Riverine groundwater discharge estimation in a dynamic river corridor using 222Rn

Groundwater discharge flux into rivers (riverine groundwater discharge or RGD) is essential information for the conservation and management of aquatic ecosystems and resources. One way to estimate area-integrated groundwater discharge into surface water bodies is to measure the concentration of a groundwater tracer within the water body. We assessed groundwater discharge using ²²²Rn, a tracer common in many surface water studies, through field measurements, surface water ²²²Rn mass balance model, and groundwater flow simulation, for the seldom studied but ubiquitous setting of a flooding river corridor. The investigation was conducted at the dam-regulated Lower Colorado River (LCR) in Austin, Texas, USA. We found that ²²²Rn in both the river water and groundwater in the river bank changed synchronously over a 12-hour flood cycle. A ²²²Rn mass balance model allowed for estimation of groundwater discharge into a 500-m long reach of the LCR over the flood. The groundwater discharge ranged between negative values (indicating recharge) to 1570 m³/h; groundwater discharge from groundwater flow simulations corroborated these estimates. However, for the dynamic groundwater discharge estimated by the ²²²Rn box model, assuming whether the groundwater ²²²Rn endmember was constant or dynamic led to notably different results. The resultant groundwater discharge estimates are also highly sensitive to river ²²²Rn values. We thus recommend that when using this approach to accurately characterize dynamic groundwater discharge, the ²²²Rn in near-stream groundwater should be monitored at the same frequency as river ²²²Rn. If this is not possible, the ²²²Rn method can still provide reasonable but approximate groundwater discharge given background information on surface water-groundwater exchange time scales.     

Investigation of submarine groundwater discharge to tidal rivers: Evidence for regional and local scale seepage

Fluxes of submarine groundwater discharge (SGD) were investigated into two tidal rivers on the north and south shore of Long Island, NY, during July 2015. Ground‐based handheld thermal infrared (TIR) imagery, combined with direct push‐point piezometer sampling, documented spatially heterogeneous small‐scale intertidal seepage zones. Pore waters were relatively fresh and enriched in nitrogen (N) within these small‐scale seeps. Pore waters sampled just 20 cm away, outside the boundary of the ground‐based TIR‐located seepage zone, were more saline and lower in N. These ground‐based TIR‐identified seeps geochemically represented the terrestrial fresh groundwater endmember, whereas N in pore waters sampled outside of the TIR‐identified seeps was derived from the remineralization of organic matter introduced into the sediment by tidal seawater infiltration. A ²²²Rn (radon‐222) time‐series was used to quantify fresh SGD‐associated N fluxes using the N endmembers sampled from the ground‐based TIR pore water profiles. N fluxes were up‐scaled to groundwater seepage zones identified from high‐resolution airborne TIR imagery using the two‐dimensional size of the airborne TIR surface water anomalies, relative to the N flux from the time‐series sampling location. Results suggest that the N load from the north‐shore tidal river to Long Island Sound is underrepresented by at least 1.6–3.6%, whereas the N load from SGD to a south‐shore tidal river may be up to 9% higher than previous estimates. These results demonstrate the importance of SGD in supplying nutrients to the lower reaches of tidal rivers and suggest that N loads in other tidal river environments may be underestimated if SGD is not accounted for.     

226Ra and222Rn contents of Galapagos Rift hydrothermal waters —the importance of low-temperature interactions with crustal rocks

