Reply to “Reply to comments on defining biominerals and organominerals: Direct and indirect indicators of life [Perry et al., Sedimentary Geology, 201, 157–179]” by R.S. Perry and M.A. Sephton: [Sedimentary Geology 213 (2009) 156]

This is a reply to R.S. Perry and M.A. Sephton's “Reply to comments on defining biominerals and organominerals: direct and indirect indicators of life [Perry et al., Sedimentary Geology, 201, 157–179]” [Sedimentary Geology 213 (2009) 156].     

Place,identity and stigma: blocks and the ‘blockies’ of Tara,Queensland, Australia

This article explores the role of geographical context in generating a stigmatised identity among residents of Tara rural subdivisions in the coal seam gas fields in Queensland’s Western Downs. The research was based on qualitative interviews with Tara ‘Blockies’, as these residents are commonly referred to, that revealed how their existence in the middle of an agrarian region resulted in the assignation of a stigma that has marked them as different, and subsequently devalued their status. We explain that this distinction and category division of the normals, referring to Tara’s Agrarian residents, from the ‘stigmatised’ led to an antagonistic relationship that prevented successful socio-cultural assimilation. We demonstrate how an immoral place becomes disadvantaged, resulting in poor well-being, and how imposed labels threaten the self-esteem of its occupants.     

Land–sea carbon and nutrient fluxes and coastal ocean CO2 exchange and acidification: Past,present, and future

Epochs of changing atmospheric CO₂ and seawater CO₂–carbonic acid system chemistry and acidification have occurred during the Phanerozoic at various time scales. On the longer geologic time scale, as sea level rose and fell and continental free board decreased and increased, respectively, the riverine fluxes of Ca, Mg, DIC, and total alkalinity to the coastal ocean varied and helped regulate the C chemistry of seawater, but nevertheless there were major epochs of ocean acidification (OA). On the shorter glacial–interglacial time scale from the Last Glacial Maximum (LGM) to late preindustrial time, riverine fluxes of DIC, total alkalinity, and N and P nutrients increased and along with rising sea level, atmospheric PCO₂ and temperature led, among other changes, to a slightly deceasing pH of coastal and open ocean waters, and to increasing net ecosystem calcification and decreasing net heterotrophy in coastal ocean waters. From late preindustrial time to the present and projected into the 21st century, human activities, such as fossil fuel and land-use emissions of CO₂ to the atmosphere, increasing application of N and P nutrient subsidies and combustion N to the landscape, and sewage discharges of C, N, P have led, and will continue to lead, to significant modifications of coastal ocean waters. The changes include a rapid decline in pH and carbonate saturation state (modern problem of ocean acidification), a shift toward dissolution of carbonate substrates exceeding production, potentially leading to the “demise” of the coral reefs, reversal of the direction of the sea-to-air flux of CO₂ and enhanced biological production and burial of organic C, a small sink of anthropogenic CO₂, accompanied by a continuous trend toward increasing autotrophy in coastal waters.     

Defining metamorphogenic mineral deposits —an introduction

Summary Early tentative hypotheses, that regional metamorphism may be genetically associated with the formation of mineral deposits are now reasonably confirmed, and the class of metamorphogenic mineral deposits is widely accepted. Two end member models define a range of possibilities occurring in nature: the prograde devolatilization model, and the retrograde leaching model. In the first, the mineralizing fluids are thought to have been generated and to have acquired their solute content within source rocks undergoing prograde metamorphism. Then they flow towards lower pressure zones, possibly accompanied by further reactions with country rocks. Finally, changes in the chemical or physical environment along the flow conduits potentially induce mineral precipitation. Retrograde leaching occurs after peak metamorphism, when a still-hot metamorphic complex is flooded and cooled by waters from outside; this will normally happen during uplift and extensional tectonics, and the resulting convection cells are open to the surface. Metamorphogenic deposits cannot be recognized as such in the field, where they appear as examples of epigenetic hydrothermal mineralization. Only the application of a broad spectrum of laboratory methods allows a correct genetic classification. It is expected that future research will increasingly quantify the evolution of metamorphic terranes through time, similar to modern basin analysis in petroleum geology.

