粤北大瑶山地区前泥盆纪地层中的火山岩特征及LA-ICP-MS锆石U-Pb年龄

通过1︰5万地质填图及剖面测制,作者在粤北大瑶山地区的震旦-寒武纪地层中首次发现多层火山岩,岩性主要为火山-沉积碎屑岩类的变质凝灰质不等粒岩屑石英砂岩、变质凝灰质不等粒长石石英砂岩、沉凝灰岩等,局部见变流纹质熔结凝灰岩。对变流纹质熔结凝灰岩、变质凝灰质砂岩用LA-ICP-MS法测定锆石U-Pb年龄,206Pb/238U年龄介于614~2869 Ma之间,年龄值较为分散,说明碎屑锆石是多来源的。火山岩年龄数据与地层时代归属矛盾,粤北大瑶山地区前泥盆纪地层的时代归属值得进一步探讨。     

Petrographic variations within thick turbidite sequences: an example from the late Palaeozoic of eastern Australia

The subdivision of thick sequences of turbidite sediments has been problematical because of the monotonous nature of the units. One method, of using detailed detrital petrography for a large number of specimens, has delineated variations with a sequence of Late Palaeozoic age in eastern Australia. The rocks occur within a single structural block and are all members of one sedimentary petrographic province. They have been subdivided into three stratigraphic units (Moombil Beds, Brooklana Beds and Coramba Beds) and greywackes from these units are quartz-poor to quartz-intermediate, feldspathic or volcanolithic types. Dacitic volcanism has provided most of the detritus and the contribution from non-volcanic sources is small. The Coramba Beds are further subdivided into four petrographic units which are parallel to the stratigraphic boundaries. These lithostratigraphic units are based on the presence or absence of detrital hornblende, and the relative ratio of volcanic lithic fragments to feldspar. Vertical petrographic variations within the entire sequence indicate that although the acid volcanic source was predominant throughout the time of deposition, there is a noticeable increase in the contribution from intermediate-volcanic, acid-plutonic, low-grade metamorphic and sedimentary sources towards the top of the sequence. Detrital hornblende is also present in the upper parts of the sequence.     

二长石地质温度计在估算乌拉山金矿碱性长石形成温度中的应用

内蒙古乌拉山金矿田内主要出露晚太古代乌拉山群区域变质岩和规模不一的花岗岩体以及不同时代、不同种类的脉状地质体。含金矿脉中主要矿物共生组合为碱性长石、石英、斜长石、碳酸盐矿物(方解石、白云石)和少量金属硫化物。矿床的显著特征为碱性长石交代作用强烈，碱性长石也广泛产于该地区其他各种类型的岩石中。本文采用电子显微探针分析了共生碱性长石和斜长石的化学成分，并采用三元二长石温度模型估计了碱性长石的平衡温度。结果表明，第一成矿阶段的碱性长石一石英含金矿脉中碱性长石的形成温度为353℃，第二成矿阶段石英含金矿脉中碱性长石的形成温度为281℃，矿脉碱性长石形成压力约为5kbar。这些结果与同类矿石中平衡共生的碳酸盐矿物和云母类矿物的地质温度计估计的形成温度以及共生石英中流体包裹体的均一温度非常一致。因此，乌拉山金矿床形成和富集的温度可估测为260～380℃，压力约为5kbar。此外，应用二长石温度计计算了本地区区域变质片麻岩和花岗岩中碱性长石的平衡温度，所得温度比采用共生铁铝榴石和黑云母温度计估计的温度要低约250℃。这表明共生的铁铝榴石和黑云母的平衡温度可能代表其寄主变质岩变质期温度及寄主花岗岩原生温度，而区域变质岩和花岗岩中的碱性长石在经历了随后多次热液作用后，可能重新平衡再生，这也与前人对乌拉山金矿的矿床地质和同位素研究的结果一致。     

Petrography and provenance of subsurface Neogene sandstones of Bengal Basin, Bangladesh

