Late Pleistocene glaciolacustrine sedimentation and paleogeography of southeastern Michigan,USA

The geomorphic, stratigraphic and sedimentological characteristics of glaciolacustrine sediments in the metropolitan Detroit, Michigan area were studied to determine environments of deposition and make paleogeographic reconstructions. Nine lithofacies were identified and paleoenvironments interpreted based on their morphostratigraphic relationships with relict landforms. The sediments studied are found southeast of the Defiance and Birmingham moraines lying beneath a lowland characterized by a low morainal swell (Detroit moraine) and a series of lacustrine terraces that descend progressively in elevation southeastward. The glaciolacustrine sediments were deposited approximately 14.3–12.4 kA BP during the Port Bruce and Port Huron glacial phases of late Wisconsinan time, and are related to proglacial paleolakes Maumee, Arkona, Whittlesey, Warren, Wayne, Grassmere, Lundy and Rouge. The glaciolacustrine section is typically 2–4 m thick and consists of a basal unit of wavy-bedded clayey diamicton overlain by a surficial deposit of stratified and cross-stratified sand and gravel. The basal unit is comprised of subaqueous debris flow deposits that accumulated as subaqueous moraine in paleolake Maumee along the retreating front of the Huron lobe. The surficial deposits of sand and gravel were formed by traction, resulting from lacustrine wave activity and fluvial processes, in lakebed plain, beach ridge and deltaic depositional settings. Much of the lake-margin sand and gravel was derived from clayey diamicton by lacustrine wave action and winnowing, and that associated with paleolakes of the Port Huron phase is largely reworked Port Bruce sediment. Paleogeographic reconstructions show that the Defiance, Birmingham and Detroit moraines, Defiance and Rochester channels, and the Rochester delta, were deposited penecontemporaneously as paleolake Maumee expanded northward across the map area. A unique type of wavy bedform is characteristic of clayey diamicton deposited by subaqueous mass flow in the study area that is useful for differentiating sediment: 1) deposited by mass flow in subaqueous vs. subaerial settings, and 2) deposited by subaqueous mass flow vs. basal till. These bedforms are a useful tool for identifying subglacial meltwater deposits, and facilitate the mapping and correlation of glacial sediments based on till sheets. The map area provides a continental record of ice sheet dynamics along the southern margin of the Laurentide ice sheet during Heinrich event H-1. The record reveals rapid glacial retreat (～ 0.8 km/yr) contemporaneous with the discharge of a large volume of meltwater. Evidence in the study area for subglacial meltwater is problematic, but indications that periglacial conditions persisted in the map area until ～ 12.7 kA BP, and extended for 200 km or more south of the ice front suggest that a frozen substrate may have contributed to instability of the LIS.     

Metal speciation in coastal marine sediments from Singapore using a modified BCR-sequential extraction procedure

The chemical speciation of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in marine sediments from two coastal regions of Singapore (Kranji in the NW, and Pulau Tekong in the NE) was determined using the latest version of the 3-step sequential extraction procedure, as described by the European Community Bureau of Reference (1999). To obtain a mass balance, a fourth step, i.e., digestion and analysis of the residue was undertaken using a microwave-assisted acid digestion procedure. The total content of all metals except for Pb in sediments was greater in Kranji than in Pulau Tekong. All metals, except Cd were more mobile and bio-available in Kranji, where metals were present at higher percentages in the acid-soluble fractions (the most labile fraction). In sediments from Kranji, the mobility order of the heavy metals studied was Cd > Ni > Zn > Cu > Pb > Cr, whereas sediments from Pulau Tekong showed the same order for Cd, Ni, Pb and Cr, but had a reverse order for Cu and Zn (Cu > Zn). The highest percentages of Cr, Ni and Pb were found in the residual fractions in both Kranji (78.9%, 54.7%, 55.9%, respectively) and Pulau Tekong (82.8%, 77.3%, 62.2%, respectively), meaning that these metals were strongly bound to the sediments. Results are consistent with findings from Barcelona, Spain where similar results for Cr and Ni have also been reported for marine sediments. The sum of the 4 steps (acid-soluble + reducible + oxidizable + residual) was in good agreement with the total content, which implies that the accuracy of the microwave extraction procedure in conjunction with the GFAAS analytical method is assured.     