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Das Erkenen metamorphogener Lagersätten-eine Einleitung

Zusammenfassung Frühe Beobachtungen über enge Zusammenhänge zwischen regionaler Metamorphose und Lagerstättenbildung wurden in jüngerer Zeit bestätigt, so daß die Klasse der metamorphogenen Lagerstätten nunmehr nahezu gesichert ist. Zwei verschiedene genetische Modelle bilden die Endglieder eines in der Natur vorkommenden Spektrums solcher Lagerstättenbildung: das Modell der prograden Devolatilisierung und das Modell einer retrograden Laugung. Im ersten Fall wurden die lagerstättenbildenden Fluide innerhalb eines Gesteinskörpers gebildet, während dieser eine prograde Metamorphose erlitt; gleichzeitig nahmen die Fluide ihre kennzeichnende Lösungsfracht auf. Danach fließen sie einem Druckgefälle folgend aus dem Bildungsraum ab, z.T. unter weiteren Reaktionen mit Nebengesteinen. Chemische oder physikalische Zustandsänderungen im Verlauf der Fließwege induzieren den Mineralabsatz. Retrograde Laugung hingegen findet statt, wenn ein noch heier metamorpher Komplex nach Durchlaufen der maximalen p/T-Bedingungen durch von außen zufließende Wässer geflutet und abgekühlt wird; dies wird gewöhnlich mit Aufstieg und Dehnungstektonik verbunden sein, weshalb die resultierenden Konvektionszellen zur Oberfläche offen sind. Metamorphogene Lagerstätten können nicht nur mit Feldmethoden als solche erkannt werden, da sie dort einfach als epigenetische hydrothermale Mineralisationen erscheinen. Nur die Anwendung eines breiten Spektrums geeigneter Labormethoden erlaubt eine richtige Zuordnung. Es wird erwartet, daß zukünftige Forschung dadurch wesentliche Fortschritte erzielt, daß die Entwicklung metamorpher Komplexe in Zeit und Raum quantitativ untersucht wird, ähnlich wie jene sedimentärer Becken in der modernen Erdölgeologie.

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This paper was presented at the IGCP 291 Project Symposium Metamorphic Fluids and Mineral Deposits, ETH Zürich, March 21–23, 1991.     

Contests and struggle: Cotton farmers and COTTCO in Rushinga district,Zimbabwe, 1999–2006

The paper examines the relations between farmers and The Cotton Company of Zimbabwe (COTTCO) in Rushinga district of Zimbabwe. Based on interviews with farmers and secondary data, it examines the practice of side marketing of contracted seed cotton. While a large body of literature has discussed the social and economic effects of contract farming on farmers, there are less critical studies on side marketing of crops by farmers in unstable economic and political environment such as Zimbabwe. The paper demonstrates that farmers taking advantage of the macroeconomic environment in Zimbabwe violated contracts by selling seed cotton to other buyers. In the process, farmers renegotiated the meaning of the contract and appealed to market rationality embedded in the neo-liberal ideology. For these farmers, side marketing was part of a survival strategy, albeit in imperfect markets and a difficult economic environment. Nonetheless, side marketing of seed cotton strained relations between farmers and COTTCO. The paper shows the tensions in contracts that require regulation by the state and the neo-liberal ideology that promote free markets and argue against strong regulation.     

Water in coesite: Incorporation mechanism and operation condition,solubility and P-T dependence,and contribution to water transport and coesite preservation

