Insights into the water retention behaviour of GMZ bentonite pellet mixture

Bentonite pellets are recognized as good buffer/backfill materials for sealing technological voids in high-level radioactive waste (HLW) repository. Compared to that of a traditional compacted bentonite block, one of the most important particularities of this material is the initially discrete pellets and the inevitable heterogeneous porosity formed, leading to a distinctive water retention behaviour. In this paper, water retention and mercury intrusion porosimetry (MIP) tests were conducted on pellet mixture (constant volume), single pellet (free swelling) and compacted block (constant volume) of GMZ bentonite, water retention properties and pore structure evolutions of the specimens were comparatively investigated. Results show that the water retention properties of the three specimens are almost similar to each other in the high suction range (>?10 MPa), while the water retention capacity of pellet mixture is lower than those of the compacted block and single pellet in the low suction range (<?10 MPa). Based on the capillary water retention theory (the Young–Laplace equation), a new concept ‘saturated void ratio’ that was positively related to water content and dependent on pore size distribution of the specimen was defined. Then, according to the product of saturated void ratio and water density in saturated void, differences of water retention properties for the three specimens at low suctions were explained. Meanwhile, MIP tests indicate that as suction decreases, the micro- and macrovoid ratios of pellet mixture and compacted block decrease as the mesovoid ratio increases, while all the void ratios of single pellets increase. This could be explained that upon wetting, water is successively adsorbed into the inter-layer, inter-particle and inter-pellet voids, leading to the subdivision of particles and swelling of aggregates and pellets. Under constant volume condition, aggregates and pellets tend to swell and fill into the inter-aggregates or inter-pellets voids. While under free swelling condition, the particles and aggregates in a single pellet tend to swell outward rather than squeezing into the inter-aggregate voids, leading to the expansion of the pores and even formation of cracks. Results including the effects of initial conditions (initial dry density and fabric) and constraint conditions (constant volume or free swelling) on the water retention capacity and pore structure evolution reached in this work are of great importance in designing of engineering barrier systems for the HLW repository.

     

Hydro-mechanical path dependency of claystone/bentonite mixture samples characterized by different initial dry densities

In the context of the French Cigéo-project, a mixture composed of 70% processed Callovo-Oxfordian claystone spoil and 30% MX80-bentonite could be a potential backfill material, whose installation aims to stabilize the surrounding rock formation and to limit the propagation of the excavation damaged zone. The backfill material must sustain the overburden pressure, despite that it might be exposed to different hydraulic and mechanical paths. The reference concept considers employing conventional compaction techniques, although their employment involves spatial variations in the dry density after compaction. In general, as the initial dry density has a significant impact on the hydro-mechanical behavior of backfill materials, it is of major importance to relate the variations in the initial dry density to differences in the behavior. This experimental laboratory study aimed to analyze how variations in the initial dry density affect the swelling and compression behavior of the claystone/bentonite mixture, in particular in unsaturated state. Further, it evaluated whether those variations affected possible hydro-mechanical path dependences. The experimental program comprised suction-controlled oedometer and constant-volume swelling pressure experiments, in which samples characterized by different initial dry densities were exposed to different hydro-mechanical paths. The analysis of microstructural and water retention characteristics complemented the program. Major results indicated that the magnitude of swelling pressure at a given suction depends considerably on the initial dry density, but it is independent of the imposed hydro-mechanical path. Interestingly, the dependency of the yield behavior on the hydro-mechanical path appears to be more pronounced as the initial dry density increases.

     

