孔隙结构和水动力对饱和多孔介质中颗粒迁移和沉积特性的耦合影响

为了研究孔隙结构和水动力对悬浮颗粒在饱和多孔介质中沉积和迁移特性的影响,对天然硅粉（悬浮颗粒）和荧光素钠（示踪剂）在饱和多孔介质中的渗流迁移特性进行土柱试验,分别得到了5种不同渗流速度（0.033、0.066、0.132、0.199、0.265 cm/s）、两种不同多孔介质（石英砂和玻璃球）的悬浮颗粒和示踪剂全组合下的20条穿透曲线。根据试验结果,研究孔隙结构、渗流速度对饱和多孔介质中颗粒迁移和沉积过程中水动力作用机制、弥散效应、加速效应的影响。研究表明,悬浮颗粒的穿透曲线可以用一阶沉积动力学对流弥散方程的解析解来描述。随着渗流速度的增大,水动力学作用对颗粒出流浓度的影响越来越大,而孔隙结构的影响则相对减弱。同时,存在一个临界渗流速度值。当渗流速度超出该值时,悬浮颗粒迁移要快于示踪剂,而且临界渗流速度对于玻璃球和石英砂两种多孔介质是不同的;其次,在两种介质中,随渗流速度增大,弥散度增加,回收率和回收悬浮颗粒粒径增大,沉积系数先增大后减小。此外,在孔隙比相近的情况下,悬浮颗粒在玻璃球介质中的回收率要大于其在石英砂中的。可见,孔隙结构和渗流速度是影响饱和多孔介质中颗粒输运的重要因素,渗流速度越大,孔隙结构的作用越明显。     

饱和多孔热弹性介质中Rayleigh波传播特性分析

基于多孔介质理论和广义的热弹性模型,研究了饱和多孔热弹性介质中Rayleigh波(R波)的传播特性。以考虑流-固耦合的饱和多孔介质波动方程和连续性方程及考虑热-弹耦合的广义热弹性基本方程出发,建立了饱和多孔介质的热-流-固耦合弹性波动模型。通过引入势函数并结合自由透水及绝热的边界条件,经过理论推导最终给出了饱和多孔热弹性介质中R波的弥散特征方程。利用数值算例分析了孔隙率、渗透系数、热膨胀系数、初始温度和松弛时间等热物理参数对R波的波速和特征衰减的影响。结果表明:孔隙率的增加将引起R波的波速下降,但使得R波的特征衰减反而增大;R波的波速随着渗透系数的增大先不变,再急剧增大,最后趋于稳定,其特征衰减随着渗透系数的增加先增大后减小,最后趋于稳定;热膨胀系数的增大将引起R波波速的增大,但对其特征衰减的影响较小;初始温度的增加导致R波波速的小幅上升,而对其特征衰减影响不大;松弛时间对R波波速和特征衰减几乎无影响。     

空气扰动技术修复氯苯污染地下水的影响因素研究

通过实验室一维砂柱模拟研究了不同影响因素下空气扰动技术(air sparging,AS)修复氯苯污染地下水的效果,包括介质渗透性、曝气方式、共存污染物、残余饱和态氯苯。结果表明:介质渗透性极大地影响着AS的效果,渗透系数越大,去除效果越好。对渗透系数为10-5m/s数量级及其以下的介质应用AS较为困难;在曝气时间相同的情况下,对于渗透系数为5.1×10-4m/s的中砂,脉冲曝气较连续曝气效果好,对于渗透系数为6.2×10-3m/s的粗砂,2种曝气方式效果相仿;苯和氯苯共存时各污染物的去除存在协同作用;AS对残余饱和态氯苯的去除存在着明显的拖尾效应。     

空心圆柱饱和多孔介质热固结问题的解析解

基于考虑热渗效应和等温热流效应的热-水-力耦合的线性热弹性固结控制方程,建立无限长空心圆柱饱和多孔介质热固结问题的一种理论求解方法。该方法先给出Laplace变换域上的解,然后,利用Stehfest法求其数值逆变换。该理论解考虑了空心圆柱体内、外透水界面随时间变化的外力和温度荷载耦合作用过程。最后,通过一算例分析了饱和多孔介质的热固结特征,给出其温度、孔压、位移和应力的演化规律     

