Spectral studies of asteroids 21 lutetia and 4 vesta as objects of space missions

Asteroid 21 Lutetia is one of the objects of the Rosetta mission carried out by the European Space Agency (ESA). The Rosetta spacecraft launched in 2004 is to approach Lutetia in July 2010, and then it will be directed to the comet Churyumov-Gerasimenko. Asteroid 4 Vesta is planned to be investigated in 2011 from the Dawn spacecraft launched by the National Aeronautics and Space Administration (NASA) in 2007 (its second object is the largest asteroid, 1 Ceres). The observed characteristics of Lutetia and Vesta are different and even contradictory. In spite of the intense and versatile ground-based studies, the origin and evolution of these minor planets remain obscure or not completely clear. The types of Lutetia and Vesta (M and V, respectively) determined from their spectra correspond to the high-temperature mineralogy, which agrees with their albedo estimated from the Infrared Astronomical Satellite (IRAS) observations. However, according to the opinion of some researchers, Lutetia is of the C type, and, therefore, its mineralogy is of the lowtemperature type. In turn, hydrosilicate formations have been found in some places on the surface of Vesta. Our observations also testify that at some relative phases of rotation (RP), the reflectance spectra of Lutetia and Vesta demonstrate features confirming the presence of hydrosilicates in the surface material. However, this fact can be reconciled with the magmatic nature of Lutetia and Vesta if the hydrated material was delivered to their surfaces by falling primitive bodies. Such small bodies are probably present everywhere in the main asteroid belt and can be the relicts of silicate-icy planetesimals from Jupiter’s formation zone or the fragments of primitive-type asteroids. When interpreting the reflectance spectra of Lutetia and Vesta, we discuss the spectral classification by Tholen (1984) from the standpoint of its general importance for the estimation of the mineralogical type of the asteroids and the study of their origin and evolution.     

Spots on asteroid surfaces: Research opportunities using ground-based instruments

We discuss possible mechanisms for the formation of albedo spots on asteroids. We infer that the most likely mechanisms are impact cratering and related processes. This is confirmed by the reflectance spectra of the asteroids 10 Hygiea, 135 Hertha, and 196 Philomela, the results of a spectral frequency analysis of the sizes of features on the surface of 4 Vesta and 21 Lutetia, and the estimates for the parameters of impact features.     

Asteroids 10 Hygiea, 135 Hertha,and 196 Philomela: Heterogeneity of the material from the reflectance spectra

The reflectance spectra of asteroids 10 Hygiea (C-type), 135 Hertha (M-type), and 196 Philomela (S-type) are obtained in a range of 0.40–0.91 μm with different time intervals. In this paper, the technique of the spectral measurements of asteroids is analyzed and the reflectance spectra of Hygiea, Hertha, and Philomela are interpreted. The main physical and chemical factors and processes influencing the spectral characteristics of asteroids are considered. It is determined that the spectra of Hertha and Hygiea contain variations exceeding the measurement errors several times at different relative rotation phases, whereas spectral variations of Philomela caused by its rotation hardly exceed the error limits. Most probably, these variations are caused by local manifestations of the impact metamorphism of the material of asteroids in serious impact events. Results show that, to determine the prevailing spectral type and the corresponding mineralogy of each asteroid, one should estimate and take into account the changes in its spectral characteristics for a time interval comparable to the rotation period.     