This study deals with petrography and provenance of the Neogene reservoir sandstones encountered in the Kailas Tila, Titas, Bakhrabad and Shahbazpur Gas Fields of Bengal Basin. Framework grains are sand-sized to silt-sized particles of mainly detrital origin. The most common detrital grains are quartz, feldspars, and rock fragments. Mica occurred as minor and non-opaque heavy minerals found as minor accessories. Among the main detrital framework grains, quartz constitutes 51–60%, feldspar 3–15%, lithic fragments 8–22%. Sandstones encountered in the studied wells have been classified as sublithic arenite, feldspathic arenite and lithic arenite in order of abundance. Different triangular plots reveal that the Neogene sandstones of the studied wells exhibit a quartzolithic composition, low feldspar, very low volcanic grains and abundant sedimentary and low grade metamorphic lithic clasts indicating that the sands were derived from quartzose recycled orogen province, such as a fold thrust province or a collision suture zone. This study suggests that either the eastern Himalayas or Indo-Burman Ranges might act as the source of the sandstones of the studied wells of the Bengal Basin.     

内蒙古苏尼特右旗白乃庙地区徐尼乌苏组的形成时代及其地质意义

本文对白乃庙地区徐尼乌苏组沉积特征、原岩建造、变质火山岩及变质碎屑岩的年代学和地球化学进行了研究,探讨了白乃庙地区早古生代构造演化。本次研究采集了徐尼乌苏组中具有代表性的变质含砾粗粒杂砂岩、变质英安质晶屑凝灰岩和变质长石石英细砂岩样品,进行了锆石LA-ICP-MS U-Pb年代学和岩石地球化学分析。结果显示,2个变质英安质晶屑凝灰岩锆石的加权平均年龄分别为440.9±1.8Ma(MSWD=0.10)和440.9±1.7Ma(MSWD=0.15),锆石Th/U比值为0.46~1.59,自形程度较好,发育有典型的岩浆锆石振荡环带结构,显示为岩浆成因锆石的特点,表明徐尼乌苏组的形成时代为早志留世。变质含砾粗粒杂砂岩的碎屑锆石年龄在452.0±1.3Ma~535.0±1.0Ma之间,最高峰值年龄为490Ma左右;变质长石石英细砂岩碎屑锆石年龄则在440.1±5.7Ma~3268.9±57.7Ma之间,最小谐和年龄为440.1±5.7Ma,峰值年龄为490Ma左右,另有1.0Ga、1.6Ga、1.8Ga和2.5Ga四个明显的峰值年龄。根据研究区徐尼乌苏组岩性组合与结构构造,可将该组划分为3个不同的沉积旋回。结合白乃庙地区徐尼乌苏组测年结果、岩石地球化学特征、原岩建造及区域岩浆岩资料,白乃庙弧后盆地沉积可划分为三个演化阶段:早期快速堆积阶段(452.3~440.9Ma),形成了一套成熟度较低的粗碎屑岩建造,物源主要来源于白乃庙岩浆弧中的岩浆岩;中期火山喷发阶段(440.9~440.1Ma),以火山沉积作用为主,为火山碎屑岩建造夹有碳酸盐建造和少量碎屑岩建造,碎屑物质主要来源于该时期的火山活动;晚期稳定沉积阶段(440.1Ma),形成一套细碎屑岩建造和碳酸盐建造,为浅海相稳定沉积,此时物源广泛,分别来源于华北克拉通基底、兴蒙造山带和白乃庙早古生代火山弧。根据徐尼乌苏组的沉积建造和火山建造特征,结合白乃庙火山弧岩浆活动特征,认为徐尼乌苏组形成于早古生代弧后盆地中,此时华北板块北缘属于安第斯型活动大陆边缘。     

祁连山老君山砾岩的碎屑组成和源区大地构造背景

老君山砾岩是一套由砾岩和杂砂岩组成的陆相粗碎屑岩.砾岩由来自下伏基底的超镁铁岩、中-基性火山岩、硅质岩、花岗岩等碎屑组成.杂砂岩中岩屑含量大于70%,石英约10%,长石约15%.岩屑以中基性火山岩和花岗岩为主;硅质岩屑是主要的沉积岩屑.锆石、磷灰石、磁铁矿是杂砂岩中最为丰富的重矿物,同时还有铬铁矿、石榴子石、电气石、金红石、黄铁矿.这些事实说明,老君山砾岩的源区曾出露有超镁铁岩、中基性火山岩、变质岩等类型的岩石.砂岩碎屑模式和粉砂岩、泥岩的地球化学成分均表明,老君山砾岩源区为大陆边缘弧和大洋岛弧,形成于活动大陆边缘与岛弧相关的沉积盆地中.     

