On different time scales of suspended matter dynamics in the Weser estuary

Long-term observations in the Weser estuary (Germany) between 1983 and 1997 provide insight into the response of the estuarine turbidity maximum (ETM) under a wide range of conditions. In this estuary the turbidity zone is closely tied to the mixing zone, and the positions of the ETM and the mixing zone vary with runoff. The intratidal suspended particulate matter (SPM) concentrations vary due to deposition during slack water periods, subsequent resubsequent and depletion of temporarily-formed and spatially-limited deposits during the following ebb or flood, and subsequent transport by tidal currents. The corresponding time history of SPM concentrations is remarkably constant over the years. Spring tide SPM concentrations can be twice the neap tide concentrations or even larger. A hysteresis in SPM levels between the falling and rising spring-neap cycle is attributed to enhanced resuspension by the stronger spring tidal currents. There is evidence that the ETM is pushed up-estuary during times of higher mean water levels due to storms. During river floods the ETM is flushed towards the outer estuary. If river floods and their decreasing parts occur during times of relatively high mean water levels, the ETM seems to be maintained in the outer estuary. If river floods and their decreasing parts occur during times of relatively low mean water levels, the ETM seems to loose inventory and may need up to half a year of non-event conditions to gain its former magnitude. During this time seasonal effects may be involved. Analyses of storm events and river floods have revealed that the conditions in the seaward boundary region play an equally important role for the SPM dynamics as those arising from the river.     

Transport and retention of suspended particulate matter and bacteria in the Humber-Ouse Estuary, United Kingdom, and their relationship to hypoxia and anoxia

Data are presented on dissolved oxygen (DO) concentrations and their relationship to salinity, suspended particulate matter (SPM), concentrations, and the turbidity maximum in the Humber-Ouse Estuary, United Kingdom, during summer 1995. Measurements in the upper Humber during March 1995 showed DO in the range 82% to 87% of saturation. Suspended particulate matter concentrations were <5000 mg l^?1 and salinity was in the range 0.5 to 12. In contrast, a pronounced DO sag occurred in the upper reaches of the Ouse during medium and spring tide, summer conditions. The DO minimum was essentially an anoxic level and was associated with the location of the turbidity maximum, at salinities between about 0.4 and 1.5. SPM concentrations at 1 m beneath the surface reached 25,000 mg l^?1 in the turbidity maximum, between about 20 km and 40 km from the tidal limit. Suspended particulate matter concentrations were much lower at neap tides, although dense suspensions of SPM (>60,000 mg l^?1) occurred within 1 m of the bed in the turbidity maximum region. A spring-neap record showed a dramatic and tidally controlled decrease in DO at very low salinities as the tides progressed from neaps to springs. An anchor station located down-channel of the turbidity maximum showed that about 95% of the variance in DO, which varied from 28% at low-water slack to 67% at high-water slack, could be explained in terms of salinity variation. At the up-channel margins of the turbidity maximum, DO increased from zero (anoxia) near high water to 60% near low water slack, in contrast to the behavior down-channel of the turbidity maximum. About 82% of the variance in DO could be explained in terms of salinity variations alone. Only 43% of the DO variance could be explained in terms of SPM alone. Up-channel of the turbidity maximum, SPM concentrations were relatively low (<3000 mg l^?1) and DO levels varied from 48% of saturation near high water to 83% near low water slack. About 76% of the variance in DO could be explained in terms of salinity variations alone. Within the turbidity maximum region, DO varied from <2% saturation on the early flood and late ebb and maximized around 7% at high water slack. About 63% of the variance in DO could be explained in terms of salinity variation alone. This increased to 70% when suspended particulate matter was taken into account. Only 29% of the DO variance could be explained in terms of suspended particulate matter alone. Because bacteria were likely to have been the cause of the observed reduction in DO, the numbers of bacteria, both free-living and attached to particles, were measured in the turbidity maximum region. Numbers of free-living bacteria were low and most of the bacteria were attached to sediment particles. There was a linear correlation between total bacterial number and suspended particulate matter concentration, suggesting that the strong DO demand was exerted locally as a result of bacterial activity associated with increased suspended particulate matter concentrations. An order of magnitude analysis of DO consumption within the Ouse’s turbidity maximum, based on the premise that DO depletion was directly related to suspended particulate matter concentrations and that DO addition was due to reaeration, indicates that complete deoxygenation could have occurred with an oxygen depletion rate of ～0.01 mg DO h^?1/g suspended particulate matter during the residence time of waters within the turbidity maximum (～7 d). This rate was sufficiently fast that anoxic to aerobic conditions were able to develop a spring-neap periodicity within the turbidity maximum, but too slow to generate substantial intratidal fluctuations in DO. This is in accordance with the observations, which show that relatively little of the intratidal variance in DO could be explained in terms of suspended particulate matter fluctuations, whereas most of the variance could be explained in terms of salinity, which behaved as a surrogate measure for the proximity of the turbidity maximum.     

