Variable nitrate concentration–discharge relationships in a forested watershed

The relationship between solute concentrations and discharge can inform an integrated understanding of hydrological and biogeochemical processes at watershed scales. Recent work from multiple catchments has shown that there is typically little variation in concentration relative to large variations in discharge. This pattern has been described as chemostatic behavior. Pond Branch, a forested headwater catchment in Maryland, has been monitored for stream nitrate (NO₃^?) concentrations at weekly intervals for 14 years. In the growing season and autumn of 2011 a high‐frequency optical NO₃^? sensor was used to supplement the long‐term weekly data. In this watershed, long‐term weekly data show that NO₃^? concentrations decrease with increasing discharge whereas 6 months of 15‐minute sensor observed concentrations reveal a more chemostatic behavior. High‐frequency NO₃^? concentrations from the sensor collected during different storm events reveal variable concentration–discharge patterns highlighting the importance of high resolution data and ecohydrological drivers in controlling solute export for biologically reactive solutes such as NO₃^?.     

Nutrient concentration patterns in streams draining alpine and subalpine catchments, Fraser Experimental Forest, Colorado

Streamwater samples were collected during 1987–1988 from two adjacent gauged watersheds, the subalpine-alpine East St. Louis and the Fool Creek Alpine, in the Fraser Experimental Forest, Colorado. The study objective was to compare the relationships between streamwater discharge and ion concentration in alpine and alpine-subalpine watersheds at a site receiving low inputs of atmospheric contaminants. Streamwater discharge accounts for much of the variation in ion concentration. Trajectories of time, discharge, and ion concentration suggest that patterns of nutrient flux are controlled primarily by the magnitude of streamwater discharge, and seasonal differences in the relative contributions of snowmelt and soil water. In the subalpine catchment, increased streamwater discharge accounted for most of the decline in concentration of ions, with high concentrations in soil water relative to precipitation. This relationship was not seen in the alpine catchment, probably because of the influence of large diurnal variation in the ratio of snowmelt to soil water. In both catchments, ions with comparatively high concentrations in precipitation and the snowpack relative to soil water showed less concentration decline with increased streamwater discharge. The recurring nature of the trajectories, especially in the subalpine catchment, suggests that the time, discharge, and ion concentration patterns may represent a general characteristic in moderate-sized, undisturbed Rocky Mountain catchments which do not receive high inputs of airborne contaminants.     

Données isotopiques (8786/Sr) et changements hydrologiques depuis 15 000 ans sur l'Altiplano andin

Abstract

In catchments characterized by spatially varying hydrological processes and responses, the optimal parameter values or regions of attraction in parameter space may differ with location-specific characteristics and dominating processes. This paper evaluates the value of semi-distributed calibration parameters for large-scale streamflow simulation using the spatially distributed LISFLOOD model. We employ the Shuffled Complex Evolution Metropolis (SCEM-UA) global optimization algorithm to infer the calibration parameters using daily discharge observations. The resulting posterior parameter distribution reflects the uncertainty about the model parameters and forms the basis for making probabilistic flow predictions. We assess the value of semi-distributing the calibration parameters by comparing three different calibration strategies. In the first calibration strategy uniform values over the entire area of interest are adopted for the unknown parameters, which are calibrated against discharge observations at the downstream outlet of the catchment. In the second calibration strategy the parameters are also uniformly distributed, but they are calibrated against observed discharges at the catchment outlet and at internal stations. In the third strategy a semi-distributed approach is adopted. Starting from upstream, parameters in each subcatchment are calibrated against the observed discharges at the outlet of the subcatchment. In order not to propagate upstream errors in the calibration process, observed discharges at upstream catchment outlets are used as inflow when calibrating downstream subcatchments. As an illustrative example, we demonstrate the methodology for a part of the Morava catchment, covering an area of approximately 10 000 km². The calibration results reveal that the additional value of the internal discharge stations is limited when applying a lumped parameter approach. Moving from a lumped to a semi-distributed parameter approach: (i) improves the accuracy of the flow predictions, especially in the upstream subcatchments; and (ii) results in a more correct representation of flow prediction uncertainty. The results show the clear need to distribute the calibration parameters, especially in large catchments characterized by spatially varying hydrological processes and responses.     