Hydrothermal waters collected by “Alvin” from the Galapagos Spreading Center are enriched in²²²Rn by factors of 50–200 over bottom waters. The²²⁶Ra in the same samples, however, is enriched by less than a factor of four over bottom waters. Enrichments of²²²Rn result primarily from α-recoil from rock surfaces while²²⁶Ra enrichments are dominantly produced by high-temperature alteration of cooling ridge volcanics. The abundances of both nuclides exhibit positive correlations with temperature. The data extrapolate to bottom water temperatures and compositions, demonstrating the importance of seawater mixing. Different vents, however, have different mixing lines, and vents with high²²²Rn have low²²⁶Ra. We propose these patterns result from variations in the extent of low-temperature crustal interaction with the hydrothermal fluids. Low-temperature crustal waters can maintain high steady state²²²Rn contents due to the α-recoil additions to the fluids. The²²⁶Ra, however, is strongly adsorbed at low-temperatures resulting in low concentrations of this nuclide in low-temperature crustal waters. Thus, physical mixing of a crustal water component with hydrothermal waters or variable crustal path lengths of the hydrothermal fluids can account for the variable mixing lines and²²²Rn/²²⁶Ra values of the hot springs.The²²²Rn/²²⁶Ra value appears to be a sensitive indicator of low-temperature crustal interaction. Values > 100 have experienced extensive crustal interaction and are indicative of diffuse hydrothermal flow. Values between 1 and 10 are indicative of primary hydrothermal fluids which have not experienced significant interaction with the crust. Values of²²²Rn/²²⁶Ra between 10³ and 10⁴ are indicative of interaction of the hydrothermal fluids with sediments. Such values are observed in water samples from the Galapagos hydrothermal mounds.     

Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn

Coastal groundwater discharge (CGD) plays an important role in coastal hydrogeological systems as they are a water resource that needs to be managed, particularly in wetland areas. Despite its importance, identifying and monitoring CGD often presents physical and logistical constraints, restraining the application of more traditional submarine groundwater discharge surveying techniques. Here we investigate the capability of electrical resistivity imaging (ERI) in the Peníscola wetland (Mediterranean coast, Spain). ERI surveying made it possible to identify and delineate an ascending regional groundwater flow of thermal and Ra‐enriched groundwater converging with local flows and seawater intrusion. The continuous inputs of Ra‐rich groundwater have induced high activities of Ra isotopes and ²²²Rn into the marsh area, becoming among the highest previously reported in wetlands and coastal lagoons. Geoelectrical imaging enabled inferring focused upward discharging areas, leaking from the aquifer roof through a confining unit and culminating as spring pools nourishing the wetland system. Forward modelling over idealized subsurface configurations, borehole datasets, potentiometric records from standpipe piezometers, petrophysical analysis, and four natural and independent tracers (²²⁴Ra, ²²²Rn, temperature and salinity) permitted assessing the geoelectrical model and a derived hydrogeological pattern. The research highlights the potential of ERI to improve hydrogeological characterization of subsurface processes in complex contexts, with different converging flows. Additionally, a hydrogeological conceptual model for a groundwater‐fed coastal wetland was proposed, based on the integration of surveying datasets. Copyright © 2013 John Wiley & Sons, Ltd.     

A multi‐tracer approach to quantifying groundwater inflows to an upland river; assessing the influence of variable groundwater chemistry

Understanding the behaviour and variability of environmental tracers is important for their use in estimating groundwater discharge to rivers. This study utilizes a multi‐tracer approach to quantify groundwater discharge into a 27 km upland reach of the Gellibrand River in southwest Victoria, Australia. Ten sampling campaigns were conducted between March 2011 and June 2012, and the distribution of ²²²Rn activities, Cl and ³H concentrations imply the river receives substantial groundwater inflows. Mass balances based on ²²²Rn, Cl and ³H yield estimates of groundwater inflows that agree to within ± 12%, with cumulative inflows in individual campaigns ranging from 24 346 to 88 467 m³/day along the studied river section. Groundwater discharge accounts for between 10 and 50% of river flow dependent on the time of year, with a high proportion (>40 %) of groundwater sustaining summer flows. Groundwater inflow is largely governed by regional groundwater flowpaths; between 50 and 90% of total groundwater inflows occur along a narrow 5–10 km section where the river intersects the Eastern View Formation, a major regional aquifer. Groundwater ²²²Rn activities over the 16 month period were spatially heterogeneous across the catchment, ranging between 2000 Bq/m³ and 16 175 Bq/m³. Although groundwater ²²²Rn activities display temporal variation, spatial variation in groundwater ²²²Rn is a key control on ²²²Rn mass balances in river catchments where groundwater and river ²²²Rn activities are within an order of magnitude of each other. Calculated groundwater discharges vary from 8.4 to 15 m³/m/day when groundwater ²²²Rn activities are varied by ± 1 σ. Copyright © 2013 John Wiley & Sons, Ltd.     