黄原胶在含水层的迁移特性及对KMnO4迁移的影响

向地下水注入化学药剂进行修复时,药剂迁移主要集中在渗透性相对较高的区域,致使低渗透区内的污染物无法有效去除。通过注入聚合物（黄原胶）对地下水进行黏度控制,可以有效提高修复药剂在低渗透区的迁移能力,从而提高修复效果。黏性流体在地层中的迁移特性是该技术应用的理论基础,因此本研究运用一维模拟柱实验分析了含水层介质对黄原胶流体的阻滞作用,黄原胶注入前后介质的压力及渗透系数的变化以及黄原胶与修复药剂KMnO4迁移同步性。实验结果表明:当黄原胶溶液注入到介质后,介质对黄原胶的阻滞导致其有效孔隙度减小,因此会在一定程度上加速后续注入溶液溶质的运移,且介质渗透系数越小,对黄原胶阻滞作用越明显;黄原胶注入导致含水层渗透性降低,流体运移阻力增加,特别是在细砂和粉砂介质中,渗透系数都降低了一个数量级;虽然黄原胶和KMnO4在迁移锋面存在一定差异,但经过2 h后迁移速率基本相同,具有较好的同步性。     

饱和多孔介质中胶体沉淀释放过程的数值模拟

地下环境中可移动的胶体能够促进强烈吸附的污染物质的运移,而胶体自身在运移过程中也会伴随发生沉淀、释放。根据高岭石胶体的土柱出流实验,对不同离子强度条件下胶体在饱和多孔介质中的沉淀和释放行为进行分析,并采用不同模型对其过程进行数值模拟。结果表明,离子强度是影响胶体沉淀和释放过程的重要因素,随着离子强度的增加,胶体的出流峰值逐渐降低,即胶体在多孔介质中的沉淀量逐渐增大,且沉淀速率系数K d 与离子强度成正相关;模型拟合的释放系数与NaCl 浓度显著相关,Grolimund 模型可以很好地模拟胶体的沉淀过程（R 2 >0.95）,但不能准确地模拟释放过程;而胶体运移方程耦合溶质运移方程能够模拟不同离子强度影响下胶体的释放过程（R 2 >0.9）     

胶态微泡沫在非饱和多孔介质中的迁移规律及影响因素

传统原位土壤淋洗修复存在淋洗效率低、淋洗液迁移难控制、污染范围易扩大的弊端。胶态微泡沫（CGAs）密度轻、粒径小、流动性好,可以有效解决传统液相淋洗修复中的问题。在修复过程中,压力作为一项重要的指标,可以有效地反映CGAs在介质中的迁移分布;因而本研究通过一维和二维动态模拟实验探讨了介质粒径、介质含水量、聚合物（黄原胶）添加等对土壤修复体系压力的影响以及CGAs在土壤中的运移规律。研究表明：随着介质粒径、介质含水量、黄原胶质量浓度的增大,体系中压力总体呈现降低趋势;CGAs从模拟槽一侧单点注入介质时,其在介质中的迁移轨迹呈现近似半圆形,在覆盖区域分布均匀,能够有效克服重力对其迁移分布的影响;随着介质粒径的增大,CGAs在介质中的波及效率先增大后减小,介质粒径为0.8~1.0 mm时波及效率最大,为34.77%;随着含水量的增加,CGAs的波及效率随之增加;黄原胶的添加有效增加了CGAs在介质中的波及效率,黄原胶质量浓度为500 mg/L时CGAs波及效率最大,为40.28%,是未添加黄原胶时的1.48倍。     

简谐线源荷载作用下热流固耦合地基的动力响应

基于Biot波动理论和广义热弹性理论,对简谐线源荷载（力荷载和热荷载）作用下的热-流-固耦合地基的动力响应问题进行了研究。将地基看成是均质各向同性、完全饱和的多孔半空间介质,利用无量纲化和Fourier变换方法对热-流-固耦合控制方程进行简化,得到了变换域内应力分量、位移分量、温度分布及超孔隙水压力的一般解,并利用Fourier逆变换得到了相应的积分形式解答。通过数值计算对按热-流-固耦合理论、饱和多孔弹性理论和热弹性理论得到的结果进行了比较,同时分析了热-流-固耦合条件下热荷载激振频率对竖向应力、竖向位移、温度分布以及超孔隙水压力的影响。     