Interpreting nested storm event suspended sediment-discharge hysteresis relationships at large catchment scales

Reducing soil erosion and sediment delivery into rivers is a major aim for land management in New Zealand. Therefore, it is important to identify areas of sediment generation and their relationship to in-stream suspended sediment concentrations and water quality attributes. It is possible to infer and assess sediment sources and dynamics using storm event suspended sediment concentration-discharge hysteresis shape and loop direction. Research in small catchments has achieved some success; however, research in larger (>10³ km²) catchments has shown the inherent difficulty of interpreting hysteresis patterns at larger scales. In this paper, we use a nested, long-term suspended sediment monitoring program across a large catchment (3,903 km²: Manawatū in New Zealand) to address these challenges. We evaluate the hysteresis patterns of five major tributaries (subcatchment areas 329–1,298 km²) of the Manawatū River together with the hysteresis patterns at the gauged catchment outlet. Hysteresis patterns of the Manawatū subcatchments can be characterized as predominantly clockwise, that is, high hysteresis index (HI) value. Larger storms (discharge >2 × 10⁷ m³) increase the likelihood of clockwise hysteresis directions, whereas smaller storms (discharge <2 × 10⁷ m³) are more likely to be anticlockwise. The link between suspended sediment concentration-discharge hysteresis and subcatchment sediment sources becomes increasingly attenuated within the larger subcatchments. High antecedent discharge negatively correlates to HI values, suggesting conditions immediately before the storm have an influence on whether the catchment is “primed” or “exhausted” with available sediment. The different storm categories indicate that within this catchment, whereas hysteresis patterns vary due to the spatial origin of discharge and sediment to some extent, storm magnitude has a stronger impact on hysteresis dynamics than spatial origin.     

High spatial-resolution monitoring to investigate nitrate export and its drivers in a mesoscale river catchment along an anthropogenic land-cover gradient

Nitrate monitoring is commonly conducted with low-spatial resolution, only at the outlet or at a small number of selected locations. As a result, the information about spatial variations in nitrate export and its drivers is scarce. In this study, we present results of high-spatial resolution monitoring conducted between 2012 and 2017 in 65 sub-catchments in an Alpine mesoscale river catchment characterized by a land-use gradient. We combined stable isotope techniques with Bayesian mixing models and geostatistical methods to investigate nitrate export and its main drivers, namely, microbial N turnover processes, land use and hydrological conditions. In the investigated sub-catchments, mean values of NO₃⁻ concentrations and its isotope signatures (δ¹⁵N_NO3 and δ¹⁸O_NO3) varied from 2.6 to 26.7 mg L⁻¹, from −1.3‰ to 13.1‰, and from −0.4‰ to 10.1‰, respectively. In this study, land use was an important driver for nitrate export. Very strong and strong positive correlations were found between percentages of agricultural land cover and δ¹⁵N_NO3, and NO₃⁻ concentration, respectively. Mean proportional contributions of NO₃⁻ sources varied spatially and seasonally, and followed land-use patterns. The mean contribution of manure and sewage was much higher in the catchments characterized by a high percentage of agricultural and urban land cover comparing to forested sub-catchments. Specific NO₃⁻ loads were strongly correlated with specific discharge and moderately correlated with NO₃⁻ concentrations. The nitrate isotope and concentration analysis results suggest that nitrate from external sources is stored and accumulated in soil storage pools. Nitrification of reduced nitrogen species in those pools plays the most important role for the N-dynamics in the Erlauf river catchment. Consequently, nitrification of reduced N sources was the main nitrate source except for a number of sub-catchments dominated by agricultural land use. In the Erlauf catchment, denitrification plays only a minor role in controlling NO₃⁻ export on a regional scale.     

Relationship of topography to surface water chemistry with particular focus on nitrogen and organic carbon solutes within a forested watershed in Hokkaido,Japan

We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m²), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ～5·0 to 7·0, with major increases in Na⁺ and Ca²⁺ and marked decreases in NO₃^? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO₃^? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO₃^? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO₃^? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO₃^? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO₃^? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd.     

Spatial patterns of sediment delivery to valley floors: sensitivity to sediment transport capacity and hillslope hydrology relations

There is considerable interest in large‐scale spatial patterns of sediment transport in catchments, and this topic is often approached using terrain‐based modelling. In such models topography influences the discharge of overland flow and its sediment transport capacity. The sediment transport capacity of overland flow is commonly expressed as a power function of slope and discharge (i.e. q_s=k₁q^βS^γ). The relationship between discharge and contributing area can also be expressed as a power function. Several reviews reveal a limited range of values for the two exponents β and γ. In this paper we examine the sensitivity of catchment‐scale patterns of sediment delivery to valley floors to a range of sediment transport capacity and hillslope hydrology parameterizations, using two catchments on the southern tablelands of New South Wales. The results indicate that, over the limited range of β and γ identified within the literature, sediment deliveries to valley floors across the two catchments are similar for all but one of five sediment transport capacity relationships. The patterns are dominated by the trend in slope through each catchment. The sensitivity to hillslope hydrology of predicted sediment delivery patterns is strong in the catchment with systematic variation in unit hillslope area, and weak in the catchment for which there are no systematic trends in unit hillslope area. We believe there is less experimental evidence to restrict choice of hillslope hydrology parameters than there is for sediment transport capacity. Copyright © 2001 John Wiley & Sons, Ltd.     