Large seasonal changes in the recharge of seawater in a subterranean estuary revealed by a radon tracer

Activities of radon (²²²Rn) in groundwater were continuously monitored in a saline aquifer from September 2010 to July 2011. The activities of ²²²Rn ranged from 200 to 4300 Bq m^?3, with a large seasonal variation. Because the activity of ²²²Rn in seawater is low, ²²²Rn in saline groundwater must be produced in the aquifer from radium (²²⁶Ra) in rocks and sediments. The ²²²Rn activities were higher in the warm‐dry seasons (September–November 2010 and April–May 2011) when the saline aquifer was stable. In contrast, the lowest ²²²Rn activities were observed in the cold‐dry season (December 2010 and January–March 2011), because of the effective exchange between groundwater and seawater. In addition, sudden decreases of ²²²Rn activities coincided with episodic drops in groundwater temperatures. These results reveal that lower seawater temperature in winter may result in density‐driven seawater intrusion. During the wet season (June–July 2011), ²²²Rn activities were more clearly affected by semi‐monthly and diurnal tidal pumping, showing higher ²²²Rn activities during low and spring tides. Such a tidal effect was not clearly observed during the warm‐dry and cold‐dry seasons. This result implies that the residence time of SGD in coastal zones is significantly affected by seasonal changes in driving forces such as tidal pumping and seawater intrusion. Copyright © 2016 John Wiley & Sons, Ltd.     

Explicit Modeling of Radon-222 in HydroGeoSphere During Steady State and Dynamic Transient Storage

Transient storage zones (TSZs) are located at the interface of rivers and their abutting aquifers and play an important role in hydrological and biogeochemical functioning of rivers. The natural radioactive tracer ²²²Rn is a particularly well-suited tracer for studying TSZ water exchange and age. Although ²²²Rn measurement techniques have developed rapidly, there has been less progress in modeling ²²²Rn activities. Here, we combine field measurements with the numerical model HydroGeoSphere (HGS) to simulate ²²²Rn emanation, decay and transport during steady state (riffle-pool sequence) and transient (bank storage) conditions. Comparing the HGS mean water ages with the conventional ²²²Rn apparent ages during steady state showed a systemic underestimation of apparent age with increasing dispersion and especially where large concentration gradients exist within the subsurface. A large underestimation of apparent water age was also observed at the advective front during bank storage where regional high ²²²Rn groundwater mixes with newly infiltrated surface water. The explicit modeling of radiogenic tracers such as ²²²Rn offers a physical interpretation of this data as well as a useful way to test simplified apparent age models.     

Mapping groundwater discharge to a coastal lagoon using combined spatial airborne thermal imaging,radon (222Rn) and multiple physicochemical variables

Coastal lagoons are significant wetland environments found on coastlines throughout the world. Groundwater seepage may be a key component of lagoon water balances, though only a few studies have investigated large (>100 km²) coastal lagoons. In this study, we combined airborne thermal infrared imagery with continuous measurements of radon (²²²Rn—a natural groundwater tracer), conductivity, water temperature and dissolved oxygen to map groundwater seepage to a large coastal lagoon in New Zealand. We found evidence of seepage along the margins of the lagoon but not away from the margins. Our findings confirmed previously known seepage zones and identified new potential locations of groundwater inflow. Both point source and diffuse seepage occurred on the western and northwestern margins of the lagoon and parallel to the barrier between the lagoon and sea. These observations imply geologic controls on seepage. The combination of remote sensing and in-situ radon measurements allowed us to effectively map groundwater discharge areas across the entire lagoon. Combined, broad-scale qualitative methods built confidence in our interpretation of groundwater discharge locations in a large, dynamic coastal lagoon.     