Sedimentology of the December 26, 2004, Sumatra tsunami deposits in eastern India (Tamil Nadu) and Kenya

The December 26, 2004 Sumatra tsunami caused severe damage at the coasts of the Indian ocean. We report results of a sedimentological study of tsunami run-up parameters and the sediments laid down by the tsunami at the coast of Tamil Nadu, India, and between Malindi and Lamu, Kenya. In India, evidence of three tsunami waves is preserved on the beaches in the form of characteristic debris accumulations. We measured the maximum run-up distance at 580 m and the maximum run-up height at 4.85 m. Flow depth over land was at least 3.5 m. The tsunami deposited an up to 30 cm thick blanket of moderately well to well-sorted coarse and medium sand that overlies older beach deposits or soil with an erosional unconformity. The sand sheet thins inland without a decrease of grain-size. The deposits consist frequently of three layers. The lower one may be cross-bedded with foresets dipping landward and indicating deposition during run-up. The overlying two sand layers are graded or parallel-laminated without indicators of current directions. Thus, it remains undecided whether they formed during run-up or return flow. Thin dark laminae rich in heavy minerals frequently mark the contacts between successive layers. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth. On the Indian shelf these depths are present at distances of up to 5 km from the coast. In Kenya only one wave is recorded, which attained a run-up height of 3 m at a run-up distance of ca. 35 m from the tidal water line at the time of the tsunami impact. Only one layer of fine sand was deposited by the tsunami. It consists predominantly of heavy minerals supplied to the sea by a nearby river. The sand layer thins landward with a minor decrease in grain-size. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth, reaching down potentially to ca. 80 m. The presence of only one tsunami-related sediment layer in Kenya, but three in India, reflects the impact of only one wave at the coast of Kenya, as opposed to several in India. Grain-size distributions in the Indian and Kenyan deposits are mostly normal to slightly positively skewed and indicate that the detritus was entrained by the tsunami from well sorted pre-tsunami deposits in nearshore, swash zone and beach environments.     

A sustained +21 m sea-level highstand during MIS 11 (400 ka): direct fossil and sedimentary evidence from Bermuda

A small, protected karstic feature exposed in a limestone quarry in Bermuda preserved abundant sedimentary and biogenic materials documenting a transgressive phase, still-stand, and regressive phase of a sea-level in excess of 21.3 m above present during Marine Isotope Stage (MIS) 11 (400 ka) as determined by U/Th dating and amino acid racemization. Cobbles and marine sediments deposited during the high-energy transgressive phase exhibit rim cements indicating a subsequent phreatic environment. This was succeeded stratigraphically by a still-stand deposition of fine calcareous lagoonal sediments containing bioclasts of red algae and benthic and planktonic foraminifera that was intensely burrowed by marine invertebrates, probably upogebiid shrimp, that could not be produced under any condition other than sustained marine submergence. Overlying this were pure carbonate beach sands of a low-energy regressive phase containing abundant remains of terrestrial and marine vertebrates and invertebrates. The considerable diversity of this fauna along with taphonomic evidence from seabird remains indicates deposition by high run-up waves over a minimum duration of months, if not years. The maximum duration has yet to be determined but probably did not exceed one or two thousand years. The most abundant snails in this fauna are two species indicative of brackish water and high-tide line showing that a Ghyben-Herzberg lens must have existed at > + 20 m. The nature of these sediments and fossil accumulation is incompatible with tsunami deposition and, given the absence of evidence for tectonic uplift of the Bermuda pedestal or platform, provide proof that sea-level during MIS 11 exceeded +20 m, a fact that has widespread ramifications for geologists, biogeographers, and human demographics along the world's coastlines.     

Metal contamination and solid phase partitioning of metals in the stream and bottom sediments in a reservoir receiving mine drainage

This study was conducted to assess the anthropogenic impact on metal concentrations in the bottom sediments of the Juam reservoir, Korea, and in stream sediments in its catchment, and to estimate the potential mobility of selected metals (Fe, Mn, Cu, Ni, Pb and Zn) using sequential extraction. A comparison of the metal concentrations in the stream sediments with mean background values in sediments collected from first- or second-order creeks shows that Pb, Cu and Ni are the most affected by anthropogenic inputs. The ²⁰⁶Pb/²⁰⁷Pb ratios of the bottom and core sediments (means: 1.2320 ± 0.0502 and 1.2212 ± 0.0040, respectively) suggest that Pb contamination is mainly due to the waste discharge of abandoned coal and metal mines rather than industrial and airborne sources. Considering the proportion of metals bound to the exchangeable, carbonate and reducible fractions, the comparative mobility of metals is suggested to decrease in the order Mn > Pb > Zn > Ni > Fe ≫ Cu.     