Influences of catchment characteristics on nitrogen concentration in largely forested streams during the base flow period

Based on measured stream nitrogen concentrations at outlets of 12 small sub‐areas (1·3–54·7 km²) in a largely forested catchment during the base flow period, we investigated the influences of discharges and different catchment characteristics on stream nitrogen concentration. Our field surveys were carried out during the 11‐month's period from April 2001 to February 2002 and the correlations between nitrogen concentrations and catchment characteristics were studied. The results showed that the vegetation cover was strongly correlated to total nitrogen (TN) and nitrate + nitrite ? nitrogen (NO_x‐N) concentrations. That is, the TN and NO_x‐N concentrations had positive correlations with mean normalized difference vegetation cover index (NDVI) of each sub‐area during dormant seasons (mean NDVI < 0 · 70) and had negative correlations during the growing season (mean NDVI ≥ 0 . 70). The significance of catchment characteristics to TN and NO_x‐N concentrations was ranked as vegetation cover > soil > topography > land use, and the best models can account for 55–64% of the variance of TN and NO_x‐N concentrations. Copyright © 2006 John Wiley & Sons, Ltd.     

The relationship between dissolved organic carbon in stream water and soil organic carbon pools at different spatial scales

The relationship between stream water DOC concentrations and soil organic C pools was investigated at a range of spatial scales in subcatchments of the River Dee system in north‐east Scotland. Catchment percentage peat cover and soil C pools, calculated using local, national and international soils databases, were related to mean DOC concentrations in streams draining small‐ (<5 km²), medium‐ (12–38 km²) and large‐scale (56–150 km²) catchments. The results show that, whilst soil C pool is a good predictor of stream water DOC concentration at all three scales, the strongest relationships were found in the small‐scale catchments. In addition, in both the small‐ and large‐scale catchments, percentage peat cover was as a good predictor of stream water DOC concentration as catchment soil C pool. The data also showed that, for a given soil C pool, streams draining lowland (<700 m) catchments had higher DOC concentrations than those draining upland (>700 m) catchments, suggesting that disturbance and land use may have a small effect on DOC concentration. Our results therefore suggest that the relationship between stream water DOC concentration and catchment soil C pools exists at a range of spatial scales and this relationship appears to be sufficiently robust to be used to predict the effects of changes in catchment soil C storage on stream water DOC concentration. Copyright © 1999 John Wiley & Sons, Ltd.     

Chemistry of streams draining grassland and forest catchments at Plynlimon,mid-Wales

Abstract

The chemistry of streamwater, bulk precipitation, throughfall and soil waters has been studied for three years in two plantation forest and two moorland catchments in mid-Wales. Na and CI are the major ions in streamwater reflecting the maritime influence on atmospheric inputs. In all streams, baseflow is characterised by high pH waters enriched in Ca, Mg, Si and HCO³. Differences in baseflow chemistry between streams reflect the varying extent of calcite and base metal sulphide mineralization within the catchments. Except for K, mean stream solute concentrations are higher in the unmineralized and mineralized forest catchments compared with their respective grassland counterparts. In the forest streams, storm flow concentrations of H⁺ are approximately 1.5 times and Al four times higher than in the moorland streams. Annual catchment losses of Na, Cl, SO⁴, NO³, Al and Si are greatest in the forest streams. In both grassland and forest systems, variations in stream chemistry be explained by mixing waters from different parts of the catchment, although NO³ concentrations may additionally be controlled by N transformations occurring between soils and streams. Differences in stream chemistry and solute budgets between forest and moorland catchments are related to greater atmospheric scavenging by the trees and changes in catchment hydrology consequent on afforestation. Mineral veins within the catchment bedrock can significantly modify the stream chemical response to afforestation.     