Remotely sensed observations of the turbidity maximum in the highly turbid Humber Estuary, UK

The Humber Estuary, UK, divides into the Ouse and Trent estuaries at the so-called Apex within its upper reaches. Remotely sensed Compact Airborne Spectrographic Imager (CASI) images and boat measurements were used to observe a strong turbidity maximum in the upper Humber and Ouse during a spring tide in November 1995. Surface suspended particulate matter (SPM) concentrations during the late ebb, as estimated from the CASI data, increased from approximately 6 to 13 g I⁻¹ moving up-estuary into the Ouse. Greater SPM concentrations (∼10 g I⁻¹) were evident in the deeper channels of the Ouse, compared with shallower areas, possibly due to faster ebb currents there and differential down-estuary advection of the turbidity maximum. Ribbons, or streaks, of lower SPM and slightly cooler waters were observed. It appears that slightly cooler and lower turbidity waters from the confluent Trent estuary remained fairly distinct for distances of approximately 2 km down-stream of its confluence with the upper Humber and Ouse. These waters eventually broke into ribbon-like or streak-like structures within the higher SPM-laden and slightly warmer waters of the Humber. They were discernible for more than 5 km down-estuary of the confluence of the Humber, Ouse, and Trent. Boat measurements showed that the turbidity maximum occurred over a fairly restricted region of the upper Humber, between about 20 to 50 km from the tidal limit at high water. The turbidity maximum’s sediment load was largely suspended in the water column during stronger currents. SPM rapidly settled close to the bed during high water and low water slack periods. At these times, SPM concentrations in a thin, near-bed layer were >60 g I⁻¹ in the turbidity maximum region of the Ouse and >30 g 1⁻¹ in the upper Humber (where channel volumes were much greater). SPM within the turbidity maximum comprised very fine-grained material and its low organic content demonstrated that the SPM was essentially mineral, clastic sediment derived originally from erosion and decay of crustal rocks.     

Particulate trace metal and major element distributions over consecutive tidal cycles in Port Jackson Estuary,Australia

Particulate trace metal (Cu, Cr, Ni, Pb and Zn) and major element (Fe, Mn and Al) concentrations have been determined following intensive sampling over two consecutive spring tidal cycles in the 'turbidity maximum zone' (TMZ) of the Port Jackson estuary, Australia. Salinity, temperature, pH, dissolved oxygen, suspended particulate matter (SPM) and chlorophyll a were also determined. A three-factor analysis of variance was used to test temporal variability in concentrations of particulate trace metals and major elements as a result of tidal oscillation. Estuarine master variables, such as temperature and pH, varied within a narrow range; nevertheless, the tidal signal was clear for surface and bottom waters. In surface water, no variance was detected in SPM concentrations between consecutive tidal cycles or between tidal stages (i.e. flood, ebb and slack water). In bottom water, however, SPM concentrations were significantly higher (PА.05) at flood tide than at slack high water and ebb tide. Concentrations of particulate trace metals and major elements in surface water do not display significant variability between tidal cycles or stages. Nevertheless, differences within each tidal stage were significant (PА.05) for all elements. In bottom water, only particulate Fe and Al exhibited significant differences (PА.05) between tidal cycles, whereas particulate Ni was the only trace element that presented significant differences (PА.05) between tidal stages, following the distribution of SPM, with highest concentrations at flood tide. Among the metals studied, significant variation was found at all three temporal scales examined (i.e. from hours to consecutive tidal cycles), although the patterns of variation were different for each metal. The semi-diurnal fluctuation of SPM and particulate trace metal concentrations during spring tides is interpreted as a resuspension-deposition cycle caused by cyclical oscillations of bottom currents. The results are discussed in the context of the implications of tidal cycle influence on the geochemistry and cycling of particulate trace metals in the Port Jackson estuary.     

