西藏冈底斯带门巴地区印支期花岗岩地球化学特征及其构造意义

门巴地区晚三叠世花岗岩主要出露在西藏冈底斯构造带的弧背断隆上,主要岩石类型为黑云角闪花岗闪长岩和黑云二长花岗岩。岩石为钙碱性,具有富SiO2、K2O的特点。K2O/Na2O平均为1.13,相对富钾。Al2O3变化于13.27%～15.53%之间,A/CNK平均为1.0,为准铝质岩石。花岗岩体稀土元素总量∑REE变化于99.5×10-6～294.72×10-6之间,轻稀土元素富集,重稀土元素亏损,具弱至中等的负Eu异常。微量元素以富K、Rb、Ba、Th等大离子亲石元素和亏损Nb、Ta、Y、Yb等高场强元素为特征。岩石学和岩石地球化学研究表明,该时代的花岗岩具I型花岗岩的特点,形成于岛弧环境,是新特提斯洋早期俯冲作用的产物。同时它也暗示着冈底斯岩浆弧带在晚三叠世就已成雏形。     

甘肃北山南带沙枣园复式岩体年代学、地球化学特征及其构造意义

北山南带沙枣园复式岩体由中细粒黑云母花岗闪长岩、细粒黑云母石英闪长岩、中粒黑云母二长花岗岩和中粗粒黑云母正长花岗岩4个岩相单元组成。LA-ICP-MS锆石U-Pb定年结果表明,中细粒黑云母花岗闪长岩、细粒黑云母石英闪长岩和中粒黑云母二长花岗岩侵位于晚二叠世(252.1±1.9Ma、252.2±2.1Ma和248.8±3.5Ma),为海西晚期的产物;而中粗粒黑云母正长花岗岩侵位于早三叠世(246.4±2.0Ma),为印支早期的产物。该花岗质岩石均具有稀土元素的球粒陨石标准化配分曲线呈右倾型,轻重稀土分馏大,轻稀土富集且分异明显,而重稀土亏损且分异不显著特征。中细粒黑云母花岗闪长岩和细粒黑云母石英闪长岩具有较高的SiO_2、Al_2O_3和Na_2O含量,以及较低的MgO含量,强烈富集Sr而亏损Yb和Y,具轻微的铕异常(δEu=0.75～1.16),表现出典型的埃达克岩特征;中粒黑云母二长花岗岩和中粗粒黑云母正长花岗岩总体富硅(SiO_2)、富钾(K_2O)、富碱(K_2O+Na_2O),Al_2O_3含量中等,铕分别呈现负异常(δEu=0.45～0.73)和强负异常(δEu=0.02～0.08)。年代学及地球化学特征研究表明:①中细粒黑云母花岗闪长岩和细粒黑云母石英闪长岩属准铝质-弱过铝质的钙碱性Ⅰ型花岗岩,并具有典型的埃达克岩特征,中粒黑云母二长花岗岩属弱过铝质的高钾钙碱性Ⅰ型花岗岩,中粗粒黑云母正长花岗岩属弱过铝质的高钾钙碱性A2型花岗岩;②中细粒黑云母花岗闪长岩、细粒黑云母石英闪长岩和中粒黑云母二长花岗岩的岩浆来源于下地壳玄武质岩石部分熔融源区,并在上升过程中混染了下地壳物质,而中粗粒黑云母正长花岗岩的岩浆来源于年轻地壳中富含黑云母的变质泥岩部分熔融源区;③中细粒黑云母花岗闪长岩、细粒黑云母石英闪长岩和中粒黑云母二长花岗岩是俯冲-碰撞构造背景条件下的岩浆产物,而中粗粒黑云母正长花岗岩是同碰撞-碰撞后构造背景条件下的岩浆产物。     