Significance of slope sediments layering on physical characteristics and interflow within the Critical Zone – Examples from the Colorado Front Range,USA

The subalpine to montane zones within the Critical Zone (CZ) of the Colorado Front Range, USA outside Pleistocene glaciation limits are characterized by the abundance of stratified and multilayered slope deposits exhibiting depths >1 m. Initial luminescence dating for the upper sediment layers in different profiles give last glacial ages ranging between 40 and 12 ka. A periglacial origin by solifluction is hypothesized for these slope deposits, which is corroborated by geomorphic and sedimentologic parameters. The stratified slope sediments have a strong influence on the physical and chemical properties as well as on soil forming processes in the CZ. Examples are provided for the sediment derived contribution of some elements and common clay minerals together and the great importance of slope sediments as barriers and pathways for the interflow that runs in sediment layers are shown.     

Distinction between the Storegga tsunami and the holocene marine transgression in coastal basin deposits of western Norway

Many coastal lakes were inundated by both the Storegga tsunami (7000 ¹⁴C yr BP) and the mid-Holocene sea-level rise (the Tapes transgression) in western Norway. The tsunami eroded lake bottoms and deposited graded and/or massive beds of sand, rip-up clasts, and coarse plant material. By contrast, when the rising sea entered the lakes, it deposited only gyttja, silt and fine sand, without causing much erosion of the underlying lake sediments. Storegga tsunami deposits in some coastal lakes were interpreted previously as ordinary marine sediments from the Tapes transgression. Our reinterpretation of these deposits shows that the transgression maximum phase was reached after 6500 yr BP, more than 1000 yr later than previously inferred for the coast of Sunnmøre. The new data cannot be combined in a shoreline diagram without showing the 6000 yr BP and 7000 yr BP shorelines as slightly warped. © 1998 John Wiley & Sons, Ltd.     

The effect of weathering on the grain-size distribution of red soils in south-eastern China and its climatic implications

Particle-size analysis is a useful way to determine the source and deposition of sediments. However, there are inconsistencies when this method is used to constrain the origin of the red soils in south-eastern China. To address this problem, we performed a detailed grain-size analysis of two red soil sequences in Xuancheng and Qiliting located along the lower reaches of the Yangtze River. By comparing their particle-size characteristics with those of the loess on the Loess Plateau in northern China, we found that the aeolian samples plot in a particular zone in the C–M (grain size of the cumulative 1% versus median grain size) plot and cluster nearer the lower left corner of the plot as their degree of weathering increases. The grain-size features suggest that the onset of large-scale aeolian deposition along the lower reaches of the Yangtze River occurred at approximately 0.8 Ma. Although both sedimentary sorting and post-depositional weathering control the grain-size variations in the deposits, the extremely strong weathering due to the humid, warm climate along the lower reaches of the Yangtze River primarily modified the grain-size distributions of the primary red soil deposits. Strong weathering increased the very fine silt (2–5 μm) fraction and decreased the coarse (>63 μm) fraction. We also found that certain grain-size parameters of the red soils varied with the weathering intensity, which can be used as indicators of palaeoclimate variations. The grain size variations in both the Qiliting and Xuancheng sequences suggest that the mid-Pleistocene climate transition (MPT) may have affected the lower reaches of the Yangtze River at 0.9 Ma.     

Mineralogy of low grade metamorphosed manganese sediments of the Urals: Petrological and geological applications

The paper describes mineralogy of the low grade metamorphosed manganese sediments, which occur in sedimentary complexes of the Pai Khoi Ridge and the Polar Urals and volcanosedimentary complexes of the Central and South Urals. The degree of metamorphism of the rocks studied corresponds to PT conditions of the prehnite–pumpellyite (deposits of Pai Khoi and Polar and South Urals) and green schist (deposits of the Central Urals) facies. One hundred and nine minerals were identified in the manganese-bearing rocks on the basis of optical and electron microscopy, X-ray diffraction, and microprobe analysis. According to the variations in the amount of major minerals of the manganese rocks of the Urals, they are subdivided on carbonate (I), oxide–carbonate–silicate (II), and oxide–silicate (III) types. Carbonates, various Mn^2 +-bearing silicates associated with oxides and carbonates, and braunite (Mn^3 +-bearing silicate) are the major Mn hosts in types I, II, and III, respectively. Because of the different oxidation state of Mn, the rocks of types I and II are termed as “reduced” and the rocks of type III, as “oxidized”. The formation of a certain mineralogical type of metamorphic assemblage is controlled by the content of organic matter in the primary sediments. The sequence type I → type II → type III reflects the decrease in the amount of organic matter in metalliferous sediments. Mineralogical data indicate that manganese in the primary sediments accumulated in a silicate form (MnSi gel, glass, etc). During diagenesis, the Mn–Si phase was transformed to neotokite with subsequent formation of caryopilite and further crystallization of pyroxmangite, rhodonite, tephroite, and other silicates due to reactions involving caryopilite. The hydrated Mn-silicates (caryopilite and/or friedelite) and the spatially associated parsettensite, stilpnomelane, and other minerals are the index minerals of the low grade metamorphism. Under PT conditions of prehnite–pumpellyite facies, nearly 70% of silicate minerals are hydrous. The metamorphosed Mn-bearing sediments are characterized by the low-temperature caryopilite (or tephroite-caryopilite-pyroxmangite ± rhodonite) and the high-temperature caryopilite-free (or tephroite-pyroxmangite ± rhodonite) facies. Their PT conditions correspond to zeolite and prehnite-pumpellyite (the low-temperature) and green schist and higher grade (the high-temperature) facies.     

