Geneses of High Chlorine and Silver–Lead–Zinc–Mineralized Granitoids in Tsushima, Japan

Abstract: Miocene granitoids of the Tsushima Islands have unique characteristics that cannot be seen in other major granitic plutons in the Japanese Islands as follows: (1) They are granitic in composition but contain synplutonic mafic dikes, abundant mafic enclaves, and intermediate facies between granite and mafic enclaves. (2) They are mixture of magnetite‐bearing and –free facies, but generally magnetite‐free in the marginal part. (3) They are high in K₂O content (K₆₅=3. 1) and intermediate in normative corundum (C₆₅=0. 1) and δ¹⁸O value (+9% at SiO₂ 70 %), which may be comparable with those of the Miocene Outer Zone granitoids. (4) Yet the initial Sr ratio is low as 0. 7037. (5) They are high in Cl and S, which occur in fluid inclusions and as pyrrhotite>pyrite, respectively. Two genetic models are considered for the source of the unique granitoid magmas: the continental crust or the upper mantle fertilized with Si, K and ¹⁸O. The latter may be the case for the Tsushima granitoids, because of the low initial Sr ratio. The age of the granitoids (16 Ma) indicates the magmatism related to the opening of the Sea of Japan. It is suggested that both basaltic and granitic magmas were generated in the continental lithosphere under an extensional tectonic setting; the two magmas could have been partly mingled. The mingled magma was originally an oxidized type, but reduced during the emplacement by repeated inflow of S and C‐bearing gases from the pelitic wall rocks. Because of the reduction, SO₃ sulfur is almost nil in the rock‐forming apatite, and most of sulfur remained in fluid phase of the magma as reduced species. Cl content was high in the original magma and concentrated in the fluid phase of the residual system which dissolved silver, lead and zinc metals. Such a fluid migrated into the Taishu fracture systems, as the magma crystallized, and formed the silver–lead–zinc deposits.     

Geochronology and Geochemistry of Mafic Rocks in the Xuhe, Shaanxi, China: Implications for Petrogenesis and Mantle Dynamics

The Xuhe mafic rocks, located in Ziyang county of Shaanxi Province, are dominated by diabase-porphyrite, gabbro–diabase, diabase, and pyroxene diorite. Primitive mantle-normalized multi-element patterns show that, the Xuhe mafic rocks are enriched in large ion lithophile elements(LITE), such as Ba and Pb, depleted in K and Sr for basic rocks, and are depleted in Sr, P and Ti for pyroxene diorite. Chondrite-normalized REE patterns display LREE enrichment(LaN/YbN = 9.34–13.99) and have normalized patterns for trace element and REE similar to that of typical OIB. Detailed SIMS zircon U–Pb dating yields emplacement ages of 438.4 ± 3.1 Ma for Xuhe mafic rocks. The relatively low Mg O(basic rock: 3.11–7.21 wt%; pyroxene diorite: 0.89–1.21 wt%) and Mg#(0.20–0.49) for Xuhe mafic rocks suggest that they were possibly originated from an extremely evolved magma. The rising parental mafic magmas underwent pyroxene and plagioclase fractionation. Crustal contamination of pyroxene diorite before emplacement occurred at a higher crustal level compared to other lithology in Xuhe mafic rocks. The degree of partial melt was low(5%–10%) and in garnetspinel transition facies. Sr-Nd isotope of pyroxene diorite and enrichment mantle characteristics for Xuhe mafic rocks suggest that mafic rocks in the North Daba Mountains were derived from a mixture of HIMU, EMII and small amount of EMI components. Furthermore, this study discusses mantle geodynamic significance of Xuhe mafic rocks in the Silurian, which indicates subduction and uplift of magma caused back-arc extension.     

The petrology of the Mt Manypeaks Adamellite and associated high‐grade metamorphic rocks near Albany,Western Australia

The Mt Manypeaks Adamellite is a composite, regionally concordant pluton at least 22 km long and 3 km wide, associated with Precambrian amphibolite facies gneisses of the Albany‐Esperance Block, and situated about 35 km east of Albany, Western Australia. The pluton is surrounded by a granitised aureole, and shows structural and mineralogical harmony with the country rocks. Contacts vary from grada‐tional to sharp. Hence field relations are consistent with syn‐ or late‐kinematic emplacement in the catazone. The normative composition of the pluton corresponds with the thermal trough in the system An‐Ab‐Or‐Q‐H2O at 7 kb PH2O, suggesting an origin involving crystal‐melt equilibria. The pluton is believed to have formed almost in situ by partial anatexis of the country rocks at 700–750°C and a depth of about 25 km during the orogenic episode responsible for regional metamorphism and deformation.     