A series of coesite,coexisting with or without a liquid phase,was synthesized in the nominal system SiO2-H2O at800-1450℃and 5 GPa.Micro-Raman spectroscopy was used to identity the crystalline phase,electron microprobe and LA-ICP-MS were employed to quantity some major and trace elements,and unpolarized FTIR spectroscopy was applied to probe the different types of hydrogen defects,explore water-incorporation mechanisms and quantify water contents.Trace amounts of A1 and B were detected in the coesite.Combining our results with the results in the literatures,we have found no positive correlation between the Al contents and the"Al"-based hydrogen concentrations,suggesting that previously proposed hydrogen-incorporation mechanism H^++Al^3+■Si^4+does not function in coesite.In contrast,we have confirmed the positive correlation between the B contents and the B-based hydrogen concentrations.The hydrogen-incorporation mechanism H^++B3^+■Si^4+readily takes place in coesite at different P-T conditions,and significantly increases the water content at both liquid-saturated and liquid-undersaturated conditions.For the SiO2-H2O system,we have found that type-Ⅰhydrogarnet substitution plays a dictating role in incorporating water into coesite at liquid-saturated condition,type-II hydrogarnet substitution contributes significantly at nearly dry condition,and both operate at conditions in between.The water solubility of coesite,as dictated by the type-Ⅰhydrogarnet substitution,positively correlates with both P and T,cH2O=-105(30)+5.2(32)×P+0.112(26)×T,with cH2O in wt ppm,P in GPa and T in℃.Due to its low water solubility and small fraction in subducted slabs,coesite may contribute insignificantly to the vertical water transport in subduction zones.Furthermore,the water solubility of any coesite in exhuming ultra-high pressure metamorphic rocks should be virtually zero as coesite becomes metastable.With an adequately fast waterdiffusion rate,this metastable coesite should be completely dry,which may have been the key factor to the partial preservation of most natural Coe.As a byproduct,a new IR experimental protocol for accurate water determination in optically anisotropic nominally anhydrous minerals has been found.Aided with the empirical method of Paterson(1982)it employs multiple unpolarized IR spectra,collected from randomly-orientated mineral grains,to approximate both total integrated absorbance and total integrated molar absorption coefficient.Its success relies on a high-level orientation randomness in the IR analyses.     

Power,perception, and adaptation: Exploring gender and social–environmental risk perception in northern Guanajuato,Mexico

This paper examines how gender relations within rural communities in north-central Mexico affect women’s perceptions of and responses to environmental and social risks. Several studies currently exist which suggest various reasons as to how people especially vulnerable to the effects of climate change perceive their risks, and how this influences their responses. In this paper, I take a feminist approach to questions of social–environmental risks and adaptation to argue that risk perception is tightly linked to knowledge production, and knowledge production is a power-laden process involving the constant negotiation of resources, responsibilities and knowledge. I base this argument on the results of fieldwork conducted from September 2009 to May 2010 with women residents of two ejidos in northern Guanajuato, Mexico. In drawing from feminist political ecology studies, I intend to show how gender, environmental knowledge, risk perception and thus, adaptation are constituted by and embedded in social relations of power.     

The Hissar–Alay and the Pamirs: Deep-Seated Structure,Geodynamic Model,and Experimental Evidence

The structural and geodynamic features of the Pamirs and the Hissar–Alay have been revealed based on geological and geophysical evidence supplemented by experimental data. It has been shown that both the Pamirs and the Hissar–Alay are geodynamic systems, the formation of which is related to interference of two geodynamic regimes: (i) global orogeny covering extensive territories of Eurasia and determining their similarity and (ii) regional regimes differing for the Pamirs and the Alay, which act independently within Central Asian and Apline–Himalayan mobile belts, respectively. The Pamirs do not act as an indentor during the formation of structure of the Hissar–Alay and areas to the north. It is stated that the Pamir–Alay segment of Asia is a reflection of the geodynamic countermotion setting (3D flow of mountain masses) of several distinct segments of the continental lithosphere, while the Pamirs are an intracontinental subduction domain at the surface, which represents a special tectonic–geodynamic type of structures.     