SULPHATE DYNAMICS IN RELATION TO GROUNDWATER–SURFACE WATER INTERACTIONS IN HEADWATER WETLANDS OF THE SOUTHERN CANADIAN SHIELD

The spatial and temporal distribution of sulphate (SO₄) concentrations in peat pore water and the outlet streams of two forested swamps was related to variations in the magnitude of upland runoff, wetland water levels and flow path. The swamps were located in headwater catchments with contrasting till depths typical of the southern Canadian Shield. Inputs of SO₄ from shallow hillslope tills and streams showed little seasonal variation in either source or concentration in both swamps. Sulphate dynamics at the outlet stream reflected hydrological and biogeochemical processes within the valley wetlands, which in turn were partly controlled by catchment hydrogeology. During high runoff, maximum water table elevations and peak surface flow in the swamps resulted in upland inputs largely bypassing anoxic peat. Consequently, SO₄ concentrations of 8–10 mg/l at the swamp outlets were similar to stream and groundwater inputs. During periods of low flow, concentrations of SO₄ at the swamp outlets declined to less than 3 mg/l. At this time lower water table elevations resulted in increased interaction of input water with anoxic peats, and therefore, SO₄ reduction. Contrasts in till depth and the nature of groundwater flow between catchments resulted in differences in SO₄ dynamics between years and swamps. In dry summers the absence of groundwater inputs to the swamp in the catchment with thin till resulted in a large water table drawdown and re-oxidation of accumulated S, which contributed to maximum SO₄ concentrations (up to 35 mg/l) during storm runoff. Continuous groundwater input to the swamp in the catchment with deeper till was critical to maintaining saturated surfaces and efficient SO₄ retention during both dry and wet summers. A conceptual model of wetland SO₄ retention and export, based on catchment hydrogeology, is developed to generalize the SO₄ dynamics of valley bottom wetlands at the landscape scale. © 1997 by John Wiley & Sons, Ltd.     

Tracking denudation and sediment production and transport with cosmogenic 10Be in arid,high-altitude Himalayan half-grabens,Zanskar, northern India

Understanding the extent to which local factors, including bedrock and structure, govern catchment denudation in mountainous environments as opposed to broader climate or tectonic patterns provides insight into how landscapes evolve as sediment is generated and transported through them, and whether they have approached steady-state equilibrium. We measured beryllium-10 (¹⁰Be) concentrations in 21 sediment samples from glaciated footwall and hanging wall catchments, including a set of nested catchments, and 12 bedrock samples in the Puga and Tso Morari half-grabens located in the high-elevation, arid Zanskar region of northern India. In the Puga half-graben where catchments are underlain by quartzo-feldspathic gneissic bedrock, bedrock along catchment divides is eroding very slowly, about 5 m/Ma, due to extreme aridity and ¹⁰Be concentrations in catchment sediments are the highest (~60–90 × 10⁵ atoms/g SiO₂) as colluvium accumulates on hillslopes, decoupled from their ephemeral streams. At Puga, ¹⁰Be concentrations and the average erosion rates of a set of six nested catchments demonstrate that catchment denudation is transport-limited as sediment stagnates on lower slopes before reaching the catchment outlet. In the Tso Morari half-graben, gneissic bedrock is also eroding very slowly but ¹⁰Be concentrations in sediments in catchments underlain by low grade meta-sedimentary rocks, are significantly lower (~10–35 × 10⁵ atoms/g SiO₂). In these arid, high-elevation environments, ¹⁰Be concentrations in catchment sediments have more to do with bedrock weathering and transport times than steady-state denudation rates. © 2020 John Wiley & Sons, Ltd.     

Modelling interannual variations in catchment evapotranspiration considering vegetation and climate seasonality using the Budyko framework

The Budyko framework is an efficient tool for investigating catchment water balance, focusing on the effects of seasonal changes in climate (S) and vegetation cover (M) on catchment evapotranspiration (ET). However, the effects of vegetation seasonality on ET remain largely unknown. The present study explored these effects by modelling interannual variations in ET considering vegetation and climate seasonality using the Budyko framework. Reconstructed 15-day GIMMS NDVI_3g timeseries data from 1982 to 2015 were used to estimate M and extract the relative duration of the vegetation growing season (GL) in the Yellow River Basin (YRB). To characterize S, seasonal variations in precipitation and potential ET were extracted using a Gaussian algorithm. Analysis of the observed datasets for 19 catchments revealed that interannual variation in the catchment parameter ϖ (in Fuh's equation) was significantly and positively correlated with M and GL. Conversely, ϖ was significantly but negatively correlated with S. Furthermore, stepwise linear regression was used to calibrate the empirical formula of ϖ for these three dimensionless parameters. Following validation, based on observations in the remaining 11 catchments, ϖ was integrated into Fuh's equation to accurately estimate annual ET. Over 79% subcatchments showed an upward trend (0.9 mm yr⁻¹), whereas fewer than 21% subcatchments showed a downward trend (−0.5 mm yr⁻¹) across YRB. In the central region of the middle reach, ET increased with increased M, prolonged GL, and decreased S, whereas in the source region of YRB, ET decreased with decreased M and shortened GL. Our study provides an alternative method to estimate interannual ET in ungauged catchments and offers a novel perspective to investigate hydrological responses to vegetation and climate seasonality in the long-term.     