Combining isotopic tracers (222Rn and δ13C) for improved modelling of groundwater discharge to small rivers

In regions where aquifers sustain rivers, the location and quantification of groundwater discharge to surface water are important to prevent pollution hazards, to quantify and predict low flows and to manage water supplies. ²²²Rn is commonly used to determine groundwater discharge to rivers. However, using this isotopic tracer is challenging because of the high diffusion capacity of ²²²Rn in open water. This study illustrates how a combination of isotopic tracers can contribute to an enhanced understanding of groundwater discharge patterns in small rivers. The aim of this paper is to combine ²²²Rn and δ¹³C_DIC to better constrain the physical parameters related to the degassing process of these tracers in rivers. The Hallue River (northern France) was targeted for this study because it is sustained almost exclusively by a fractured chalk aquifer. The isotopes ²²²Rn, δ¹³C_DIC, δ²H and δ¹⁸O were analysed along with other natural geochemical tracers. A mass balance model was used to simulate ²²²Rn and δ¹³C_DIC. The results of δ²H and δ¹⁸O analyses prove that evaporation did not occur in the river. The calibration of a numerical model to reproduce ²²²Rn and δ¹³C_DIC provides a best‐fit diffusive layer thickness of 3.21 × 10^?5 m. This approach is particularly useful for small rivers flowing over carbonate aquifers with high groundwater DIC where the evolution of river DIC reflects the competing processes of groundwater inflow and CO₂ degassing. This approach provides a means to evaluate groundwater discharge in small ungauged rivers. Copyright © 2014 John Wiley & Sons, Ltd.     

Tracing anthropogenically driven groundwater discharge into a coastal lagoon from southern Brazil

We investigated the distribution of naturally occurring geochemical tracers (²²²Rn, ²²³Ra, ²²⁴Ra, ²²⁶Ra, CH₄, δ¹⁸O, and δ²H) in the water column and adjacent groundwater of Mangueira Lagoon as proxies of groundwater discharge. Mangueira Lagoon is a large (90 km long), shallow (4–5 m deep), fresh, and non-tidal coastal lagoon in southern Brazil surrounded by extensively irrigated rice plantations and numerous irrigation canals. We hypothesized that the annual, intense irrigation for rice agriculture creates extreme conditions that seasonally change groundwater discharge patterns in the adjacent lagoon. We further supposed that dredging of irrigation canals alters groundwater fluxes.

While the activities of ²²²Rn in shallow groundwater were 2–3 orders of magnitude higher than in surface water, CH₄ and radium isotopes were only 1 order of magnitude higher. Therefore, ²²²Rn appears to be the preferred groundwater tracer in this system. Radon concentrations and conductivities were dramatically higher near the pump house of rice irrigation canals, consistent with a groundwater source. Modeling of radon inventories accounting for total inputs (groundwater advection, diffusion from sediments, and decay of ²²⁶Ra) and losses (atmospheric evasion, horizontal mixing and decay) indicated that groundwater advection rates in the irrigation canals (25 cm/d) are over 2 orders of magnitude higher than along the shoreline (0.1 cm/d). Nearly 75% of the total area of the canals is found in the southern half of the lagoon, where groundwater inputs seem to be higher as also indicated by methane and stable isotope trends. In spite of the relatively small area of the canals, we estimate that they contribute nearly 70% of the total (57,000 m³/d) groundwater input into the entire Mangueira Lagoon. We suggest that the dredging of these canals cut through aquitards which previously restricted upward advection from the underlying permeable strata. The irrigation channels may therefore represent an important but previously overlooked source of nutrients and other dissolved chemicals derived from agricultural practices into the lagoon.     

Geothermal springs of the West Florida continental shelf: Evidence for dolomitization and radionuclide enrichment

On the sea bed of the West Florida continental shelf about 45 km SSW of Ft. Myers, Florida, an 85-km² area has been discovered in which six thermal springs discharge warm, chemically altered seawater from vents and seepage zones. The spring water apparently originates in the subsurface ocean around the Florida Platform and penetrates the highly porous strata of the platform about 500–1000 meters below sea level. It percolates toward the interior of the platform and is geothermally heated to about 40°C en route. Then it rises along more vertical flow channels and is discharged in warm submarine springs.Beneath the platform, several chemical processes alter the percolating seawater. One process seems to be a secondary dolomitization of the limestone of the platform because, in the discharging seawater, magnesium is lower by 2.7 mmole/kg and calcium higher by 3.6 mmole/kg than in normal seawater with the same chlorinity. Other reactions within the sediments of the platform enrich the spring effluents 1000-fold in²²⁶Ra, 10,000-fold in²²²Rn, and 90-fold in²²⁸Ra compared to the seawater surrounding the platform. Thus, the springs may be important sources of radionuclides for the Gulf of Mexico. The percolating seawater also loses all of its oxygen and nitrate to reduction processes, loses most of its phosphate and 40% of its²³⁸U, and roughly quadruples its silica content.Coastal carbonate platforms are fairly common geological features. Thus, processes like those beneath the West Florida Shelf may function on a world-wide basis to play an important role in the diagenesis of carbonate sediments.     