Strontium isotopic and chemical variations of the granitic rocks in the Tsukuba district,Japan

Initial ⁸⁷Sr/⁸⁶Sr ratios, major and trace element compositions have been determined for the Paleogene granitic rocks in the Tsukuba district, Japan. Isotopic ages strongly suggest that the granitic rocks (seven units) were continuously emplaced and solidified during a short time interval. Initial ⁸⁷Sr/⁸⁶Sr ratios for seven granitic units vary from 0.7082 to 0.7132, while sedimentary and metasedimentary country rocks have ratios at the time of granitic magma emplacement ranging from 0.7149 to 0.7298. Continuous linear arrays for the granitic rocks in the diagrams of initial ⁸⁷Sr/⁸⁶Sr ratios versus some chemical parameters can be explained by either of following two processes. One is the assimilation — fractional crystallization (AFC) process between the parental magma (SiO₂ of 68% and initial ratio of 0.7078) and sedimentary country rocks, and the other is magma mixing process between above parental magma and sediment derived acidic magma (melt) (SiO₂ of 75%). The high initial ratios (0.7078–0.7098) for basic rocks such as gabbro or diorite in the Tsukuba district and the similar characteristics observed in the rocks of Ryoke belt (SW Japan) suggest that the parental magma had the same source region as the basic rocks, probably the lower crustal source.     

The Aguablanca Ni–(Cu) sulfide deposit, SW Spain: geologic and geochemical controls and the relationship with a midcrustal layered mafic complex

The Aguablanca Ni–(Cu) sulfide deposit is hosted by a breccia pipe within a gabbro–diorite pluton. The deposit probably formed due to the disruption of a partially crystallized layered mafic complex at about 12–19 km depth and the subsequent emplacement of melts and breccias at shallow levels (<2 km). The ore-hosting breccias are interpreted as fragments of an ultramafic cumulate, which were transported to the near surface along with a molten sulfide melt. Phlogopite Ar–Ar ages are 341–332 Ma in the breccia pipe, and 338–334 Ma in the layered mafic complex, and are similar to recently reported U–Pb ages of the host Aguablanca Stock and other nearby calc-alkaline metaluminous intrusions (ca. 350–330 Ma). Ore deposition resulted from the combination of two critical factors, the emplacement of a layered mafic complex deep in the continental crust and the development of small dilational structures along transcrustal strike-slip faults that triggered the forceful intrusion of magmas to shallow levels. The emplacement of basaltic magmas in the lower middle crust was accompanied by major interaction with the host rocks, immiscibility of a sulfide melt, and the formation of a magma chamber with ultramafic cumulates and sulfide melt at the bottom and a vertically zoned mafic to intermediate magmas above. Dismembered bodies of mafic/ultramafic rocks thought to be parts of the complex crop out about 50 km southwest of the deposit in a tectonically uplifted block (Cortegana Igneous Complex, Aracena Massif). Reactivation of Variscan structures that merged at the depth of the mafic complex led to sequential extraction of melts, cumulates, and sulfide magma. Lithogeochemistry and Sr and Nd isotope data of the Aguablanca Stock reflect the mixing from two distinct reservoirs, i.e., an evolved siliciclastic middle-upper continental crust and a primitive tholeiitic melt. Crustal contamination in the deep magma chamber was so intense that orthopyroxene replaced olivine as the main mineral phase controlling the early fractional crystallization of the melt. Geochemical evidence includes enrichment in SiO₂ and incompatible elements, and Sr and Nd isotope compositions (⁸⁷Sr/⁸⁶Sr_i 0.708–0.710; ¹⁴³Nd/¹⁴⁴Nd_i 0.512–0.513). However, rocks of the Cortegana Igneous Complex have low initial ⁸⁷Sr/⁸⁶Sr and high initial ¹⁴³Nd/¹⁴⁴Nd values suggesting contamination by lower crustal rocks. Comparison of the geochemical and geological features of igneous rocks in the Aguablanca deposit and the Cortegana Igneous Complex indicates that, although probably part of the same magmatic system, they are rather different and the rocks of the Cortegana Igneous Complex were not the direct source of the Aguablanca deposit. Crust–magma interaction was a complex process, and the generation of orebodies was controlled by local but highly variable factors. The model for the formation of the Aguablanca deposit presented in this study implies that dense sulfide melts can effectively travel long distances through the continental crust and that dilational zones within compressional belts can effectively focus such melt transport into shallow environments.Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Age of granite emplacement in the Norseman region of Western Australia