Theory and context in analyzing livelihoods,land use,and land cover: Lessons from Petén,Guatemala

Most studies on the causes of deforestation have sought to link the phenomenon to specific economic, political, or demographic factors, usually through statistical or spatial-statistical modeling. However, generalizations about the link between deforestation and specific variables or classes of variables are of questionable validity. Another approach, one that is receiving growing attention, seeks instead to identify particular contexts or situations, as created by an array of interacting factors, which encourage forms of land use or other economic activity that can generate deforestation pressure. Such an approach was used in this study to explore recent trends and dynamics in the Petén region of northern Guatemala. The research found a number of regional and national scale factors that in combination have led to a process of de-agrarianization and dispossession among smallholders, while large scale, commercial activities in agriculture, ranching and plantation forestry increasingly dominate. Rapid land concentration, in conjunction with limited employment generation through emergent activities, is intensifying pressure on remaining areas of forest. A focus on two distinct areas within Petén reveals how broader-scale trends and features can have differing outcomes at the local level, with contrasting socioeconomic and environmental effects. Finally, the paper explores the implications of recent dynamics in Petén for both policy and theory in relation to deforestation, agrarian change, and regional development. Key factors and questions are highlighted that should be considered when exploring influences on regional socioeconomic and environmental conditions.     

A Statistical Approach to Defining Proterozoic Crustal Provinces and Testing Continental Reconstructions of Australia and Laurentia - SWEAT or AUSWUS?

A new statistical method is proposed to compare crustal terranes and to cluster terranes into crustal provinces, regions and realms. Geochronological data on mafic igneous rocks, felsic igneous rocks, deformation history and Nd model age were collected from the recent literature for over 100 terranes.The 54 selected Laurentian terranes cluster into 9 provinces including a previously well recognized very distinctive SW USA province, region and realm. The 38 selected Australian terranes cluster into six provinces including a distinctive Gawler Province. A combined dendrogram of the 100 terranes from Laurentia, Australia and Antarctica results in 8 superprovinces and 11 provinces. Five of the superprovinces contain both Laurentian and Australian terranes.The inclusion of the Nevada-Californian Mojave and the San Gabriel terranes in an otherwise Australian superprovince that includes Broken Hill and Mt Isa terranes, strongly supports the AUSWUS Laurentia-Australia reconstruction rather than the SWEAT reconstruction. Low statistical similarities between western Laurentia and eastern Antarctica fail to support the SWEAT hypothesis whilst high similarities between Canadian and north Australian terranes provides weak support for AUSWUS.     

Upper Cretaceous amber from Vendée,north-western France: Age dating and geological,chemical, and palaeontological characteristics

The Upper Cretaceous lignite deposits of La Garnache, Vendée (north-western France), consist of two lignitic clay series, Garnache 1 and Garnache 2, separated by a fault. The first series cropped out to the south of the fault during road works until 2002 but is now covered by an embankment. It has provided numerous pieces of amber containing arthropod and micro-organism inclusions. The second lignitic series, exposed to the north of the fault, is rich in fossil wood but devoid of amber. Palynological analysis of Garnache 1 revealed several Normapolles species belonging to the genera Atlantopollis, Complexiopollis, Osculapollis, Plicapollis and Trudopollis, but larger forms typical of Senonian deposits are absent. By contrast, Garnache 2 proved to be dominated taxonomically and numerically by spores (Appendicisporites, Camarozonosporites, Gleicheniidites, Patellasporites, Stereisporites), associated with a few gymnosperm (Cerebropollenites, Phyllocladidites, Classopollis) and angiosperm (Liliacidites, Retitricolpites and a single specimen of the Normapolles Complexiopollis) taxa. Garnache 1 is, therefore, younger than Garnache 2, the latter being clearly Cenomanian in age whereas Garnache 1 is more likely to be Turonian. Lignitic clay of Garnache 1 contains numerous translucent, orange to red, pieces of amber. Vendean amber is rich in aquatic arthropods, such as tanaids and epicarideans (Crustacea), as well as marine or brackish siliceous micro-organisms such as diatoms and sponge spicules. These aquatic inclusions indicate that resin-producing trees grew along and close to the seashore. The amber-bearing clay was deposited in a calm, estuarine or lagoonal, muddy environment.     

