Design of Lysimeter Leak Detector Networks for Surface Impoundments and Landfills

Sampling of soil pore moisture in the vadose zone underneath land disposal facilities (landfills and surface impoundments) for hazardous waste has been suggested as an "early warning system" to detect leakage from these facilities. Some states require vadose zone moisture sampling at such sites. Given a leak of a particular size, mathematical models can estimate the necessary moisture sample volume collection times and lysimeter spacings to guarantee detection of the leak in a homogeneous medium. Examination of 47 hazardous waste sites existing in 1984 indicated the most were located in areas with water tables too shallow to permit vadose zone detection monitoring. Several of the 47 sites had soils that could be described as loamy sand, silt loam or silty clay. Using these three soils as examples, the process of lysimeter leak-detector network design has been illustrated. For a particular loamy sand with a saturates hydraulic conductivity of 10^-6 cm/ sec, the maximum ceramic lysimeter spacing is 15.5 feet at a depth of 30 feet to collec a moisture sample of 10 mL in one week from a 1 ft2 leak. For a silt loam, maximum lysimeter spacing would be 17 feet at depth of 15 feet. For silty clays, the maximum lysimeter spacing is 7 feet at a depth of 2 feet; maximum emplacement depth is about 9 feet. Calculations show that in some soils, suction lysimeters will not be able to collect usable moisture samples. Since soil properties vary widely and lysimeter spacing is strongly dependent on soil-moisture characteristics appropriate soil measurements and modeling must be performed at each disposal facility to estimate lysimete performance and to select locations for emplacement.     

Effects of Hydrogel Amendment to Different Soils on Plant Available Water and Survival of Trees under Drought Conditions

The effect of super absorbent polyacrylate (SAP) hydrogel amendment to different soil types on plant available water (PAW), evapotranspiration and survival of Eucalyptus grandis, Eucalyptus citriodora, Pinus caribaea, Araucaria cunninghamii, Melia volkensii, Grevillea robusta, Azadirachta indica, Maesopsis eminii and Terminalia superba was investigated. The seedlings were potted in 3 kg size polythene bags filled with sand, loam, silt loam, sandy loam and clay soils, amended at 0 (control), 0.2 and 0.4% w/w hydrogel. The tree seedlings were allowed to grow normally with routine uniform watering in a glass house set up for a period of eight weeks, after which they were subjected to drought conditions by not watering any further. The 0.4% hydrogel amendment significantly (p < 0.05) increased the PAW by a factor of about three in sand, two fold in silt loam and one fold in sandy loam, loam and clay soils compared to the control. Similarly, the addition of either 0.2 or 0.4% hydrogel to the five soil types resulted in prolonged tree survival compared to the controls. Araucaria cunninghammi survived longest at 153 days, while Maesopsis eminii survived least (95 days) in sand amended at 0.4% after subjection to desiccation. Evapotranspiration was reduced in eight of the nine tree species grown in sandy loam, loam, silt loam and clay soils amended at 0.4% hydrogel. It is probable that soil amendment with SAP decreased the hydraulic soil conductivity that might reduce plant transpiration and soil evaporation.     

A New Method for Collecting Core Samples Without a Drilling Rig

A new piston sampler allows the collection of high-quality core samples from sand, silt or clay, up to depths of 18 meters. The sampler is operated by a one- or two-person crew without a drilling rig. The sampler and ancillary equipment fit easily into a half-ton truck, making this a highly portable sampling system. Other advantages include minimal mechanical disturbance and precisely known sample depth. Casing is not required to maintain an open corehole below the water table and drilling fluid is not used in the corehole, so the solids and pore water of the sample should not be contaminated by foreign fluids. High-quality samples for physical, geochemical, and microbiological characterization of the subsurface are easily obtained with this new device.     