Dynamics of the turbidity maximum zone in a micro-tidal estuary: Hawkesbury River, Australia

Bed sediment, velocity and turbidity data are presented from a large (145 km long), generally well-mixed, micro-tidal estuary in south-eastern Australia. The percentage of mud in the bed sediments reaches a maximum in a relatively narrow zone centred ≈30–40 km from the estuary mouth. Regular tidal resuspension of these bed sediments produces a turbidity maximum (TM) zone in the same location. The maximum recorded depth-averaged turbidity was 90 FTU and the maximum near-bed turbidity was 228 FTU. These values correspond to suspended particulate matter (SPM) concentrations of roughly 86 and 219 mg l^?1, respectively. Neither of the two existing theories that describe the development and location of the TM zone in the extensively studied meso- and macro-tidal estuaries of northern Europe (namely, gravitational circulation and tidal asymmetry) provide a complete explanation for the location of the TM zone in the Hawkesbury River. Two important factors distinguish the Hawkesbury from these other estuaries: (1) the fresh water discharge rate and supply of sediment to the estuary head is very low for most of the time, and (2) suspension concentrations derived from tidal stirring of the bed sediments are comparatively low. The first factor means that sediment delivery to the estuary is largely restricted to short-lived, large-magnitude, fluvial flood events. During these events the estuary becomes partially mixed and it is hypothesized that the resulting gravitational circulation focuses mud deposition at the flood-determined salt intrusion limit (some 35 km seaward of the typical salt intrusion limit). The second factor means that easily entrained high concentration suspensions (or fluid muds), typical of meso- and macro-tidal estuaries, are absent. Maintenance of the TM zone during low-flow periods is due to an erosion-lag process, together with a local divergence in tidal velocity residuals, which prevent the TM zone from becoming diffused along the estuary axis.     

Fine sediment transport and accumulations at the mouth of the Seine estuary (France)

A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year.     

Sediment transport and trapping in the Hudson River estuary

The Hudson River estuary has a pronounced turbidity maximum zone, in which rapid, short-term deposition of sediment occurs during and following the spring freshet. Water-column measurements of currents and suspended sediment were performed during the spring of 1999 to determine the rate and mechanisms of sediment transport and trapping in the estuary. The net convergence of sediment in the lower estuary was approximately 300,000 tons, consistent with an estimate based on sediment cores. The major input of sediment from the watershed occurred during the spring freshet, as expected. Unexpected, however, was that an even larger quantity of sediment was transported landward into the estuary during the 3-mo observation period. The landward movement was largely accomplished by tidal pumping (i.e., the correlation between concentration and velocity at tidal frequencies) during spring tides, when the concentrations were 5 to 10 times higher than during neap tides. The landward flux is not consistent with the long-term sediment budget, which requires a seaward flux at the mouth to account for the excess input from the watershed relative to net accumulation. The anomalous, landward transport in 1999 occurred in part because the freshet was relatively weak, and the freshet occurred during neapetides when sediment resuspension was minimal. An extreme freshet occurred during 1998, which may have provided a repository of sediment just seaward of the mouth that re-entered the estuary in 1999. The amplitude of the spring freshet and its timing with respect to the spring-neap cycle cause large interannual variations in estuarine sediment flux. These variations can result in the remobilization of previously deposited sediment, the mass of which may exceed the annual inputs from the watershed.     

On the advection of turdidity in the saint lawrence middle estuary

The suspension transport away from the extensive turbidity zone of the St. Lawrence estuary is largely determined by the channel topography. The suspended sediments are advected downstream by a 40 km long turbid plume which takes its source in a turbidity maximum at the head of the estuary and flows downstream partly confined by the South Channel. During the ebbing phase of tidal cycles, the turbid waters of the plume are forced downstream through narrow converging sections of the channel, and slowed down through more opened diverging regions, particularly down-stream of the St. Roch Traverse. These, large fluctuations in stratification modulate the vertical transport of suspended material from the bottom to the surface layer. Midway down the estuary, dispersion of the plume occurs along a frontal zone which seasonally migrates 30 km or more in response to changes in fresh water discharge. The plume is reinforced and the turbidity gradient is intensified by local injections of inshore waters from Ste. Anne Bay, a subtidal platform highly enriched in suspended material by intertidal exchanges with large mudllats. Lateral erosion of the plume and cross-channel transport of suspended matter from the South into the North Channel is made possible by large horizontal shears developing in the central part of the middle estuary during the early flood. These are created by a one-hour tidal phase difference between the North and the South Channel.     