Ion probe U‐Th‐Pb dating of zircons from the Late Archaean granites of the Norseman region of the southeastern Yilgarn shows the existence of two distinct magmatic episodes. Large regional tonalite and granodiorite plutons were emplaced between 2685 and 2690 Ma, whereas large regional granite, and small tonalite and leucogranite plutons that intrude the greenstones have ages of 2660–2665 Ma. A small body of granite that intrudes the western edge of the greenstones has an inferred emplacement of 2672 ± 7Ma, and contains inherited zircon that is ～2800 Ma. The monzogranite core from a second pluton in a similar structural position also contains ～2800 Ma zircon; this age is similar to published Sm‐Nd and Rb‐Sr whole rock ages for banded gneisses associated with other members of this suite of domal plutons and is interpreted as representing the age of a significant component within the source region for these distinctive rocks.

Available geochemical and isotopic data are interpreted as indicating derivation of both the older granodiorite and younger granite suites through anatexis of pre‐existing crust of broadly andesitic composition, whereas both the domal granites and the small, late tonalite plutons could have been derived by anatexis of heterogeneous material similar to that represented by the banded gneisses.

If regional metamorphism was related to the emplacement of large volumes of felsic magma within the upper crust, as suggested by Binns et al. (1976), then the Norseman area has probably undergone two periods of regional metamorphism of comparable intensity at approximately 2660 and 2685 Ma.     

The granite problem as exposed in the southern Snake Range,Nevada

A geochemically and mineralogically diverse group of granitoids is present within an area of 900 km² in the southern Snake Range of eastern Nevada. The granitoids exposed range in age from Jurassic through Cretaceous to Oligocene and include two calcic intrusions, two different types of two-mica granites, and aplites. The younger intrusions appear to have been emplaced at progressively more shallow depths. All of these granitoid types are represented elsewhere in the eastern Great Basin, but the southern Snake Range is distinguished by the grouping of all these types within a relatively small area. The Jurassic calcic pluton of the Snake Creek-Williams Canyon area displays large and systematic chemical and mineralogical zonation over a horizontal distance of five km. Although major element variations in the pluton compare closely with Daly's average andesite-dacite-rhyolite over an SiO₂ range of 63 to 76 percent, trace element (Rb, Sr, Ba) variations show that the zonation is the result of in situ fractional crystallization, with the formation of relatively mafic cumulates on at least one wall of the magma chamber. Models of trace element and isotopic data indicate that relatively little assimilation took place at the level of crystallization. Nonetheless, an initial ⁸⁷Sr/⁸⁶Sr value of 0.7071 and δ ¹⁸O values of 10.2 to 12.2 permil suggest a lower crustal magma that was contaminated by upper crustal clastic sedimentary rocks before crystallization. The involvement of mantle-derived magmas in its genesis is difficult to rule out. Two other Jurassic plutons show isotopic and chemical similarities to the Snake Creek-Williams Canyon pluton. Cretaceous granites from eastern Nevada that contain phenocrystic muscovite are strongly peraluminous, and have high initial Sr-isotope ratios and other features characteristic of S-type granitoids. They were probably derived from Proterozoic metasediments and granite gneisses that comprise the middle crust of this region. Another group of granitoids (including the Tertiary aplites) show chemical, mineralogic, and isotopic characteristics intermediate between the first two groups and may have been derived by contamination of magmas from the lower crust by the midcrustal metasediments.     

Mesoproterozoic Fraser Complex: Geochemical evidence for multiple subduction‐related sources of lower crustal rocks in the Albany‐Fraser Orogen,Western Australia

The 1300 Ma Fraser Complex in the Albany‐Fraser Orogen of Western Australia is a thrust stack of mainly gabbroic rocks metamorphosed to granulite facies. This package of fault‐bounded units was elevated from a deep crustal level onto the margin of the Yilgarn Craton during continental collision between the Mawson and Yilgarn Cratons. Incompatible trace‐element distributions demand at least three mantle sources. Primitive‐mantle‐normalised incompatible‐element distributions show strong negative Ta–Nb anomalies, typical of subduction‐derived magmas. Three lines of evidence indicate that the mafic magmas did not acquire these anomalies by assimilation of crustal rocks: (i) major‐element compositions do not allow appreciable contamination with felsic material; (ii) Ni contents of many mafic rocks are too high for a significant contribution from a felsic assimilant; and (iii) Sr and Nd isotopic data support a largely juvenile source for the magmas that produced the Fraser Complex. Hence, the Ta–Nb anomalies are interpreted to reflect subduction‐related magmatic sources. On multielement diagrams, depletions in Sr, Eu, P, and Ti can be explained by fractional crystallisation, whereas Th and Rb depletions in many of the Fraser Complex rocks probably reflect losses during granulite‐facies metamorphism. These results suggest that the lower crust in this region at 1300 Ma was dominantly of arc origin, and there is no evidence to support mantle plume components. The Fraser Complex is interpreted as remnants of oceanic arcs that were swept together and tectonically interleaved with the margin of the Mawson Craton just before, or during, collision with the Yilgarn Craton at 1300 Ma.     