SfM-MVS Photogrammetry for Splash Erosion Monitoring under Natural Rainfall

An understanding of splash erosion is the basis to describe the impact of rain characteristics on soil disturbance. In typical splash cup experiments, splashed soil is collected, filtered, and weighed. As a way to collect additional data, our experiments have been supplemented by a photogrammetric approach. A total of three soils were tested across three sites, one in the Czech Republic and two in Austria, all equipped with rain gauges and disdrometers to measure rainfall parameters. The structure from motion multiview stereo (SfM-MVS) photogrammetric method was used to measure the raindrops impact on the soil surface. The images were processed using Agisoft PhotoScan, resulting in orthophotos and digital elevation models (DEMs) with a resolution of 0.1 mm/pix. The surface statistics included the mean surface height (whose standard deviation was used as a measure of surface roughness), slope, and other parameters. These parameters were evaluated depending on soil texture and rainfall parameters. The results show a linear correlation between consolidation and splash erosion with a coefficient of determination (R²) of approximately 0.65 for all three soils. When comparing the change in soil volume with rainfall parameters, the best correlation was found with the maximum 30-minintensity (I₃₀), resulting in R² values of 0.48 (soil A, silt loam, 26% clay), 0.59 (soil B, silt loam, 18% clay), and 0.68 (soil C, loamy sand, 12% clay). The initial increase in the sample volume for the lowest splashed mass corresponds with the increase in the clay content of each of the soils. Soil A swells the most. Soil B swells less. Soil C does not swell at all and consolidates the most. We derived the relationship between the photogrammetrically measured change in surface height and the splash erosion (measured by weight) by accounting for the effect of the clay content.     

Research on Dynamic Parameters of Soil Site in the Tianjin Coastal Area

The Tianjin coastal area is a typical soft soil region,where the soil is a marine deposit of the late Quaternary.The soil dynamic parameters from seismic risk assessment reports are collected,and drilling of 15 holes was carried out to sample the soils and measure their dynamic characteristics.The data was divided into 7 types based on lithology,namely,muddy clay,muddy silty clay,silt,silty clay,clay,silty sand and fine sand.Statistics of the dynamic parameters of these soils are collected to obtain the mea...     

LNAPL Distribution in a Cohesionless Soil: A Field Investigation and Cryogenic Sampler

Lighter-than-water Non-Aqueous Phase Liquids (LNAPLs), such as jet fuels or gasolines, are common contaminants of soils and ground water. However, the total volume and distribution of an LNAPL is difficult to accurately determine during a site investigation. LNAPL that is entrapped in the saturated zone due to fluctuating water table conditions is particularly difficult to quantify. Yet, the amount of entrapped product in the saturated zone is theoretically higher, per volume of soil, than the residual product in the unsaturated zone, and small amounts of LNAPL in the saturated zone can contaminate large volumes of ground water.
The only method currently available to quantify the amount of LNAPL is direct soil-core sampling combined with laboratory analysis of the fluid extracted from the soil cores. However, direct sampling of saturated ground water systems with conventional samplers presents a number of problems. In this study, a new sampler was developed that can be used to retrieve undisturbed soil and pore fluid samples from below the water table in cohesionless soils. The sampler uses carbon dioxide to cool the bottom of a saturated soil sample in situ to near freezing. Results of a field study where a prototype sampler was tested demonstrate the usefulness of a cryogenic sampler and show that the amount of LNAPL entrapped below the water table can be a significant part of the total LNAPL in the soil.     

An Integrated Ground Water Monitoring Program Using Multilevel Gas-Driven Samplers and Conventional Monitoring Wells

Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.     

Evaluation of a simple,inexpensive, in situ sampler for measuring time‐weighted average concentrations of suspended sediment in rivers and streams

The accurate measurement of suspended sediment (<200 μm) in aquatic environments is essential to understand and effectively manage changes to sediment, nutrient, and contaminant concentrations on both temporal and spatial scales. Commonly used sampling techniques for suspended sediment either lack the ability to accurately measure sediment concentration (e.g., passive sediment samplers) or are too expensive to deploy in sufficient number to provide landscape‐scale information (e.g., automated discrete samplers). Here, we evaluate a time‐integrated suspended sediment sampling technique, the pumped active suspended sediment (PASS) sampler, which collects a sample that can be used for the accurate measurement of time‐weighted average (TWA) suspended sediment concentration and sediment particle size distribution. The sampler was evaluated against an established passive time‐integrated suspended sediment sampling technique (i.e., Phillips sampler) and the standard discrete sampling method (i.e., manual discrete sampling). The PASS sampler collected a sample representative of TWA suspended sediment concentration and particle size distribution of a control sediment under laboratory conditions. Field application of the PASS sampler showed that it collected a representative TWA suspended sediment concentration and particle size distribution during high flow events in an urban stream. The particle size distribution of sediment collected by the PASS and Phillips samplers were comparable and the TWA suspended sediment concentration of the samples collected using the PASS and discrete sampling techniques agreed well, differing by only 4% and 6% for two different high flow events. We should note that the current configuration of the PASS sampler does not provide a flow‐weighted measurement and, therefore, is not suitable for the determination of sediment loads. The PASS sampler is a simple, inexpensive, and robust in situ sampling technique for the accurate measurement of TWA suspended sediment concentration and particle size distribution.     

