Inverse magnetic fabric in carbonate-bearing rocks

The observation of a magnetic susceptibility ellipsoid whose maximum axis corresponds to the minimum axis of petrofabric (pole of bedding or schistosity) is referred to as an inverse magnetic fabric. The investigation of the magnetic properties of some ferroan carbonate monocrystals and paramagnetic limestones demonstrates thatc-axis preferred orientation of paramagnetic carbonates results in a maximum susceptibility parallel to the flattening direction.Inverse magnetic fabrics due to magnetite are also encountered in weakly deformed limestones. A mineralogical model based on the property of single-domain grains to have a zero susceptibility parallel to their long axis is proposed. However, more complex cases are also encountered.     

秦岭造山带晚三叠世糜署岭岩体的岩石磁学及磁组构可靠性约束

近年来,针对秦岭造山带晚三叠世花岗岩体侵位机制的巨大争议,一些研究采用磁组构方法分析了岩体的内部组构特征及其与区域构造的关系,提出了具有重要意义的新认识.然而,目前这些研究均缺乏对岩体磁组构本质意义的分析,利用该方法约束岩体内部组构的可靠性并不十分清晰.针对这一问题,本文以秦岭造山带内具典型代表性意义的晚三叠世糜署岭花岗岩体为例,开展了该岩体的磁组构、岩石磁学、矿物形态组构和显微构造的综合研究.结果表明,糜署岭岩体的磁化率总体较低,属钛铁矿系列花岗岩.绝大部分样品的磁化率受控于顺磁性的黑云母等铁镁硅酸盐矿物,部分高磁化率样品包含了少量多畴磁铁矿等铁磁性组分的贡献,且随磁化率增大,铁磁性组分的贡献更为明显.样品的磁组构也主要是黑云母组构或由黑云母与磁铁矿的亚组构复合而成.由于样品中磁铁矿含量较低且与黑云母密切共生,磁组构与黑云母形态组构基本一致,因此,黑云母与磁铁矿的亚组构基本共轴.糜署岭岩体的磁组构本质上等同于黑云母组构,反映了黑云母等页硅酸盐矿物在岩体中的分布,可以有效的指示岩体的内部构造特征.宏观和显微构造观察还显示,糜署岭岩体的内部组构形成于岩浆侵位的晚期阶段,叠加了同岩浆期区域构造的关键信息,是从岩体构造角度开展区域构造演化的良好载体.     

北京房山岩体的磁组构特征及其 对岩体侵位的约束

岩浆岩的磁组构与岩浆流动、侵位时应力和冷凝后遭受后期构造改造作用有关.本文分析了北京房山岩体东山口-凤凰亭剖面岩石磁化率各向异性(AMS)变化.热磁曲线和磁滞回线分析显示,岩石的主要载磁矿物为多畴磁铁矿颗粒.AMS磁化率椭球体呈压扁状,磁面理发育且产状陡倾,磁化率各向异性度P值平均值高达1.189.自边缘相(东山口)到中心相(凤凰亭),岩石磁化率椭球的扁率E值和形状因子T值逐渐减小,说明磁组构主要反映岩浆流动和岩体侵位时近NNE-SSW方向的挤压作用,在侵位冷凝后并没有遭受到明显的构造改造.     

Frequency-dependent susceptibility and other magnetic properties of Celtic and Mediaeval graphitic pottery from Bohemia: an introductory study