A plausible link between the asteroid 21 Lutetia and CH carbonaceous chondrites

A crucial topic in planetology research is establishing links between primitive meteorites and their parent asteroids. In this study, we investigate the feasibility of a connection between asteroids similar to 21 Lutetia, encountered by the Rosetta mission in July 2010, and the CH3 carbonaceous chondrite Pecora Escarpment 91467 (PCA 91467). Several spectra of this meteorite were acquired in the ultraviolet to near‐infrared (0.3–2.2 μm) and in the midinfrared to thermal infrared (2.5–30.0 μm or 4000 to ~333 cm⁻¹), and they are compared here to spectra from the asteroid 21 Lutetia. There are several similarities in absorption bands and overall spectral behavior between this CH3 meteorite and 21 Lutetia. Considering also that the bulk density of Lutetia is similar to that of CH chondrites, we suggest that this asteroid could be similar, or related to, the parent body of these meteorites, if not the parent body itself. However, the apparent surface diversity of Lutetia pointed out in previous studies indicates that it could simultaneously be related to other types of chondrites. Future discovery of additional unweathered CH chondrites could provide deeper insight in the possible connection between this family of metal‐rich carbonaceous chondrites and 21 Lutetia or other featureless, possibly hydrated high‐albedo asteroids.     

Absorption bands near three micrometers in diffuse reflectance spectra of carbonaceous chondrites: Comparison with asteroids

Abstract— We measured infrared diffuse reflectance spectra of several carbonaceous chondrites in order to obtain additional information on the surface materials of their presumed parent bodies, C-type asteroids. The presence and intensity of absorption bands near 3 μm in the reflectance spectra are due to the presence and abundance of hydrates and/or hydroxyl ions. The absorption features of the 3 μm hydration bands of carbonaceous chondrites were compared with those of asteroids 1 Ceres and 2 Pallas. They are commonly classified into separate subtypes, G- and B-type. The spectral shapes of Pallas and Renazzo (CR2 chondrite) around the 3 μm absorption band are an excellent match. This result may suggest that the amount of hydrous minerals in the surface material of Pallas is smaller than that in the CM2 or CI chondrites, and the hydrous minerals on the surface of Pallas may be similar to those found in Renazzo. The spectral features around the 3 μm band of Ceres are different from those of carbonaceous chondrites studied in this paper.     

Vesta,Vestoids, and the howardite,eucrite, diogenite group: Relationships and the origin of spectral differences

Abstract— Spectra of asteroid 4 Vesta and 21 small (estimated diameters less than 10 km) asteroids with Vesta‐like spectral properties (Vestoids) were measured at visible and near‐infrared wavelengths (～0.44 to ～1.65 μm). All of the measured small asteroids (except for 2579 Spartacus) have reflectance spectra consistent with surface compositions similar to eucrites and howardites and consistent with all being derived from Vesta. None of the observed asteroids have spectra similar to diogenites. We find no spectral distinction between the 15 objects tabulated as members of the Vesta dynamical family and 6 of the 7 sampled “non‐family” members that reside just outside the semi‐major axis (a), eccentricity (e), and inclination (i) region of the family. The spectral consistency and close orbital (a‐e‐i) match of these “non‐family” objects to Vesta and the Vesta family imply that the true bounds of the family extend beyond the subjective cut‐off for membership. Asteroid 2579 Spartacus has a spectrum consistent with a mixture of eucritic material and olivine. Spartacus could contain olivine‐rich material from Vesta's mantle or may be unrelated to Vesta altogether. Laboratory measurements of the spectra of eucrites show that samples having nearly identical compositions can display a wide range of spectral slopes. Finer particle sizes lead to an increase in the slope, which is usually referred to as reddening. This range of spectral variation for the best‐known meteoritic analogs to the Vestoids, regardless of whether they are actually related to each other, suggests that the extremely red spectral slopes for some Vestoids can be explained by very fine‐grained eucritic material on their surfaces.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

The material of the interstellar dust and the surface of asteroids: A comparison of the spectral properties in the 0.3–1.1-μm range

From the data on bright stars of different spectral and luminosity classes from the 13-color photometry catalog, the selective extinction of light by the interstellar dust has been studied. The stars from the 1000-pc vicinity of the Sun were investigated. In the optical spectral range, the interstellar extinction curves show systematic deviations from the “λ^?1” law, which allows one to sort them into three types. The observed curves of the interstellar dust extinction were compared with the theoretical curves calculated from the reflectance spectra of the asteroids under the approximation of the Rayleigh particles. The calculated extinction curves for the surface material of D-type asteroids and the Tagish Lake carbonaceous chondrite agree rather well with the observed curves of the interstellar extinction of the first type.     