The geochemical and Sr–Nd isotopic characteristics of Eocene to Miocene NW Anatolian granitoids: Implications for magma evolution in a post-collisional setting

Early Eocene to Early Miocene magmatic activity in northwestern Anatolia led to the emplacement of a number of granitoid plutons with convergent margin geochemical signatures. Granitoid plutons in the area are mainly distributed within and north of the suture zone formed after the collision of the Anatolide-Tauride platform with the Pontide belt. We present geochemical characteristics of three intrusive bodies in the region in order to identify their source characteristics and geodynamic significance. Among these, the Çataldağ and Ilıca-Şamlı plutons are located to the north and the Orhaneli pluton is located to the south of the IAESZ (Izmir-Ankara-Erzincan Suture Zone). The plutons are calc-alkaline, metaluminous, and I-type with compositions from granite to monzonite. They display clear enrichments in LILE and LREE and depletions in HFSE relative to N-MORB compositions and have high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd ratios.The results of theoretical Fractional Crystallization (FC) model show that the samples are affected by fractionation of K-feldspar, plagioclase, biotite and amphibole. Assimilation and Fractional Crystallization (AFC) modeling indicates that the r value, the proportion of variable contamination to fraction, is high, indicating significant crustal contamination in the genesis of granitoid magmas. Combined evaluation of isotopic and trace element data indicates that the granitoids are the products of mantle-derived mafic magmas variably differentiated by simultaneous crustal contamination and fractional crystallization in lower to middle crustal magma chambers in a post-collisional setting.     

Synplutonic mafic dykes from late Archaean granitoids in the Eastern Dharwar Craton,southern India

We present a first overview of the synplutonic mafic dykes (mafic injections) from the 2.56–2.52 Ga calcalkaline to potassic plutons in the Eastern Dharwar Craton (EDC). The host plutons comprise voluminous intrusive facies (dark grey clinopyroxene-amphibole rich monzodiorite and quartz monzonite, pinkish grey porphyritic monzogranite and grey granodiorite) located in the central part of individual pluton, whilst subordinate anatectic facies (light grey and pink granite) confined to the periphery. The enclaves found in the plutons include highly angular screens of xenoliths of the basement, rounded to pillowed mafic magmatic enclaves (MME) and most spectacular synplutonic mafic dykes. The similar textures of MME and adjoining synplutonic mafic dykes together with their spatial association and occasional transition of MME to dismembered synplutonic mafic dykes imply a genetic link between them. The synplutonic dykes occur in varying dimension ranging from a few centimeter width upto 200 meters width and are generally dismembered or disrupted and rarely continuous. Necking of dyke along its length and back veining of more leucocratic variant of the host is common feature. They show lobate as well as sharp contacts with chilled margins suggesting their injection during different stages of crystallization of host plutons in magma chamber. Local interaction, mixing and mingling processes are documented in all the studied crustal corridors in the EDC. The observed mixing, mingling, partial hybridization, MME and emplacement of synplutonic mafic dykes can be explained by four stage processes: (1) Mafic magma injected during very early stage of crystallization of host felsic magma, mixing of mafic and felsic host magma results in hybridization with occasional MME; (2) Mafic magma introduced slightly later, the viscosities of two magmas may be different and permit only mingling where by each component retain their identity; (3) When mafic magma injected into crystallizing granitic host magma with significant crystal content, the mafic magma is channeled into early fractures and form dismembered synplutonic mafic dykes and (4) Mafic injections enter into largely crystallized (>80% crystals) granitic host results in continuous dykes with sharp contacts. The origin of mafic magmas may be related to development of fractures to mantle depth during crystallization of host magmas which results in the decompression melting of mantle source. The resultant hot mafic melts with low viscosity rise rapidly into the crystallizing host magma chamber where they interact depending upon the crystallinity and viscosity of the host. These hot mafic injections locally cause reversal of crystallization of the felsic host and induce melting and resultant melts in turn penetrate the crystallizing mafic body as back veining. Field chronology indicates injection of mafic magmas is synchronous with emplacement of anatectic melts and slightly predates the 2.5 Ga metamorphic event which affected the whole Archaean crust. The injection of mafic magmas into the crystallizing host plutons forms the terminal Archaean magmatic event and spatially associated with reworking and cratonization of Archaean crust in the EDC.     