铬污染地下水的PRB反应介质筛选及修复试验

通过实验研究筛选出一种经济可行的用于修复Cr(Ⅵ)污染地下水的PRB反应介质。实验以Cr(Ⅵ)污染地下水为研究对象,选用MB、Fe0、粉煤灰和活性炭4种材料进行PRB介质筛选的静态实验,选取处理效果好且经济的MB作为PRB反应介质进行动态修复实验。结果表明:以MB作为PRB反应介质可以使Cr(Ⅵ)的质量浓度从0.50 mg/L降低到0.05 mg/L以下,达到地下水水质Ⅲ类标准;且MB具有吸附量大、固液分离容易、无解吸、无二次污染等优点。以MB作为PRB反应介质修复Cr(Ⅵ)污染的地下水是可行的。     

有效压力对低渗透多孔介质孔隙度、渗透率的影响

以低渗透多孔介质为研究对象,通过实验得出孔隙度、渗透率随有效压力变化曲线。研究表明,流体在低渗透多孔介质中渗流时,流固耦合效应十分显著。这是因为低渗透多孔介质的孔隙很小,而孔隙度的微小变化,都会对渗透率产生大的影响,因此低渗透介质随有效应力的变化十分明显。由于流固耦合效应的存在,在低渗透油气藏的开发中,不宜采用降压开采,进行油藏数值模拟时,也应进行油藏流固耦合数值模拟。      

凹凸棒石-双交联水凝胶微球钝化修复镉污染土壤研究

为研究凹凸棒石-双交联水凝胶微球(SA/PVA/ATP)对镉污染土壤钝化修复的效果,将SA/PVA/ATP添加到镉浓度为3.72 mg/kg的土壤中进行淹水培育,采用模拟酸雨、二乙烯三胺五乙酸(DTPA)和三乙醇胺(TEA)混合提取剂(DTPA提取剂)提取土壤有效态镉;采用欧共体标准局顺序提取方法(BCR)提取土壤中不同形态镉;讨论了SA/PVA/ATP添加量、土壤有效态镉和各形态镉的相关性;计算了钝化容量、修复效率和重金属风险评价指数,探究了SA/PVA/ATP对土壤镉的钝化机理。结果显示,随着SA/PVA/ATP的增加,DTPA提取剂和酸雨提取的有效态镉含量分别从1.72 mg/kg和0.024 mg/kg下降到0.66 mg/kg和0.004 4 mg/kg;土壤中的弱酸可提取态镉和可还原态镉含量分别从1.40 mg/kg和0.81 mg/kg下降到1.01 mg/kg和0.41 mg/kg,而可氧化态镉和残渣态镉含量分别从0.86 mg/kg和0.63 mg/kg增加到0.95 mg/kg和1.27 mg/kg。材料添加量与土壤中有效态镉、弱酸提取态镉和可还原态镉含量呈极显著负...     

水蒸气增湿非饱和黄土热湿迁移规律研究

温度梯度、含水率梯度和压力梯度对非饱和土体中的水热迁移有重要影响。用非饱和黄土填筑室内模型,通入0.10MPa高温水蒸气,研究蒸汽压梯度、温度梯度和含水率梯度耦合作用下的水热迁移规律。结果表明:在水蒸气迁移范围之内,土体的升温速率、增湿速率和增湿程度较大,以蒸汽传热和压力梯度驱动的水蒸气增湿为主。而在水蒸气未到位置,以温度梯度引起的热传导和含水率梯度与温度梯度耦合驱动的水热迁移为主;水蒸气迁移时,受土颗粒阻碍和蒸汽压消散的影响,土体升温速率、增湿速率和温度传导速率均随径向距离的增大而减小,且增湿速率小于升温速率;水蒸气增湿土体的最大含水率接近最优含水率,增湿效果较好,可有效提高一定范围内土体的压实性能;基于模型试验边界条件,确定含湿毛细多孔介质中二维热湿迁移方程的一组代数显式特解,并以20 cm测点为例,将温度和含水率实测值和计算值进行对比分析。研究结果可为非饱和黄土水-汽-热耦合传输规律和水蒸气增湿新技术研究提供理论支持。     