Wind-driven estuarine turbidity maxima in Mandovi Estuary,central west coast of India

Systematic studies on the suspended particulate matter (SPM) measured on a seasonal cycle in the Mandovi Estuary, Goa indicate that the average concentrations of SPM at the regular station are ∼20mg/l, 5mg/l, 19mg/l and 5mg/l for June–September, October–January, February–April and May, respectively. SPM exhibits low-to-moderate correlation with rainfall indicating that SPM is also influenced by other processes. Transect stations reveal that the SPM at sea-end stations of the estuary are at least two orders of magnitude greater than those at the river-end during the monsoon. Estuarine turbidity maximum (ETM) of nearly similar magnitude occurs at the same location in two periods, interrupted by a period with very low SPM concentrations. The ETM occurring in June–September is associated with low salinities; its formation is attributed to the interactions between strong southwesterly winds (5.1–5.6ms⁻¹) and wind-induced waves and tidal currents and, dominant easterly river flow at the mouth of the estuary. The ETM occurring in February–April is associated with high salinity and is conspicuous. The strong NW and SW winds (3.2–3.7ms⁻¹) and wind-driven waves and currents seem to have acted effectively at the mouth of the estuary in developing turbidity maximum. The impact of sea breeze appears nearly same as that of trade winds and cannot be underestimated in sediment resuspension and deposition     

The freshwater-saltwater interface and its relationship to the turbidity maximum in the Tamar Estuary,United Kingdom

Data are presented from several experiments in the freshwater-saltwater interface (FSI) region of the Tamar Estuary. Longitudinal surveys of salinity and suspended particulate matter (SPM) at high water showed that the location of the FSI could be predicted in terms of a power-law regression with freshwater runoff. Longitudinal transects also were surveyed over periods of several hours. The FSI was observed to advect into the region on the flood with strong vertical mixing. After high water, stratification became intense as fresher water ebbed in the surface layers. The near-bed water in the stratified region began to ebb between 2 h and 3 h before low water. A model of the vertical structure of longitudinal currents showed that the enhanced stratification on the ebb, coupled with the longitudinal density gradient, partly produced this long period of slack, near-bed currents following high water. A strong turbidity maximum (TM) occurred during spring tides and was located slightly up-estuary of the FSI at high water. Longitudinal transects during a period of low freshwater runoff and large neap tide showed that at the start of the flood the TM was associated with the FSI region. As the FSI advected up-estuary on the flood there was considerable resuspension of sediment at the FSI. Some of this SPM moved with the FSI and reached the limit of saline intrusion, where it formed a slowly-eroding TM as particles settled during the long, high-water slack period. As the near-bed currents increased on the ebb and the FSI moved down-estuary, strong vertical mixing and resuspension of recently deposited sediment occurred in the unstratified water behind the FSI and the associated TM advected down-estuary. Additional effects were present with stronger tides and increased runoff.     

Abundance of larval rainbow smelt (Osmerus mordax) in relation to the maximum turbidity zone and associated macroplanktonic fauna of the middle St. Lawrence estuary

We tested the hypothesis that the distribution and retention of larval smelt (Osmerus mordax) in the middle estuary of the St. Lawrence River is related to the maintenance of other planktonic organisms in the maximum turbidity zone (MTZ). We documented the horizontal and vertical distribution of larval smelt, macrozooplankton, and suspended particulate matter over four tidal cycles at each of three stations located along the major axis of the turbid upstream portion of the middle estuary. During summer, the turbid, warm, and low salinity waters of the two upstream stations were characterized byNeomysis americana, Gammarus sp. (principallyG. tigrinus), larval smelt,Mysis stenolepsis, andCrangon septemspinosus. The more stratified and less turbid waters of the downstream station were characterized by a coastal marine macrozooplanktonic community and the almost total absence of smelt larvae. Within the MTZ, the distribution ofN. americana coincided with the zone of longest average advective replacement times (null zone). Smelt larvae were distributed further upstream within the MTZ thanN. americana. Overall, larger larvae were distributed further upstream than smaller larvae. The relationship between turbidity and larval density at a specific time was weak (due to resuspension of sediments but not larvae), but the mechanism responsible for producing higher residence times for both sediment and larvae on a longer term basis appears the same. The daily movement and skewed nature of the null zone (due to the general cyclonic circulation of the middle estuary) defines a geographic zone over which the larval smelt population oscillates and remains despite the mean downstream velocities over the water column.     