Relating nitrogen export patterns from a mixed land use catchment in NW Spain with rainfall and streamflow

The temporal variability in nitrogen (N) transport in the Corbeira agroforestry catchment (NW Spain) was analysed from October 2004 to September 2008. Nitrate (NO₃–N) and total Kjeldahl nitrogen (TKN) loads and concentrations were determined at various timescales (annual, seasonal and event). The results revealed a strong intra‐annual and inter‐annual variability in N transport influenced by weather patterns and consequently by the hydrological regime. Mean annual export of total N in the catchment was 5.5 kg ha^?1 year^?1, with NO₃–N being the dominant form. Runoff events comprised 10% of the study period but contributed 40 and 61% of the total NO₃–N and TKN loads, respectively. The NO₃–N and TKN concentrations were higher during runoff events than under baseflow conditions, pointing to diffuse sources of N. The mobilization of TKN during runoff events was attributed to surface runoff, while NO₃–N might be related to subsurface and groundwater flow. Runoff events were characterized by high variability in N loads and concentrations. Higher variability was observed in N loads than in N concentrations, indicating that event magnitude plays an important role in N transport in this catchment; event magnitude explained approximately 96% of the NO₃–N load. However, a combination of variables related to runoff event intensity (rainfall, discharge increase and kinetic energy) explained only 66% of the TKN load. Copyright © 2014 John Wiley & Sons, Ltd.     

Derivation and verification of empirical catchment response time equations for medium to large catchments in South Africa

Despite uncertainties and errors in measurement, observed peak discharges are the best estimate of the true peak discharge from a catchment. However, in ungauged catchments, the catchment response time is a fundamental input to all methods of estimating peak discharges; hence, errors in estimated catchment response time directly impact on estimated peak discharges. In South Africa, this is particularly the case in ungauged medium to large catchments where practitioners are limited to use empirical methods that were calibrated on small catchments not located in South Africa. The time to peak (T_P), time of concentration (T_C) and lag time (T_L) are internationally the most frequently used catchment response time parameters and are normally estimated using either hydraulic or empirical methods. Almost 95% of all the time parameter estimation methods developed internationally are empirically based. This paper presents the derivation and verification of empirical T_P equations in a pilot scale study using 74 catchments located in four climatologically different regions of South Africa, with catchment areas ranging from 20 km² to 35 000 km². The objective is to develop unique relationships between observed T_P values and key climatological and geomorphological catchment predictor variables in order to estimate catchment T_P values at ungauged catchments. The results show that the derived empirical T_P equation(s) meet the requirement of consistency and ease of application. Independent verification tests confirmed the consistency, while the statistically significant independent predictor variables included in the regressions provide a good estimation of catchment response times and are also easy to determine by practitioners when required for future applications in ungauged catchments. It is recommended that the methodology used in this study should be expanded to other catchments to enable the development of a regional approach to improve estimation of time parameters on a national‐scale. However, such a national‐scale application would not only increase the confidence in using the suggested methodology and equation(s) in South Africa, but also highlights that a similar approach could be adopted internationally. Copyright © 2016 John Wiley & Sons, Ltd.     