Frequency-dependent magnetic susceptibility, its anisotropy (AMS), its temperature variation, natural remanent magnetization and time-dependent isothermal remanent magnetization as well as M?ssbauer spectroscopy of a small collection of Celtic and Mediaeval graphitic pottery from Southern Bohemia were investigated. The mineral composition of the pottery is dominated by fragments of quartz, accompanied mainly by various silicates from granitoids and paragneisses, or by calcite, within the plastic component being probably illite but also graphite. No ferrimagnetic minerals were found in optical microscope, among Fe-oxides only limonite was observed, even though the bulk susceptibility of the pottery varies in the orders of 10^?4 to 10^?2 [SI]. This may indicate presence of ferromagnetic particles in the ultrafine (superparamagnetic, SP) state, which is confirmed by frequency-dependent susceptibility ranging from 3% to almost 16%. The low temperature susceptibility vs. temperature curves are only moderately sloped, showing the Verwey transition only in one case. The high temperature curves mostly show presence of two magnetic phases, maghemite and magnetite. Cooling curves show distinctly lower susceptibilities than the heating curves indicating instability of the assemblage of ferrimagnetic minerals, particularly in temperatures slightly under 700 °C. M?ssbauer spectroscopy confirmed the results of the frequency-dependent susceptibility, showing the increase of ferrimagnetic sextets in the spectra measured at 4.2K, likely indicating maghemite as the distinct ferrimagnetic phase. The frequency-dependent AMS indicates preferred orientation of SP1,16 particles, coaxiality between SP_1,16 grain AMS and whole specimen AMS indicate that all grains, ultrafine and coarser ones, were oriented by the same process, i.e. copying the pottery structure created during wheel-turning.     

Heating-induced changes in the anisotropy of magnetic susceptibility of impact breccias, Chicxulub Crater (Mexico)

Initial results of a thermal treatment study on the anisotropy of magnetic susceptibility (AMS) of impact breccias from Chicxulub crater are used to investigate the nature of the magnetic fabrics. Chicxulub impact breccias are heterogeneous materials, with carbonate, basement and melt clasts within carbonate-rich or melt-rich matrix. Samples studied come from the carbonate-rich basal unit Lower Suevite in the Yaxcopoil-1 borehole impactite sequence (core depth interval: 885?C895 m). The Lower Suevite is characterized by mixed prolate and oblate ellipsoids with shallow to steep principal susceptibility axes, which had been related to emplacement as an excavation flow with ground-surge components during the early cratering stages. Thermal treatment results in changes in the fabrics with a tendency to oblate fabrics. Stepwise thermal treatment up to 700°C reveals different behaviors for the oblate, neutral and prolate fabrics marked by changes in AMS parameters and principal susceptibility axis orientations. A sample with oblate fabrics and vertical minimum axes showed an increase of magnetic susceptibility at high temperatures, indicating formation of secondary magnetite and fabric enhancement. A sample with neutral ellipsoid showed heating-induced changes towards oblate fabrics and vertical minimum susceptibility axes. Samples characterized by prolate ellipsoids with horizontal maximum axes showed no directional changes. In a sample with apparent intermediate or inverse fabrics, vertical maximum axes showed changes to horizontal inclinations, with the intermediate and maximum axes switching positions. Changes induced by stepwise thermal treatment appear useful to characterize the fabrics of impact lithologies. Further investigation of heating-induced effects in mineralogy, grain size and textural changes is, however, required to relate the different behaviors observed after stepwise thermal treatment with the magnetic mineralogy and emplacement mode of the breccias.     

Anisotropy of magnetic susceptibility in welded tuffs: application to a welded-tuff dyke in the tertiary Trans-Pecos Texas volcanic province,USA

Consideration of published anisotropy of magnetic susceptibility (AMS) studies on welded ignimbrites suggests that AMS fabrics are controlled by groundmass microlites distributed within the existing tuff fabric, the sum result of directional fabrics imposed by primary flow lineation, welding, and (if relevant) rheomorphism. AMS is a more sensitive indicator of fabric elements within welded tuffs than conventional methods, and usually yields primary flow azimuth estimates. Detailed study of a single densely welded tuff sample demonstrates that the overall AMS fabric is insensitive to the relative abundances of fiamme, matrix and lithics within individual drilled cores. AMS determinations on a welded-tuff dyke occurring in a choked vent in the Trans-Pecos Texas volcanic field reveals a consistent fabric with a prolate element imbricated with respect to one wall of the dyke, while total magnetic susceptibility and density exhibit axially symmetric variations across the dyke width. The dyke is interpreted to have formed as a result of agglutination of the erupting mixture on a portion of the conduit wall as it failed and slid into the conduit, followed by residual squeezing between the failed block and in situ wallrock. Irrespective of the precise mechanism, widespread occurrence of both welded-tuff dykes and point-welded, aggregate pumices in pyroclastic deposits may imply that lining of conduit walls by agglutionation during explosive volcanic eruptions is a common process.     