Flocculation Potential of Estuarine Particles: The Importance of Environmental Factors and of the Spatial and Seasonal Variability of Suspended Particulate Matter

Estuarine systems are complex environments where seasonal and spatial variations occur in concentrations of suspended particulate matter, in primary constituents, and in organic matter content. This study investigated in the laboratory the flocculation potential of estuarine-suspended particulate matter throughout the year in order to better identify the controlling factors and their hierarchy. Kinetic experiments were performed in the lab with a “video in lab” device, based on a jar test technique, using suspended sediments sampled every 2 months over a 14-month period at three stations in the Seine estuary (France). These sampling stations are representative of (1) the upper estuary, dominated by freshwater, and (2) the middle estuary, characterized by a strong salinity gradient and the presence of an estuarine turbidity maximum. Experiments were performed at a constant low turbulent shear stress characteristic of slack water periods (i.e., a Kolmogorov microscale >1,000 μm). Flocculation processes were estimated using three parameters: flocculation efficiency, flocculation speed, and flocculation time. Results showed that the flocculation that occurred at the three stations was mainly influenced by the concentration of the suspended particulate matter: maximum floc size was observed for concentrations above 0.1 g l⁻¹ while no flocculation was observed for concentrations below 0.004 g l⁻¹. Diatom blooms strongly enhanced flocculation speed and, to a lesser extent, flocculation efficiency. During this period, the maximum flocculation speed of 6 μm min⁻¹ corresponded to a flocculation time of less than 20 min. Salinity did not appear to automatically enhance flocculation, which depended on the constituents of suspended sediments and on the content and concentration of organic matter. Examination of the variability of 2D fractal dimension during flocculation experiments revealed restructuring of flocs during aggregation. This was observed as a rapid decrease in the floc fractal dimension from 2 to 1.4 during the first minutes of the flocculation stage, followed by a slight increase up to 1.8. Deflocculation experiments enabled determination of the influence of turbulent structures on flocculation processes and confirmed that turbulent intensity is one of the main determining factors of maximum floc size.     

Seasonal distributions of suspended particulate material and dissolved nutrients in a coastal plain estuary

The temporal and spatial distributions of salinity, dissolved oxygen, suspended particulate material (SPM), and dissolved nutrients were determined during 1983 in the Choptank River, an estuarine tributary of Chesapeake Bay. During winter and spring freshets, the middle estuary was strongly stratified with changes in salinity of up to 5‰ occurring over 1 m depth intervals. Periodically, the lower estuary was stratified due to the intrusion of higher salinity water from the main channel of Chesapeake Bay. During summer this intrusion caused minimum oxygen and maximum NH₄ ⁺ concentrations at the mouth of the Choptank River estuary. Highest concentrations of SPM, particulate carbon (PC), particulate nitrogen (PN), total nitrogen (TN), total phosphorous (TP) and dissolved inorganic nitrogen (DIN) occurred in the upper estuary during the early spring freshet. In contrast, minimum soluble reactive phosphate (SRP) concentrations were highest in the upper estuary in summer when freshwater discharge was low. In spring, PC:PN ratios were >13, indicating a strong influence by allochthonous plant detritus on PC and PN concentrations. However, high concentrations of PC and PN in fall coincided with maximum chlorophyll a concentrations and PC:PN ratios were <8, indicating in situ productivity controlled PC and PN levels. During late spring and summer, DIN concentrations decreased from >100 to <10 μg-at l^?1, resulting mainly from the nonconservative behavior of NO₃ ^?, which dominated the DIN pool. Atomic ratios of both the inorganic and total forms of N and P exceeded 100 in spring, but by summer, ratios decreased to <5 and <15, respectively. The seasonal and spatial changes in both absolute concentrations and ratios of N and P reflect the strong influence of allochthonous inputs on nutrient distributions in spring, followed by the effects of internal processes in summer and fall.     