Remote spectroscopic identification of carbonaceous chondrite mineralogies: Applications to Ceres and Pallas

High-resolution spectroscopic observations of asteroids Ceres and Pallas have been obtained in the 1.0- to 2.6-μm region. Combined with previous spectralmeasurements at other wavelengths, this work presents the broadband spectral reflectances of these asteroids over the 0.4 to 3.6-um region. This extended coverage permits new analyses of the surface mineralogies of these objects. Using laboratory comparison spectra of meteorites and mixtures of terrestrial minerals, the surfaces of Ceres and Pallas are consistent with mixtures of opaques and hydrated silicates, such as are found in types C1 and C2 meteorites. This research emphasizes the importance of the 3-um spectral region for studying by remote methods the relationship of carbonaceous chondrite mineralogies to asteroid surfaces.     

Nature and degree of aqueous alteration in CM and CI carbonaceous chondrites

We investigated the petrologic, geochemical, and spectral parameters that relate to the type and degree of aqueous alteration in nine CM chondrites and one CI (Ivuna) carbonaceous chondrite. Our underlying hypothesis is that the position and shape of the 3 μm band is diagnostic of phyllosilicate mineralogy. We measured reflectance spectra of the chondrites under dry conditions (elevated temperatures) and vacuum (10^?8 to 10^?7 torr) to minimize adsorbed water and mimic the space environment, for subsequent comparison with reflectance spectra of asteroids. We have identified three spectral CM groups in addition to Ivuna. “Group 1,” the least altered group as determined from various alteration indices, is characterized by 3 μm band centers at longer wavelengths, and is consistent with cronstedtite (Fe‐serpentine). “Group 3,” the most altered group, is characterized by 3 μm band centers at shorter wavelengths and is consistent with antigorite (serpentine). “Group 2” is an intermediate group between group 1 and 3. Ivuna exhibits a unique spectrum that is distinct from the CM meteorites and is consistent with lizardite and chrysotile (serpentine). The petrologic and geochemical parameters, which were determined using electron microprobe analyses and microscopic observations, are found to be consistent with the three spectral groups. These results indicate that the distinct parent body aqueous alteration environments experienced by these carbonaceous chondrites can be distinguished using reflectance spectroscopy. High‐quality ground‐based telescopic observations of Main Belt asteroids can be expected to reveal not just whether an asteroid is hydrated, but also details of the alteration state.     

Material composition assessment and discovering sublimation activity on asteroids 145 Adeona, 704 Interamnia, 779 Nina,and 1474 Beira

Spectrophotometric observations of 145 Adeona, 704 Interamnia, 779 Nina, and 1474 Beira—asteroids of close primitive types—allowed us to detect similar mineralogical absorption bands in their reflectance spectra centered in the range 0.35 to 0.92 μm; the bands are at 0.38, 0.44, and 0.67–0.71 μm. On the same asteroids, the spectral signs of simultaneous sublimation activity were found for the first time. Namely, there are maxima at ～0.35–0.60 μm in the reflectance spectra of Adeona, Interamnia, and Nina and at ～0.55–075 μm in the spectra of Beira. We connect this activity with small heliocentric distances of the asteroids and, consequently, with a high insolation at their surfaces. Examination of the samples of probable analogues allowed us to identify Fe³⁺ and Fe²⁺ in the material of these asteroids through the mentioned absorption bands. For analogues, we took powdered samples of carbonaceous chondrites Orgueil (CI), Mighei (CM2), Murchison (CM2), and Boriskino (CM2), as well as hydrosilicates of the serpentine group. Laboratory spectral reflectance study of the samples of low-iron Mg serpentines (<2 wt % FeO) showed that the equivalent width of the absorption band centered at 0.44–0.46 μm strongly correlates with the content of Fe³⁺ in octahedral and tetrahedral coordinations. Our conclusion is that this absorption band can be used as a qualitative indicator of Fe³⁺ in the surface matter of asteroids and other solid celestial bodies. The comparison of the listed analog samples and the asteroids by parameters of the spectral features suggests that the silicate component of the asteroids' surface material is a mixture of hydrated and oxidized compounds, including oxides and hydroxides of bivalent and trivalent iron and carbonaceous-chondritic material. At the same time, the sublimation activity of Adeona, Interamnia, Nina, and Beira at high surface temperatures points to a substantial content of water ice in their material. This contradicts the previously existing notions on the C-type and similar asteroids as bodies containing water only in the bound state. Moreover, since the sublimation process simultaneously occurs in four primitive-type bodies at small heliocentric distances, we may suppose that this phenomenon is common for the main-belt asteroids.     