Using new mass balance methods to estimate gross surface water and groundwater exchange with naturally occurring tracer 222Rn in data poor regions: a case study in northwest China

Given that the concentration of ²²²Rn in groundwater is much higher than that in surface water and that its radioactive half‐life (3.83 d) is short, ²²²Rn is an effective tracer of groundwater–surface water interactions. In this study, a new mass balance method is presented, which can be used to estimate specific groundwater–surface water interactions within a river reach. Three possible situations of interaction between groundwater and surface water are considered, and equations based on the mass conservation of ²²²Rn are formulated for judging specific groundwater–surface water interaction processes and for calculating water flux. A case study was conducted for the Nalenggele River, Northwest China, to demonstrate the usefulness of this method. Samples of river water and groundwater containing ²²²Rn were collected from the study area to estimate the interactions between groundwater and surface water. The amount of water exchanged during these interactions was estimated and the results show that transformations between groundwater and surface water are frequent along the stream. The ²²²Rn mass balance method is highly sensitive for studying such interactions, even in areas for which conventional hydrologic data are sparse. Copyright © 2014 John Wiley & Sons, Ltd.     

Submarine groundwater discharge into the coast revealed by water chemistry of man-made undersea liquefied petroleum gas cavern

The occurrence of submarine groundwater discharge (SGD) as well as its supply of many nutrients and metals to coastal seawaters is now generally known. However, previous studies have focused on the chemical and radiological analysis of groundwater, surface seawater, shallow marine sediments and their pore waters, as well as the measurement of upward flow through the marine sediments, as end members of the discharge process. In this study, chemical and isotopic analysis results of marine subsurface waters are reported. These were obtained from deep boreholes of an undersea liquefied petroleum gas (LPG) storage cavern, located about 8 km off the western coast of Korea. The cavern is about 130–150 m below the sea bottom, which is covered by a 4.8–19.5 m silty clay stratum. An isotopic composition (δ²H and δ¹⁸O) of the marine subsurface waters falls on a mixing line between terrestrial groundwater and seawater. Vertical EC profiling at the cavern boreholes revealed the existence of a fresh water zone. An increase in the contents of ferrous iron and manganese and a decrease in levels of nitrate, bicarbonate and cavern seepage were recorded in August 2006, indicating a decreased submarine groundwater flux originating from land, mainly caused by an elevated cavern gas pressure. It is suggested in this study that the main source of fresh waters in the man-made undersea cavern is the submarine groundwater discharge mainly originating from the land.     

226Ra behavior in the Pee Dee River-Winyah Bay estuary

Concentrations of dissolved²²⁶Ra in Winyah Bay, South Carolina, and in the adjacent Atlantic Ocean are augmented by the desorption of radium from sediments in the low-salinity area of the estuary and diffusion from bottom sediments. Desorption of²²⁶Ra is reflected by lower concentrations in suspended sediments from higher-salinity regions of the estuary. Bottom sediments from the high-salinity region have lower²²⁶Ra/²³⁰Th activity ratios than those from the low-salinity end.The shape of the dissolved²²⁶Ra vs. salinity profile is influenced by the river discharge. During average-discharge conditions, desorption of²²⁶Ra from suspended and bottom sediments increases the dissolved²²⁶Ra concentrations by a factor of 3.5 as the water passes through Winyah Bay. High river discharge produces an initial increase of dissolved²²⁶Ra by a factor of 2 to 3 and apparently reflects only desorption from suspended sediments. By driving the salt wedge down the estuary and reducing the zone of contact of salt water with bottom sediments, the high-flow conditions sharply reduce the flux of²²⁶Ra from bottom sediments.     