西藏冈底斯带昂仁县差绒—丁欧复式花岗岩的成因：锆石U-Pb年代学及地球化学制约

西藏冈底斯带昂仁县措迈乡差绒—丁欧复式花岗岩岩石类型为石英闪长岩、黑云二长花岗岩和二长花岗岩,各侵入体之间为突变接触关系,闪长岩U- Pb同位素年龄为155.4±2.7Ma;黑云二长花岗岩U- Pb同位素年龄为152.0±13Ma、153.96±0.92Ma,时代均为晚侏罗世。岩石地球化学显示三者均为高钾钙碱性系列岩石,石英闪长岩为弱铝质―准铝质;黑云二长花岗岩和二长花岗岩则为准铝质—过铝质。黑云二长花岗岩和二长花岗岩相比石英闪长岩表现为富硅、富碱、贫Ca、Ti、Mg,轻稀土元素更富集,轻稀土分馏程度更高,分异更加明显的特点,微量元素二长花岗岩Ba、Sr、P、Ti亏损最为明显,黑云二长花岗岩的Rb、Th、K富集最为明显,石英闪长岩相比黑云二长花岗岩和二长花岗岩的Rb/Sr（0.18~0.46）、Rb/Ba值（0.13~0.26）最低,指示其分异演化程度较低。差绒—丁欧花岗岩应是同时代不同期次侵入的复式岩体,早期为I型的石英闪长岩和黑云二长花岗岩,晚期为S型二长花岗岩,该复式岩体并非产出于单一的俯冲环境,二长花岗岩可能为弧陆碰撞时的产物。     

阿尔泰巴利尔斯河一带岩体LA MC ICP MS锆石U Pb年代学、岩石成因及地质意义

新疆阿尔泰巴利尔斯河一带岩体岩石类型复杂,主要岩石组合为花岗闪长岩、黑云二长花岗岩和二长花岗岩。花岗闪长岩和二长花岗岩中LA MC ICP MS锆石 U Pb测年结果分别为(3864±28) Ma和(3868±12) Ma。花岗闪长岩、黑云二长花岗岩和二长花岗岩地球化学分析结果显示,岩石SiO2含量为7433%～7670%,里特曼指数为149～204,A/CNK值介于100～107,大离子亲石元素Rb、Th等和轻稀土元素相对富集,高场强元素Sr、Ti、Nb等和重稀土元素则相对亏损,具较强的负Eu异常(δEu=031～084),表明该岩石为具有富钾、钙碱性、弱过铝质特征的高分异I型花岗岩。综合研究认为,巴利尔斯河一带岩体形成于与俯冲作用有关的活动大陆边缘的岩浆弧构造环境,是古亚洲洋向北俯冲消减过程中岩浆上侵就位的产物。     

岩浆作用对岩浆热液金铜成矿制约的元素地球化学和锆石CL图像记录——以延边小西南岔富金铜矿床为例

通过对延边小西南岔大型富金铜床矿区产出的与成矿密切的角闪花岗闪长岩、黑云花岗闪长岩、黑云二长花岗岩(花岗杂岩)侵入体和闪长玢岩岩脉的地质、岩相学和元素地球化学研究,结合单颗粒锆石CL图象特征及精细测年结果,初步确定:它们的岩浆就位发生在晚中生代早白垩世末期(112 Ma～102 Ma),适值伊泽奈崎板块向古亚洲板块俯冲的大陆边缘环境;金铜矿化发生在角闪花岗闪长岩(111.7 Ma±2.8 Ma)、黑云花岗闪长岩(106.7 Ma±1.6 Ma)、黑云二长花岗岩(104.6 Ma±2.5 Ma)与闪长玢岩(102.1Ma±2.2 Ma)的就位之间;花岗杂岩是先存的岩石圈地幔受到俯冲大洋板片提供流体的交代,形成的次生岩石圈地幔,次生岩石圈地幔的部分熔融产生的埃达克质岩浆在MOSH面附近与下地壳重熔产生的钾质熔体混合,混合后的岩浆经以斜长石为主的矿物相分离结晶作用先后上侵就住形成;而闪长玢岩岩脉则是埃达克质岩浆直接上侵就位形成;矿质主要来自俯冲大洋板块,埃达克岩浆和地壳重熔岩浆的形成以及两者的混合作用、混合岩浆的结晶分离作用是导致成矿物质活化、迁移、富集的根源.     