Actively forming Kuroko-type volcanic-hosted massive sulfide (VHMS) mineralization at Iheya North,Okinawa Trough,Japan

Modern seafloor hydrothermal systems provide important insights into the formation and discovery of ancient volcanic-hosted massive sulfide (VHMS) deposits. In 2010, Integrated Ocean Drilling Program (IODP) Expedition 331 drilled five sites in the Iheya North hydrothermal field in the middle Okinawa Trough back-arc basin, Japan. Hydrothermal alteration and sulfide mineralization is hosted in a geologically complex, mixed sequence of coarse pumiceous volcaniclastic and fine hemipelagic sediments, overlying a dacitic to rhyolitic volcanic substrate. At site C0016, located adjacent to the foot of the actively venting North Big Chimney massive sulfide mound, massive sphalerite-(pyrite-chalcopyrite ± galena)-rich sulfides were intersected (to 30.2% Zn, 12.3% Pb, 2.68% Cu, 33.1 ppm Ag and 0.07 ppm Au) that strongly resemble the black ore of the Miocene-age Kuroko deposits of Japan. Sulfide mineralization shows clear evidence of formation through a combination of surface detrital and subsurface chemical processes, with at least some sphalerite precipitating into void space in the rock. Volcanic rocks beneath massive sulfides exhibit quartz-muscovite/illite and quartz-Mg-chlorite alteration reminiscent of VHMS proximal footwall alteration associated with Kuroko-type deposits, characterized by increasing MgO, Fe/Zn and Cu/Zn with depth. Recovered felsic footwall rocks are of FII to FIII affinity with well-developed negative Eu anomalies, consistent with VHMS-hosting felsic rocks in Phanerozoic ensialic arc/back-arc settings worldwide.Site C0013, ∼100 m east of North Big Chimney, represents a likely location of recent high temperature discharge, preserved as surficial coarse-grained sulfidic sediments (43.2% Zn, 4.4% Pb, 5.4% Cu, 42 ppm Ag and 0.02 ppm Au) containing high concentrations of As, Cd, Mo, Sb, and W. Near surface hydrothermal alteration is dominated by kaolinite and muscovite with locally abundant native sulfur, indicative of acidic hydrothermal fluids. Alteration grades to Mg-chlorite dominated assemblages at depths of >5 mbsf (metres below sea floor). Late coarse-grained anhydrite veining overprints earlier alteration and is interpreted to have precipitated from down welling seawater as hydrothermal activity waned. At site C0014, ∼350 m farther east, hydrothermal assemblages are characterized by illite/montmorillonite, with Mg-chlorite present at depths below ∼30 mbsf. Recovered lithologies from distal, recharge site C0017 are unaltered, with low MgO, Fe₂O₃ and base metal concentrations.Mineralization and alteration assemblages are consistent with the Iheya North system representing a modern analogue for Kuroko-type VHMS mineralization. Fluid flow is focussed laterally along pumiceous volcaniclastic strata (compartmentalized between impermeable hemipelagic sediments), and vertically along faults. The abundance of Fe-poor sphalerite and Mg-rich chlorite (clinochlore/penninite) is consistent with the lower Fe budget, temperature and higher oxidation state of felsic volcanic-hosted hydrothermal systems worldwide compared to Mid Ocean Ridge black smoker systems.     

Sedimentology of tsunami inflow and backflow deposits: key differences revealed in a modern example