A ternary feldspar-mixing model based on calorimetric data: development and application

A mixing model for high structural state ternary feldspars in the NaAlSi₃O₈–KAlSi₃O₈–CaAl₂Si₂O₈ system is presented based exclusively on calorimetric and volumetric measurements. Comparisons with existing mixing models, which are based on phase-equilibrium experiments, reveal distinct differences. The incorporation of K into Ca-rich plagioclase and of Ca into K-rich alkali feldspar is more strongly limited by our calorimetry-based model, whereas the stability field of Na-rich feldspars is broadened. Natural feldspar assemblages from well-studied magmatic and high-grade metamorphic rocks (i.e. a teschenite sill in Scotland, the Klokken syenogabbro in Greenland, and a granulite-facies metapelite in Sri Lanka) were used to test the mixing models. It was found that the new model largely eliminates discrepancies between observed and predicted feldspar compositions that were present in earlier attempts. The reasons for the problems associated with phase-equilibrium based mixing models are discussed.     

Triclinicity and barium content of potassium feldspars from muscovite pegmatites

Potassium feldspars in pegmatites of the Mama district are microclines and orthoclases. In granitoid pegmatites and undifferentiated vein pegmatites, unaffected by postmagmatic processes, the feldspars are represented by orthoclase with the X-ray triclinism (△p) as 0.0-0.4. Wherever postmagmatic solutions were active, in granitoid pegmatitic fields or zonal bodies of vein pegmatites, the feldspars are represented by microcline with △p as 0.5-1.0. At that, the ultimate microcline is recorded only in micaceous zones. There is a connection between △p and Ba content of the feldspars High concentrations of Ba interfere with order in the feldspar crystal structures. There is a definite inverse relationship between △p and Ba in feldspars containing 0.9-2.6% Ba. In feldspars which are low in Ba, △p may vary at one and the same concentration of Ba. Such state of the crystal structure of feldspars is metastable. The magnitude of △p depends upon conditions of the original crystallization and on factors conducive to orderliness in the crystal structure, as well as the interferences, specifically the effect of the admixture elements. — Authors.     

新疆库车盆地晚三叠世-早侏罗世沉积碎屑矿物成分及其物源区示踪与构造意义

通过同构造沉积物质记录了解物源区剥蚀作用过程进而探索盆山构造相互关系,是大陆构造动力学研究的一个重要方面。砂岩骨架成分分析和重矿物及部分标型矿物分析方法,已被较多地用来探索新疆天山造山带与其南部库车盆地晚中生代以来的相互关系和构造演变过程,但是关于中生代较早时期库车盆地构造属性及北部造山带隆升剥蚀过程的认识仍存在较大分歧。本文运用电子探针微区成分分析方法,对库车盆地北缘中段晚三叠世和早侏罗世砂岩中具代表性的15个砂岩样品中的38颗碎屑长石和26颗碎屑白云母矿物进行了矿物化学成分分析。结果表明,长石主要来自变质岩物源区,25颗碎屑白云母均属多硅白云母,表明其源区岩石曾经历了高压变质作用。这些多硅白云母中Si原子含量显示它们比目前保留在天山造山带高压变质带蓝片岩和榴辉岩中的多硅白云母形成的压力要低,可能反映了源区高压变质岩的正常剥露顺序。这项研究结果表明,至少在晚三叠世-早侏罗世时期,库车盆地北部天山造山带中的高压变质岩已经剥露于地表并遭受剥蚀成为物源供给区。具体是中天山南缘早古生代高压变质带还是晚古生代南天山高压变质带作为重要物源区,尚需进一步的研究工作。     

Microtextures of authigenic Or-rich feldspar in the Upper Jurassic Humber Group, UK North Sea