Modeling and assessment of polychlorinated biphenyls contamination in soil at a burial site of power capacitors

Numerous industrial or burial sites contaminated by persistent organic pollutants such as polychlorinated biphenyls (PCBs) and pesticides were discovered in China recently. Due to improper choice of technology, many remediation cases had cost too much; however, failed to attain expected goals. In this study, the distribution and transport of PCBs at a burial site were investigated using tested PCBs concentration in order to support the choice of remediation technology and estimate the remediation results. Site characterization was carried out in order to investigate the hydrogeological condition and PCBs pollution nearby the capacitor burial site located in Shanxi, China. Results of PCBs measurement indicated that the proportion of contaminated soil with concentration above 500 mg/kg is 7.8 % and the value for soil with concentration between 50 and 500 mg/kg is 18.0 %. Considering adsorption and biodegradation, the two-dimensional PCBs transport model was established based on advection–dispersion equation. The model calibration showed a good agreement between measured and computed values, indicating the feasibility of this model used for predicting the transport and disappearance of PCBs in soil. Results of 100 years’ simulation demonstrated the slow migration and biodegradation of PCBs. Simulations were conducted for before and after remediation scenarios. Comparison of the results indicates that the remediation alternatives of excavation–incineration and thermal desorption have successfully removed most of the organics and thus reduced the environmental risk to a low level.     

MICP技术联合多孔硅吸附材料对锌铅复合污染土固化/稳定化修复的试验研究

近年来,工业和科技的快速发展使得重金属污染土固化/稳定化的修复研究成为热点。运用微生物诱导碳酸钙沉淀(MICP)技术联合吸附材料对锌铅复合重金属污染土进行固化/稳定化的修复,通过无侧限抗压强度试验、毒性浸出试验,评价处理前后污染土的固化效果与重金属的稳定化效果,结合扫描电镜(SEM)和X射线衍射(XRD)等检测手段,揭示MICP技术处理锌铅重金属污染土的修复机制。研究结果表明,采用MICP技术对锌铅重金属污染土进行固化/稳定化之后,可以有效降低污染土中有害重金属的浸出性。当矿化时间为10d时,试样无侧限抗压强度为942.5k Pa;铅的浸出浓度为4.20mg/L,比未处理时降低了44.81%;锌的浸出浓度为4.31mg/L,比未处理时降低了46.19%,效果显著。在此基础上,添加10%的多孔硅吸附材料后,试样无侧限抗压强度可达到1 021 kPa,强度提高了8.3%;铅的浸出浓度为2.45mg/L,与未经处理时相比,降幅达到了67.81%,与单纯MICP方法处理时相比,铅浸出浓度被二次降低了41.67%;锌的浸出浓度仅为2.93 mg/L,与未经处理时相比,降幅达到了63.4%,与单纯...     

Electrokinetic retention, migration and remediation of nitrates in silty loam soil under hydraulic gradients

Contamination of groundwater by nitrates leaching from intensive agricultural and livestock operations have become a major concern for surrounding communities that use groundwater as their water supply. High levels of nitrate in drinking water poses a significant risk to human health, i.e., methaemoglobinaemia (“blue baby” syndrome).

The traditional pump-and-treat method is ineffective in medium to fine-textured agricultural soils due to the low hydraulic conductivity. This paper presents the results of a laboratory experiment investigating the feasibility of using electrokinetic treatment in retaining, accumulating, moving and remediating nitrates in a silty loam soil under hydraulic gradients.

A hydraulic gradient of 1.25 was applied to the horizontal soil columns to simulate a groundwater movement system. The study was performed in two stages. During the first stage of the experiment, the anode located at the inflow end of the columns was able to retard the movement of nitrates even under a hydraulic gradient of 1.25. After 15 days of flow, the effluent nitrate concentration in the control column rose to 90 mg l⁻¹ while no nitrates were detected in the effluent from columns subjected to the electrokinetic treatment.