Onshore tsunami deposits may consist of inflow and backflow deposits. Grain sizes can range from clay to boulders of several metres in diameter. Grain‐size distributions reflect the mode of deposition and may be used to explore the hydrodynamic conditions of transport. The absence of unique sedimentary features identifying tsunami deposits makes it difficult in some cases to distinguish inflow from backflow deposits. On Isla Mocha off central Chile, the 27 February 2010 tsunami left behind inflow and backflow deposits of highly variable character. Tsunami inflow entrained sands, gravels and boulders in the upper shoreface, beach, and along coastal terraces. Boulders of up to 12 t were transported up to 300 m inland and 13 m above sea‐level. Thin veneers of coarse sand were found up to the maximum runup at 600 m inland and 19 m above sea‐level. Backflow re‐mobilized most of the sands and gravels deposited during inflow. The orientation of erosional structures indicates that significant volumes of sediment were entrained also during backflow. A major feature of the backflow deposits are widespread prograding fans of coarse sediment developed downcurrent of terrace steps. Fan sediments are mostly structureless but include cross‐bedding, imbrication and ripples, indicating deposition from bedload traction currents. The sediments are poorly sorted, grain sizes range between medium to coarse sand to gravel and pebbles. An assessment of the backflow transport conditions of this mixed material suggests that bedload transport at Rouse numbers >2·5 was achieved by supercritical flows, whereas deposition occurred when currents had decelerated sufficiently on the low‐gradient lower coastal plain. The sedimentary record of the February 2010 tsunami at Isla Mocha consists of backflow deposits to more than 90%. Due to the lack of sedimentary structures, many previous studies of modern tsunami sediments found that most of the detritus was deposited during inflow. This study demonstrates that an uncritical use of this assumption may lead to erroneous interpretations of palaeotsunami magnitudes and sedimentary processes if unknowingly applied to backflow deposits.     

Late Miocene continental sedimentation in southwestern Amazonia and its regional significance: Biotic and geological evidence

Fossil content (vertebrate paleofauna and palynology) indicates that the sediments of the Solimões Formation in Acre (SW Brazilian Amazonia) are continental, having been deposited by avulsive fluvial belts in a floodbasin–floodplain environment. The main source area was the Andes chain. Widespread lacustrine swampy deposits, stacked channel deposits, and paleosoils are typical elements that characterize the Solimões Formation sediments that outcrop in southwestern Brazilian Amazonia. New data on fossil vertebrate assemblages and palynology corroborate the Late Miocene age suggested previously and assign the fossils to the Huayquerian mammalian biozone, spanning 9–6.5 Ma. These geological and paleontological data show that the existence of an intracontinental seaway through SW Amazonia during the Late Miocene (11–10 Ma), connecting the Caribbean Sea with the Parana Basin as previously proposed is unsustainable, because the sediments used by previous authors to propose the seaway were deposited in a continental environment and are younger than 11–10 Ma.     

Geochemistry of coastal sands of Eastern Mediterranean: The case of Nisyros volcanic materials

Coastal sand samples collected from the northern part of Nisyros volcanic island (Dodecanese, Greece) were investigated for first time for their potential in strategic metals and compared with parental rocks of the island which are Quaternary volcanics with alternating lava flows, pyroclastic layers and lava domes and relevant materials located near granitoids of Northern Greece. The PXRD and SEM-EDS study of the sands revealed enhanced content of feldspars, Fe-Mn oxides, magnetite, tourmaline, pyroxenes, ilmenites, along with zircons, apatite and sulfide inclusions. The fresh hydrothermally deposited clayely material collected from the Nisyros caldera crater had a rather different mineralogical composition from the coastal one (alunite, anhydrite, opal-CT, quartz, kaolinite). UCC-normalized spidergrams indicated that the weathering processes contributed to accumulation of heavy minerals (mainly ilmenite), and strategic metals including V (1920 mg/kg) and Nb (245 mg/kg), in the coastal sand. The low REE concentration (ΣREE + Y = 240 mg/kg) could be attributed to the absence of REE-rich minerals. Moreover, the sands exhibit different geochemical patterns compared to the volcanic source rocks of the island, which are especially enriched in Large-Ion Lithophile Elements (LILE) and depleted in High Field Strength Elements (HFSE), such as Nb and Ta. On the other hand, the caldera material is enriched in volatile components, sulfur, chalcophile elements (Se, Bi, Hg, As, Pb) and Ba. Micro-XRF analyses of representative crystals showed that the high Nb content of the sands was associated with the Ti/Fe-rich phases (e.g. ilmenites). The geochemical composition of N Greece sands showed, because of their origin, enrichment not only in HFSE but also in REE.The study of the coastal heavy mineral sands originating from different geological environments of Greece provides information about the association of their mineral components with REE, other elements of economic interest (e.g. Co, Nb, Ta) and natural actinides. In addition, the study of the black sands of Nisyros island could be considered as a characteristic example of those from other parts of Hellenic Volcanic Arc (HVA) and other relevant Mediterranean regions.     