内蒙古北山造山带百合山地区350 Ma石英闪长岩的成因及对红石山-百合山洋俯冲时限的制约

对内蒙古白山岩浆弧内百合山石英闪长岩进行了LA-ICP-MS锆石U-Pb测年、Hf同位素及岩石地球化学分析。结果显示,该岩体的形成年龄为350.8±1.5 Ma,岩浆锆石的ε_(Hf)(t)值在5.28～9.88之间,模式年龄为724～1018 Ma。地球化学数据显示,百合山石英闪长岩为一套I型钙碱性系列岩石,富碱(Na_2O+K_2O=6.03%～6.96%),富钠(Na_2O/K_2O2),较低的Mg~#(35.48～39.78)、Ni(2.06×10~(-6)～5.54×10~(-6))和Cr(2.11×10~(-6)～7.93×10~(-6))含量。相对富集轻稀土元素,重稀土分馏不明显,较低的(La/Yb)_N值(4.28～5.60),无明显Eu异常,相对富集Rb、K、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素等,地球化学成分表明,石英闪长岩具有俯冲带成因的特征。石英闪长岩的锆石U-Pb年龄和岩石成因证明了350 Ma石英闪长岩是晚古生代白山岩浆弧内首次发现的可以明确与红石山-百合山洋俯冲消减作用有关的最早的弧岩浆记录。表明红石山-百合山洋于约350 Ma之前就已经开始发生俯冲消减,比前人一般认为的俯冲开始的时间提前了22 Ma。     

广西六万山早二叠世花岗闪长岩岩石地球化学特征及其大地构造意义

花岗岩与大地构造环境之间存在着成因联系,因为岩浆活动受到了构造环境的控制。在大地构造演化的各个阶段中,花岗岩的岩石化学成分表现出了有序的演化趋势,这种趋势在主量元素、微量及稀土元素等方面都有反映。本文通过对广西六万大山早二叠世中细粒(斑状)堇青黑云花岗闪长岩的岩石化学和地球化学特征的分析研究,结合相关的图解,讨论和判别其岩浆源及成因、对应的大地构造环境和阶段,认为六万山中细粒斑状堇青黑云花岗闪长岩的化学成分特征是富铝,具过铝质花岗岩特征,Na2O/K2O1,岩石中出现堇青石,未出现角闪石,为S型花岗岩。扬子板块与华夏板块结合带西南端存在古生代洋盆,六万山中细粒斑状堇青黑云花岗闪长岩形成于早二叠世印支运动早期、该古生代多岛洋中微板块之间发生的追上式软碰撞的火山弧环境,当时其北西侧的前陆盆地(钦州-防城洋盆)仍未关闭。     

西藏狮泉河地区晚侏罗世中性侵入岩锆石U-Pb年龄、地球化学特征及构造意义

侵位于狮泉河结合带南缘和结合带南侧古生代地层的晚白垩世侵入岩中,解体出一套中性侵入岩,呈岩珠、岩枝状产出,主要岩石类型为石英闪长岩、英云闪长岩和花岗闪长岩,其中石英闪长岩和英云闪长岩的LA-ICP-MS锆石U-Pb年龄为157.3±1.5 Ma(MSWD=0.96)和159.3±3.7 Ma(MSWD=2.30),指示岩浆活动时间为晚侏罗世牛津期。该岩体Si O2含量在59.65%~64.57%之间,K2O为1.95%~2.69%之间,Na2O为1.97%~3.42%,K2O/Na2O在0.74~1.29之间,P2O5为0.085%~0.139%之间,Al2O3为13.63%~15.68%之间,A/CNK为0.89~1.07,属于准铝质—弱过铝质花岗岩。岩石稀土元素总量(∑REE)为107.37×10-6~148.33×10-6,LREE/HREE在6.77~9.67之间,轻重稀土分异程度强,δEu为0.63~0.84,铕略具负异常;在原始地幔标准化蛛网图上,富Rb、Th等大离子亲石元素(LILE)而亏损Nb、Ta、Ti和P等高场强元素(HFSE),具有岛弧钙碱性岩浆的地球化学性质。从岩石学、岩石地球化学特征研究表明,该时期岩石显示同源岩浆演化的特征,具有典型I型花岗岩特征,形成于板块俯冲下的岛弧环境。表明狮泉河一带在晚侏罗世已经存在俯冲型花岗岩,研究认为该时期岩浆活动很可能是狮泉河洋盆北缘(北亚带)持续扩张时,向南缘(南亚带)及中冈底斯带北缘俯冲的产物。     

