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离子交换-比色法测定农业地质普查样品中的微量碘(Fe3十-CNS--NO-2) 总被引:1,自引:0,他引:1
本文采用离子交换-比色法测定农业地质样品中的微量碘,本方法检出限为0.5×10-6,精密度达到2.4%.方法准确、快速、简便、成本低,适合大批量样品的测定. 相似文献
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通过用过氧化钠分解试样,盐酸-酒石酸-双氧水浸取,电感耦合等离子体发射光谱法测定样品中的锡。该方法检出限为10μg/g,相对标准偏差为1.95%~4.83%。该方法经国家一级标准物质验证,分析结果与国家标准值相符,且实验步骤简单,快速准确,提高了工作效率,可用于大批量样品的检测。 相似文献
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本法在离心分离甲醛法的基础上,采用了以减压过滤代替了离心分离。经过多次试验,效果满意。本法设备简单,经大批量测定(每人每天可测定24—30个矿样),结果稳定,适用于野外地质队大批量的测定。 相似文献
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Stanley E. CHURCH 《Geostandards and Geoanalytical Research》1981,5(2):133-160
Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) has been applied for simultaneous, multielement analysis of a diverse suite of igneous rocks and minerals, metamorphic and sedimentary rocks, coals and soils using a single matrix calibration procedure and a single sample preparation. Analytical results determined on 40 elements in 54 geochemical reference samples are presented. A sample analysis time of about three minutes allows the analyst to run several hundred samples per day, but does not include sample dissolution. The instrumental method described here provides the capability for rapid, simultaneous, multielement determination of the major (except silica), minor, and trace elements in rocks using a single sample preparation technique. Analytical data collected on the Geochemical Reference Samples (GRS) demonstrate the general utility of the method. Analytical results show an excellent agreement with previously published results for the major and minor elements. Of the 28 trace elements studied, 17 can be routinely determined in crustal rocks, but the concentration of several of the others can be determined only if present at concentrations several times above their crustal-abundance level. 相似文献
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Ernest S. GLADNEY Colleen E. BURNS Iwan ROELANDTS 《Geostandards and Geoanalytical Research》1984,8(2):119-154
Concentration data for as many as 64 constituents in the six United States Geological Survey's (USGS) Geochemical Exploration Reference Samples (GXR) have been collected from journal articles and technical reports published since these reference materials were issued in 1971. These data are summarized into mean +/- one standard deviation values and compared with our previously calculated concentrations based upon USGS round-robin data published in 1978. All new literature data located are presented in the appendices. 相似文献
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Geochemical data for granulite terrain are presented in the northernmost portion of the Guaxupé Massif, at Mantiqueira Province, SE Brazil. Several types of granulites are recognized in the area: basic, intermediate and acid granulite. Major and trace elements (including REE) point to only one magma source for these granulites generated at different times. Geochemical data point to plagioclase and apatite fractionation as the responsable by the REE behaviour in intermediate and more basic rocks. Overall composition of the Guaxupé Granulites is similar to average described worldwide in the literature to the lower crust. 相似文献
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地壳全元素探测——构建“化学地球” 总被引:17,自引:1,他引:16
地壳物质探测是地壳探测工程的重要组成部分。化学元素是地球物质组成的最基本单位,被称为地球的基因。矿产资源是由化学元素组成的,环境是受化学元素行为制约的,因此,对地壳中所有元素精确含量和分布的探测,对解决人类所面临的资源和环境问题具有重大意义。地壳全元素探测项目拟发展4种地球化学探测技术,包括地壳中所有天然元素的精确分析技术,中下地壳物质成分识别技术,穿透性地球化学探测技术,海量地球化学数据和图形显示技术。建立1个覆盖全国的地球化学基准网,系统采集代表性岩石样品10000件,疏松物样品6000件,按标准化的方法分析其主量元素和微量元素含量(包含78种元素),建立中国大陆地球化学基准值,为研究化学元素的分布、演化和成矿物质背景提供基准参考数据。进行总长度3300km的3条地球化学走廊带的实验与示范,采集各类代表性岩石样品5000件,进行元素和同位素测定,构建走廊带地壳地球化学模型、跨越不同大地构造单元的元素空间变化和大型矿集区成矿物质背景。为开展全国地壳探测工程奠定基础,并为最终建立"化学地球"进行技术准备和先导性实验。 相似文献
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要认识地球的演化和全球变化,就必须有一致性的全球尺度地球化学基准或基线作为参照标尺。文中阐述了地球化学基准概念、建立方法和应用实例。地球化学基准是指系统记录元素及其化合物在地球表层的含量和空间分布,作为了解过去地球化学演化和预测未来地球化学变化的定量参照标尺。要建立全球地球化学基准,首先必须建立一个覆盖全球的地球化学基准网,在中国以1∶20万图幅为基准网格单元,在全国系统采集有代表性岩石组合样品约10 000件,疏松沉积物样品约6 000件,精确分析涵盖元素周期表上除惰性气体以外几乎所有元素的含量,制作化学元素时空分布基准地球化学图,提供衡量中国大陆化学元素演化和未来变化的标尺。以不同时代岩石代表性样品建立原生岩石圈地球化学基准,作为了解过去地球化学演化参照标尺,如云南禄丰龙产地楚雄—兰坪盆地白垩系-古近系界面(K-T界面)的凝灰质灰岩和凝灰质泥岩中发现Ir的含量为0.25~0.8ng/g,是白垩系和古近系地层基准含量的10~20倍。以疏松沉积物样品建立次生土壤圈地球化学基准,用于作为预测未来变化的参照标尺,如CaO含量分布与气候和酸雨分布有关,CaO在南方酸雨作用下淋失贫化,在西北碱性条件下富集。在过去15年里,由于酸雨的持续作用,CaO平均含量下降了22.6%,CaO含量<1%的分布面积扩大了23.0%。同时,这种原生和次生地球化学基准的建立,提供了具有时间和空间分布的成矿物质背景,对矿产资源评价和预测具有重要意义。 相似文献
