-20° from 50°N to 70°N and at L_s = 135-140° from 70°N to 90°N. The most active quadrant was 0-90°W in MY 28, shifting to 180-270°W in MY 29. The majority of regional storms in both years developed in longitudes from 10°W to 60°W. During late summer the larger storms obscure the North Polar Region in a cloud of dust that transitions to north polar hood condensate clouds around autumnal equinox.Changes in the distribution of perennial ice deposits, especially in Olympia Planum, were observed between the 2 years, with the MY 29 ice distribution being the most extensive observed to date. Modeling suggests that the small, bright ice patches on the residual cap are not the result of slope or elevation effects. Rather we suggest that they are the result of local meteorological effects on ice deposition. The annual darkening and brightening of peripheral areas of the residual cap around summer solstice can be explained by the sublimation of a brighter frost layer revealing an underlying darker, ice rich layer that itself either sublimes to reveal brighter material below or acts as a cold trap, attracting condensation of water vapor that brightens the surface. An alternative explanation invokes transport and deposition of dust on the surface from the cap interior, and later removal of that dust. The decrease in cap albedo and accompanying increase in near surface atmospheric stability may be related to the annual minimum of polar storm activity near northern summer solstice.