华北克拉通东北部新太古代晚期岩浆作用和地壳增生:锆石U-Pb-Hf同位素、微量元素和地球化学制约

辽西-辽南地区新太古代花岗质岩石的锆石LA-ICP-MS U-Pb年代学和微量元素及全岩地球化学和锆石Hf同位素研究为探讨华北克拉通东北部前寒武纪地壳生长和演化提供了制约。结果表明,辽西地区钓鱼台二长花岗岩和辽南地区城子坦片麻状石英闪长岩、安波花岗质片麻岩中锆石均发育岩浆生长环带,结合相对高的Th/U比值(0.24~1.75)和锆石稀土元素特征,暗示它们均为岩浆锆石。定年结果显示,钓鱼台二长花岗岩、城子坦片麻状石英闪长岩和安波花岗质片麻岩的原岩分别形成于2519±9Ma、2505±10Ma和2519±11Ma,即它们均形成于新太古代晚期。辽西-辽南地区新太古代花岗质岩石均具有高SiO2(61.85%~73.38%)、低MgO(0.36%~2.83%)、富Na2O+K2O(7.64%~10.86%)的特征,为准铝质-弱过铝质的高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素,发育弱的Eu负异常和Sr、P、Ti的亏损。岩浆锆石均具有正的εHf(t)值,介于0.4~5.9之间,tDM1变化于2595~2798Ma之间,峰值年龄为2740Ma,与华北克拉通最重要的一次地壳增生事件相一致。辽西-辽南地区新太古代花岗质岩石形成于板块俯冲的弧构造环境下新增生下地壳物质的部分熔融。     

华北板块北缘中段早中二叠世的构造属性：来自花岗岩类锆石U-Pb年代学及地球化学的制约

内蒙古温都尔庙南-铁沙盖黑云角闪石英闪长岩和角闪黑云花岗闪长岩位于华北板块北缘中段晚古生代构造岩浆活动带中;锆石LA-ICP-MS U-Pb定年结果显示,其形成时代分别为271.8±2.4Ma,271.4±1.3Ma、268.7±1.3Ma。主量元素SiO₂含量61.42%~71.73%,K₂O含量3.10%~5.11%,K₂O/Na₂O值介于0.93~1.96之间,Mg^#值介于42.54~49.93之间,A/CNK为0.90~1.03;副矿物为锆石、磷灰石和磁铁矿,属亚碱性高钾钙碱性系列、I型花岗岩类;富集轻稀土(LREEs)、大离子亲石元素(LILEs,Cs、Rb、K、Ba、Th和U),亏损重稀土元素(HREEs)及高场强元素(HFSEs,Nb、Ta和Ti),弱Eu负异常(δEu=0.55~0.95),形成于活动大陆边缘弧环境,是上地壳部分熔融的产物。黑云角闪石英闪长岩和角闪黑云花岗闪长岩中发育大量暗色微粒包体(黑云闪长岩),包体可能是岩石圈地幔部分熔融的产物,相对于寄主岩石贫Si、K富Fe、Mg、Ca、Ti、大离子亲石元素(LILEs,Rb、Cs、Sr和U)和高场强元素(HFSEs,Nb、Ta、Zr、Hf)。本文花岗岩类的侵位反映了早中二叠世古亚洲洋俯冲于华北板块北缘之下及岩浆混合作用的岩浆事件。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。