Distribution and fractionation of rare earth elements and Yttrium in suspended and bottom sediments of the Kali estuary,western India

Concentrations of rare earth elements (REE) and yttrium (Y), and major metals (Al, Fe and Mn) were measured in suspended particulate matter (SPM) and bottom sediments of the Kali estuary, western India, for their distribution and fractionation. The contents of SPM and metals in it were more uniform along the longitudinal transect during the monsoon. During the post- and pre-monsoons, low SPM in the upper/middle estuary coincided with high Fe and Mn and total REE (∑REE). But in the lower estuary SPM and its ∑REE content increased seaward, while Fe and Mn decreased. The Y/Ho ratios decreased seaward during the monsoon but increased during the post-monsoon. Sm/Nd ratios were more uniform along the transect during monsoon but decreased marginally seaward in other seasons. The Post-Archean Average Australian Shale (PAAS)-normalized REE patterns exhibited middle REE and heavy REE enrichment with positive Ce (\({\text{Ce}}/{\text{Ce}}^{*}\)), Eu (\({\text{Eu}}/{\text{Eu}}^{*}\)) and Y anomalies. The \({\text{Ce}}/{\text{Ce}}^{*}\) increased but \({\text{Eu}}/{\text{Eu}}^{*}\) decreased marginally seaward. The fine-grained sediments showed higher ∑REE and lower Y/Ho ratios than in coarse-grained sediments. The PAAS-normalized REE patterns of sediment were similar to that of SPM. The results revealed two processes, colloidal flocculation and coagulation of metals in the low-salinity zone and an estuarine turbidity maximum in the high salinity zone. Rare earths and yttrium (REY) in SPM and sediments primarily reflected the source rock composition than that of chemical weathering. Apart from physico-chemical processes, the mineralogy and grain size of sediments controlled the distribution and fractionation of REY in the estuary.     

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ Measurements

We used high-resolution in situ measurements of turbidity and fluorescent dissolved organic matter (FDOM) to quantitatively estimate the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, a tidal wetland. Turbidity and FDOM??representative of particle-associated and filter-passing Hg, respectively??together predicted 94?% of the observed variability in measured total mercury concentration in unfiltered water samples (UTHg) collected during a single tidal cycle in spring, fall, and winter, 2005?C2006. Continuous in situ turbidity and FDOM data spanning at least a full spring-neap period were used to generate UTHg concentration time series using this relationship, and then combined with water discharge measurements to calculate Hg fluxes in each season. Wetlands are generally considered to be sinks for sediment and associated mercury. However, during the three periods of monitoring, Browns Island wetland did not appreciably accumulate Hg. Instead, gradual tidally driven export of UTHg from the wetland offset the large episodic on-island fluxes associated with high wind events. Exports were highest during large spring tides, when ebbing waters relatively enriched in FDOM, dissolved organic carbon (DOC), and filter-passing mercury drained from the marsh into the open waters of the estuary. On-island flux of UTHg, which was largely particle-associated, was highest during strong winds coincident with flood tides. Our results demonstrate that processes driving UTHg fluxes in tidal wetlands encompass both the dissolved and particulate phases and multiple timescales, necessitating longer term monitoring to adequately quantify fluxes.     

Oceanic and Hydrologic Influences on Flow and Water Properties in the St. Jones River Estuary,Delaware

Influences of tides, freshwater discharge, and winds on water properties in the St. Jones River estuary (USA), a Delaware National Estuarine Research Reserve, were investigated using multiyear records of sea level, salinity, and turbidity, supplemented by a current profiler time series in 2007. Results demonstrate that instantaneous properties fluctuate with semidiurnal tides and resonant overtides, whereas tidal mean variations are forced by seasonal freshwater inflow and offshore winds. Mean sea level and salinity are highest in summer and vary with seasonal water temperature and rainfall, whereas sea level variability and turbidity are highest in winter on account of storm effects. Salinity and discharge modeling suggest that much (43–65%) of the freshwater resident in the estuary is derived from non-point sources below the head of tide. This diffuse freshwater inflow produces a seaward surface slope and weak mean current, which temporarily reverses under the influence of storm–wind setup within Delaware Bay.     