Changes in magnetic and fractal properties of fractured granites near the Nojima Fault, Japan

Abstract Anisotropy of magnetic susceptibility (AMS) has been used to infer finite strain fabrics in plastically deformed rocks, but there are few studies of magnetic properties in fractured fault rocks. Changes in magnetic and fractal properties of fractured granites from the Disaster Prevention Research Institute, Kyoto University (DPRI) 500 m drilling core towards the Nojima Fault and of the well-foliated fault gouge are described. Fractal analysis of fractured granites shows that the fractal dimension ( D ) increases linearly toward the gouge zone of the fault. In weakly fractured granites ( D = 1.05–1.24), it was found that the degree of AMS correlates positively with the fractal dimension, suggesting a fracture-related magnetic fabric due to fracturing. In strongly fractured granites ( D = 1.25–1.50), weaker, nearly isotropic AMS is found, suggesting erasure by the fragmentation of the magnetic minerals. Within the fault gouge zone, an isotropic AMS fabric was found, as well as twofold increases in magnetic intensity and susceptibility. These changes reflect the production of new magnetite grains, subsequently confirmed by hysteresis studies, which suggests that fault gouge might be regarded as the source of the regional geomagnetic field contrast along active faults. Thus, AMS is clearly a potentially useful tool for inferring the fracturing texture of magnetic minerals in fractured rocks and detecting active faults from the high susceptibility contrast of fault gouge.     

Influence of magnetic interactions on the anisotropy of magnetic susceptibility: the case of single domain particles packed in globule aggregates

The influence of magnetic interactions on the anisotropy of magnetic susceptibility (AMS) have been largely studied by several theoretical models or experiments. Numerical models have shown that when magnetostatic interactions occur, the distributions of particles over the volume rather than their individual orientations control the AMS. We have shown recently from a comprehensive rock magnetic study and from a theoretical 2-dimensional (2-D) model that single domain particles closely packed in globule aggregates could produce strong local random interaction magnetic fields which could influence the magnetic susceptibility and decrease the degree of anisotropy. In this paper, we first present in detail this 2-D theoretical model and then we extend it to the 3-D case. The possible distribution function of the magnetostatic interaction fields comprises two extreme states: it is either isotropic or ordered. The former case corresponds to the thermal-demagnetized state while the second case corresponds to the alternating field (AF) demagnetized state. We show that when easy axes of magnetization are not uniformly distributed, the degree of anisotropy decreases as the interaction field increases in both AF- and thermal-demagnetized states in 2-D and 3-D geometry. Thus we conclude that random magnetic fields generated by a random arrangement of magnetic particles over the sample volume decrease the degree of anisotropy of AMS and may alter the magnetic fabric.     

Calibration of magnetic granulometric trends in oceanic basalts

The validity of magnetic granulometric estimates relies heavily on the ability to distinguish ultrafine particles from coarser grains. For example, populations with dominantly superparamagnetic (SP) or multidomain (MD) grains both are characterized by low remanence and coercivity, and distinguishing these endmembers may provide valuable clues to the origin of magnetization in the intervening stable single domain (SD) size range. The natural grain size variations associated with variable cooling rates in submarine lavas provide a rare opportunity for examining progressive changes in average magnetic grain size, from SP–SD mixtures in submarine basaltic glass to SD–MD mixtures in flow interiors. Based on microanalysis and rock magnetic measurements on pillow basalt samples dredged from the flanks of the Mid-Atlantic Ridge (ages <1 Ma to 70 Ma), a model of preferential dissolution with time of the finest-grained titanomagnetites has recently been suggested as the major process contributing to long-term temporal changes in remanent intensity of mid-ocean ridge basalts. We evaluated the local and long-term temporal trends in effective magnetic grain size predicted by this model using hysteresis data from a large number of submarine basalt samples which span a range of ages from 0 to 122 Ma. Specimens were systematically taken along transects perpendicular to the chilled margin of each sample. The large number of data (750 loops) and the inferred progressive change in grain size approaching the chilled margin allow recognition of mixing trends between MD and SD grains and between SD and SP grains on a Day-plot. These trends in hysteresis parameters are crucial to resolving the inherent, but frequently overlooked, ambiguity in inferring grain size from hysteresis parameters. We illustrate that two additional rock magnetic tests (warming of a low-temperature isothermal remanence and hysteresis loop shapes) often used to address these ambiguities are inconclusive, requiring some independent knowledge of whether SP or MD grains are likely to be present. Even with a considerably larger data set the substantial intrasample variability in oceanic basalts precludes recognition of any systematic trend in magnetic grain size with age.     