H,O, Sr,Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions,New Mexico,and relations between evolution of a continental magmatic center and modifications of the lithosphere

Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5–19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary ¹⁸O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in ¹⁸O. Initial ⁸⁷Sr/⁸⁶Sr ratios (0.705 to 0.708), ¹⁸O values (-2 to-7), and ²⁰⁶Pb/²⁰⁴Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (25 Ma) and Rio Hondo (21 Ma) plutons have relatively homogeneous initial ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. ¹⁸O values for all the postcaldera plutons overlap those of the precaldera rocks and Amalia Tuff, except for those for two late-stage rhyolite dikes associated with the Rio Hondo pluton that have ¹⁸O values of-8.6 and-9.5; these dikes are the only Latir rocks which may be largely crustal melts.Chemical and isotopic data from the Latir field suggest that large fluxes of mantle-derived basaltic magma are necessary for developing and sustaining large-volume volcanic centers. Development of a detailed model suggests that 6–15 km of new crust may have been added beneath the volcanic center; such an addition may result in significant changes in the chemical and Sr and Nd isotopic compositions of the crust, although Pb isotope ratios will remain relatively unchanged. If accompanied by assimilation, crystallization of pooled basaltic magma near the MOHO may produce substantial cumulates beneath the MOHO that generate large changes in the isotopic composition of the upper mantle. The Latir field may be similar to other large-volume, long-lived intracratonal volcanic fields that fundamentally owe their origins to extensive injection of basaltic magma into the lower parts of their magmatic systems. Such fields may overlie areas of significant crustal growth and hybridization.     

The genesis of Variscan (Hercynian) plutonic rocks: Inferences from Sr,Pb, and O studies on the Maladeta igneous complex,central Pyrenees (Spain)

The Maladeta plutonic complex formed during the latest stages of the Variscan orogeny. It was emplaced into the Paleozoic sedimentary sequence of the Pyrenees. The eastern part, investigated in the present study, consists of an early intrusion of cumulate gabbronorites followed in order of emplacement by the main biotite-hornblende granodiorite, which was itself intruded by two small stocks of two-mica cordierite granite. An ⁸⁷Rb-⁸⁷Sr isochron dates the granodiorite at 277±7 m.y. with an initial (⁸⁷Sr/⁸⁶Sr)_o ratio of 0.7117±3. Gabbroic rocks have lower strontium initial ratios, down to 0.7092, while those of granite range from that of the granodiorite up to about 0.715. The three rock types have distinctive ¹⁸O values: 8.7 to 9.6 for the gabbronorites, 9.4 to 10.4 for the granodiorites and 10.3 to 11.8 for the granites. Lead isotopic compositions of rocks and feldspars are all radiogenic. Feldspars give consistent Pb model ages around 280 m.y., with and values of about 9.7 and 4.05, respectively. No pristine, mantle-derived magma was found among the investigated samples and the rocks cannot be related to one another by any simple mechanism of fractional crystallization. Some type of mixing process involving two end members seems to be required: a high-¹⁸O, high-⁸⁷Sr material that is clearly of crustal origin, and a lower-¹⁸O, lower-⁸⁷Sr end member derived from the mantle. Examination of various mixing models does not support magma mixing nor assimilation of crustal rocks by a mafic magma. The most acceptable model involves melting at different levels of a vertically-zoned source in the continental crust; this source was formed by mixing between mantle-derived magmas and crustal metasediments. This material was apparently thickened, tectonically downwarped and partially melted. None of the Maladeta magma-types appear to have been derived at a consuming plate boundary.Contribution Number 3280, Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA     

K‐Ar age determination,whole‐rock and oxygen isotope geochemistry of the post‐collisional Bizmişen and Çaltı plutons,SW Erzincan,eastern Central Anatolia,Turkey