Scaling struggles over land and law: Autonomy,investment, and interlegality in Myanmar’s borderlands

This article explores the relevance of spatial global legal pluralism—an emerging field at the interstices of geography, anthropology, and socio-legal studies—for research on the global land rush, and the study of land law and investment in particular. I argue that a focus on the spatial dimensions of law—coupled with attention to the interlegality, scalar politics, and spatio-temporalities of semi-autonomous law—offers important insights into the dynamic forces, actors, and stakes in the global land rush. In Myanmar, the prospects for peace—however tenuous—have led to an acceleration of land law development including the creation of ‘semi-autonomous land law’ by ethnic armed groups and activists in its borderlands. I discuss the ways in which such policies not only anticipate peace but seek to shape its political-economy over multiple spatio-temporalities. By recognizing both international human rights law and customary law, such ‘non-state’ laws bring these two scales into an intermediary legal jurisdiction, contributing to the sedimentation of Kawthoolei and Kachinland as political scales in their own right.     

Fourier’s heat conduction equation: History, influence, and connections

The equation describing the conduction of heat in solids has, over the past two centuries, proved to be a powerful tool for analyzing the dynamic motion of heat as well as for solving an enormous array of diffusion-type problems in physical sciences, biological sciences, earth sciences, and social sciences. This equation was formulated at the beginning of the nineteenth century by one of the most gifted scholars of modern science, Joseph Fourier of France. A study of the historical context in which Fourier made his remarkable contribution and the subsequent impact his work has had on the development of modern science is as fascinating as it is educational. This paper is an attempt to present a picture of how certain ideas initially led to Fourier’s development of the heat equation and how, subsequently, Fourier’s work directly influenced and inspired others to use the heat diffusion model to describe other dynamic physical systems. Conversely, others concerned with the study of random processes found that the equations governing such random processes reduced, in the limit, to Fourier’s equation of heat diffusion. In the process of developing the flow of ideas, the paper also presents, to the extent possible, an account of the history and personalities involved. Reprinted by permission from theAmerican Geophysical Union, @ 1999. Originally published inReviews of Geophysics as “Fourier’s Heat Conduction Equation: History, Influence and Connections,” Vol. 37, issue 1, pages 151–172, February 1999. Appended here are eight figures of historical importance.     

Impacts,volcanism and mass extinction: random coincidence or cause and effect?

Large impacts are credited with the most devastating mass extinctions in Earth's history and the Cretaceous?–?Tertiary (K/T) boundary impact is the strongest and sole direct support for this view. A review of the five largest Phanerozoic mass extinctions provides no support that impacts with craters up to 180 km in diameter caused significant species extinctions. This includes the 170 km-diameter Chicxulub impact crater regarded as 0.3 million years older than the K/T mass extinction. A second, larger impact event may have been the ultimate cause of this mass extinction, as suggested by a global iridium anomaly at the K/T boundary, but no crater has been found to date. The current crater database suggests that multiple impacts, for example comet showers, were the norm, rather than the exception, during the Late Eocene, K/T transition, latest Triassic and the Devonian?–?Carboniferous transition, but did not cause significant species extinctions. Whether multiple impacts substantially contributed to greenhouse warming and associated environmental stresses is yet to be demonstrated. From the current database, it must be concluded that no known Phanerozoic impacts, including the Chicxulub impact (but excluding the K/T impact) caused mass extinctions or even significant species extinctions. The K/T mass extinction may have been caused by the coincidence of a very large impact (>?250 km) upon a highly stressed biotic environment as a result of volcanism. The consistent association of large magmatic provinces (large igneous provinces and continental flood-basalt provinces) with all but one (end-Ordovician) of the five major Phanerozoic mass extinctions suggests that volcanism played a major role. Faunal and geochemical evidence from the end-Permian, end-Devonian, end-Cretaceous and Triassic/Jurassic transition suggests that the biotic stress was due to a lethal combination of tectonically induced hydrothermal and volcanic processes, leading to eutrophication in the oceans, global warming, sea-level transgression and ocean anoxia. It must be concluded that major magmatic events and their long-term environmental consequences are major contributors, though not the sole causes of mass extinctions. Sudden mass extinctions, such as at the K/T boundary, may require the coincidence of major volcanism and a very large Impact.