222Rn as Natural Tracer for LNAPL Recovery in a Crude Oil‐Contaminated Aquifer

The objective of this study was to investigate whether ²²²Rn in groundwater can be used as a tracer for light non‐aqueous phase liquid (LNAPL) quantification at a field site treated by dual‐phase LNAPL removal. After the break of a pipeline, 5 ha of soil in the nature reserve Coussouls de Crau in southern France was contaminated by 5100 m³ of crude oil. Part of this oil seeped into the underlying gravel aquifer and formed a floating oil body of about 3.9 ha. The remediation consists of plume management by hydraulic groundwater barriers and LNAPL extraction in the source zone. ²²²Rn measurements were performed in 21 wells in and outside the source zone during 15 months. In uncontaminated groundwater, the radon activity was relatively constant and remained always >11 Bq/L. The variability of radon activity measurements in wells affected by the pump‐and‐skim system was consistent with the measurements in wells that were not impacted by the system. The mean activities in wells in the source zone were, in general, significantly lower than in wells upgradient of the source zone, owing to partitioning of ²²²Rn into the oil phase. The lowest activities were found in zones with high non‐aqueous phase liquid (NAPL) recovery. LNAPL saturations around each recovery well were furthermore calculated during a period of high groundwater level, using a laboratory‐determined crude oil–water partitioning coefficient of 38.5 ± 2.9. This yielded an estimated volume of residual crude oil of 309 ± 93 m³ below the capillary fringe. We find that ²²²Rn is a useful and cheap groundwater tracer for finding zones of good LNAPL recovery in an aquifer treated by dual‐phase LNAPL removal, but that quantification of NAPL saturation using Rn is highly uncertain.     

Correcting for potential 222Rn loss in 210Pb dating of sediments from the South Adriatic Pit

Measurement of ²²⁶Ra activity concentrations is often used to estimate supported levels of ²¹⁰Pb for purposes of geochronology. However, the implicit assumption that supported ²¹⁰Pb and ²²⁶Ra are in secular radioactive equilibrium may not always be true because of the migration of an intermediate product, gaseous ²²²Rn. As a consequence, supported ²¹⁰Pb activity concentration might be lower than the measured ²²⁶Ra value, which was the case in a core collected from the South Adriatic Pit. Here we present a new approach to improve the determination of supported ²¹⁰Pb, which is based on correction of ²²⁶Ra activity concentrations using the average (²¹⁰Pb/²²⁶Ra) activity ratio in deeper sediment layers. Using this approach, sedimentation rates for the South Adriatic Pit with a constant rate of supply model and a constant initial concentration model were 0.054 g/cm²/a and 0.070 g/cm²/a, respectively.     

Natural 222Rn as a tracer of mixing and volatilization in a shallow aquifer during a CO2 injection experiment

This study aims to evaluate the application of ²²²Rn in groundwater as a tracer for monitoring CO₂ plume migration in a shallow groundwater system, which is important to detect potential CO₂ leakage in the carbon capture and storage (CCS) project. For this research, an artificial CO₂-infused water injection experiment was performed in a shallow aquifer by monitoring hydrogeochemical parameters, including ²²²Rn. Radon in groundwater can be a useful tracer because of its sensitivity to sudden changes in subsurface environment. To monitor the CO₂ plume migration, the data were analysed based on (a) the influence of mixing processes on the distribution of ²²²Rn induced by the artificial injection experiment and (b) the influence of a carrier gas role by CO₂ on the variation of ²²²Rn. The spatio-temporal distributions of radon concentrations were successfully explained in association with horizontal and vertical mixing processes by the CO₂-infused water injection. Additionally, the mixing ratios of each monitoring well were calculated, quantitatively confirming the influence of these mixing processes on the distribution of radon concentrations. Moreover, one monitoring well showed a high positive relationship between ²²²Rn and Total dissolved inorganic carbon (TIC) by the carrier gas effect of CO₂ through volatilization from the CO₂ plume. It indicated the applicability of ²²²Rn as a sensitive tracer to directly monitor CO₂ leakage. When with a little effect of carrier gas, natural ²²²Rn in groundwater can be used to compute mixing ratio of CO₂-infused water indicative of CO₂ migration pathways. CO₂ carrier gas effect can possibly increase ²²²Rn concentration in groundwater and, if fully verified with more field tests, will pose a great potential to be used as a natural tracer for CO₂.     