Laboratory Comparison of Polyethylene and Dialysis Membrane Diffusion Samplers

The ability of diffusion samplers constructed from regenerated cellulose dialysis membrane and low density, lay flat polyethylene tubing to collect volatile organic compounds and inorganic ions was compared in a laboratory study. Concentrations of vinyl chloride, cis -1, 2-dichloroethene, bromochloromethane, trichloroethene, bromodichloromethane, and tetrachloroethene collected by both types of diffusion samplers reached equilibrium with the concentrations of these compounds in test solution within three days. Concentrations of bromide and iron collected by the dialysis membrane diffusion samplers reached equilibrium with the concentrations of these compounds in a test solution within three to seven days. No detectable concentrations of bromide or iron were found in polyethylene diffusion samplers even after 21 days. No measurable concentrations of aluminum, arsenic, barium, cadmium, chromium, iron, mercury, manganese, nickel, and lead, or sulfide, were leached out of dialysis membrane samplers over seven days. Compared with using a gas-tight syringe to sample the diffusion sampler, clipping the bag and pouring the water sample into a sample vial resulted in only a small 6.2% average loss of volatile organic compounds. Dialysis membrane diffusion samplers offer promise for use in sampling ground water for inorganic constituents as well as volatile organic compounds.     

A new sampler for extracting bed material sediment from sand and gravel beds in navigable rivers

Grain‐size distributions of bed material sediment in large alluvial rivers are required in various scientific and management applications, but characterizing gravel beds in navigable rivers is hampered by difficulties in sediment extraction. The newly developed and preliminarily tested sampler reported here can extract sediment from a range of riverbeds. The 36 × 23 × 28 cm stainless steel toothed sampler is deployed from and dragged downstream by the weight of a jet boat, and it improves upon previous samplers that are unable to penetrate gravel bed surfaces, have small apertures, and/or cannot retain fine sediment. The presented sampler was used to extract 167 bed material sediment samples of up to 16 kg (dry weight) with an average sample size of ～6 kg from 67 cross‐sections spanning 160 river kilometres along the Sacramento River. It was also tested at three sites on a subaerial bar to compare surface, subsurface, and sampler distributions. Sampler penetration is ～5 cm. The device collects individual samples that satisfy the criterion for bed material sediment whereby the largest particle comprises no more than 5% of the total sample mass in gravel and sand beds, except where the degree of surface armouring is large (e.g. armor ratios >> 2) and where more than 10% of bed material sediment is composed of grains larger than 64 mm. When aggregated samples exceed 15 kg, all satisfy the criterion whereby the largest particle comprises no more than 1% of the total sample mass. Samples closely resemble surface size distributions, except where armouring is strong. The sampler should be subject to more rigorous field testing, but many of its current limitations are expected to become negligible with the advent a larger, heavier version of the sampling device. Copyright © 2008 John Wiley & Sons, Ltd.     

The Use of a Standpipe to Evaluate Ground Water Samplers

A standpipe system was developed for testing the reliability of ground water samplers. The unit consists of a stainless steel pipe 5 inches (13 centimeters) in diameter and 100 feet (30.5 meters) in height. It has 14 sampling ports from which control samples can be withdrawn at the same time and position as the samples are collected by a sampler lowered to that position. Test solutions were made in two mixing tanks, totaling 260 gallons (980 liters), by diluting the concentrate of five volatile chlorohydrocarbons in water at two levels of concentration: 10-to-30 and 100-to-200 parts per billion (micrograms per liter).
A gas chromatograph interfaced with a purge-and-trap system was used to perform the analyses. Comparisons of the control samples with the sampler-collected samples have indicated that the three non-pumping samplers had recoveries in the range of 92.4 to 103.5 percent and the three pumping samplers had recoveries ranging from 97.7 to 101.5 percent.     