ABSTRACT Detrital alkali feldspars currently at burial depths of 3·2–3·5 km in the Upper Jurassic Humber Group of the Fulmar oilfield, UK North Sea, are overgrown and have been partially replaced by authigenic Or‐rich feldspar. Intracrystal microtextures suggest several different provenances for the detrital grains. The overgrowths are uniformly non‐cathodoluminescent and have occasional celsian‐rich zones. Transmission electron microscopy shows that they are composed of a microporous mosaic of subµm‐ to µm‐sized sub‐grains associated with barite, illite and pyrite. The subgrains are somewhat rounded but have an approximate {110} Adularia habit and display a faint modulated microtexture on the nanometre scale. They have triclinic symmetry, but the lattice angles depart only slightly from monoclinic symmetry. These features are characteristic of K‐feldspar precipitated relatively rapidly and at low temperature. Authigenic Or‐rich feldspar has also partially replaced microcline and perthitic albite within the detrital grains, often at a suboptical scale. Although, like diagenetic albitization, replacement by K‐feldspar is probably a very common diagenetic reaction, it has rarely been reported owing to difficulties in imaging the diagnostic textures with the scanning electron microscopy techniques used by most workers. The permeability of the subgrain microtexture may significantly hinder the use of feldspar overgrowths for K/Ar and ⁴⁰Ar/³⁹Ar dating of diagenesis, and the existence of suboptical, replacive authigenic K‐feldspar within detrital grains may significantly modify the apparent Ar ages of detrital grains. Similar subgrain microtextures in optically featureless quartz overgrowths are also illustrated.     

对藏北羌塘地体阿木岗群的新认识

依据地质填图和实测剖面获得的资料,对羌塘地体阿木岗群的层序特征、岩石地球化学特征变质作用特征等方面进行了研究,并变质岵与盖层之间的角度不整保关系,火山－沉积变质岩的Ｓｍ－Ｎｄ年龄对阿木岗群的原岩时代和变质年龄进行了重新厘定,得出其原岩为一套陆源碎屑岩和少量火山岩,经历了三期变质作用的演化,火山－沉积变质岩Ｓｍ－Ｎｄ年龄为２６８．６Ｍａ。     

秦岭造山带东段秦岭岩群的年代学和地球化学研究

对东秦岭地区的陕西省洛南县、宁陕县、长安县和河南省淅川县出露的四个秦岭岩群变质岩进行的岩石学和地球化学研究表明,样品主要由变质火山岩和变质沉积岩组成.详细的锆石U-Pb定年结果显示三个正变质岩均形成于新元古代早期(971～843Ma),而副变质岩中富集大量新元古代碎屑锆石,根据最年轻的谐和年龄(859Ma)和早古生代的变质年龄,推测其沉积时代为新元古代中晚期.因此,北秦岭南部的秦岭岩群的变质岩主要由新元古代早期的火成岩和新元古代中晚期的沉积岩组成.变质作用主要发生在加里东期,局部有燕山期的变质作用叠加.指示北秦岭的造山作用主要发生在早古生代.岩石地球化学研究还显示秦岭岩群的新元古代火山岩均形成于火山弧构造环境,沉积岩沉积于大陆弧-活动大陆边缘环境,指示秦岭造山带在新元古代早期是一个火山弧.秦岭岩群的火山岩和沉积岩在形成时代和构造环境方面与扬子克拉通西缘的特征非常相似,表明位于北秦岭造山带的秦岭岩群应归属于扬子克拉通陆块,是扬子北缘的一个大陆边缘弧.     

丽水-椒江凹陷西斜坡明月峰组上段碎屑锆石物源

沉积物源对油气储层发育具有重要影响.为研究丽水-椒江凹陷西斜坡明月峰组上段物源的岩性组成及其分布特征,选取4口钻井4个砂岩样品进行碎屑锆石U-Pb定年,并对陆上潜在物源区岩层(体)的岩性和年龄进行统计分析.结果显示:(1)样品中碎屑锆石以岩浆锆石为主,主要的年龄区间为125~90 Ma、145~125 Ma及170~145 Ma,还有少量变质锆石,其年龄区间为235~210 Ma及2 087~1 653 Ma;(2)陆上潜在物源区中以火山岩占绝对优势(173~94 Ma),局部区域可能有较大规模白垩系永康群沉积岩,而变质岩(＞210 Ma)和侵入岩(107.0~87.8 Ma)仅零星出露.综合分析认为:研究区东北部明月峰组上段的物源以永康群火山-沉积岩和九里坪组火山岩为主,含有少量晚白垩世侵入岩;西南部以九里坪组、西山头组火山岩及元古代区域变质岩为主,侏罗纪火山岩为辅,这一区域可能更有利于优质储层的发育.      