Sediment dynamics of turbidity maximum in Changjiang River mouth in dry season

High-resolution current velocity and suspended sediment concentration (SSC) data were collected by using an Acoustic Doppler Current Profiler (ADCP) at two anchor stations and a cross-section in the South Channel of the Changjiang River mouth during meso and neap tides on Nov. 16, 2003. In addition, tidal cycle (13-hour) observation at two stations was carried out with traditional methods during the spring tide. Results indicated that resuspension occurred not only at the flood and ebb maximum, but also in the early phase of ebb in the meso and neap tide. When tidal current transited from high to ebb phase, current speed accelerated. Subsequently, fine-grained sediment with low critical threshold was resuspended and increased concentration. The river mouth area remained in siltation in the meso and neap tidal phase during the observation season, with calculated resuspension flux in the order of magnitude of 10⁻⁴–10⁻⁷ kg·m−2/s. Suspended sediment transport in the South Channel was dominated by freshwater discharge, but the Storks drift, vertical circulation and vertical shear effect due to tidal oscillation also played an important role in resuspension and associated sediment transport. In contrast, resuspension sediment flux in the spring tide was larger than that in meso and neap tide, especially at the ebb maximum and flood maximum. The present study revealed that intensive resuspension corresponded well with the larger current velocity during winter. In addition, the ‘tidal pumping’ effect and tidal gravity circulation were also vital for forming the turbidity maximum in the Changjiang River estuary.     

Flux of particulate matter in the tidal marshes and subtidal shallows of the Rhode River estuary

There was a net influx of suspended particulate matter to the uppermost part of the Rhode River estuary during the several years of this study. Most of the influx was due to episodic discharges of suspended sediment from the watershed during heavy rains. In contrast, tidal exchange of particulate matter was not related to rainstorms. Sediment composition data and historical records indicate that marsh accretion accounts for only 13% of the sediment trapping although marshes occupy 60% of the study area. Influx of particulate matter to the marshes is directly related to the amount of time they are submerged during tidal cycles.     

Transformation of phosphorus in the Elbe estuary

The distribution of dissolved and particle-bound phosphorus (P) was investigated in the Elbe estuary during March 1995. The forms of particulate P were studied with a sequential extraction technique. Organic P dominated particle-bound P in the outer reaches of the estuary (52%), decreased to a minimum of 21% in the turbidity zone, and increased to 33% further upstream. Fe-bound P was the second most important P species in the outer reaches (27%) and dominated in the turbidity zone (up to 57%) and upstream of the turbidity zone (up to 48%). The P:Fe ratio increased with decreasing salinity, from 0.11 in the outer reaches to about 0.22 at zero salinity. Dissolved inorganic P release from reverine suspended matter was about two to three times larger than release, from marine suspended matter and was dominated by release of Fe-bound P. Dissolved inorganic P release from marine and from riverine organic matter were of equal importance. Because marine suspended matter dominates in the estuary, this suggests riverine organic matter is remineralized much faster than marine organic matter. This is in line with the refractory nature of marine organic matter (no phytoplankton bloom) and the easily degradable character of the riverine suspended matter (phytoplankton bloom) in the Elbe estuary during March 1995.     

Seasonal and tidal monthly patterns of particulate matter dynamics in the Columbia River estuary

We investigated seasonal and tidal-monthly, suspended particulate matter (SPM) dynamics in the Columbia River estuary from May to December 1997 using acoustic backscatter (ABS) and velocity data from four long-term Acoustic Doppler Profiler (ADP) moorings in or near the estuarine turbidity maximum (ETM). ABS profiles were calibrated and converted to total SPM profiles using pumped SPM samples and optical backscatter (OBS) data obtained during three seasonal cruises. Four characteristic settling velocity (W _s) classes were defined from Owen Tube samples collected during the cruises. An inverse analysis, in the form of a non-negative least squares minimization, was used to determine the contribution of the four,W _s-classes to each, total SPM profile. The outputs from the inverse analyses were 6–8 mo time-series ofW _s-specific SPM concentration and transport profiles at each mooring. The profiles extended from the free surface to 1.8–2.7 m from the bed, with 0.25–0.50 m resolution. These time series, along with Owen Tube results and disaggregated size data, were used to investigate SPM dynamics. Three non-dimensional parameters were defined to investigate how river flow and tidal forcing affect particle trapping: Rouse numberP (balance between vertical mixing and settling) trapping efficiencyE (ratio of maximum SPM concentration in the estuary to fluvial source concentration), and advection numberA (ratio of height of maximum SPM concentration to friction velocity). The most effective particle trapping (maximum values ofE) occurs on low-flow neap tides. The location of the ETM and the maximal trapping migrated seasonally in a manner consistent with the increase in salinity intrusion length after the spring freshet. Maximum advection (high values ofA) occurred during highly stratified neap tides.