Using a Simple Soil Column Method to Evaluate Soil Phosphorus Leaching Risk

The impacts of soil P leaching on water eutrophication have widely been concerned. However, there is no dependable method to quantitatively estimate the P leaching risk of soils. In this study, a simple soil column method was developed using two calcareous Fluvisols, silt loam and loam. The soil column was 20 cm in length and 5 cm in diameter, and distilled water was continuously supplied from the top. The volume and dissolved reactive P (DRP) concentrations of leachate were measured. Results showed that DRP concentrations in leachate increased slowly for the low soil Olsen‐P levels but rapidly for the high Olsen‐P levels. According to these two‐phase changes in the DRP versus soil Olsen‐P contents, the thresholds of P leaching risk were estimated to be 41.1 and 62.3 mg P kg^?1 (Olsen‐P) for silt loam and loam, respectively. The P leaching intensity of soils increased by 3‐ to 540‐fold if the soil Olsen‐P contents accumulated from 6.6 to 155.5 mg P kg^?1. The outcomes derived from this study regarding the determination of P leaching threshold and intensity by the soil column method also need a further verification on more soils with a wide range of physical and chemical properties.     

石河子北开发区土层剪切波速与土层深度经验关系

收集了石河子市北开发区已有的土层钻孔资料及有关报告.对所有的剪切波速资料进行了整理.在前人研究和数据整理、分析的基础上,分别采用线性模型、幂函数模型和一元二次多项式模型,对石河子市北开发区的土层剪切波速与土层深度关系进行了拟合.以拟合优度为评价指标给出了粉土、粉质粘土、粉砂、细砂、砾砂和圆砾的推荐模型参数.最后对结果的合理性、适用性进行了评价.     

Loss of soil and PM10 from agricultural fields associated with high winds on the Columbia Plateau

Winter wheat–summer fallow is the conventional cropping system employed on >1·5 million ha within the Columbia Plateau of eastern Washington and northern Oregon. Wind erosion contributes to poor air quality in the region, yet little is known concerning the magnitude of soil and PM10 (particulate matter of ≤10 µm in aerodynamic diameter) loss from agricultural lands. Therefore, loss of soil and PM10 was assessed from a silt loam in eastern Washington during 2003 and 2004. Field sites were maintained in fallow using conventional tillage practices in 2003 (9 ha field) and 2004 (16 ha field) and instrumented to assess horizontal soil flux and PM10 concentrations at the windward and leeward positions in the field during high‐wind events. Soil flux was measured using creep and airborne sediment collectors while PM10 concentrations were measured using high‐volume PM10 samplers. Aggregate size distribution of parent soil and eroded sediment was characterized by rotary and sonic sieving. Six high‐wind events occurred over the two year period, with soil loss ranging from 43 kg ha^?1 for the 12–22 September 2003 event to 2320 kg ha^?1 for the 27–29 October 2003 event. Suspension‐sized particulates (<100 µm in diameter) comprised ≥90 per cent of the eroded sediment, indicating that direct suspension may be an important process by which the silt loam eroded. The corresponding loss of PM10 for these two events ranged from 5 to 210 kg ha^?1. Loss of PM10 comprised 9–12 per cent of the total soil loss for the six events. This study suggests that the relatively small loss of PM10 from eroding agricultural fields maintained in summer fallow can affect air quality in the Columbia Plateau. Therefore, alternative tillage practices or cropping systems are needed for minimizing PM10 emissions and improving air quality in the region. Copyright © 2006 John Wiley & Sons, Ltd.     

Comparison of Stainless Steel vs. PTFE Miniwells for Monitoring Halogenated Organic Solute Transport

Field tests of organic solute transport behavior have often been monitored using small-diameter wells (miniwells). To determine if experimental results could be significantly biased by sorption to, desorption from, or diffusion through sampling lines, dissolved concentrations of tetrachloroethene and carbon tetrachloride were measured in ground water samples collected simultaneously from the same spatial location during a forced-gradient test in the Borden aquifer using polytetrafluoroethene (PTFE) and stainless steel miniwells (1/8-inch O.D.).
A semiautomated organic analytical system was used on-site to obtain real-time results, which avoided sample holding problems and permitted optimizing sampling times. The breakthrough curves (plots of concentration vs. time) for both organic compounds indicate that under the conditions of this experiment (low organic solute concentrations, short exposure time of sampling lines to the plume, adequate flushing of sampling lines) there is no significant difference between concentration histories (breakthrough curves) collected using a polytetrafluoroethene sampling line and those collected using a stainless steel sampling line. This suggests that organic solute tailing seen in this and also in a similar transport experiment previously conducted at the site is the result of transport processes in the aquifer rather than an artifact introduced by the PTFE miniwells.     

