朝鲜半岛与华北地质之对比研究:进展与问题

华北与朝鲜半岛山水相连,传统上称为中朝克拉通或中朝地块。但是中朝的地质对比研究并不深入。作者所在的研究组有幸同时与南北朝鲜半岛双方展开了合作研究达十年以上,内容涉及到前寒武纪基底、古生代沉积盆地、造山带演化、以及中生代岩浆活动。本文是对我们最新研究成果的一个简要总结,并提出一些仍未解决的或具争议的相关地质问题,希望以此能推动中朝地质和东北亚地质的研究。研究结果总结如下:(1)朝鲜半岛可划分为三个陆块,从北到南分别为狼林、京畿和岭南陆块,分别被临津江和沃川构造带分割;(2)三个陆块的前寒武纪基底虽有差别,但本文认为它们是相似的,并可与华北克拉通基底对比;(3)狼林地块的平南古生代盆地以及位于京畿陆块和岭南陆块之间的太白山古生代盆地与华北古生代盆地可对比;(4)临津江和沃川构造带的演化还有待深入研究,它们并不具有陆陆碰撞造山带的特征;(5)在京畿陆块西南部发现了含榴辉岩的三叠纪变质杂岩(洪城杂岩),其变质时代和岩石组合都可以和苏鲁造山带对比,不含超高压变质矿物。这表明苏鲁造山带东延到朝鲜半岛,并在半岛的京畿陆块西南缘登陆。但是洪城杂岩出露有限,没有穿越切割半岛的证据,因此可能沿半岛西部断裂局部分布或在半岛西缘尖灭,其空间分布需进一步研究;(6)中生代岩浆岩在朝鲜半岛广泛存在,三叠纪岩浆作用可能与印支期造山作用有关;侏罗纪和白垩纪的岩浆岩分布与华北在时代和空间分布上有所差别,晚白垩世岩浆岩在朝鲜半岛集中出露于庆尚盆地。本文还在最后一部分,提出了朝鲜半岛以及中朝对比研究中有争议的和尚需进一步研究的关键问题。     

大别-苏鲁造山带在朝鲜半岛可能的构造表现

在晚二叠世—早三叠世期间,中国的华北与扬子板块俯冲碰撞形成了大别-苏鲁造山带。针对这次碰撞作用向东在朝鲜半岛的延伸方式,近些年来不同学者提出了多种模式,但都有其局限性。通过比较临津江带、沃川带与大别造山带之间的构造活动关系,结合已有的变质地质学和地质年代学数据,建立了大别-苏鲁造山带在朝鲜半岛的东延模式。推测自临津江带至沃川带构成了一条较完整的中生代造山带,即大别-苏鲁造山带在朝鲜的东部延伸,原来意义上的“京畿地块”已不复存在。而岭南地块上与华北板块相似的信息可能是造山作用后期伸展拆离作用下来自朝鲜半岛北部的外来构造岩片所致。     

大别山北部榴辉岩的大地构造属性及冷却史

岩石地球化学及同位素年代学研究表明，大别山北部榴辉岩的大部分属印支期扬子俯冲陆壳（下地壳）的一部分；大致沿磨子潭－晓天断裂附近分布的含榴辉岩、大理岩和变质橄榄岩的镁铁－超镁失质岩带可能代表扬子与华北2个大陆板块之间的变质构造混杂岩带，它应接近于扬子与华北2个大陆板块之间的缝合线（镁铁－超镁铁质岩带以北），而五河－水吼剪切带则可能代表扬子腐冲陆壳内部的1条拆离带或滑脱带。冷却史研究表明，大别山北部榴辉岩峰期变质后初期（230－210Ma)仅抬升到下地壳水平，因而未经历降温过程并具有比大别山南部榴辉岩较低的抬升速率，峰期变质后较慢的抬升速率及相应的近于等温或局部升温阶段也许是造成大别山北部榴辉岩与南部超高压带中榴辉岩差异的重要原因之一；同时，也许是研究区榴辉岩很少见有保留早期超高压变质证据的重要原因。     