Kalgan volcanic complex: optical properties of its alkali feldspar phenocrysts

The Mesozoic Kalgan volcanic complex is distributed around the city of Kalgan in an area of about 1000–1200 km² and contains a great variety of rocks, among which are basalts, augite clacites, quartz-trachytes, quartz porphyry, rhyolite and various kinds of glassy rocks, tuffs and other volcanic ejecta. These diverse forms of volcanic rock impart the splendid geomorphological features. Six extinct craters were found, all of the central type; positions of eruptive centers were shifted from the southeast of the area in the early period to the northwest later. Two vertical sections of volcanic bodies of quartz porphyry and rhyolite were chosen to study precisely the optical angles of feldspars from each specimen. Results showed that there are different variation features of 2V between the basal, intermediate and top portions of volcanic bodies. Values of 2V are smaller, and of 2Vd, greater in the basal and top portions than those in the intermediate portions. Two main varieties of alkali feldspar occur in the Kalgan volcanic rocks. One is high temperature variety-low sanidine (–)2V=26°?40°, distributed mainly in the rhyolite and glassy rocks; another is the intermediate temperature variety-high orthoclase (–)2V=40°–62° , found mostly in the quartz porphyry. But their compositions are all in the intermediate range of K-Na feldspar series. Variations of the optical angles of alkali feldspar in the Kalgan complex proved that 2V is a sensitive optical constant of petrogenesis. Its variation is not only shown in one and the same extrusive or intrusive body, but also in one and the same specimen of rocks or crystal, with some definite regulations. – Author.     

内蒙古索伦地区晚古生代沉积构造背景——来自上二叠统哲斯组碎屑锆石年代学的制约

上二叠统哲斯组广泛出露于东北地区南部,主要由砂岩、泥岩、灰岩、页岩组成,含腕足、苔藓虫和腹足化石. 对内蒙古索伦地区的哲斯组中粗粒长石岩屑砂岩和中细粒长石砂岩样品进行了LA-ICP-MS锆石U-Pb测年,数据记录了4个年龄区间：（265±2）~（348±8）Ma,峰值年龄为（272±2）Ma;（358±3）~（453±4）Ma,峰值年龄（403±3）Ma;（470±6）~（555±4）Ma,峰值年龄为（511±3）Ma;剩余的前寒武纪锆石（693±7）Ma,（834±9）Ma,（854±6）Ma,（886±5）Ma,（1 175±7）Ma,（1 440±8）Ma,（1 748±17）Ma和（2 150±13）Ma. 其中峰值年龄为272 Ma的锆石年龄占绝对优势（达到51%）,并与大石寨组火山岩和北侧的岛弧岩浆岩一致,403 Ma和511 Ma峰值年龄为东北地区泛非期变质杂岩的年龄范围,其余古老年龄也均为大兴安岭变质基底的年龄范围. 上述年龄特征显示,哲斯组物源主要来自相邻地区分布的早古生代岛弧火山岩,少量来自东北相邻地块的变质基底. 鉴于东北地区哲斯组分布范围广,岩性多为碳酸岩和碎屑岩,古生物化石保存完整,沉积环境稳定,证明哲斯组应为大陆边缘沉积.     

中条山绛县群碎屑锆石LA-ICP-MS U-Pb测年及其地质意义

中条山位于山西省的南缘,主要由涑水杂岩、绛县群、中条群、担山石群和西阳河群组成.其中绛县群主要由变质的砂岩、半泥质岩、泥质岩、碳酸岩和火山岩组成.在取自绛县群的两个变质沉积岩样品中,利用LA-ICP-MS定年方法,获得85个单颗粒碎屑锆石,锆石年龄主要介于2416～2899Ma之间,样品05ZR02-1中的主峰值年龄为约2667Ma,样品05YQ12-1中的主峰值年龄为约2537Ma,表明这些变质沉积岩主要源于华北克拉通中部带,以晚太古代老地壳物质为主.在这些碎屑锆石中,最年轻的年龄为2160±17Ma,可代表其沉积时的最大年龄,绛县群变质沉积岩的的沉积作用应该发生在2200Ma之后,而不是在晚太古代后的2.5～2.3Ga,绛县群与北峪花岗岩之间并不是呈现侵入接触关系.     