Quaternary hinterland evolution of the active Banda Arc: Surface uplift and neotectonic deformation recorded by coral terraces at Kisar,Indonesia

Coral terrace surveys and U-series ages of coral yield a surface uplift rate of ∼0.5 m/ka for Kisar Island, which is an emergent island in the hinterland of the active Banda arc–continent collision. Based on this rate, Kisar first emerged from the ocean as recently as ∼450 ka. These uplifted terraces are gently warped in a pattern of east–west striking folds. These folds are strike parallel to more developed thrust-related folds of similar wavelength imaged by a seismic reflection profile just offshore. This deformation shows that the emergence of Kisar is influenced by forearc closure along the south-dipping Kisar Thrust. However, the pinnacle shape of Kisar and the protrusion of its metamorphic rocks through the forearc basin sediments also suggest a component of extrusion along shear zones or active doming.Coral encrusts the island coast in many locations over 100 m above sea level. Terrace morphology and coral ages are best explained by recognizing major surfaces as mostly growth terraces and minor terraces as mostly erosional into older terraces. All reliable and referable coral U-series ages determined by MC-ICP-MS correlate with marine isotope stage (MIS) 5e (118–128 ka). The only unaltered coral samples are found below 6 m elevation; however an unaltered Tridacna (giant clam) shell in growth position at 95 m elevation yields a U-series age of 195 ± 31 ka, which corresponds to MIS 7. This age agrees with the best-fit uplift model for the island. Loose deposits of unaltered coral fragments found at elevations between 8 and 20 m yield U-series ages of <100 years and may represent paleotsunami deposits from previously undocumented tectonic activity in the region.     

New geochemical and mineralogical constraints on the genesis of the Vani hydrothermal manganese deposit at NW Milos island,Greece: Comparison with the Aspro Gialoudi deposit and implications for the formation of the Milos manganese mineralization

The Mn-Ba-Pb deposit at Aspro Gialoudi in NW Milos is shown to be a fossil inhalative-exhalative hydrothermal deposit that represents the deepest part of the Vani succession at the western extremity of the main Vani manganese deposit. The geology of the Vani-Aspro Gialoudi area is characterized by Upper Pliocene-Lower Pleistocene dacitic and rhyodacitic lava domes, which are overlain by the Vani volcaniclastic unit considered to be part of the 2.66–1.44 Ma magmatic event at Milos Island. The presence of in-situ and intrusive hyaloclastite breccias surrounding the coherent lava domes at Aspro Gialoudi and Vani areas indicates submarine emplacement for the domes. The dacitic-rhyodacitic domes are variously altered (mainly propylitic and/or argillic alteration, silicified and in some cases locally exhibiting adularia alteration). Both Aspro Gialoudi and main Vani deposit are located proximal to fault systems: the main Vani manganese deposit is adjacent to the NW-trending Kondaros-Katsimouti-Vani Dome fault, whereas the Aspro Gialoudi deposit is adjacent to the relatively minor NE-trending fault on the west coast of Milos. At Aspro Gialoudi, mineralization took place in a subseafloor and/or seafloor environment and is characterized by a stratabound Mn-barite-rich deposit mainly within a package of propylitized intrusive hyaloclastites and within the overlying sandstones. Banded epithermal veins trending NE-SW and composed of chalcedonic silica/quartz + barite + Mn-oxide ± sulfides crosscut the dacitic lavas, the hyaloclastites and the overlying volcaniclastic sequence at Aspro Gialoudi and are considered to represent the feeder zones of the manganese-barite mineralization. Within the veins, early sulfide (galena-sphalerite) barite and quartz deposition is followed by manganese oxides and aragonite, thus resembling the epithermal-style Pb-Zn-Ag-Mn mineralization across the NW-trending Katsimoutis-Kondaros-Vani fault. Mineralization in Aspro Gialoudi and Vani deposits seems to be controlled by alternating cycles of deposition of sulfides and hydrothermal manganese oxides within the faults. Manganese deposition in both deposits formed in a similar manner, namely by transport of hydrothermal fluids through the adjacent fault systems into a reservoir of volcanoclastic sandstone and hyaloclastites to produce a deposit initially consisting of principally of pyrolusite and occasionally ramsdellite, which were subsequently replaced by cryptomelane, hollandite, coronadite and hydrohaeterolite. Precipitation of hydrothermal manganese oxides took place very quick and under microbial Mn(II) oxidation. Compositional data show that metallic elements most enriched in the Aspro Gialoudi and Vani manganese deposits relative to the average continental crust, lie in the sequences Pb > Cd > Mn > As > Sb > Zn > W > Tl > Ba > Cu > Mo > Co > Bi and As > Sb > Pb > Mn > Tl > Cd > Zn > W > Cu > Ba > Mo > Co, respectively. Mineralogical and geochemical (e.g. REE) data from both Aspro Gialoudi and main Vani deposit are taken to indicate mainly a seawater source for the hydrothermal fluids. These two deposits are genetically and spatially related to base- and precious metal intermediate-sulfidation epithermal mineralization. They formed successively by similar processes and are considered to be integral parts of the same hydrothermal system.     