大别-苏鲁造山带在朝鲜半岛的延伸方式——基于~(40)Ar/~(39)Ar构造年代学的约束

本文结合野外构造变形特征观测,在朝鲜半岛的不同构造单元采集14件糜棱岩和片麻岩样品进行~(40)Ar/~(39)Ar年代学分析,在此基础上通过对比朝鲜半岛与大别造山带不同构造单元的变形特征,探讨大别苏鲁构造带在朝鲜半岛的东延特征,取得如下认识:朝鲜半岛中部的主要构造带在中生代经历了碰撞阶段(~210Ma)、逆冲推覆(200~150Ma)、造山后伸展阶段(140~90Ma)三个主要的构造过程;从变形期次和变形特征看,临津江构造带与大别造山带的北淮阳构造带、苏鲁构造带北部威海地区具有可比性,沃川构造带与南大别构造带有相似之处;在朝鲜半岛,自临津江带至沃川带构成了较完整的中生代碰撞造山带,即大别-苏鲁造山带的东延部分,原认为的"京畿地块"应属造山带的一部分。     

大别山北大别杂岩的大地构造属性

北大别杂岩主要由花岗质片麻岩及斜长角闪岩组成 ,含有不同类型、大小不等的麻粒岩岩块和变质超镁铁质岩块 ,侵入有大量白垩纪花岗岩和辉石 -辉长岩类。其中的花岗质片麻岩、斜长角闪岩具有岛弧环境的岩石地球化学特征 ,代表拼贴于扬子陆块北缘的新元古代古岛弧。北大别杂岩北可与庐镇关群相连 ,南俯于超高压变质岩之下 ,在三叠纪扬子陆块与华北陆块的碰撞过程中 ,曾与超高压变质岩一起俯冲到地幔深度并经受榴辉岩相变质作用 ,然后在折返过程中叠加了麻粒岩相及角闪岩相变质作用 ,是扬子陆块北缘陆壳俯冲基底的一部分     

青岛榴辉岩及胶南群片麻岩的锆石U-Pb 年龄——胶南群中晋宁期岩浆事件的证据

研究表明，苏鲁地体是扬子与华北陆-陆碰撞造山带的一部分（东段）。其主要变质岩系——胶南群，是扬子陆块北缘俯冲陆壳的基底。在已有的文献中，人们均将胶南群划为早、中元古代地体。组成胶南群的主要岩石是长英质片麻岩，在其中间包含有少量斜长角闪岩、大理岩、超镁铁岩和榴辉岩。大量的Sm-Nd 及 40Ar/39Ar 同位素定年已证明了，胶南群在三叠纪时，经历了与华北和扬子陆块碰撞有关的高压或超高压变质作用，原岩的时代缺乏可靠的年龄测定，被认为是早、中元古代岩石。然而最近我们对青岛附近仰口的退变质榴辉岩及胶南群片麻岩的     

胶东莱西地区高压麻粒岩的Sm-Nd同位素年代学

在胶东地区莱西-莱阳-栖霞一带的晚太古代花岗片麻岩中,出露一条长约200多公里,NE向展布的高压基性麻粒岩-超镁铁质岩带。由于这条岩带东邻苏鲁高压-超高压变质带,西接华北克拉通基底的古老变质岩,因此其区域构造归属以及大地构造意义是一个十分重要的问题。本文分析的高压基性麻粒岩样品具有降压退变质结构,退变质矿物组合为麻粒岩相。矿物-全岩Sm-Nd等时线年龄为1752Ma,全岩T(DM)模式年龄为2788Ma,与华北克拉通北缘的高压基性麻粒岩的同位素年龄完全相似。根据高压麻粒岩-超镁铁质岩的围岩片麻岩特征和同位素年龄,可以确定这条出露于华北陆块东缘的岩带是早前寒武纪华北克拉通下地壳岩石,其抬升与华北陆块与扬子陆块的拼合有关。     