Post‐collisional granitoid plutons intrude obducted Neo‐Tethyan ophiolitic rocks in central and eastern Central Anatolia. The Bizmişen and Çaltı plutons and the ophiolitic rocks that they intrude are overlain by fossiliferous and flyschoidal sedimentary rocks of the early Miocene Kemah Formation. These sedimentary rocks were deposited in basins that developed at the same time as tectonic unroofing of the plutons along E–W and NW–SE trending faults in Oligo‐Miocene time. Mineral separates from the Bizmişen and Çaltı plutons yield K‐Ar ages ranging from 42 to 46 Ma, and from 40 to 49 Ma, respectively. Major, trace, and rare‐earth element geochemistry as well as mineralogical and textural evidence reveals that the Bizmişen pluton crystallized first, followed at shallower depth by the Çaltı pluton from a medium‐K calcalkaline, I‐type hybrid magma which was generated by magma mixing of coeval mafic and felsic magmas. Delta ¹⁸O values of both plutons fall in the field of I‐type granitoids, although those of the Çaltı pluton are consistently higher than those of the Bizmişen pluton. This is in agreement with field observations, petrographic and whole‐rock geochemical data, which indicate that the Bizmişen pluton represents relatively uncontaminated mantle material, whereas the Çaltı pluton has a significant crustal component. Structural data indicating the middle Eocene emplacement age and intrusion into already obducted ophiolitic rocks, suggest a post‐collisional extensional origin. However, the pure geochemical discrimination diagrams indicate an arc origin which can be inherited either from the source material or from an upper mantle material modified by an early subduction process during the evolution of the Neo‐Tethyan ocean. Copyright © 2005 John Wiley & Sons, Ltd.     

Fractionation,hybridisation and magma-mixing in the Kialineq centre East Greenland

The igneous rocks of the Kialineq centre on the coast of East Greenland at 67°N include a number of quartz syenite and granite plutons intruded 35my BP. These are subvolcanic bodies emplaced by cauldron subsidence and with ring-dike and bell-jar form. Associated with the major intrusions is an extensive acid-basic mixed magma complex. Two-liquid structures, chilling of basic against acid magma, pillows of basic in acid, and net-veining of basic by acid magma, are superbly displayed. The basic magma was of a transitional or alkaline type and underwent varying degrees of fractionation in a regime of repeated intrusions and diverse chambers. Heterogeneous hybrid rocks intermediate between basalt and quartz syenite are strongly developed and were formed by repeated mechanical mixing of contrasting magmas. The energy for this mixing probably came in the main from cauldron-block subsidence. The quartz syenite magma, which itself fractionated towards granite, has initial ⁸⁷Sr/⁸⁶Sr ratios the same as the basic magma and is itself believed to be a fractionation product of alkali basalt magma.     

The radiometric age of the Albany Granite and the Stirling Range Beds,Southwest Australia

The reported age of 1,100 ± 50 m.y. for the Albany Granite is taken as marking the waning stages of the main orogeny in the south coast of Western Australia. The high initial ⁸⁷Sr/⁸⁶Sr for this granite, 0.7118 ± 0.0064, suggests an anatectic or rheomorphic origin which is consistent with petrographic evidence for the absence of a later metamorphism. Shales from the Stirling Range Beds indicate a metamorphic event at 1,150 ± 40 m.y. which is considered to be the time of upthrusting of rocks of higher metamorphic grade to their present position adjacent to the Stirling Range Beds. The minimum age of deposition for the Stirling Range Beds is postulated as 1,340 m.y.     

Evidence for Multiple Mechanisms of Crustal Contamination of Magma from Compositionally Zoned Plutons and Associated Ultramafic Intrusions of the Alaska Range

Models of continental crustal magmagenesis commonly invoke theinteraction of mafic mantle-derived magma and continental crustto explain geochemical and petrologic characteristics of crustalvolcanic and plutonic rocks. This interaction and the specificmechanisms of crustal contamination associated with it are poorlyunderstood. An excellent opportunity to study the progressiveeffects of crustal contamination is offered by the compositeplutons of the Alaska Range, a series of nine early Tertiary,multiply intruded, compositionally zoned (Peridotite to granite)plutons. Large initial Sr and Nd isotopic contrasts betweenthe crustal country rock and likely parental magmas allow evaluationof the mechanisms and extents of crustal contamination thataccompanied the crystallization of these ultra-mafic throughgranitic rocks. Three contamination processes are distinguishedin these plutons. The most obvious of these is assimilationof crustal country rock concurrent with magmatic fractionalcrystallization (AFC), as indicated by a general trend towardcrustal-like isotopic signatures with increasing differentiation.Second, many ultramafic and mafic rocks have late-stage phenocrystreaction and orthocumulate textures that suggest interactionwith felsic melt. These rocks also have variable and enrichedisotopic compositions that suggest that this felsic melt wasisotopically enriched and probably derived from crustal countryrock. Partial melt from the flysch country rock may have reactedwith and contaminated these partly crystalline magmas followingthe precipitation and accumulation of the cumulus phenocrystsbut before complete solidification of the magma. This suggeststhat in magmatic mush (especially of ultramafic composition)crystallizing in continental crust, a second distinct processof crustal contamination may be super imposed on AFC or magmamixing involving the main magma body. Finally, nearly all rocks,including mafic and ultramafic rocks, have (⁸⁷Sr/⁸⁶Sr)_i thatare too high, and (T) _Nd that are too low, to represent theexpected isotopic composition of typical depleted mantle. However,gabbro xenoliths with typical depicted-mantle isotopic compositionsare found in the plutons. This situation requires either anadditional enriched mantle component to provide the parentalmagma for these plutons, or some mechanism of crustal contaminationof the parent magma that did not cause significant crystallizationand differentiation of the magma to more felsic compositions.Thermodynamic modeling indicates that assimilation of alkali-andwater-rich partial melt of the metapelite country rock by fractionating,near-liquidus basaltic magma could cause significant contaminationwhile suppressing significant crystallization and differentiation. KEY WORDS: crustal contamination; Alaska Range; isotope geochemistry; zoned plutons; assimilation ^*Corresponding author. e-mail: preiners{at}u.washington.edu; fax: (206) 543-3836.     