A late Pleistocene human presence at Huaca Prieta,Peru, and early Pacific Coastal adaptations

Archaeological excavations in deep pre-mound levels at Huaca Prieta in northern Peru have yielded new evidence of late Pleistocene cultural deposits that shed insights into the early human occupation of the Pacific coast of South America. Radiocarbon dates place this occupation between ~ 14,200 and 13,300 cal yr BP. The cultural evidence shares certain basic technological and subsistence traits, including maritime resources and simple flake tools, with previously discovered late Pleistocene sites along the Pacific coast of Peru and Chile. The results help to expand our knowledge of early maritime societies and human adaption to changing coastal environments.     

Pyrite compositions from VHMS and orogenic Au deposits in the Yilgarn Craton,Western Australia: Implications for gold and copper exploration

The Archaean Yilgarn Craton (Western Australia) is a world-class metallogenic province, hosting considerable resources of Au, Ag, Ni, Cu, Zn and Fe. Here we present trace element compositions of pyrite from > 30 orogenic Au and 5 volcanic hosted massive sulphide (VHMS) deposits across the Yilgarn. Pyrites from VHMS deposits tend to have higher Sn, Se, Cu, Pb, Bi and lower Ni relative to orogenic deposits. VHMS deposit pyrites commonly have Co > Ni, As > 100Au, Te > Au, Se > Te. Orogenic gold deposits could be subdivided based on association of Au with As or Te. Pyrites from AuAs ores generally have Pb/Bi > 5, Se/Te > 5, Pb/Sb < 5 and Tl/Te > 100 and the majority of Au is refractory (in pyrite structure). At the same time AuTe association pyrites are characterised by lower values of Pb/Bi, Se/Te and Tl/Te, higher values of Ag/Au, Pb/Sb and Au generally resides in inclusions of different compositions. Our data can be used at the exploration stage to distinguish between VHMS vs Orogenic Au signatures. For all studied deposits inclusion populations are summarised with implications for Au and Ag deportment. Orogenic Au deposits from the Yilgarn mostly have multistage formation histories reflected in the presence of multiple generations of pyrites. However, only some deposits record multiple high Au mineralisation events.     

Beach deposits of MIS 5e high sea stand as indicators for tectonic stability of the Carmel coastal plain,Israel

Ten beach deposits, mainly beachrock, on the Carmel coastal plain, northern Israel, are discussed. Six are reported for the first time. The deposits are situated within or close to the following seasonal stream (locally termed Nahal) channels: Nahal Ahuza, Amiram, Ovadia, Galim, Megadim, Bir Ibdawiya, Me’arot and Kebara. The morphology and lithology of most of the deposits are similar: their uppermost altitude varies from 0 to 9 m above the present sea level. Most of the deposits are composed mainly of fine quartz sand and marine mollusk shells carbonate cemented. The dominant mollusk families are Glycymerididae, Cardiidae and Donacidae. Most of the beach deposits are situated between cemented aeolian sandstones (locally termed kurkar) layers on the Carmel coast ridge. In the Nahal Ahuza deposit, a marine gastropod Lentigo latus, an index fossil for the MIS 5e high sea stand in the Mediterranean area was discovered.According to lithology and chronostratigraphy, the presence of Lentigo latus, Th/U, AAR and RTL dating and flint artifacts, the beach deposits were related to the Last Interglacial maximum about 125 ka BP, i.e. the MIS 5e high sea stand. These beach deposits are used to identify the palaeo sea levels and coastlines and to study the tectonics along the Carmel coastal plain. By comparing the elevations and characteristics of the beach deposits to known MIS 5e deposits elsewhere, and by analyzing archaeological data, it is concluded that during the last 125 ka, the maximum possible vertical displacement was less than 48 mm/ka, and the Carmel coastal plain was relatively tectonically stable.     