全吸力范围生物炭−黏土混合土的土−水特性

土−水特征曲线在研究非饱和土的水力与力学特性中发挥着重要的作用。生物炭具有多孔结构、高比表面积和强吸附的特性。将生物炭改性土应用于垃圾填埋场上覆盖层,因受自然环境因素的影响会使其水力特性发生改变。为了研究全吸力范围内生物炭掺量对生物炭−黏土混合土保水特性的影响,利用蒸汽平衡法（吸力范围 3～368 MPa）、滤纸法（吸力范围 0 ～40 MPa）和压力板法（吸力范围 0～1.5 MPa）控制土样的吸力,测定吸力平衡后土样的含水率和饱和度,得到全吸力范围内生物炭−黏土混合土的土−水特征曲线。试验结果表明：（1）3种吸力测试方法很好地表达了生物炭−黏土混合土全吸力范围内的土−水特征曲线。（2）生物炭能够影响黏土的保水性,但在一定的吸力范围内,生物炭−黏土混合土的保水性还与孔隙结构和孔隙中水的形态相关。（3）通过压力板法测得,试样的进气值随着生物炭掺量的增加而减小。当吸力值小于进气值时,曲线出现水平段,土样始终处于饱和状态,生物炭掺量越大,试样的保水性越好。（4）由生物炭−黏土混合土微观孔隙结构以及生物炭在黏土中的分布形态来解释生物炭改性黏土的保水能力随生物炭掺量的变化关系。     

膨润土颗粒混合物的堆积性质与水-力特性研究进展

膨润土颗粒混合物是高放废物深地质处置库中的一种缓冲/回填材料,掌握其堆积性质与水-力特性是开展处置库安全性能评估的关键基础。本文全面回顾和总结了近年来国内外学者对膨润土颗粒混合物的堆积性质、持水特性、结构特征、渗透特性、胀缩特性及本构模型等方面的研究进展与取得的成果,展望了几个值得进一步研究的问题。结果表明,颗粒混合物的堆积性质与粒径级配密切相关;湿化过程中,颗粒混合物由初始松散结构逐渐转变为胶结融合结构,孔隙结构逐渐趋于均一化,并伴随着颗粒破碎和错动,进而影响其水-力特性。考虑到处置库实际运营环境的复杂性,颗粒混合物的原位填充技术以及多场(热-水-力-化)耦合条件下颗粒混合物的水-力特性是今后值得深入研究的方向。     

Model suggested for an important part of the hydro-mechanical behaviour of a water unsaturated bentonite

The hydro-mechanical behaviour of a clay-based buffer material for nuclear waste disposal has been investigated in a laboratory program. In this program, the main focus was on the influence of confinement on water uptake and swelling pressure during suction decrease. The laboratory program and some of the results are presented by Dueck [Dueck, A., 2006. Laboratory results from hydro-mechanical tests on a water unsaturated bentonite. submitted for publication.].

The results from the laboratory tests were used to find a relationship between water content, void ratio, swelling pressure and suction. Two equations for swelling pressure represent the outline of the model.

In the first equation, the swelling pressure developed during water uptake is normalised by a pressure corresponding to the swelling pressure at saturation. This is done in order to be independent of void ratio. A relationship between the normalised swelling pressure and the degree of saturation is suggested.

The second equation describes a relationship between the swelling pressure, the water content and the actual suction (or relative humidity). The equation is based on a thermodynamic relationship and includes the retention curve (i.e. water content vs. suction under free swelling conditions).

The model can be used for a state where two of the four variables; water content, void ratio, swelling pressure and suction are known and can thus be useful to evaluate field measurements and model late stages of the wetting process. An example of an application is given. The equations are mainly based on results from tests with increasing degrees of saturation under constant void ratio but are also suggested for use with increasing void ratio.     

An experimental study of the water transfer through confined compacted GMZ bentonite

GMZ bentonite has been considered as a possible material for engineered barrier in the Chinese program of nuclear waste disposal at great depth. In the present work, the hydraulic conductivity of this bentonite was determined by simultaneous profile method. A specific infiltration cell equipped with five resistive relative humidity probes was designed for this purpose. The water retention properties were studied under both confined and unconfined conditions; the results show that at high suctions (> 4 MPa) the water retention capacity is independent of the confining condition, and by contrast, at low suctions (< 4 MPa) the confined condition resulted in significant low water retention. Furthermore, the microstructure was investigated at mercury intrusion porosimetry (MIP) and Environmental Scanning Electron Microscope (ESEM) in different states: on oven-dried powder, bentonite slurry, as-compacted and wetted samples. It has been observed that the soil powder is constituted of aggregates of various sizes; these aggregates are destroyed by full saturation at a water content equal to the liquid limit; compaction at the initial water content of 11–12% and a dry density of 1.7–1.75 Mg/m³ led to a microstructure characterized by a dense assembly of relatively well preserved aggregates; saturation of the compacted sample under constant volume condition defined a non-homogeneous microstructure with the presence of well preserved aggregates. This non-homogeneous microstructure would be due to the non uniform distribution of the generated swelling pressure within the soil sample upon wetting. The hydraulic conductivity determined has been found decreasing first and then increasing with suction decrease from the initial value of about 80 MPa to zero; the decrease can be attributed to the large pore clogging due to soft gel creation by exfoliation process, as observed at ESEM.     