Anisotropies of in-phase,out-of-phase,and frequency-dependent susceptibilities in three loess/palaeosol profiles in the Czech Republic; methodological implications

The relationship between the anisotropy of frequency-dependent magnetic susceptibility (fdAMS) and the anisotropy of out-of-phase magnetic susceptibility (opAMS) was investigated theoretically and also empirically at three loess/palaoesol profiles in Prague and in Southern Moravia. The data treatment was made in terms of mean susceptibility, degree of AMS, and orientations of principal susceptibilities. It has shown that the fdAMS and opAMS can serve as indicators of the preferred orientations of ultrafine magnetic particles that are on transition between superparamagnetic and stable single domain states in rocks, soils and environmental materials. In loess/palaeosol sequences, the fdAMS and opAMS correlate reasonably, because they are due to magnetic particles of similar grain sizes. The fdAMS and opAMS can be both coaxial with standard AMS (i.e. anisotropy of in-phase susceptibility - ipAMS) or non-coaxial indicating slightly different orientations of viscous magnetic particles.     

磁组构与构造变形

磁组构通常指磁化率各向异性,即AMS(Anisotropy of Magnetic Susceptibility),是一种重要的岩石组构,是弱变形沉积岩地区灵敏的应变指示计.近年来,AMS在造山带及前陆地区的广泛应用为构造变形研究提供了极大的帮助,同时提升了该方法的理论认识.本文在研读最新相关文献与著作的基础上,结合笔者及研究团队在龙门山地区获得的磁组构研究成果,综述了磁组构在沉积岩地区构造变形研究中的应用进展,并基于现有的研究认识对关键问题进行讨论,提出以下几点认识:(1)磁性矿物分析是AMS研究的关键,应结合多种岩石磁学实验及光学与电子显微构造研究手段展开详细的磁性矿物学分析;(2)磁化率椭球与应变椭球的对应主轴在绝大多数情况下相互平行,但在不同期次、不同种类复杂的磁性矿物组成,或者多期次构造变形的影响下,AMS与应变的关系相对复杂,应比对高场和低温AMS及非磁滞剩磁各向异性(AARM)测试结果,获得不同矿物的优选定向特征,并对获得的组构进行分期;(3)AMS可以揭示造山带及其前陆地区的构造演化历史,并且是分析断层相关褶皱的有限应变特征和变形机制的重要方法,同时也是厘定断裂带变形性状和期次及运动学分析的有效手段;(4)磁组构形成于成岩作用早期或构造变形的最早阶段,能很好地记录褶皱和逆冲作用之前的平行层缩短变形,因此可以揭示同沉积阶段的古构造应力方向.后期足够强烈的构造变形能局部改造或彻底掩盖先存AMS记录,构造流体有关的同构造期结晶矿物或先存矿物的重结晶导致的再定向被认为是其根本原因;(5)斜交磁线理是一种特殊的磁组构类型,反映了区域构造叠加或多期构造变形作用或隐伏斜向逆冲等可能的构造过程,有必要结合多方面的地质证据对其成因作出合理解释.     