The dark side of Iapetus

This paper presents new photometric and spectrophotometric observations of the dark (leading) hemisphere of Saturn's satellite Iapetus. Spectrophotometry from 0.3–1.0 um (May 1979) shows the dark hemisphere to be very red, similar to a few asteroids and the Moon, but with no spectral features attributable to olivine or pyroxene. Near-infrared spectrophometry in the regions 1.4–2.5 um (May 1981) and 3.0–3.8 um (February 1981) reveals water ice absorption bands, probably resulting from the polar caps intruding onto the dark hemisphere. The reflectance of Iapetus is unlike that of carbonaceous chondrites or C-type asteroids and most closely resembles the reflectance (and low albedo) of carbonaceous (organic) residue from the Murchison C2 carbonaceous chondrite. The Murchison material has the same red slope and a probable spectral feature near 0.6 um seen in Iapetus data. Three hypotheses for the formation of the dark hemisphere are discussed in light of the observational data. The favored hypothesis is that debris from Phoebe or other unknown outer satellites of Saturn impacts the dark hemisphere of Iapetus as Poynting-Robertson drag causes the debris to spiral toward Saturn. The high-velocity impacts preferentially remove ice from the satellite's surface, causing enrichment of included carbonaceous material intrinsic to Iapetus. The reflectance of Phoebe itself is significantly different from that of Iapetus, suggesting that relatively little Phoebe debris lies on the dark hemisphere. There remains the possibility that the impacting debris originates from another body of composition similar to the Murchison residue and that this material is exposed on the surface of Iapetus.     

Delivery of dark material to Vesta via carbonaceous chondritic impacts

NASA’s Dawn spacecraft observations of Asteroid (4) Vesta reveal a surface with the highest albedo and color variation of any asteroid we have observed so far. Terrains rich in low albedo dark material (DM) have been identified using Dawn Framing Camera (FC) 0.75 μm filter images in several geologic settings: associated with impact craters (in the ejecta blanket material and/or on the crater walls and rims); as flow-like deposits or rays commonly associated with topographic highs; and as dark spots (likely secondary impacts) nearby impact craters. This DM could be a relic of ancient volcanic activity or exogenic in origin. We report that the majority of the spectra of DM are similar to carbonaceous chondrite meteorites mixed with materials indigenous to Vesta. Using high-resolution seven color images we compared DM color properties (albedo, band depth) with laboratory measurements of possible analog materials. Band depth and albedo of DM are identical to those of carbonaceous chondrite xenolith-rich howardite Mt. Pratt (PRA) 04401. Laboratory mixtures of Murchison CM2 carbonaceous chondrite and basaltic eucrite Millbillillie also show band depth and albedo affinity to DM. Modeling of carbonaceous chondrite abundance in DM (1–6 vol.%) is consistent with howardite meteorites. We find no evidence for large-scale volcanism (exposed dikes/pyroclastic falls) as the source of DM. Our modeling efforts using impact crater scaling laws and numerical models of ejecta reaccretion suggest the delivery and emplacement of this DM on Vesta during the formation of the ～400 km Veneneia basin by a low-velocity (<2 km/s) carbonaceous impactor. This discovery is important because it strengthens the long-held idea that primitive bodies are the source of carbon and probably volatiles in the early Solar System.     