Coupled modelling of hydro‐mechanical behaviour of unsaturated compacted expansive soils

The Barcelona basic model cannot predict the mechanical behaviour of unsaturated expansive soils, whereas the Barcelona expansive model (BExM) can only predict the stress–strain behaviour of unsaturated expansive soils without the water‐retention behaviour being incorporated. Moreover, the micro‐parameters and the coupling function between micro‐structural and macro‐structural strains in the BExM are difficult to determine. Experimental data show that the compression curves for non‐expansive soils under constant suctions are shifted towards higher void ratios with increasing suction, whereas the opposite is true for expansive soils. According to the observed water‐retention behaviour of unsaturated expansive soils, the air‐entry value increases with density, and the relationship between the degree of saturation and void ratio is linear at constant suction. According to the above observation, an elastoplastic constitutive model is developed for predicting the hydraulic and mechanical behaviour of unsaturated expansive soils, based on the existing hydro‐mechanical model for non‐expansive unsaturated soil. The model takes into consideration the effect of degree of saturation on the mechanical behaviour and that of void ratio on the water‐retention behaviour. The concept of equivalent void ratio curve is introduced to distinguish the plastic potential curve from the yield curve. The model predictions are compared with the test results of an unsaturated expansive soil, including swelling tests under constant net stress, isotropic compression tests and triaxial shear tests under constant suction. The comparison indicates that the model offers great potential for quantitatively predicting the hydraulic and mechanical behaviour of unsaturated expansive soils. Copyright © 2011 John Wiley & Sons, Ltd.     

Swelling pressure–suction relationship of heavily compacted bentonite–sand mixtures

This paper presents results of an experimental work to determine a relationship between swelling pressure and suction of heavily compacted bentonite–sand mixtures. For comparison, tests were also carried out on heavily compacted bentonite specimens. A series of swelling pressure tests were performed using multi-step constant-volume method where suction of the specimens tested was reduced in a stepwise manner toward a zero value. The suction reduction was induced using vapor equilibrium and axis-translation techniques. It is shown that compacted specimens did not exhibit any collapse upon suction decrease and exhibited maximum swelling pressures at zero-equilibrium suction. The development of swelling pressure with decreasing suction of the specimens showed threshold suctions below which a further reduction in suction yields an increase in the swelling pressure of the same magnitude. The magnitude of threshold suction was found to be a function of bentonite content in compacted specimens.     

Application of Hysteretic Trends in the Preconsolidation Stress of Unsaturated Soils

This paper involves an evaluation of a relationship describing the evolution in yield stress of unsaturated soils during hydraulic hysteresis, and an application of this relationship in an elasto-plastic framework to predict the compression curves of unsaturated soils under drained (free outflow of air and water with constant suction) or undrained (constant water content with no outflow of water and varying suction) conditions. The yield stress was quantified as the apparent mean effective preconsolidation stress obtained from compression tests reported in the literature on specimens that had experienced different hydraulic paths. It was observed that the preconsolidation stress does not follow a hysteretic path when plotted as a function of matric suction, but does when plotted as a function of the degree of saturation. Accordingly, an existing logarithmic relationship between the preconsolidation stress and matric suction normalized by the air entry suction was found to match the experimental preconsolidation stress results. This same relationship was also able to satisfactorily predict the trends in preconsolidation stress with degree of saturation by substituting the hysteretic soil–water retention curve (SWRC) into the place of the matric suction. The relationship between preconsolidation stress and suction was combined with an elasto-plastic framework to predict the compression curves of soils during drained compression, while the wetting-path relationship between preconsolidation stress and degree of saturation was combined with the framework to predict the compression curves of soils during undrained (constant water content) compression. A good match was obtained with experimental data from the literature, indicating the relevance of considering the hysteretic SWRC and preconsolidation relationships when simulating the behavior of unsaturated soils following different hydro-mechanical paths.     