新疆东天山旱草湖环状岩体锆石U-Pb年龄、地球化学特征及成因

以新疆东天山旱草湖地区中酸性环状岩体为研究对象,进行LA-ICP-MS锆石U-Pb年龄和全岩地球化学研究,探讨其成因和地质意义。结果表明,侵入英云闪长岩的最老年龄为275.0±2.9Ma(MSWD=4.8),侵位时代为二叠纪。岩体Al_2O_3含量为14.46%～17.05%,A/CNK为0.93～1.09,属准铝质和弱过铝质系列,较富集K_2O,MgO含量较低,为0.71%～2.84%,Mg~#值为33.3～48.6。微量元素高Sr、低Y,Sr含量为217×10~(-6)～740×10~(-6),Y含量为4.26×10~(-6)～21.4×10~(-6),Sr/Y值为16.87～145.07,富集大离子亲石元素Rb、Sr、Ba,亏损高场强元素Nb、Ta、Ti。稀土元素配分模式图呈现平坦右倾的轻稀土元素富集、重稀土元素亏损,表明岩体来源于石榴子石和金红石较稳定而斜长石不稳定的区域,属于角闪岩相向榴辉岩相过渡阶段,可能是同时期底侵的产物。地球化学特征表明岩体不是一期岩浆事件结晶分离演化的结果,不同岩性的岩体之间没有发生结晶分离。部分熔融程度和新生幔源组分的不同导致了旱草湖环状花岗质岩体的形成,二叠纪旱草湖地区存在较强烈的中酸性岩浆活动,是东天山二叠纪构造-岩浆演化的响应。     

Isotopic Signatures of Neoproterozoic to Cambrian Ultrapotassic Syenitic Magmas,Northeastern Brazil: Evidence for an Enriched Mantle Source

Neoproterozoic to Cambrian ultrapotassic (K₂O up to 13 wt%) peralkalic alkali-feldspar-rich syenitic plutons were emplaced along the boundary between the Cachoeirinha-Salgueiro and Alto Pajeu tectonostratigraphic terranes of the Borborema structural province, northeastern Brazil. Syenite and alkalic pyroxenitic magmas coexisted in these plutons, which locally carry mica pyroxenite xenoliths. In the Triunfo batholith, the largest peralkalic pluton in the region, syenites and alkalic pyroxenites have high pyroxene-corrected δ¹⁸O values (+8.1 to + 8.5‰_SMOW in the syenite and +7.6 to + 7.7‰ in the alkalic pyroxenite), high δ³⁴S (+12.3‰_CDT in syenite and + 11.2‰_CDT in alkalic pyroxenite), high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7098, syenite and alkalic pyroxenite data lying on the same Rb-Sr isochron), and low εNd (?15.3 to ?17.2 in syenite and ?16.1 in pyroxenite). Whole-rock δ¹⁸O_SMOW for mica pyroxenite xenoliths varies from +7.5 to +8.0‰_SMOW. Syenite, alkalic pyroxenite, and xenoliths all are enriched in large-ion lithophile elements (LILE). These geochemical and isotopic signatures suggest that the magmas were derived from an incompatible-element-enriched mantle source; this protolith probably resulted from hybridization by addition of crustal material via subduction at ～2.4 Ga, as estimated from Nd model ages. Partial melting of metasomatized material and magma emplacement at a late stage of the Brasiliano Orogeny (566 Ma) were controlled by mantle-deep shear zones during the amalgamation of the Cachoeirinha-Salgueiro and Alto Pajeu terranes.     