The Late Quaternary sediment successions of Llangorse Lake,south Wales

The last British-Irish Ice Sheet (BIIS) created a landscape with many sedimentary basins that preserve archives of paleoenvironmental and paleoclimatic change during the Last Glacial-Interglacial Transition (LGIT; ~ 18-8 ka BP). The typical lithostratigraphic succession of these archives is composed of minerogenic/allogenic sediments formed during cold climatic conditions and organic-rich/authigenic sediments during warmer climates. This paper presents a multi-core lithostratigraphy compiled from the extant lake and surrounding basin at Llangorse Lake, south Wales, a basin lying within the southernmost limits of the last BIIS. This lake contains one of the longest continuous terrestrial sediment successions in the UK. Uncertainty previously existed concerning the presence and distribution of sediments at the site related to the Windermere Interstadial (~ 14.7 to ~ 12.9 ka BP) and Loch Lomond Stadial (~ 12.9 to 11.7 ka BP). A new borehole survey demonstrates that LGIT-age sediments are present at the site with nekron mud (gyttja), corresponding to the Lateglacial Interstadial, deposited in the deeper part of the lake waters and that these deposits are equivalent in age to marl deposits found at shallower depths at the margins of the basin. These deposits are associated with warmer conditions experienced during the Windermere Interstadial and Holocene, whilst minerogenic-rich sediments were deposited during the colder climatic conditions of the Dimlington Stadial and the Loch Lomond Stadial with rangefinder radiocarbon dates confirming this attribution. A model of lake level changes shows that drainage of the Dimlington Stadial glacial lake caused the largest fall, but there was also a further, smaller lake level fall at the end of the Windermere Interstadial and/or the start of the Loch Lomond Stadial, before the level rose in the early Holocene. The lithostratigraphic results presented here form the framework for further paleoenvironmental and paleoclimatic research at Llangorse Lake.     

Fluid origin of fluorite-rich carbonate-hosted Pb–Zn mineralization of the Himalayan–Zagros collisional orogenic system: A case study of the Mohailaheng deposit,Tibetan Plateau,China

A significant belt of carbonate-hosted Pb–Zn mineralization occurs in the Himalayan–Zagros collisional orogenic system. Three differing types of these Pb–Zn deposits within this belt have been identified based on variations in gangue mineral assemblages, leading to the classification of carbonate-, quartz- and fluorite-rich classes of Pb–Zn deposits. The third Pb–Zn mineralization (fluorite-rich) type is common in this orogenic system, but little research has been undertaken on it. Here, we focus on the Mohailaheng deposit, a large-sized fluorite-rich carbonate-hosted Pb–Zn deposit (> 100 Mt Pb + Zn ores with average grade of 2.18%–4.23%); the deposit is located in the Sanjiang Cenozoic thrust-fold belt, an important part of the Himalayan–Zagros collisional orogenic system and an area that formed during the early Tertiary India–Eurasia collision. The main orebodies in this deposit are stratabound and are hosted by Carboniferous limestones that are located along secondary faults associated with a regional thrust fault. The main assemblage is a sphalerite + galena + pyrite sulfide assemblage associated with a calcite + fluorite + barite + quartz + dolomite gangue assemblage. Detailed field and experimental work indicates that the deposit formed during three distinct phases of hydrothermal activity. Studies on fluid inclusion and stable isotopes of gangue minerals indicate that two dominant distinct fluids involving the deposit formation. They include (1) a low-temperature (130–140 °C), high-salinity (23–24 wt.% NaCl equivalent) basinal brine containing Na⁺–K⁺–Mg^2 +–Ca^2 +–Cl⁻ ions and abnormally high SO₄^2 − concentrations, which probably derived from Tertiary basins in the regional district, and (2) a low- to moderate-temperature (170–180 °C) and moderate- to high-salinity (19–20 wt.% NaCl equivalent) metamorphic fluid containing Na⁺–K⁺–Mg^2 +–Cl^––SO₄^2 − ions and abnormally high F⁻ and organic matter concentrations, that probably formed during regional metamorphism. Some evaporated seawaters and meteoric fluids were also identified in mixtures with these two dominant fluids. The Pb–Zn mineralization at Mohailaheng formed during three distinct stages, consistent with the regional tectonic history. The first stage involved the formation of favorable lithological and structural traps at Mohailaheng during regional thrusting, leading to the migration of compressed metamorphic waters at depth along a detachment zone, sequestering metals from sediments within the region. Basinal brines at the surface also began to infiltrate down along the secondary faults, dissolving gypsum from the underlying sediments. The second stage was associated with the cessation of thrusting and the onset of strike-slip movements along these thrust faults. Metamorphic fluids containing high concentrations of halogen ions, organic gases, and metals ascended into the structural traps at Mohailaheng along the reactivated thrust faults, causing fluorite, calcite, and some sulfide precipitation. Then, basinal brines rich in SO₄^2 − quickly descended into the structural traps along the reactivated faults, causing reduction of SO₄^2 − by organic matter, and producing significant amounts of H₂S. The reduced sulfur then reacted with the metals in the fluids, causing significant sulfide precipitation. The third stage was associated with metal-depleted fluids, which only resulted in the precipitation of calcite from the diluted basinal brines. Combining these findings with research results on other fluorite-rich carbonate-hosted Pb–Zn deposits in the Himalayan–Zagros orogenic system suggests that this type of carbonate-hosted Pb–Zn deposits can also be classified as Mississippi Valley-type (MVT) deposits, and that the origin of the fluorite in these deposits may be related to multiple hydrothermal fluids involved in the mineralization evolution.