On the use of effective stress in three-dimensional hydro-mechanical coupled model

In the last decades, a number of hydro-mechanical elastoplastic constitutive models for unsaturated soils have been proposed. Those models couple the hydraulic and mechanical behaviour of unsaturated soils, and take into account the effects of the degree of saturation on the stress–strain behaviour and the effects of deformation on the soil–water characteristic response with a simple reversible part for the hysteresis. In addition, the influence of the suction on the stress–strain behaviour is considered. However, until now, few models predict the stress–strain and soil–water characteristic responses of unsaturated soils in a fully three-dimensional Finite Element code. This paper presents the predictions of an unsaturated soil model in a Three-dimensional Framework, and develops a study on the effect of partial saturation on the stability of shallow foundation resting on unsaturated silty soil. Qualitative predictions of the constitutive model show that incorporating a special formulation for the effective stress into an elastoplastic coupled hydro-mechanical model opens a full range of possibilities in modelling unsaturated soil behaviour.     

A fully coupled simple model for unsaturated soils

Different phenomena influence the strength and volumetric behavior of unsaturated soils. Among the most important are suction hardening, hydraulic hysteresis, and the influence of volumetric strain on the soil-water retention curves. Fully coupled hydro-mechanical models require including all three phenomena in their constitutive relationships. Among these phenomena, suction hardening is the most influencing as it determines the apparent preconsolidation stress, the position of the loading-collapse yield surface, and the shift of both the isotropic consolidation and the critical state lines. In this paper, a fully coupled hydro mechanical model is presented. It is based on the modified Cam-Clay model but includes a yield surface with anisotropic hardening that takes account of the shift of the critical state line with suction. For highly overconsolidated materials, the sub-loading surface concept has been included in order to increase the precision of the model for these materials. The shift of the retention curves produced by volumetric strains is simulated using a hydraulic model based on the grain and current pore size distribution of the soil.     

Hydromechanical behaviour of an expansive bentonite/silt mixture in cyclic suction-controlled drying and wetting tests

To further our knowledge of coupling between the hydraulic cycles and mechanical behaviour of the swelling soils, this paper presents an experimental study on a bentonite/silt mixture using an odometer with suction controlled by the osmotic technique. A loading/unloading cycle was applied to each of the samples at different constant suctions (0, 2, 3 and 8 MPa). Moreover, successive wetting and drying cycles were applied under constant vertical stress at a suction range of 0 to 8 MPa, followed by a loading/unloading cycle at similar suctions (0, 2, 3 and 8 MPa). Finally, the compression curves of the aforementioned suctions with and without the application of suction cycles were compared, so as to analyse the influence of hydraulic cycles on the soil fabric and the mechanical parameters. It is observed that the wetting and drying cycles applied to both the micro- and macrostructure significantly influenced the virgin compression index λ(s), the apparent preconsolidation stress p₀(s) and the elastic compression index values κ. However, the hydraulic cycles imposed only on the micro- or macrostructure induce negligible changes in the mechanical parameters of the soil.     

混合型缓冲回填材料非饱和水分扩散试验研究

设计了专门的浸水试验装置,测定了膨润土-石英砂混合物在非膨胀条件下吸水引起的水分分布及膨胀应力变化,研究了混合型缓冲回填材料非饱和水力学性质。试验结果表明,干密度约1.70 g/cmP3、掺砂率为30%的GMZ001膨润土-砂混合物的水分扩散系数与含水率的关系呈U型变化,即随着含水率增加,汽态水分扩散系数减小,液态水分扩散系数增大。根据理论推导建立非饱和导水率估算方程。计算发现,混合物的非饱和导水率随含水率的增大而增大。其中,汽态水分非饱和导水率先增大后略有减小,液态水非饱和导水率始终增大。试验发现,试样吸水后干密度趋于均匀化,试样内部不同位置的应力发展与水分迁移过程密切相关：渗入端的应力在入渗初期增长很快,随后减慢;渗出端的应力持续稳定增长;入渗96 h后,两端应力趋于一致。估算出的水分扩散系数及非饱和导水率,可用于评价混合型缓冲回填材料阻隔核素迁移安全性。     