Rock magnetic properties and ore microscopy of the iron ore deposit of Las Truchas, Michoacan, Mexico

Iron ore and host rocks have been sampled (90 oriented samples from 19 sites) from the Las Truchas mine, western Mexico. A broad range of magnetic parameters have been studied to characterize the samples: saturation magnetization, Curie temperature, density, susceptibility, remanence intensity, Koenigsberger ratio, and hysteresis parameters. Magnetic properties are controlled by variations in titanomagnetite content, deuteric oxidation, and hydrothermal alteration. Las Truchas deposit formed by contact metasomatism in a Mesozoic volcano-sedimentary sequence intruded by a batholith, and titanomagnetites underwent intermediate degrees of deuteric oxidation. Post-mineralization hydrothermal alteration, evidenced by pyrite, epidote, sericite, and kaolin, seems to be the major event that affected the minerals and magnetic properties. Magnetite grain sizes in iron ores range from 5 to >200 μm, which suggest dominance of multidomain (MD) states. Curie temperatures are 580±5°C, characteristic of magnetite. Hysteresis parameters indicate that most samples have MD magnetite, some samples pseudo-single domain (PSD), and just a few single domain (SD) particles. AF demagnetization and IRM acquisition indicate that NRM and laboratory remanences are carried by MD magnetite in iron ores and PSD–SD magnetite in host rocks. The Koenigsberger ratio falls in a narrow range between 0.1 and 10, indicating the significance of MD and PSD magnetites.     

Anisotropy of magnetic susceptibility variations in Icelandic columnar basalts

The anisotropy of magnetic susceptibility (AMS) has been determined for 81 samples from eleven horizontal columnar segments from two Icelandic near-vertical dikes. Near-vertical orientation of short AMS axes and corresponding long-axis horizontal orientations in most columns represents alignments consistent with compactive effects due to vertically directed forces exerted by overlying columns. These data are inconsistent with primary orientations resulting from thermal contractive stresses, but such stresses may be responsible for the secondary orientations observed.     

Rock magnetic properties of Nihewan sediments at Xujiayao

Rock magnetic measurements of Nihewan sediments from Xujiayao section demonstrate that magnetite, hematite and maghemite are dominant remanent magnetization carriers. Monitoring the variations of magnetic susceptibility (MS) and saturating isothermal remanent magnetization (SIRM) at low temperature are the attractive ways of detecting the presence of magnetite, maghemitization and superparamagnetic grain sizes. Low-temperature MS investigations suggest that susceptibility enhancement for Xujiayao samples is mainly due to the remarkable presence of SD/MD magnetite to some degree though some magnetite grains have been partially oxidized at some depths. It is tentatively concluded that both SD/MD magnetite and hematite are of detrital origin and carry a characteristic remanent magnetization (ChRM), whereas maghemite can be attributed to be chemical origin, overprinting a reversed polarity component of Matuyama age.     

嵊泗岛辉绿岩墙群的侵位方式:来自磁组构的证据

岩墙磁组构能反映岩浆的侵位方式.中国东部嵊泗岛广泛发育了晚白垩世辉绿岩岩墙群.我们对其中8条不同走向岩墙进行了采样,沿岩墙两边部及横跨岩墙剖面获得共273个独立定向岩芯样品.岩石磁学分析表明辉绿岩的主要携磁矿物为多畴贫钛磁铁矿,可能含少量磁赤铁矿.各条岩墙的磁组构均具有低的各向异性度Pj＜1.2,且主轴的空间方位各不相...     

Composite magnetic fabric deciphered using heating treatment

In a number of AMS studies, the presence and deciphering of composite magnetic fabrics is of major importance for a correct interpretation of the data. On the basis of several examples from intrusive rocks (diorites and dolerites) we show that the use of laboratory heatings can help to extract at least one component of the composite magnetic fabrics usually present. The procedure includes comparison of the fabrics measured after stepwise laboratory heating with the fabrics determined by tensor difference and by linear regression analysis. In the diorite samples, the measured AMS results from the superimposition of different component fabrics and does not correspond exactly to any of these fabrics. In these dykes, isolated magnetic fabric during thermal treatment corresponds to that of the main magnetic mineral (Ti-poor titanomaghemite) and reveals an unknown structure. In volcanic flow or doleritic dykes, a “parasitic” fabric related to late or post-magmatic evolution superimposed to the flow fabric can produce important scattering of the AMS principal directions. Decomposition of magnetic fabric during thermal treatment allows isolation of the flow fabric.     