Xiba Granitic Pluton in the Qinling Orogenic Belt,Central China: Its Petrogenesis and Tectonic Implications

Xiba granitic pluton is located in South Qinling tectonic domain of the Qinling orogenic belt and consists mainly of granodiorite and monzogranite with significant number of microgranular quartz dioritic enclaves. SHRIMP zircon U–Pb isotopic dating reveals that the quartz dioritic enclaves formed at 214±3 Ma, which is similar to the age of their host monzogranite (218±1 Ma). The granitoids belong to high-K calc-alkaline series, and are characterized by enriched LILEs relative to HFSEs with negative Nb, Ta and Ti anomalies, and right-declined REE patterns with (La/Yb)N ratios ranging from 15.83 to 26.47 and δEu values from 0.78 to 1.22 (mean= 0.97). Most of these samples from Xiba granitic pluton exhibit εNd(t) values of ?8.79 to ?5.38, depleted mantle Nd model ages (TDM) between 1.1 Ga and 1.7 Ga, and initial Sr isotopic ratios (87Sr/86Sr)i from 0.7061 to 0.7082, indicating a possible Meso- to Paleoproterozoic lower crust source region, with exception of samples XB01-2-1 and XB10-1 displaying higher (87Sr/86Sr)i values of 0.779 and 0.735, respectively, which suggests a contamination of the upper crustal materials. Quartz dioritic enclaves are interpreted as the result of rapid crystallization fractionation during the parent magmatic emplacement, as evidenced by similar age, texture, geochemical, and Sr-Nd isotopic features with their host rocks. Characteristics of the petrological and geochemical data reveal that the parent magma of Xiba granitoids was produced by a magma mingling process. The upwelling asthenosphere caused a high heat flow and the mafic magma was underplated into the bottom of the lower continent crust, which caused the partial melting of the lower continent crustal materials. This geodynamic process generated the mixing parent magma between mafic magma from depleted mantle and felsic magma derived from the lower continent crust. Integrated petrogenesis and tectonic discrimination with regional tectonic evolution of the Qinling orogen, it is suggested that the granitoids are most likely products in a post-collision tectonic setting.     

Eocene I-type magmatism in the Eastern Pontides,NE Turkey: insights into magma genesis and magma-tectonic evolution from whole-rock geochemistry,geochronology and isotope systematics

ABSTRACT

The Eastern Pontides orogenic belt in NE Turkey hosts numerous I-type plutons of Eocene epoch. Here, we report new U–Pb SHRIMP zircon ages and in situ zircon Lu-Hf isotopes along with bulk-rock geochemical and Sr-Nd-Pb-O isotope data from the Kemerlikda??, Ayd?ntepe and Pelitli plutons and mafic microgranular enclaves (MMEs) to constrain their parental melt source(s) and evolutionary processes. U-Pb SHRIMP zircon dating yielded crystallization ages between 45 and 44 Ma for the studied plutons and their MMEs. The plutons range from gabbro to granite and have I-type, medium to high-K calc-alkaline, and metaluminous to slightly peraluminous characteristics. On the primitive mantle-normalized multi-trace-element variations, the plutons and their MMEs are characterized by signi?cant enrichment in LILE/HFSE. Chondrite-normalized REE patterns of the plutons and their MMEs are close to each other and show moderate enrichment with variable negative Eu anomalies. The studied plutons have fairly homogeneous isotope composition (⁸⁷Sr/⁸⁶Sr_(i) = 0.70502 to 0.70560; εNd_(i) = +0.9 to – 1.4; δ¹⁸O = +5.0 to +8.7‰, εHf_(i) = – 2.2 to +13.5). The MMEs show medium to high-K calc-alkaline and metaluminous character. Although the isotope signatures of the MMEs (⁸⁷Sr/⁸⁶Sr_(i) = 0.70508 to 0.70542; εNd_(i) = +0.9 to ?1.1; δ¹⁸O = +5.8 to +8.0, εHf_(i) = +4.3 to +10.4) are very similar to those of the host rocks. Fractionation of plagioclase, amphibole, pyroxene and Fe-Ti oxides played an important role in the evolution of the plutons. The isotopic composition of the studied plutons and MMEs are similar to I-type plutons derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. The parental magma(s) of the studied plutons were generated from the enriched lithospheric mantle and then modified by fractional crystallisation, and lesser assimilation and mixing/mingling in the crustal magma chambers.