全吸力范围南阳膨胀土的土-水特征曲线

膨胀土的失水收缩、吸水膨胀过程分别对应着土-水特征曲线的脱湿和吸湿阶段。土-水特征曲线对于研究非饱和土的水力与力学特性有着重要作用。用压力板法（吸力范围0～1.5 MPa）、滤纸法（吸力范围0～40 MPa）和蒸汽平衡法（吸力范围3～368 MPa）,分别对南阳膨胀土进行了土-水特性试验,得到全吸力范围内的土-水特征曲线。试验结果表明：初始孔隙比大致相同土样的土-水特征曲线,在低吸力范围内脱湿曲线与吸湿曲线具有明显的滞回现象。当吸力大于300 MPa时,土-水特征曲线的滞回效应基本消失,即脱湿曲线与吸湿曲线基本重合。滤纸法所测出的土-水特性落在主脱湿和主吸湿曲线的滞回圈内。当吸力等于367.54 MPa时,含水率仅为0.325%,几乎近于0。孔隙比随着吸力的变化规律中,不仅受到吸力大小的影响,还受到吸力历史和吸力路径影响;孔隙比与吸力关系中,相同吸力时吸湿路径的孔隙比要比脱湿路径的大;在吸力低范围,吸湿路径与脱湿路径的孔隙比相近。孔隙比与饱和度关系因吸力路径的不同也存在着明显的滞回效应,接近饱和时趋近一致。变吸力情况条件下,饱和度随着孔隙比的增加而增加,蒸汽平衡法得出的孔隙比与饱和度的关系具有明显的线性关系,而压力板法做出来的低吸力范围内的线性关系不明显。     

Experimental study on the swelling behaviour of bentonite/claystone mixture

A mixture of the MX80 bentonite and the Callovo-Oxfordian (COx) claystone were investigated by carrying out a series of experiments including determination of the swelling pressure of compacted samples by constant-volume method, pre-swell method, zero-swell method and swell–consolidation method. Distilled water, synthetic water and humidity controlled vapour were employed for hydration. Results show that upon wetting the swelling pressure increases with decreasing suction; however, there are no obvious effects of synthetic water chemistry and hydration procedure on the swelling behaviour in both short and long terms. For the same initial dry density, the swelling pressure decreases with increasing pre-swell strain; whereas there is a well defined logarithmic relation between the swelling pressure and final dry density of the sample regardless of the initial dry densities and the experimental methods. It was also found that swelling pressure depends on the loading-wetting conditions as a consequence of the different microstructure changes occurred in different conditions. Furthermore, it was attempted to elaborate a general relationship between the swelling pressure and the final dry density for various reference bentonites.     

考虑毛细滞回效应的非饱和多孔介质渗流与变形耦合本构模型

在Wheeler本构模型框架的基础上,提出了一个水力与力学耦合的本构模型。该模型中的土-水特征曲线采用毛细滞回内变量模型,能够更好地描述水力历史变化下毛细滞回现象对非饱和多孔介质变形的影响,同时也可描述非饱和多孔介质变形对渗流的影响。非饱和土的强度不仅与吸力有关,而且受到饱和度的影响。相同的吸力下,土样经过吸湿和脱湿路径的饱和度不同,因此,非饱和土的强度也不同。此模型以体积含水率的塑性变化和体变的塑性变化为硬化参数,不仅能描述基质吸力对非饱和土的强化作用,而且考虑了饱和度对强度及变形的影响。试验结果与模型预测基本吻合,证明该模型能够模拟非饱和土的主要特性。为了简化,此模型是在各向同性荷载下推得的,有待于推广到一般的应力状态     

Influence of Unsaturated Soil Properties Uncertainty on Moisture Flow Modeling

The quality of a numerical modeling solution of moisture flow through unsaturated soil, in part, depends on properly described unsaturated soil properties. The variability of the Soil Water Characteristic Curve, SWCC, is attributed to hysteresis and reproducibility of measurement. Because the unsaturated conductivity function is rarely directly measured, the variability of the unsaturated soil hydraulic conductivity function is attributed to the uncertainty associated with the estimation of this parameter with currently available fitting functions, and hence a range of reasonable variation was considered. One-dimensional modeling of expansive soil under dry initial conditions (suction of 1,500 kPa) was performed; both potential evaporation and infiltration boundary conditions were considered. It was found that small variations in the unsaturated soil hydraulic conductivity function result in significantly different modeling outputs, as expected, while substential variation in SWCC alone (assuming the same unsaturated soil hydraulic conductivity for all SWCCs) produced almost identical soil response in terms of soil suction when the slope of the SWCC is similiar. Thus, proper characterization of the slope of the SWCC is important to proper suction profile determination.     