Fluxes of inorganic carbon from two forested catchments in the Appalachian mountains

This study uses long‐term records of stream chemistry, discharge and air temperature from two neighbouring forested catchments in the southern Appalachians in order to calculate production of dissolved CO₂ and dissolved inorganic carbon (DIC). One of the pair of catchments was clear‐felled during the period of the study. The study shows that: (1) areal production rates of both dissolved CO₂ and DIC are similar between the two catchments even during and immediately after the period of clear‐felling; (2) flux of total inorganic carbon (dissolved CO₂+ DIC) rises dramatically in response to a catchment‐wide acidification event; (3) DIC and dissolved CO₂ are dominantly released on the old water portion of the discharge and concentrations peak in the early autumn when flows in the study catchments are at their lowest; (4) total fluvial carbon flux from the clear‐felled catchment is 11·6 t km⁻² year⁻¹ and for the control catchment is 11·4 t km⁻² year⁻¹. The total inorganic carbon flux represents 69% of the total fluvial carbon flux. The method presented in the study provides a useful way of estimating inorganic carbon flux from a catchment without detailed gas monitoring. The time series of dissolved CO₂ at emergence to the stream can also be a proxy for the soil flux of CO₂. Copyright © 2005 John Wiley & Sons, Ltd.     

Sediment yield studies of headwater catchments in Sussex,S.E. England

The transport of sediment from six small (0.2 to 17.6 km²) headwater catchments is described. The catchments under investigation were located in relation to predominant lithological deposits within the Cretaceous rock succession; two of the areas were underlain by (Weald) clay, two by sandstone (Ashdown Sand and Tunbridge Wells Sand) and two by chalk. The climate of the region under investigation is temperate, with an average annual precipitation (850 mm) in excess of potential evapotranspiration (450 mm). The transport of suspended material from within the catchments was examined by collecting samples of the water-sediment mixture draining the areas, using hand held depth-integrating and permanently installed stage sampling systems. The results of the regularly maintained sampling programme, over a two-year period, are described. Attempts were made to both measure and compute bed load transport. Suspended sediment concentrations are compared between catchments and related to hydrological characteristics. The nature of the material in transit is examined. Sediment rating curves are derived for each of the headwater catchments, defining the relationship in the form y = Ax^b (where y = suspended sediment concentration (mg/1) and x = water discharge (m³/s)). Annual rating curves are used to derive annual suspended sediment loads by combination with water discharge data, using a log-incremental computerized approach. Multiple regression techniques have been used to examine annual loads in terms of hydrological and morphological characteristics of the headwater catchments. Based on the field information available, a generalized model for the relationship between suspended sediment concentration and water discharge is described. Finally, the derived annual loads from the headwater catchments are combined with both limited observations from the larger Sussex rivers and data available for other catchment investigations in the British Isles, to produce a series of prediction equations for catchment yield under temperate climatic conditions.     

Seasonal,hydrological, and land management factors controlling dissolved organic carbon concentrations in the loch fleet catchments,Southwest Scotland

Dissolved organic carbon (DOC) was measured at hourly or two-hourly intervals during more than 30 events in one forested and two moorland subcatchments of the Loch Fleet catchment in southwest Scotland. The dominantly peaty soils in the catchments resulted in small discharge-related DOC variations within individual events, with a maximum range of about 2 mg 1^?1. Seasonal variations were larger with an amplitude of 8-9 mg 1^?1 and maximum concentrations in the summer months. The forested stream had the highest mean DOC, twice as large as the comparable moorland stream in the preliming phase. Applications of lime to the catchments increased stream DOC concentrations, with the largest increases in the moorland catchments.     

Characterization and prediction of stormwater runoff quality in sub-tropical rural catchments

Due to scarcity of local data on stormwater pollution levels and rainfall-runoff generation process, very few attempts have been made towards the management of stormwater in sub-tropical rural catchments. An attempt has been made in the present study to characterize and predict the stormwater runoff characteristics using regression modeling from five rural catchments in north-west India. Stormwater samples and flow data were collected from 75 storm events. Samples were analyzed for pH, total suspended solids (TSS), 5-day biochemical oxygen demand (BOD₅), chemical oxygen demand (COD), total kjeldhal nitrogen (TKN), total phosphorous (TP), nitrate-nitrogen (NO ₃ ^- –N), total coliform count (TC), fecal coliform count (FC), Zn, Cu and Fe. It was found that size of the catchment and the land use practices influenced the stormwater quality even in predominantly rural areas, otherwise thought to be homogeneous. The results obtained were related with the antecedent dry days (ADD) and average rainfall. ADD was found to be positively correlated with pollutant loads whereas average rainfall showed negative correlation. The study highlights the importance of ADD in causing greater mean pollutant concentrations except for TKN, TP and NO ₃ ^- –N. Regression models were developed for the studied catchments to estimate mean pollutant concentrations as a function of rainfall variables. Results revealed that measured pollutant concentrations demonstrated high variability with ADD and average rainfall in small rural catchments, whereas in large catchments, factors like land use, extent of imperviousness etc. resulted in low predictability of measured parameters.