陡岭杂岩:秦岭造山带中一个新元古代变质的新太古代岩片

<正>陡岭杂岩位于商丹断裂带南侧的南秦岭构造带中,它是夹持于华北、扬子陆块边界地体中的一个重要构造单元。作为新元古代—古生代浅变质—未变质地层中的一个结晶基底,陡岭杂岩的形成和演化历史可以为秦岭造山带的演化过程提供重要的信息。陡岭杂岩的岩石组合主要为一套中级变质杂岩,由条带状闪长质-花岗质片麻岩(包括角闪斜长片麻岩、黑云斜长片麻岩、斜长片麻岩和二长片麻岩)组成,夹斜长角闪岩、变泥质岩、钙硅酸盐变粒岩和大理     

小秦岭-熊耳山地区岩墙锆石SHRIMP年代学研究——秦岭造山带岩石圈拆沉的证据

对小秦岭-熊耳山地区岩墙锆石开展了SHRIMP Ⅱ U-Pb法年代学研究显示,岩墙岩浆源区的锆石主要表现为华北南缘陆壳基底中的继承性锆石特征.根据地质关系确定的侵位于中生代花岗岩中的岩墙,其锆石年龄定年结果主要表现为1843±10Ma和768±15Ma左右的年龄,多数锆石表现为该区域熊耳群火山活动事件1850Ma左右的年龄,只有很少的锆石颗粒记录了中生代时期128Ma左右的侵位年龄.总体看来,岩墙中锆石较全面地记录了区域构造演化的历史.锆石测年结果反映出华北陆块阜平运动(2500～2400Ma)、华北南缘熊耳群火山喷发事件(1850Ma)、震旦纪构造活动(850～700Ma)、扬子陆块俯冲拼贴于华北南缘的造山事件(约200Ma)和燕山期(约130Ma)的岩墙岩浆侵位活动.岩墙的Sr、Nd、Pb同位素示踪揭示了岩墙岩浆源区与扬子陆块的亲缘性,从而证明新元古代-晚古生代时期扬子陆块向华北陆块南缘俯冲,以及后来秦岭造山带在造山期后华北南缘下地壳基底拆沉的地球动力学过程.岩墙中锆石测年结果多显示为老的继承性锆石的原因可能是中生代时期生长的锆石颗粒较小,而继承性锆石颗粒较大,锆石单矿物分选过程中主要挑选出继承性锆石的缘故.     

大别山北部卢镇关杂岩的Pb同位素特征及大地构造属性

Pb同位素组成研究表明,卢镇关杂岩中花岗片麻岩的^204Pb为1．366％～1．392％(平均为1．381％)、^206Pb／^204Pb为17．083～17．874(平均为17．463)和^204Pb／^204Pb为38．161～38．794(平均为38．438);斜长角闪岩的^204Pb为1．386％～1．412％(平均1．400％),其^206Pb／^204Pb为17．001～17．492(平均17．227)和^208Pb／^204Pb37．390～38．151(平均37．713)。二者的总平均为：^204Pb1．389％,^204Pb／^204Pb17．362,^208Pb／^204Pb38．127。与北部杂岩带和南部超高压变质带比较,卢镇关杂岩明显类似于南部超高压变质带的Ph同位素组成即表现为贫非放射成因铅和富集放射成因铅,表明它们应属于扬子大陆板块的一部分。考虑到北部杂岩带在地壳结构上应位于南部超高压带之下,以及北大别正片麻岩具有中、下地壳性质而南大别花岗片麻岩则具有上地壳特征。因此,卢镇关杂岩也应属于扬子大陆的上地壳,华北与扬子两个陆块之间的缝合线应在卢镇关杂岩以北。但是,由于在北淮阳带中一直未发现榴辉岩或榴辉岩相岩石等高压一超高压岩石以及有关印支期变质作用记录,说明至少卢镇关杂岩在印支期未卷入深俯冲,大别山的印支期俯冲带应位于卢镇关杂岩的南侧即磨子潭晓天断裂附近,大别山印支期深俯冲应属于扬子板块的陆内俯冲。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。