After 15 days, the polarity of the electrodes was switched and this second stage lasted another 20 days. The cathode near the inflow end promoted the conversion of nitrates entering the column to other forms. The anode near the outflow end promoted the migration and accumulation of negatively charged nitrate ions towards the outflow end. By the 12th day, the nitrate concentrations in the electrokinetically treated columns were brought down to <5 mg NO₃-N l⁻¹. Electrokinetic treatment retarded nitrate movement against a hydraulic gradient of 1.25 and effectively restored a medium-textured soil contaminated with NO₃-N.

The NO₂-N level remained below 1 mg l⁻¹ throughout the experiment. The hydraulic conductivity varied between 1.0E–7 and 3.6E–7 m s⁻¹. The current requirement varied between 3 and 6 mA.     

氯苯(CB)在粘土上的解吸特征

为探索低浓度乙醇溶液中氯苯(Chlorobenzene,简称CB)在土壤中的迁移行为,以武汉市某化工厂受CB污染土壤为研究对象,设计正交试验,开展了淋洗条件筛选、最佳条件的验证和解吸动力学研究3组实验.优化出的最佳淋洗条件为常温、液土比(mL/g)为25∶1、淋洗液中乙醇体积浓度为10%、淋洗时间为2 h;在最优淋洗条件下,CB的提取率为90%;且CB解吸规律符合Freundlich吸附模型.以低浓度乙醇为淋洗剂修复受CB污染土壤,不仅可实现污染土壤修复的目标,同时还能够保留土壤功能,避免造成二次污染.      

电化学循环井驱动模拟含水层化学氧化降解三氯乙烯

传统原位化学氧化地下水修复技术存在氧化剂迁移距离短和利用率低等问题。本研究在双井循环模式促进传质的基础上,通过注水井中的地下水电解原位提供O₂和H₂,配合乙二胺四乙酸(ethylenediamine tetraacetic acid,EDTA)络合溶解出含水层Fe(Ⅱ),活化O₂产生羟基自由基(•OH),实现地下水三氯乙烯(TCE)的氧化降解。在填充了砂土和黏土互层的二维砂槽中,设置电流为0.2 A、流速为72 cm/d、初始TCE浓度为3 mg/L,经过9 d的连续通电处理后,TCE浓度降低到1 mg/L,降解率达到67%。通电前投加0.5 mmol/L EDTA,经过1 d水流循环后含水层中溶解态Fe(Ⅱ)浓度从02 mg/L增加到414 mg/L,黏土区域较高。通电过程中,循环井促进O₂、Fe(Ⅱ)-EDTA和TCE的有效接触与反应,使TCE氧化降解。通电初期,黏土区域Fe(Ⅱ)氧化速率、TCE降解速率较周围慢,后期差异逐渐减小。未通电时加入醋酸钠可促进Fe(Ⅲ)还原,使含水层中铁循环利用。该修复过程通过循环井提升了氧化剂迁移距离,使用源于含水层的Fe(Ⅱ)-EDTA和稳定性较好的O₂提高了氧化剂利用率,有望应用于有机污染地下水修复。     

Ozonation of diesel fuel in unsaturated porous media

The objectives of this study were to determine the feasibility of ozonation in unsaturated porous media, and consequently to observe its features and to identify possible limiting factors. Diesel fuel was chosen to represent a complex organic contaminant that is widespread in the environment. In this experiment, the effects of several ozonation features were investigated. Sand was spiked with commercially available diesel fuel (17.024 g diesel/kg dry sand), and packed into a column. Ozone was supplied into the column in a downward direction. When the sand was treated for 7 h at 20 mg ozone/l of air, 40% of the diesel was removed. As the ozone concentration increased from 5 to 20 mg ozone/l, the removal efficiency increased. The removal rate varied significantly depending on the ozone concentration and the treatment duration. At higher ozone concentration, significant quantities of ozone were consumed by the intermediates produced by the ozonation process, and therefore, the removal efficiency and the apparent removal rate of diesel became lowered. The low removal efficiency of diesel results from the high concentrations of normal alkanes. Total hydrocarbon concentration (THC) in the effluent gas was measured using a total hydrocarbon analyzer. The THC decreased with the period of exposure and increasing ozone concentration. Ozonation decreased the gas-extractable fraction and accordingly, the THC decreased. Water-extractable fractions formed by the action of ozone were further oxidized by ozone. Due to the reduction of WEOC (water-extractable organic C) caused by ozone treatment, the potential spread of contamination can be reduced.