Analyses of the chondritic meteorite Orvinio (H6): Insight into the origins and evolution of shocked H chondrite material

Abstract— We have studied the petrography, reflectance spectra, and Ar‐Ar systematics of the Orivinio meteorite. Orvinio is an H chondrite not an L chondrite as sometimes reported. The material in the meteorite was involved in several impact events. One impact event produced large swaths of impact melt from H chondrite material surrounding relict clasts of chondrule‐bearing material. Not only were portions of a bulk H chondrite planestesimal melted during the impact event, but shock redistribution of metal and sulfide phases in the meteorite dramatically altered its reflectance spectra. Both the melt and relict clasts are darker than unshocked H chondrite material, bearing spectral similarities to some C‐class asteroids. Such shock metamorphism, which lowers the albedo of an object without increasing its spectral slope, may partially explain some of the variation among S‐class asteroids and some of the trends seen on asteroid 433 Eros. Noble gases record the evidence of at least two, and perhaps three, impact events in the meteorite and its predecessor rocks. The most significant evidence is for an event that occurred 600 Ma ago or less, perhaps ?325 Ma ago or less. There is also a signature of 4.2 Ga in the Ar‐Ar systematics, which could either reflect complete degassing of the rock at that time or partial degassing of even the most retentive sites in the more recent event.     

The composition of asteroid 2 Pallas and its relation to primitive meteorites

High resolution spectroscopic observations of asteroid 2 Pallas from 1.7-3.5 μm are reported. These data are combined with previous measurements from 0.4-1.7 μm to interpret Pallas' surface mineralogy. Evidence is found for low-Fe²⁺ hydrated silicates, opaque components, and low-Fe²⁺ anhydrous silicates. This assemblage is very similar to carbonaceous chondrite matrix material such as is found in type CI and CM meteorites, but it has been subjected to substantial aqueous alteration and there is a major extraneous anhydrous silicate component. This composition is compared to that of asteroid 1 Ceres. Although there are substantial differences in their broad band spectral reflectances, it appears that both asteroids are genetically related to known carbonaceous chondrites.     

When are spectral reflectance curves comparable?

Spectral reflectance curves of flat laboratory samples of the carbonaceous chondrite Allende, a basalt, and the ordinary chondrite Bruderheim measured in a bidirectional geometry are shown to differ from those measured using an integrating sphere. In general, reflectance curves obtained by the bidirectional method are redder than those obtained with an integrating sphere. The degree of difference increases with increasing absolute reflectance. When spectral reflectance curves obtained by the two methods are compared to the reflectance curves expected for spherical and aspherical planets covered with the same materials, it is found that in general the integrating sphere measurements provide a better match to a planet at small phase angles. As the phase angle increases, bidirectional reflectance curves provide a closer match.     

Plausible parent bodies for enstatite chondrites and mesosiderites: Implications for Lutetia's fly-by

We present new irradiation experiments performed on the enstatite chondrite Eagle (EL6) and the mesosiderite Vaca Muerta. These experiments were performed with the aims of (a) quantifying the spectral effect of the solar wind on their parent asteroid surfaces and (b) identifying their parent bodies within the asteroid belt. For Vaca Muerta we observe a reddening and darkening of the reflectance spectrum with progressive irradiation, consistent with what is observed in the cases of silicates and silicate-rich meteorites such as OCs and HEDs. For Eagle we observe little spectral variation, and therefore we do not expect to observe a significant spectral difference between EC meteorites and their parent bodies. We evaluated possible parent bodies for both meteorites by comparing their VNIR spectra (before and after irradiation) with those of ∼400 main-belt asteroids. We found that 21 Lutetia (Rosetta's forthcoming fly-by target) and 97 Klotho (both Xc types in the new Bus-DeMeo taxonomy) have physical properties compatible with those of enstatite chondrite meteorites while 201 Penelope, 250 Bettina and 337 Devosa (all three are Xk types in the Bus-DeMeo taxonomy) are compatible with the properties of mesosiderites.     