强剩磁强退磁条件下的二维井中磁测反演

强剩磁、强退磁改变了总磁化强度的大小和方向,给磁测资料解释带来困难.为此,本文利用二维井中磁测数据反演磁化强度矢量的二维分布.首先利用井中磁测的磁异常模量反演磁化强度大小的分布.然后,在已知磁化强度大小分布的前提下,拟合磁场分量,反演磁化强度方向的分布.其中,磁化强度大小和方向均用共轭梯度法求解,并通过预优矩阵改善磁化强度大小的反演效果.理论模拟说明,该方法能准确获得磁化强度矢量分布.磁化强度矢量反演结果包括感磁、剩磁及退磁的影响,这为研究强剩磁、高磁化率矿床提供了一种有效方法.     

The development of magnetic susceptibility anisotropy through crystallographic preferred orientation in a calcite rock

High-field torque-meter measurements of diamagnetic susceptibility anisotropy of a suite of samples of Carrara marble, axially shortened by amounts up to 50% at (1.5–3.0) · 10⁸ Pa confining pressure and at 20–500°C (mainly 400°C), have been compared with optical measurements of preferred crystallographic orientation. A revised value for the susceptibility anisotropy of calcite has been obtained from studies of single crystals, and it has been shown to be almost independent of the state of intracrystalline plastic strain. From the measured anisotropy of calcite, quantitative comparison of optical and magnetic fabric measurements is possible. It is found that these measurements agree and the implications of the observed progressive development of fabric intensity with strain are discussed.     

New insights into asymmetric folding by means of the anisotropy of magnetic susceptibility,Variscan and Pyrenean folds (SW Pyrenees)

Magnetic fabric allows to unravel the petrofabrics of sedimentary rocks and to assess their deformational history. The use of this technique, in addition to classical structural field observations in the limbs of seven asymmetric folds in the Pyrenees, helps to determine the differences of internal deformation as well as the folding kinematics. Three folds developed during the Variscan Orogeny in Ordovician and Devonian rocks, and four folds developed during the Pyrenean Orogeny in Eocene rocks, are studied. Folds show a variety of structural locations, in different thrust sheets of the Southern Central Pyrenees, different cleavage development, age, geometry and lithology. Sampling follows an equivalent lithological layer in the two limbs, except for one case, of the selected folds. Results show a modified tectonic magnetic fabric in most sites with the magnetic lineation on the tectonic foliation plane. A larger scattering of the magnetic lineation (maximum magnetic anisotropy axis) and a higher intensity of the preferred orientation of minerals (eccentricity of the anisotropy of magnetic susceptibility - AMS ellipsoid) is better observed in the overturned (short) limb of the asymmetric Variscan folds than in the normal (long) limb. On the other hand, the shape parameter in Alpine folds is generally larger in the overturned (short) limb then in the normal (long) one. A good clustering of the minimum magnetic anisotropy axes is observed in all limbs. The combination of the AMS data with the structural data helps to understand and better constrain the deformation degree in these asymmetric folds and to unravel the deformational history.     

Anisotropy of magnetic susceptibility of rocks in the Rayleigh Law region: Modelling errors arising from linear fit to non-linear data

The anisotropy of magnetic susceptibility (AMS) within the Rayleigh Law range was investigated theoretically, using mathematical modelling. It was revealed that the orientations of the principal susceptibilities and the shape parameter vary with field so weakly that these variations can be regarded as negligible from the practical point of view. The degree of AMS increases with field according to the degree of anisotropy of the initial susceptibility used and according to the intensity of susceptibility change with field of the mineral considered. The degree of AMS calculated using linear theory is very near to the degree of AMS following from the analysis of AMS within the Rayleigh Law range. If it is desirable to correct the field-dependent degree of AMS, a simple technique is suggested based on measurement of the AMS in two fields. fhrouda@agico.cz