Determination of the early Paleozoic accretionary complex in Southwestern Yunnan,China: Implications for the tectonic evolution of the Proto-Tethys Ocean

Accretionary complex study provides important knowledge on the subduction and the geodynamic processes of the oceanic plate, which represents the ancient ocean basin extinction location. Nevertheless, there exist many disputes on the age, material source, and tectonic attribute of the Lancang Group, located in Southwest Yunnan, China. In this paper, the LA-ICP-MS detrital zircon U–Pb chronology of nine metamorphic rocks in the Lancang Group was carried out. The U–Pb ages of the three detrital zircons mainly range from 590–550 Ma, 980–910 Ma, and 1150–1490 Ma, with the youngest detrital zircons having a peak age of about 560 Ma. The U–Pb ages of the six detrital zircons mainly range from 440–460 Ma and 980–910 Ma, and the youngest detrital zircon has a peak age of about 445 Ma. In the Lancang Group, metamorphic acidic volcanic rocks, basic volcanic rocks, intermediate-acid intrusive rocks, and high-pressure metamorphic rocks are exposed in the form of tectonic lens in schist, rendering typical melange structural characteristics of “block + matrix”. Considering regional deformation and chronology, material composition characteristics, and the previous data, this study thinks the Lancang Group may be an early Paleozoic tectonic accretionary complex formed by the eastward subduction of the Changning-Menglian Proto-Tethys Ocean, which provides an important constraint for the Tethys evolution.©2023 China Geology Editorial Office.     

西藏尼木地区变质火山岩的地球化学特征、锆石U-Pb年龄及其地质意义

西藏尼木地区分布一套增生杂岩,其对冈底斯火山岩浆弧的演化具有重要意义。本文对该套增生杂岩中的变质火山岩的地质特征、矿物学、全岩地球化学和锆石U-Pb年代学等方面进行了综合研究。变质火山岩以斜长角闪岩、角闪斜长片麻岩为主,其中,角闪石主要为镁质角闪石,共生的斜长石主要为拉长石;变质火山岩经历了高温-中压变质作用;岩石富Al_2O_3和贫TiO_2,弱富集轻稀土元素(LREE),富集Rb、Sr、Ba等大离子亲石元素(LILE),亏损Nb、Ta、Ti等高场强元素(HFSE),其地球化学特征与火山弧玄武岩的地球化学特征相似,其形成的构造环境为洋内岛弧或活动大陆边缘弧;岩浆锆石U-Pb年龄值为151.4±1.6Ma和150.7±1.4Ma,表明岩石的形成时代为晚侏罗世。综合研究认为,增生杂岩中的变质火山岩是新特提斯洋在晚侏罗世北向俯冲的产物,在陆-陆碰撞之前卷入增生系统,该套变质火山岩不是以往所认为的变质结晶基底。     

Feldspar concentrations in lower Cambrian limestones of the Moroccan Atlas: Pyroclastic vs authigenic processes

Carbonate strata containing abundant euhedral feldspar, usually considered as authigenic, are characteristic of some lower Cambrian exposures in the Atlas Mountains, Morocco. Impure limestones are abundant in the Issendalenian Amouslek Formation of the western Anti-Atlas, and in the Banian Lemdad Formation of the southern High Atlas. Some of their limestone beds contain up to 40% acid insoluble residue, of which feldspar comprises as much as 65% in some samples, the remainder consisting of detrital and authigenic quartz, apatite, pyrite, and clay minerals. The host limestones are bioclastic tempestites, ooidal–oncoidal–bioclastic shoal complexes, archaeocyathan-microbial peri-reef settings (mainly flanks but not reef cores), and microbial reefs. A volcanic origin is adopted for the feldspars based on: (i) fluctuations in feldspar concentration paralleling bedding, but unrelated to host-facies (except for the aforementioned archaeocyathan-microbial reef cores that were controlled by turbidity); (ii) the local association with glassy fragments (with feldspars embedded in glass shards); and (iii) the scattered occurrence of gradational lithofacies from silty tuff to tuffitic limestone.The mineral and chemical composition of the host-rock and diagenetic fluids was the determining factor for the kind of feldspar preservation. Although the primary type of K–feldspar replacement is albitization, secondary albite subsequently suffered from illitization, chloritization, and/or replacement by calcite. A direct implication of this work is the possible geochronological dating of both volcanic eruptions and archaeocyath- and trilobite-bearing host-rocks based on radiometric analyses within unaltered K–feldspar pyroclasts extracted after etching.