Ganymede,Europa, Callisto,and Saturn's rings: Compositional analysis from reflectance spectroscopy

The reflectance spectra of Ganymede, Europa, Callisto, and Saturn's rings are analyzed using recent laboratory reflectance studies of water frost, water ice, and water and mineral mixtures. It is found that the spectra of the icy Galilean satellites are characteristic of water ice (e.g., ice blocks or possibly very large ice crystals ? 1 cm) or frost on ice rather than pure water frost, and that the decrease in reflectance at visible wavelengths is caused by other mineral grains in the surface. The spectra of Saturn's rings are more characteristic of water frost with some other mineral grains mixed in the frost but not on the surface. The impurities on all these objects are not in spectrally isolated patches but appear to be intimately mixed with the water. The impurity grains appear to have reflectance spectra typical of minerals containing Fe³⁺. Some carbonaceous chondrite meteorite spectra show the necessary spectral shape. Ganymede is found to have more water ice on the surface than previously thought (～90 wt%), as is Callisto (30–90 wt%). The surface of Europa has a vast frozen water surface with only a few percent impurities. Saturn's rings also have only a few percent impurities. The amount of bound water or bound OH for these objects is 5 ± 5 wt% averaged over the entire surface. Thus with the small amount of nonicy material present on these objects, no hydrated minerals can be ruled out. A new absorption feature is identified in Ganymede, Callisto, and probably Europa at 1.5 μm which is also seen in the spectra of Io but not in Saturn's rings. This feature has not been seen in laboratory studies and its cause is unknown.     

The Surface Structure of the M-Type Asteroid 21 Lutetia: Spectral and Frequency Analysis

A preliminary study of the surface of the asteroid 21 Lutetia with ground-based methods is of significant importance, because this object is included into the Rosetta space mission schedule. From August 31 to November 20, 2000, about 50 spectra of Lutetia and the same number of spectra of the solar analog HD10307 (G2V) and regional standards were obtained with a resolution of 4 and 3 nm at the MTM-500 telescope television system of the Crimean astrophysical observatory. From these data, the synthetic magnitudes of the asteroid in the BRV color system have been obtained, the reflected light fluxes have been determined in absolute units, and its reflectance spectra have been calculated for a range of 370–740 nm. In addition, from the asteroid reflectance spectra obtained at different rotation phases, the values of the equivalent width of the most intensive absorption band centered at 430–440 nm and attributed to hydrosilicates of the serpentine type have been calculated. A frequency analysis of the values V(1, 0) confirmed the rotation period of Lutetia 0.^d3405 (8.^h172) and showed a two-humped light curve with a maximal amplitude of 0.^m25. The color indices B-V and V-R showed no noticeable variations with this period. A frequency analysis of the equivalent widths of the absorption band of hydrosilicates near 430–440 nm points to the presence of many significant frequencies, mainly from 15 to 20 c/d (c/d is the number of cycles per day), which can be caused by a heterogeneous distribution of hydrated material on the surface of Lutetia. The sizes of these heterogeneities (or spots) on the asteroid surface have been estimated at 3–5 to 70 km with the most frequent value between 30 and 40 km.     

Albedo and color contrasts on asteroid surfaces

Asteroids in general display only small or negligible variations in spectrum or albedo during a rotational cycle. Color variations with rotation are described in the literature but are usually comparable to the noise in the measurements. Twenty-four asteroids have been systematically monitored for such color changes. Only 3 Juno, 4 Vesta, 6 Hebe, 71 Niobe, 349 Dembowska, and 944 Hidalgo display color variations larger than 0.03 mag. In each of these cases the asteroid appears redder near maximum brightness. Of seven asteroids monitored polarimetrically, only 4 Vesta shows a convincing variation, attributed to an albedo change with rotation. The lightcurve can be explained by albedo differences alone; Vesta apparently has a nearly spheroidal shape. Notwithstanding the above results, the degree of uniformity of most asteroid surfaces is remarkable. If asteroids exist with large discrete domains of ferrosilicate, metallic, and/or carbonaceous material together on their surfaces, they have not yet been identified.