Groundwater–surface water connectivity in a chain-of-ponds semiarid river

Semiarid rivers are often characterized by chains of small pools connected by riffles and wet meadows. The pools can be maintained by wet season surface runoff, groundwater discharge, or some combination thereof. Using synoptic surveys for several environmental tracers (δD and δ¹⁸O of H₂O, specific electrical conductance at 25°C [EC], chloride and ²²²Rn), we evaluated the groundwater—surface water connectivity of the Light River (South Australia) along an 8 km section in the vicinity of a proposed mining development. In all three surveys (representing spring, summer and winter conditions), the pools were maintained by regional groundwater discharge based on an elevated surface water EC (9–12 dS m⁻¹) similar to regional groundwater, elevated radon-222 activities (0.09–3.0 Bq L⁻¹) and low rainfall. Most pools were perennial, either because they directly received groundwater discharge or, indirectly, had an inflow originating from upstream groundwater-fed pools. The elevated salinity of regional groundwater is a key factor for the maintenance of perennial pools in the Light River because the potential for baseflow depletion by groundwater pumping is more limited.     

Chemical reaction rates and entrainment within the Endeavour Ridge hydrothermal plume

The aging of the hydrothermal plume over the Endeavour segment of the Juan de Fuca Ridge was estimated by measuring the²²²Rn³He ratio in the plume as it dispersed. Despite uncertainties in the source function of hydrothermal input, it wa determined that the relative sequence of removal from the plume isH₂ > Δc >²²²Rn>CH₄ Mn, whereΔc is a measure of particle concentration and the mean life of²²²Rn is 5.5 days. H₂ is removed from the plume within hours of input while Mn is not removed within the two-week timescale of the radon-helium clock.Entrainment of bottom water within the buoyant plume may introduce additional chemical signatures into the spreading effluent layer over that which would be introduced by hydrothermal discharge alone. This is particularly significant for those chemical species which are not greatly enriched in the vent fluids relative to bottom water concentration and which display a nutrient-like profile in the deep ocean. Thus we found that significant fractions of the Si and²²⁶Ra anomalies in the plume were not of hydrothermal origin but were derived from entrained bottom water which has a higher concentration of these elements than ambient water at plume height.     

230Th,226Ra and222Rn in abyssal sediments

A model that predicts the flux of²²²Rn out of deep-sea sediment is presented. The radon is ultimately generated by²³⁰Th which is stripped from the overlying water into the sediment. Data from many authors are compared with the model predictions. It is shown that the continental contribution of ionium is not significant, and that at low sedimentation rates, biological mixing and erosional processes strongly affect the surface concentration of the ionium. Two cores from areas of slow sediment accumulation, one from a manganese nodule region of the central Pacific and one from the Rio Grande Rise in the Atlantic were analyzed at closely spaced intervals for²³⁰Th,²²⁶Ra, and²¹⁰Pb. The Pacific core displayed evidence of biological mixing down to 12 cm and had a sedimentation rate of only 0.04 cm/kyr. The Atlantic core seemed to be mixed to 8 cm and had a sedimentation rate of 0.07 cm/kyr. Both cores had less total excess²³⁰Th than predicted.Radium sediment profiles are generated from the²³⁰Th model. Adsorbed, dissolved, and solid-phase radium is considered. According to the model, diffusional losses of radium are especially important at low sedimentation rates. Any particulate, or excess radium input is ignored in this model. The model fits the two analyzed cores if the fraction of total radium available for adsorption-desorption is about 0.5–0.7, and ifK, the distribution coefficient, is about 1000.Finally, the flux of radon out of the sediments is derived from the model-generated radium profiles. It is shown that the resulting standing crop of²²²Rn in the overlying water may be considered as an added constraint in budgeting²³⁰Th and²²⁶Ra in deep-sea sediments.