The influence of soil properties on the erodibility of Belgian loamy soils: A study based on rainfall simulation experiments

Twenty soils from the Leuven region were tested in the laboratory with a rainfall simulator. Their texture varied from loam to loamy sand. On the basis of the results obtained, they were classified as a function of the runoff and splash erodibility. For every soil, several properties were determined and tentatively used to explain the classifications based on the runoff and splash erodibility. Significant negative correlations were found between silt content, aggregate stability, C_5–10 index, water content at saturation, and cohesion on the one side and erodibility on the other; a positive correlation was found between sand content and erodibility.     

Suspended sediment monitoring in alluvial gullies: A laboratory and field evaluation of available measurement techniques

Gully erosion is a significant source of fine suspended sediment (<63 μm) and associated nutrient pollution to freshwater and marine waterways. Researchers, government agencies, and monitoring groups are currently using monitoring methods designed for streams and rivers (e.g., autosamplers, rising stage samplers, and turbidity loggers) to evaluate suspended sediment in gullies. This is potentially problematic because gullies have several hydrological features and monitoring operational challenges that differ to those of continually flowing streams and rivers (e.g., short and intense flows, high suspended sediment concentrations, and rapid scouring and aggradation). Here we present a laboratory and field-based assessment of the performance of common suspended sediment monitoring techniques applied to gullies. We also evaluate a recently-described method; the pumped active suspended sediment (PASS) sampler, which has been modified for monitoring suspended sediment in gully systems. Discrete autosampling provided data at high temporal resolution, however, it had poor collection efficiency (25 ± 10%) of coarser sediment particles (i.e., sand). Rising stage sampling, while robust and cost-effective, suffered from large amounts of condensation under field conditions (25–35% of sampler volume), due to harsh climatic conditions creating large diurnal temperature differences at the field site, thereby diluting sample concentrations and introducing additional measurement uncertainty. The turbidity logger exhibited a highly variable response when calibrated at each site with physically collected suspended sediment samples (R² = 0.17–0.83), highlighting that this approach should be used with caution. The modified PASS sampler proved to be a reliable and representative measurement method for gully sediment water quality, however, the time-integrated nature of the method limits its temporal resolution compared to the other monitoring methods. We recommend monitoring suspended sediment in alluvial gully systems using a combination of complementary techniques (e.g., PASS and RS samplers) to account for the limitations associated with individual methods.     

Accuracy of two sampling methods used to estimate sediment concentrations in runoff from soil-loss plots

The use of a bottle sampler and a soil pipette to quickly and accurately sample soil-water mixtures of known sediment concentrations was tested. Both devices failed to sample adequately soil-water mixtures containing 1–187 gl^?1 of solid particles. Poor sampling ability was attributed to rapid settlement of larger particles and to innate deficiencies in the sediment trapping ability of the samplers. These sampling devices should not be used to estimate sediment loads in runoff from soil-loss plots, and erosion data from plot studies which have used a sediment sampling procedure should be treated with caution.     

Sampling VOCs with Porous Suction Samplers in the Presence of Ethanol: How Much Are We Losing?

Porous suction samplers have been widely used to obtain ground water samples from the vadose zone. However, previous studies identified different mechanisms that may compromise the sample's representativeness, such as volatilization and sorption. This issue is particularly important when dealing with volatile organic compounds (VOCs) as in gasoline spills. Ethanol is common in modern fuels and so may be present in ground water contamination from fuel releases. The objective of this work was to evaluate the losses of VOCs in the presence of ethanol when using porous suction samplers. Laboratory experiments were performed using a ceramic porous suction sampler to sample test solution containing benzene, toluene, xylenes, trimethylbenzenes, naphthalene, and different volumetric fractions of ethanol. Significant losses were found up to 30% for ethylbenzene. Ethanol was found to affect the accuracy of the readings by two main mechanisms: first, negatively, by increasing the headspace in the sampling tube, and second, positively, increasing partition to the aqueous phase due to the cosolvent effect and therefore decreasing the mass loss by volatilization. As a consequence, the highest losses of VOCs were found at intermediate ethanol volume fractions: 10% and 20% (v/v). The losses can be anticipated by measuring the ratio of gas to water in the sampling line and then by applying simple partition models considering cosolvency by ethanol. The importance of adequate purging when using porous suction samplers was also shown.