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由于Au、Pt、Pd等元素分析测试技术的突破,使中国的贵金属地球化学勘查得到迅速发展。甘肃省自80年代以来,金矿地球化学勘查取得了丰硕的成果。90年代初,在研究改进Pt、Pd、Au化学-光谱法快速联测分析方法的基础上,在祁连山地区开展了针对金和铂族元素的区域地球化学勘查。工作结果,Pt、Pd、Au的报出率都达到了100%,从而可靠地圈定了Pt、Pd、Au的地球化学异常。这一案例证明,地球化学勘查在寻找金和铂族元素矿产方面都是有效的 相似文献
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G. MEYER E.S. GLADNEY J.J. GRUFFAT L. RAIMBAULT 《Geostandards and Geoanalytical Research》1988,12(1):53-56
Six roches standards de I'USGS : GXR-1 à GXR-6 ont été analysées par activation neutronique instrumentale (INAA) pour le dosage de 17 éléments traces et par fluorescence X (XRF) pour les autres éléments difficiles à doser par activation neutronique. Les travaux précédemment publiés par Gladney et al. ont été pris comme référence en particulier les valeurs recommandées (R.V.) qui sont généralement en bon accord avec nos résultats. Quelques remarques et corrections sont proposées pour expliquer certaines disparités.
Six United States Geological Survey's (USGS) Geochemical Exploration References Samples (GXR) have been analyzed by instrumental neutron activation analysis (INAA) for the determination of seventeen trace elements and by X-ray fluorescence spectrometry (XRFS) for other trace elements difficult to determine by INAA. Our results compare favourably with the values recommended by E.S. Gladney et al. Some suggestions and corrections are proposed to explain some discrepancies. 相似文献
Six United States Geological Survey's (USGS) Geochemical Exploration References Samples (GXR) have been analyzed by instrumental neutron activation analysis (INAA) for the determination of seventeen trace elements and by X-ray fluorescence spectrometry (XRFS) for other trace elements difficult to determine by INAA. Our results compare favourably with the values recommended by E.S. Gladney et al. Some suggestions and corrections are proposed to explain some discrepancies. 相似文献
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N. V. Ramamohana Rao N. Rao K. Surya Prakash Rao R. D. Schuiling 《Environmental Geology》1993,21(1-2):84-89
Geochemical and hydrochemical studies were conducted in Nalgonda District (A.P.), to explore the causes of high fluorine in waters, causing a widespread incidence of fluorosis in the local population. Samples of granitic rocks, soils, stream sediments, and waters were analyzed for F and other salient chemical parameters. Samples from the area of Hyderabad city were analyzed for comparison. The F content of waters in areas with endemic fluorosis ranges from 0.4 to 20 mg/l. The low calcium content of rocks and soils, and the presence of high levels of sodium bicarbonate in soils and waters are important factors favoring high levels of F in waters. 相似文献
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地球化学填图与地球化学勘查 总被引:3,自引:0,他引:3
在中国与西方国家,地球化学填图的目的与做法并不相同,西方的地球化学填图是由研究机构开展的,使用等离子焰光量计、X射线荧光光谱仪等大型仪器进行多元素分析,目的是取得多种元素在地球表层分布的基础性资料。地球化学勘查则由矿业公司主要分析少量成矿元素,目的是为了找矿。而中国的地球化学填图计划却做出了巨大努力,使地球化学填图取得的资料既有学术价值又对矿产勘查具有重大的实用意义。本文详细讨论了西方国家与中国地球化学填图与地球化学勘查的思路、方法与技术的演变,并瞻望了地球化学填图在21世纪的巨大发展前景。 相似文献
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A new quantitative transportation model for geochemical elements in stream sediment samples is proposed and used to estimate mineral sources of anomalous concentrations and to adjust both location and concentration for the transportation effect. Subsequent to transportation analysis, data on 14 geochemical elements in the Walker Lake quadrangle are analyzed for geochemical signatures for three types of mineralization environments: epithermal gold-silver deposits, porphyry-skarn copper deposits, and a mixed occurrence. Geochemical signatures are analyzed using a multidimensional scaling method referred to as the pijk model, which is a factor-like model generalized to include nonlinear associations, as well as linear, among triple variables (elements). A result of this analysis is that Pb is the best indicator for epithermal gold-silver mineralization, Mo and Zn for mixed mineralization, and Cu for porphyry-skarn mineralization. 相似文献