A density‐dependent elastoplastic hydro‐mechanical model for unsaturated compacted soils

This paper presents a three‐dimensional elastoplastic constitutive model for predicting the hydraulic and mechanical behaviour of unsaturated soils. It is based on experimental results obtained from a series of controlled‐suction triaxial tests on unsaturated compacted clay with different initial densities. Hydraulic hysteresis in the water‐retention behaviour is modelled as an elastoplastic process, with the elastic part modelled by a series of scanning curves and the elastoplastic part modelled by the main drying and wetting curves. The effect of void ratio on the water‐retention behaviour is studied using data obtained from controlled‐suction wetting–drying cyclic tests on unsaturated compacted clay with different initial densities. The effect of the degree of saturation on the stress–strain‐strength behaviour and the effect of void ratio on the water‐retention behaviour are considered in the model, as is the effect of suction on the hydraulic and mechanical behaviour. The initial density dependency of the compacted soil behaviour is modelled by experimental relationships between the initial density and the corresponding yield stress and, thereby, between the initial density and the normal compression line. The model is generalized to three‐dimensional stress states by assuming that the shapes of the failure and yield surfaces in the deviatoric stress plane are given by the Matsuoka–Nakai criterion. Model predictions of the stress–strain and water‐retention behaviour are compared with those obtained from triaxial tests with different initial densities under isotropic compression, triaxial compression and triaxial extension, with or without variation in suction. The comparisons indicate that the model accurately predicts the hydraulic and mechanical behaviour of unsaturated compacted soils with different initial densities using the same material constant. Copyright © 2006 John Wiley & Sons, Ltd.     

非饱和重塑黏土渗透性试验研究

工程中常常遇到非饱和土渗流问题,其渗透性是非饱和土的重要研究内容。采用常规压力板仪详细研究了重塑黏土在3种不同击实功和5种不同击实含水率下的土-水特征曲线,并用变水头法测量了相应的饱和土渗透系数。结合土水曲线和饱和渗透系数,基于Van Genuchten模型和Fredlund模型,详细探讨了重塑非饱和重塑黏土在不同击实条件下的渗透性。结果表明,土样饱和渗透系数随着击实含水率的增大而减小,且随着基质吸力的增大土样渗透性差别逐渐减小。当试样吸力达到1 MPa时,可认为不同击实含水率下试样的渗透性基本相同;在轻型击实和简化轻型击实下,试样渗透性很相似。重型击实功下试样的渗透系数和轻型击实下土样渗透系数的比值 随着吸力的增大而逐渐增大,在饱和状态时比值约为1/100,当吸力达到1 MPa时比值逐渐稳定在1/10右。     

Influence of different strain rates on hydro-mechanical behaviour of reconstituted unsaturated soil

The hydro-mechanical behaviour of a reconstituted unsaturated soil under different suctions and strain rates was studied through various rate-controlled unsaturated/undrained triaxial tests. The fully saturated reconstituted specimens were desaturated to four different initial suctions (s₀?=?0, 100 kPa, 200 kPa and 300 kPa) and then triaxially sheared (conventional triaxial compression) at three different strain rates in undrained conditions (\(\dot{\varepsilon }_{1} = 0.001\) h^?1, 0.01 h^?1, and 0.1 h^?1). The observed hydro-mechanical behaviour during shearing including the volumetric strain, deviatoric stress, degree of saturation and suction is presented and discussed in this paper. The results indicate that when the strain rate rises at the given initial suctions (or pore water pressures), the maximum deviatoric stress (q_max), critical net stress ratio (M) and critical state suction (s_c) increase but the degree of saturation (S_rc) and volumetric strain at the critical state (ε^c_v ) reduce. The critical effective stress ratio (M′) is not dependent on the strain rate for saturated and unsaturated samples. The critical state lines for unsaturated soils with the constant strain rates are parallel with each other in the e???lnp′ space.